arXiv subjects
Publications and source records attributed to Paul Martini.
We present a study of cationic and protonated clusters of neon and krypton. Recent studies using argon have shown that protonated rare gas clusters can have very different magic sizes than pure, cationic clusters. Here we find that neon behaves similarly to argon, but that the cationic krypton is more similar to its protonated counterparts than the lighter rare gases are, sharing many of the same magic numbers.
We have studied complexes of gold atoms and imidazole (C$_3$N$_2$H$_4$, abbreviated Im) produced in helium nanodroplets. Following the ionization of the doped droplets we detect a broad range of different Au$_m$Im$_n^+$ complexes, however we find that for specific values of $m$ certain $n$ are "magic" and thus particularly abundant. Our density functional theory calculations indicate that these abundant clusters sizes are partially the result of particularly stable complexes, e.g. AuIm$_2^+$, and partially due to a transition in fragmentation patterns from the loss of neutral imidazole molecules for large systems to the loss of neutral gold atoms for smaller systems.
Helium tagging in action spectroscopy is an efficient method for measuring the absorption spectrum of complex molecular ions with minimal perturbations to the gas phase spectrum. We have used superfluid helium nanodroplets doped with corannulene to prepare cations of these molecules complexed with different numbers of He atoms. In total we identify 13 different absorption bands from corannulene cations between 5500 Å and 6000 Å. The He atoms cause a small, chemically induced redshift to the band positions of the corannulene ion. By studying this effect as a function of the number of solvating atoms we are able to identify the formation of solvation structures that are not visible in the mass spectrum. The solvation features detected with the action spectroscopy agree very well with the results of atomistic modeling based on path-integral molecular dynamics simulations. By additionally doping our He droplets with D$_2$, we produce protonated corannulene ions. The absorption spectrum of these ions differs significantly from the case of the radical cations as the numerous narrow bands are replaced by a broad absorption feature that spans nearly 2000 Å in width.
There has long been a discrepancy between the size distributions of Ar$_n^+$ clusters measured by different groups regarding whether or not magic numbers appear at sizes corresponding to the closure of icosahedral (sub-)shells. We show that the previously observed magic cluster size distributions are likely the result of an unresolved Ar$_n$H$^+$ component, that is, from protonated argon clusters. We find that the proton impurity gives cluster geometries that are much closer to those for neutral rare gas clusters, which are known to form icosahedral structures, than the pure cationic clusters, explaining why the mass spectra from protonated argon clusters better matches these structural models. Our results thus show that even small impurities, e.g.\ a single proton, can significantly influence the properties of clusters.
MegaMapper is a proposed ground-based experiment to measure Inflation parameters and Dark Energy from galaxy redshifts at 2<z<5. A 6.5-m Magellan telescope will be coupled with DESI spectrographs to achieve multiplexing of 20,000. MegaMapper would be located at Las Campanas Observatory to fully access LSST imaging for target selection.
We present the status of the Dark Energy Spectroscopic Instrument (DESI) and its plans and opportunities for the coming decade. DESI construction and its initial five years of operations are an approved experiment of the US Department of Energy and is summarized here as context for the Astro2020 panel. Beyond 2025, DESI will require new funding to continue operations. We expect that DESI will remain one of the world's best facilities for wide-field spectroscopy throughout the decade. More about the DESI instrument and survey can be found at https://www.desi.lbl.gov.
The \lya forest at high redshifts is a powerful probe of reionization. Modeling and observing this imprint comes with significant technical challenges: inhomogeneous reionization must be taken into account while simultaneously being able to resolve the web-like small-scale structure prior to reionization. In this work we quantify the impact of inhomogeneous reionization on the \lya forest at lower redshifts ($2 < z < 4$), where upcoming surveys such as DESI will enable precision measurements of the flux power spectrum. We use both small box simulations capable of handling the small-scale structure of the \lya forest and semi-numerical large box simulations capable of representing the effects of inhomogeneous reionization. We find that inhomogeneous reionization could produce a measurable effect on the \lya forest power spectrum. The deviation in the 3D power spectrum at $z_{\rm obs} = 4$ and $k = 0.14 \ \rm{Mpc}^{-1}$ ranges from $19 - 36\%$, with a larger effect for later reionization. The corrections decrease to $2.0 - 4.1\%$ by $z_{\rm obs} = 2$. The impact on the 1D power spectrum is smaller, and ranges from $3.3 - 6.5\%$ at $z_{\rm obs}=4$ to $0.35 - 0.75\%$ at $z_{\rm obs}=2$, values which are comparable to the statistical uncertainties in current and upcoming surveys. Furthermore, we study how can this systematic be constrained with the help of the quadrupole of the 21 cm power spectrum.
Using the Ly$α$ mass assignment scheme (LyMAS), we make theoretical predictions for the 3-dimensional 3-point correlation function (3PCF) of the Ly$α$ forest at redshift $z=2.3$. We bootstrap results from the (100 $h^{-1} \mbox{ Mpc}$)$^3$ Horizon hydrodynamic simulation to a (1 $h^{-1}$ Gpc)$^3$ $N$-body simulation, considering both a uniform UV background (UVB) and a fluctuating UVB sourced by quasars with a comoving $n_q \approx 10^{-5}$ $h^3$ Mpc$^{-3}$ placed either in massive halos or randomly. On scales of $10-30$ $h^{-1} \mbox{ Mpc}$, the flux 3PCF displays hierarchical scaling with the square of the 2PCF, but with an unusual value of $Q \equiv ζ_{123}/(ξ_{12} ξ_{13} + ξ_{12} ξ_{23} + ξ_{13} ξ_{23}) \approx -4.5$ that reflects the low bias of the Ly$α$ forest and the anti-correlation between mass density and transmitted flux. For halo-based quasars and an ionizing photon mean free path of $λ= 300$ $h^{-1} \mbox{ Mpc}$ comoving, UVB fluctuations moderately depress the 2PCF and 3PCF, with cancelling effects on $Q$. For $λ= 100$ $h^{-1} \mbox{ Mpc}$ or 50 $h^{-1} \mbox{ Mpc}$, UVB fluctuations substantially boost the 2PCF and 3PCF on large scales, shifting the hierarchical ratio to $Q \approx -3$. We scale our simulation results to derive rough estimate of the 3PCF detectability in observational data sets for the redshift range $z=2.1 - 2.6$. At $r = 10$ $h^{-1} \mbox{ Mpc}$ and 20 $h^{-1} \mbox{ Mpc}$, we predict a signal-to-noise (SNR) of $\sim$ 9 and $\sim$ 7, respectively, for both BOSS and eBOSS, and $\sim$ 37 and $\sim$ 25 for DESI. At $r = 40$ $h^{-1} \mbox{ Mpc}$ the predicted SNR is lower by $\sim$ 3$-$5 times. Measuring the flux 3PCF would be a novel test of the conventional paradigm of the Ly$α$ forest and help separate the contributions of UVB fluctuations and density fluctuations to Ly$α$ forest clustering.
We present new Gemini/GMOS optical spectroscopy of 16 extreme variability quasars (EVQs) that dimmed by more than 1.5 mag in the $g$ band between the Sloan Digital Sky Survey (SDSS) and the Dark Energy Survey (DES) epochs (separated by a few years in the quasar rest frame). The quasar sample covers a redshift range of $0.5 < z < 2.1$. Nearly half of these EVQs brightened significantly (by more than 0.5 mag in the $g$ band) in a few years after reaching their previous faintest state, and some EVQs showed rapid (non-blazar) variations of greater than 1-2 mag on timescales of only months. Leveraging on the large dynamic range in continuum variability between the earlier SDSS and the new GMOS spectra, we explore the associated variations in the broad Mg II,$\lambda2798$ line, whose variability properties have not been well studied before. The broad Mg II flux varies in the same direction as the continuum flux, albeit with a smaller amplitude, which indicates at least some portion of Mg II is reverberating to continuum changes. However, the width (FWHM) of Mg II does not vary accordingly as continuum changes for most objects in the sample, in contrast to the case of the broad Balmer lines. Using the width of broad Mg II to estimate the black hole mass therefore introduces a luminosity-dependent bias.
There is wide consensus that galaxy outflows are one of the most important processes determining the evolution of galaxies through cosmic time, for example playing a key role in shaping the galaxy mass function. Our understanding of outflows and their drivers, however, is in its infancy --- this is particularly true for the cold (neutral atomic and molecular) phases of outflows, which present observational and modeling challenges. Here we outline several key open questions, briefly discussing the requirements of the observations necessary to make progress, and the relevance of several existing and planned facilities. It is clear that galaxy outflows, and particularly cold outflows, will remain a topic of active research for the next decade and beyond.
The expansion of the Universe is understood to have accelerated during two epochs: in its very first moments during a period of Inflation and much more recently, at $z < 1$, when Dark Energy is hypothesized to drive cosmic acceleration. The undiscovered mechanisms behind these two epochs represent some of the most important open problems in fundamental physics. The large cosmological volume at $2 < z < 5$, together with the ability to efficiently target high-$z$ galaxies with known techniques, enables large gains in the study of Inflation and Dark Energy. A future spectroscopic survey can test the Gaussianity of the initial conditions up to a factor of ~50 better than our current bounds, crossing the crucial theoretical threshold of $σ(f_{NL}^{\rm local})$ of order unity that separates single field and multi-field models. Simultaneously, it can measure the fraction of Dark Energy at the percent level up to $z = 5$, thus serving as an unprecedented test of the standard model and opening up a tremendous discovery space.
Quasars that exhibit blue-shifted, broad absorption lines (BAL QSOs) are an important probe of black hole feedback on galaxy evolution. Yet the presence of BALs is also a complication for large, spectroscopic surveys that use quasars as cosmological probes because the BAL features can affect redshift measurements and contaminate information about the matter distribution in the Lyman-$α$ forest. We present a new BAL QSO catalog for quasars in the Sloan Digital Sky Survey (SDSS) Data Release 14 (DR14). As the SDSS DR14 quasar catalog has over 500,000 quasars, we have developed an automated BAL classifier with a Convolutional Neural Network (CNN). We trained our CNN classifier on the C IV $λ1549$ region of a sample of quasars with reliable human classifications, and compared the results to both a dedicated test sample and visual classifications from the earlier SDSS DR12 quasar catalog. Our CNN classifier correctly classifies over 98% of the BAL quasars in the DR12 catalog, which demonstrates comparable reliability to human classification. The disagreements are generally for quasars with lower signal-to-noise ratio spectra and/or weaker BAL features. Our new catalog includes the probability that each quasar is a BAL, the strength, blueshifts and velocity widths of the troughs, and similar information for any Si IV $λ1398$ BAL troughs that may be present. We find significant BAL features in 16.8% of all quasars with $1.57 < z < 5.56$ in the SDSS DR14 quasar catalog.
While we observe a large amount of cold interstellar gas and dust in a subset of the early-type galaxy (ETG) population, the source of this material remains unclear. The two main, competing scenarios are external accretion of lower mass, gas-rich dwarfs and internal production from stellar mass loss and/or cooling from the hot interstellar medium (ISM). We test these hypotheses with measurements of the stellar and nebular metallicities of three ETGs (NGC 2768, NGC 3245, and NGC 4694) from new long-slit, high signal-to-noise ratio spectroscopy from the Multi-Object Double Spectographs (MODs) on the Large Binocular Telescope (LBT). These ETGs have modest star formation rates and minimal evidence of nuclear activity. We model the stellar continuum to derive chemical abundances and measure gas-phase abundances with standard nebular diagnostics. We find that the stellar and gas-phase abundances are very similar, which supports internal production and is very inconsistent with the accretion of smaller, lower metallicity dwarfs. All three of these galaxies are also consistent with an extrapolation of the mass-metallicity relation to higher mass galaxies with lower specific star formation rates. The emission line flux ratios along the long-slit, as well as global line ratios clearly indicate that photoionization dominates and ionization by alternate sources including AGN activity, shocks, cosmic rays, dissipative magnetohydrodynamic waves, and single degenerate Type Ia supernovae progenitors do not significantly affect the line ratios.
Using stellar population models, we predicted that the Dark Energy Survey (DES) - due to its special combination of area (5000 deg. sq.) and depth ($i = 24.3$) - would be in the position to detect massive ($\gtrsim 10^{11}$ M$_{\odot}$) galaxies at $z \sim 4$. We confront those theoretical calculations with the first $\sim 150$ deg. sq. of DES data reaching nominal depth. From a catalogue containing $\sim 5$ million sources, $\sim26000$ were found to have observed-frame $g-r$ vs $r-i$ colours within the locus predicted for $z \sim 4$ massive galaxies. We further removed contamination by stars and artefacts, obtaining 606 galaxies lining up by the model selection box. We obtained their photometric redshifts and physical properties by fitting model templates spanning a wide range of star formation histories, reddening and redshift. Key to constrain the models is the addition, to the optical DES bands $g$, $r$, $i$, $z$, and $Y$, of near-IR $J$, $H$, $K_{s}$ data from the Vista Hemisphere Survey. We further applied several quality cuts to the fitting results, including goodness of fit and a unimodal redshift probability distribution. We finally select 233 candidates whose photometric redshift probability distribution function peaks around $z\sim4$, have high stellar masses ($\log($M$^{*}$/M$_{\odot})\sim 11.7$ for a Salpeter IMF) and ages around 0.1 Gyr, i.e. formation redshift around 5. These properties match those of the progenitors of the most massive galaxies in the local universe. This is an ideal sample for spectroscopic follow-up to select the fraction of galaxies which is truly at high redshift. These initial results and those at the survey completion, which we shall push to higher redshifts, will set unprecedented constraints on galaxy formation, evolution, and the re-ionisation epoch.
The Dark Energy Spectroscopic Instrument (DESI) is under construction to measure the expansion history of the Universe using the Baryon Acoustic Oscillation technique. The spectra of 35 million galaxies and quasars over 14000 sq deg will be measured during the life of the experiment. A new prime focus corrector for the KPNO Mayall telescope will deliver light to 5000 fiber optic positioners. The fibers in turn feed ten broad-band spectrographs. We will describe the methods and results for the commissioning instrument metrology program. The primary goals of this program are to calculate the transformations and further develop the systems that will place fibers within 5um RMS of the target positions. We will use the commissioning instrument metrology program to measure the absolute three axis Cartesian coordinates of the five CCDs and 22 illuminated fiducials on the commissioning instrument.
We describe the design of the Commissioning Instrument for the Dark Energy Spectroscopic Instrument (DESI). DESI will obtain spectra over a 3 degree field of view using the 4-meter Mayall Telescope at Kitt Peak, AZ. In order to achieve the required image quality over this field of view, a new optical corrector is being installed at the Mayall Telescope. The Commissioning Instrument is designed to characterize the image quality of the new optical system. The Commissioning Instrument has five commercial cameras; one at the center of the focal surface and four near the periphery of the field and at the cardinal directions. There are also 22 illuminated fiducials, distributed throughout the focal surface, that will be used to test the system that will map between the DESI fiber positioners and celestial coordinates. We describe how the commissioning instrument will perform commissioning tasks for the DESI project and thereby eliminate risks.
The Dark Energy Spectroscopic Instrument (DESI) is under construction to measure the expansion history of the Universe using the Baryon Acoustic Oscillation technique. The spectra of 35 million galaxies and quasars over 14000 square degrees will be measured during the life of the experiment. A new prime focus corrector for the KPNO Mayall telescope will deliver light to 5000 fiber optic positioners. The fibers in turn feed ten broad-band spectrographs. We present an overview of the instrumentation, the main technical requirements and challenges, and the current status of the project.
The incidence of Active Galactic Nuclei (AGN) with local environment is a potentially valuable probe of the mechanisms that trigger and provide fuel for accretion onto supermassive black holes. While the correlation between AGN fraction and environment has been well-studied in the local universe, AGN fractions have been measured for relatively few dense environments at high redshift. In this paper we present a measurement of the X-ray AGN fraction in the USS 1558-003 protocluster associated with the z=2.53 radio galaxy 4C-00.62. Our measurement is based on a 100ks Chandra observation, follow-up spectroscopy from the Multi-Object Double Spectrograph on the Large Binocular Telescope, and broad and narrow band photometry. These data are sensitive to AGN more luminous than $L_{X}>2\times10^{43}$ erg s$^{-1}$ in the rest-frame hard X-ray band (2-10 keV). We have identified two X-ray AGN at the redshift of USS 1558-003, one of which is the radio galaxy. We have determined that $2.0^{+2.6}_{-1.3}$% of the H$α$ emitters in the protocluster are X-ray AGN. Unlike most other high-redshift cluster progenitors studied with similar techniques, USS 1558-003 does not have a significantly higher fraction of AGN than field galaxies at similar redshifts. This lower AGN fraction is inconsistent with the expectation that the higher gas fractions at high redshift, combined with the high galaxy densities and modest relative velocities in protoclusters, should produce higher AGN fractions.