arXiv subjects

Patrick Huber

Publications and source records attributed to Patrick Huber.

At least 163 records · Page 9Linked to original sources

arXiv2012

Molecular dynamics of n-hexane: A quasi-elastic neutron scattering study on the bulk and spatially nanochannel-confined liquid

We present incoherent quasi-elastic neutron scattering measurements in a wavevector transfer range from 0.4 AA^{-1} to 1.6AA^{-1} on liquid n-hexane confined in cylindrical, parallel-aligned nanochannels of 6 nm mean diameter and 260 micrometer length in monolithic, mesoporous silicon. They are complemented with, and compared to, measurements on the bulk system in a temperature range from 50K to 250K. The time-of-flight spectra of the bulk liquid can be modeled by microscopic translational as well as fast localized rotational, thermally-excited, stochastic motions of the molecules. In the nano-confined state of the liquid, which was prepared by vapor condensation, we find two molecular populations with distinct dynamics, a fraction which is immobile on the time scale of 1ps to 100ps probed in our experiments and a second component with a self-diffusion dynamics slightly slower than observed for the bulk liquid. No hints of an anisotropy of the translational diffusion with regard to the orientation of the channels' long axes have been found. The immobile fraction amounts to about 5% at 250K, gradually increases upon cooling and exhibits an abrupt increase at 160K (20K below bulk crystallization), which indicates pore freezing

cond-mat.soft↗

arXiv2012

Capillary Condensation, Freezing, and Melting in Silica Nanopores: A Sorption Isotherm and Scanning Calorimetry Study on Nitrogen in Mesoporous SBA-15

Condensation, melting and freezing of nitrogen in a powder of mesoporous silica grains (SBA-15) has been studied by combined volumetric sorption isotherm and scanning calorimetry measurements. Within the mean field model of Saam and Cole for vapor condensation in cylindrical pores a liquid nitrogen sorption isotherm is well described by a bimodal pore radius distribution. It encompasses a narrow peak centered at 3.3 nm, typical of tubular mesopores, and a significantly broader peak characteristic of micropores, located at 1 nm. The material condensed in the micropores as well as the first two adsorbed monolayers in the mesopores do not exhibit any caloric anomaly. The solidification and melting transformation affects only the pore condensate beyond approx. the second monolayer of the mesopores. Here, interfacial melting leads to a single peak in the specific heat measurements. Homogeneous and heterogeneous freezing along with a delayering transition for partial fillings of the mesopores result in a caloric freezing anomaly similarly complex and dependent on the thermal history as has been observed for argon in SBA-15. The axial propagation of the crystallization in pore space is more effective in the case of nitrogen than previously observed for argon, which we attribute to differences in the crystalline textures of the pore solids.

physics.chem-ph↗

arXiv2012

On the determination of anti-neutrino spectra from nuclear reactors

In this paper we study the effect of, well-known, higher order corrections to the allowed beta decay spectrum on the determination of anti-neutrino spectra resulting from the decays of fission fragments. In particular, we try to estimate the associated theory errors and find that induced currents like weak magnetism may ultimately limit our ability to improve the current accuracy and under certain circumstance could even largely increase the theoretical errors. We also perform a critical evaluation of the errors associated with our method to extract the anti-neutrino spectrum using synthetic beta spectra. It turns out, that a fit using only virtual beta branches with a judicious choice of the effective nuclear charge provides results with a minimal bias. We apply this method to actual data for U235, Pu239 and Pu241 and confirm, within errors, recent results, which indicate a net 3% upward shift in energy averaged anti-neutrino fluxes. However, we also find significant shape differences which can in principle be tested by high statistics anti-neutrino data samples.

hep-ph↗

arXiv2011

Potential measurement of the weak mixing angle with neutrino-electron scattering at low energy

We study the possibility to measure sin^2 theta_W by neutrino-electron scattering at a value of the momentum transfer Q ~ 30 MeV with a precision of 0.24% which is only a factor three below the one obtained by LEP-I at the Z-pole. The neutrino source is a proton beam dump providing a clean beam from muon decay at rest and the detector is a 100 kt scale water Cerenkov detector, which results in about 20 million signal events.

hep-ph↗

arXiv2011

Imbibition in mesoporous silica: rheological concepts and experiments on water and a liquid crystal

We present, along with some fundamental concepts regarding imbibition of liquids in porous hosts, an experimental, gravimetric study on the capillarity-driven invasion dynamics of water and of the rod-like liquid crystal octyloxycyanobiphenyl (8OCB) in networks of pores a few nanometers across in monolithic silica glass (Vycor). We observe, in agreement with theoretical predictions, square root of time invasion dynamics and a sticky velocity boundary condition for both liquids investigated. Temperature-dependent spontaneous imbibition experiments on 8OCB reveal the existence of a paranematic phase due to the molecular alignment induced by the pore walls even at temperatures well beyond the clearing point. The ever present velocity gradient in the pores is likely to further enhance this ordering phenomenon and prevent any layering in molecular stacks, eventually resulting in a suppression of the smectic phase in favor of the nematic phase.

cond-mat.soft↗

arXiv2011

Two experiments for the price of one? -- The role of the second oscillation maximum in long baseline neutrino experiments

We investigate the quantitative impact that data from the second oscillation maximum has on the performance of wide band beam neutrino oscillation experiments. We present results for the physics sensitivities to standard three flavor oscillation, as well as results for the sensitivity to non-standard interactions. The quantitative study is performed using an experimental setup similar to the Fermilab to DUSEL Long Baseline Neutrino Experiment (LBNE). We find that, with the single exception of sensitivity to the mass hierarchy, the second maximum plays only a marginal role due to the experimental difficulties to obtain a statistically significant and sufficiently background-free event sample at low energies. This conclusion is valid for both water Cherenkov and liquid argon detectors. Moreover, we confirm that non-standard neutrino interactions are very hard to distinguish experimentally from standard three-flavor effects and can lead to a considerable loss of sensitivity to θ_{13}, the mass hierarchy and CP violation.

hep-ph↗

arXiv2011

Transition from van-der-Waals to H Bonds dominated Interaction in n-Propanol physisorbed on Graphite

Multilayer sorption isotherms of 1-propanol on graphite have been measured by means of high-resolution ellipsometry within the liquid regime of the adsorbed film for temperatures ranging from 180 to 260 K. In the first three monolayers the molecules are oriented parallel to the substrate and the growth is roughly consistent with the Frenkel-Halsey-Hill-model (FHH) that is obeyed in van-der-Waals systems on strong substrates. The condensation of the fourth and higher layers is delayed with respect to the FHH-model. The fourth layer is actually a bilayer. Furthermore there is indication of a wetting transition. The results are interpreted in terms of hydrogen-bridge bonding within and between the layers.

physics.chem-ph↗

arXiv2011

Optimization of the Neutrino Factory, revisited

We perform the baseline and energy optimization of the Neutrino Factory including the latest simulation results on the magnetized iron detector (MIND). We also consider the impact of tau decays, generated by nu_mu to nu_tau or nu_e to nu_tau appearance, on the mass hierarchy, CP violation, and theta_{13} discovery reaches, which we find to be negligible for the considered detector. For the baseline-energy optimization for small theta_{13}, we qualitatively recover the results with earlier simulations of the MIND detector. We find optimal baselines of about 2500 km to 5000 km for the CP violation measurement, where now values of E_mu as low as about 12 GeV may be possible. However, for large theta_{13}, we demonstrate that the lower threshold and the backgrounds reconstructed at lower energies allow in fact for muon energies as low as 5 GeV at considerably shorter baselines, such as FNAL-Homestake. This implies that with the latest MIND analysis, low- and high-energy versions of the Neutrino Factory are just two different versions of the same experiment optimized for different parts of the parameter space. Apart from a green-field study of the updated detector performance, we discuss specific implementations for the two-baseline Neutrino Factory, where the considered detector sites are taken to be currently discussed underground laboratories. We find that reasonable setups can be found for the Neutrino Factory source in Asia, Europe, and North America, and that a triangular-shaped storage ring is possible in all cases based on geometrical arguments only.

hep-ph↗

arXiv2010

LSND reloaded

In view of the recent result from the anti-neutrino run of MiniBooNE, we suggest to repeat the original Liquid Scintillator Neutrino Detector (LSND) experiment using Super-Kamiokande, doped with Gadolinium, as detector. Due to the more than 100 times larger detector mass offered by Super-Kamiokande, the neutrino source requires a proton beam power of less than 300kW at a proton energy around a 1 GeV. A one year run of this setup can corroborate or refute both the LSND and MiniBooNE claims at more than 5 sigma confidence level. If a signal is observed, the large size of Super-Kamiokande combined with its good ability to determine the position of an anti-neutrino event allows to establish the characteristic L/E-dependence of oscillation.

hep-ph↗

arXiv2010

Orientational Order in Liquids upon Condensation in Nanochannels: An Optical Birefringence Study on Rodlike and Disclike Molecules in Monolithic Mesoporous Silica

We present high-resolution optical birefringence measurements upon sequential filling of an array of parallel-aligned nanochannels (14~nm mean diameter) with rod-like (acetonitrile) and disc-like (hexafluorobenzene) molecules. We will demonstrate that such birefringence isotherms, when performed simultaneously with optically isotropic and index-matched counterparts (neopentane and hexafluoromethane), allow one to characterize the orientational state of the confined liquids with a high accuracy as a function of pore filling. The pore condensates are almost bulk-like, optically isotropic liquids. For both anisotropic species we find, however, a weak orientational order (of a few percent at maximum) upon film-condensation in the monolithic mesoporous membrane. It occurs upon formation of the second and third adsorbed layer, only, and vanishes gradually upon onset of capillary condensation. Presumably, it originates in the breaking of the full rotational symmetry of the interaction potential at the cylindrical, free liquid-vapor interface in the film-condensed state rather than at the silica-liquid interface. This conclusion is corroborated by comparisons of our experimental results with molecular dynamics simulations reported in the literature.

cond-mat.soft↗

arXiv2010

Thermotropic Nematic and Smectic Order in Silica Glass Nanochannels

Optical birefringence measurements on a rod-like liquid crystal (8OCB), imbibed in silica channels (7 nm diameter), are presented and compared to the thermotropic bulk behavior. The orientational and positional order of the confined liquid evolves continuously at the paranematic-to-nematic and sizeably broadened at the nematic-to-smectic order transition, resp., in contrast to the discontinuous and well-defined second-order character of the bulk transitions. A Landau-de-Gennes analysis reveals identical strengths of the nematic and smectic ordering fields (imposed by the walls) and indicates that the smectic order is more affected by quenched disorder (originating in channel tortuosity and roughness) than the nematic transition.

cond-mat.soft↗

arXiv2010

Submarine neutrino communication

We discuss the possibility to use a high energy neutrino beam from a muon storage ring to provide one way communication with a submerged submarine. Neutrino interactions produce muons which can be detected either, directly when they pass through the submarine or by their emission of Cerenkov light in sea water, which, in turn, can be exploited with sensitive photo detectors. Due to the very high neutrino flux from a muon storage ring, it is sufficient to mount either detection system directly onto the hull of the submersible. The achievable data transfer rates compare favorable with existing technologies and do allow for a communication at the usual speed and depth of submarines.

hep-ph↗

arXiv2010

A new approach to anti-neutrino running in long baseline neutrino oscillation experiments

We study the possibility to replace the anti-neutrino run of a long baseline neutrino oscillation experiment, with anti-neutrinos from muon decay at rest. The low energy of these neutrinos allows the use of inverse beta decay for detection in a Gadolinium-doped water Cerenkov detector. We show that this approach yields a factor of five times larger anti-neutrino event sample. The resulting discovery reaches in theta_13, the mass hierarchy and leptonic CP violation are compared with those from a conventional superbeam experiment with combined neutrino and anti-neutrino running. We find that this approach yields a greatly improved reach for CP violation and theta_13 while leaving the ability to measure the mass hierarchy intact.

hep-ph↗

arXiv2010

Polymorphism of the glass former ethanol confined in mesoporous silicon

X-ray diffraction patterns of ethanol confined in parallel-aligned channels of approx. 10 nm diameter and 50 micrometer length in mesoporous silicon have been recorded as a function of filling fraction, temperature and for varying cooling and heating rates. A sorption isotherm, recorded in the liquid state, indicates a three monolayer thick, strongly adsorbed wall layer and a capillary condensed fraction of molecules in the pore center. Though the strongly adsorbed film remains in an amorphous state for the entire temperature range investigated, the capillary condensed molecules reproduce the polymorphism of bulk solid ethanol, that is the formation of either crystalline or glass-like states as a function of cooling rate. The critical rate necessary to achieve a vitrification in the mesopores is, however, at least two orders of magnitude smaller than in the bulk state. This finding can be traced both to pure geometrical constraints and quenched disorder effects, characteristic of confinement in mesoporous silicon.

cond-mat.soft↗

arXiv2010

Capillary Rise and Imbibition of Liquids in Nanoporous Matrices: Rheological Concepts and Experiments

Liquid flow propelled by capillary forces is one of the most important transport mechanisms in porous environments. It is governed by a fascinating interplay of interfacial, viscous drag as well as gravitational forces which liquids encounter upon invasion into geometries with often complex topologies, such as capillary networks of trees or interconnected fractures in soils and ice. Here, we present fundamentals, concepts and an experimental, gravimetric study on the capillarity-driven invasion dynamics of liquids in networks of pores a few nanometers across in monolithic, nanoporous silica glass (porous Vycor). A variation of the complexity of the building blocks of the liquids investigated along with a variation of the humidity and the temperature upon spontaneous imbibition allows us to gain information regarding the fluidity and capillarity of liquids in such nanoporous environments. We observe square-root of time imbibition dynamics for all liquids applied, which we can quantitatively describe by both a conserved bulk fluidity in the pore center and bulk capillarity at the advancing menisci, if we assume a sticky boundary layer (negative velocity slip length). Moreover, pecularities of nanopore-confined liquids, such as transport via the vapor phase leading to preadsorbed liquid layers, have to be properly accounted for. Upon increasing the chain-length in the case of the n-alkanes, we found hints towards a transition from stick- to slip-flow at the pore walls with increasing chain-length and thus polymeric behavior. Meniscus freezing is reported for n-tetracosane confined in porous Vycor. For the rheology of a rod-like liquid nematogen (8OCB) we found no hints of the viscosity drop upon entering into the nematic phase, typical of the bulk rheology of this liquid crystal.

cond-mat.soft↗

arXiv2010

Exploring neutrino parameters with a beta-beam experiment from FNAL to DUSEL

We discuss in detail the physics reach of an experimental set-up where electron neutrinos (anti-neutrinos) produced in a beta-beam facility at Fermi National Accelerator Laboratory (FNAL) are sent, over a distance of L~1300km, to the Deep Underground Science and Engineering Laboratory (DUSEL). A 300kt Water Cherenkov (WC) detector and a 50kt Liquid Argon Time Projection Chamber (LArTPC) are considered as possible detector choices. We propose to use 18Ne and 6He as source ions for electron neutrino and electron anti-neutrino beams, respectively. The maximum Lorentz boost factor, gamma, available for these ions using the Tevatron are gamma_Ne=585 and gamma_He=350. This particular set-up provides the opportunity to probe the first oscillation maximum using the neutrino beam and the second oscillation maximum using the anti-neutrino beam which helps to evade some parameter degeneracies. The resulting physics sensitivities for theta_13, CP violation and the mass hierarchy are compared to those of a conventional superbeam from FNAL to DUSEL.

hep-ph↗

arXiv2010

Criticality of an isotropic-to-smectic transition induced by anisotropic quenched disorder

We report combined optical birefringence and neutron scattering measurements on the liquid crystal 12CB nanoconfined in mesoporous silicon layers. This liquid crystal exhibits strong nematic-smectic coupling responsible for a discontinuous isotropic-to-smectic phase transition in the bulk state. Confined in porous silicon, 12CB is subjected to strong anisotropic quenched disorder: a short-ranged smectic state evolves out of a paranematic phase. This transformation appears continuous, losing its bulk first order character. This contrasts with previously reported observations on liquid crystals under isotropic quenched disorder. In the low temperature phase, both orientational and translational order parameters obey the same power-law.

cond-mat.mes-hall↗

arXiv2010

Constraining sterile neutrinos with a low energy beta-beam

We show that a low energy beta-beam facility can be used to search for sterile neutrinos by measuring the disappearance of electron anti-neutrinos. This channel is particularly sensitive since it allows to use inverse beta decay as detection reaction; thus it is free from hadronic uncertainties, provided the neutrino energy is below the pion production threshold. This corresponds to a choice of the Lorentz gamma=30 for the 6He parent ion. Moreover, a disappearance measurement allows the constraint of sterile neutrino properties independently of any CP violating effects. A moderate detector size of a few 100 tons and ion production rates of 2E13 per second are sufficient to constrain mixing angles as small as \sin^22θ=0.01 at 99% confidence level.

hep-ph↗