arXiv subjects

Paul Mollière

Publications and source records attributed to Paul Mollière.

At least 19 recordsLinked to original sources

arXiv2026

The effect of the atmospheric C/O ratio on interiors of hot Jupiters

The atmosphere is the outer boundary of a gas giant exoplanet's interior. Therefore, compositional changes in the atmosphere can affect interior inferences. Typically, only metallicity is considered in atmospheric boundary conditions, while other elemental ratios, in particular the C/O ratio, are assumed to be solar. In light of the observational constraints now achievable with JWST, this assumption might no longer be justified. In this work, we investigate the effect of the C/O ratio on atmospheric boundary conditions, interiors and radii of hot Jupiters. We construct an atmospheric boundary grid, consisting of one-dimensional atmospheric models in radiative-convective and thermochemical equilibrium. This grid is coupled to a static interior structure model at the radiative-convective boundary (RCB). Because in the temperature regime of hot Jupiters, the C/O ratio determines the dominant species in the atmosphere, it can significantly alter the opacity and, consequently, the pressure and temperature at the RCB. This temperature change propagates into the convective interior, thus affecting the calculated radius. The radius difference relative to a solar C/O-atmosphere significantly exceeds observed radius uncertainties of 3 per cent for planets with equilibrium temperatures $\gtrsim$ 1500 K and super-solar atmospheric metallicities. As an example, we demonstrate that, for WASP-19~b, higher C/O ratios result in higher inferred intrinsic temperatures. These results highlight the importance of treating atmospheric composition and interior structure as a coupled system. As atmospheric constraints improve, incorporating measured C/O ratios into atmospheric boundary conditions is necessary to obtain robust inferences of hot Jupiter interiors.

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arXiv2026

The JWST Early Release Science Program for Direct Observations of Exoplanetary Systems VIII: patchy forsterite and enstatite clouds in the atmosphere of VHS 1256 b, retrieval lessons learned and outlook to the future

JWST defines a new era for the data-driven approach of retrieval modelling, which has become a cornerstone tool for the statistical inference of exoplanetary and brown dwarf properties. The Early Release Science program #1386 observations of VHS 1256 b represent a huge jump in data quality, data quantity and spectral coverage for such objects. VHS 1256 b is a young, planetary mass and extremely variable companion that populates the enigmatic L/T cohort of substellar atmospheres. In this first retrieval analysis of the full 1 - 18 micron dataset, we apply the Brewster retrieval framework to the NIRSpec and MIRI spectroscopic observations of VHS 1256 b, exploring a variety of cloud species and structures. Using Delta(BIC) we find that the data is best described by a forsterite (Mg$_{2}$SiO$_{4}$) and enstatite (MgSiO$_{3}$) cloud combination. Our analysis shows a strong preference for patchy silicate cloud coverage, which aligns with VHS 1256 b's extensive and well documented spectral variability. Our retrieval is able to place constraints on the abundances of H$_{2}$O, CO, CO$_{2}$, CH$_{4}$ as well as NH$_{3}$. We also show that the retrieved parameters are sensitive to the data used and the relative signal-to-noise ratios between data from different instruments. We conclude with the next steps for the wider retrieval community to better understand young and cloudy exoplanetary atmospheres.

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arXiv2026

The panchromatic JWST dayside spectrum of WASP-121 b reveals a refractory-rich formation

One path to understand how planets form is to link their present-day atmospheric composition to predictions from planet formation models. For the hottest planets, the abundances of refractory species can provide a useful formation tracer, complementing the traditionally used C/O and overall metallicity. Here we investigate the refractory abundance in the atmosphere of the ultra-hot Jupiter WASP-121 b, combining new JWST MIRI/LRS observations with archival NIRSpec/G395H and NIRISS/SOSS data to obtain a panchromatic dayside emission spectrum from 0.6 to 12 $μ$m. Our retrieval analysis detects the refractory tracer SiO gas at high confidence, in addition to previously detected volatile species. The atmosphere is enriched in volatile and refractory species, with enhanced refractory-to-volatile ratios of Si/O=$3.54^{+0.86}_{-0.69}$x stellar and Si/C=$3.05^{+1.12}_{-0.80}$x stellar, relative to new stellar abundance constraints from ESPRESSO data. In addition, we confirm the depletion of TiO and the need for an additional source of reflected light opacity with a geometric albedo of $0.22\pm0.03$. The retrieved dayside temperature profile has a strong inversion layer, with a more complex structure than standard parameterizations can accommodate, and an eclipse map analysis indicates a small eastward hotspot offset of $4.8^{+2.7\circ}_{-2.8}$. Comparing our results with models of planet formation, we find that the measured enrichment pattern was shaped by accretion from multiple reservoirs, either through a mixture of solid and gas accretion interior to the water ice line or through continued solid accretion during inward migration from farther out in the disk. Finally, we model the planet's dynamical history and find that it could reach its current high-obliquity orbit as a consequence of a post-formation dynamical event, such as planet-planet scattering or von Zeipel-Lidov-Kozai cycles.

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arXiv2026

$^{13}$CO and potential variability in $β$ Pictoris b with GRAVITY+

The $^{12}$CO/$^{13}$CO ratio was introduced as an indicator for where in the disk a planet has formed. Previously a lower value compared to the host star's was suggested to show that a planet accreted CO ice beyond the disk's CO ice line. In this letter we aim to determine the $^{12}$CO/$^{13}$CO value of the directly imaged planet $β$ Pictoris b, and whether we can link it to its formation. Its apparent brightness results in an exceptional S/N of up to ~60 per wavelength point. We present the first science observations with the upgraded GRAVITY+ instrument at a spectral resolution of R ~ 4000, which we analyse with petitRADTRANS. Our retrievals robustly indicate the presence of $^{13}$CO with a $^{12}$CO/$^{13}$CO ratio of 91$^{+24}_{-17}$, consistent with both a solar to ISM-like value. Our $^{12}$CO/$^{13}$CO value corroborates recent interpretations that $^{13}$CO may be a less useful tracer of formation location in the disk than previously thought; nonetheless, we discuss theories with which this value is consistent. As our observations span ~7 hours, this enabled us to search for atmospheric variability in $β$ Pictoris b; we report a tentative constraint on the variability amplitude of about 1.4$^{+0.6}_{-0.7}$%.

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arXiv2026

Panchromatic View of the Frigid Jovian Exoplanet COCONUTS-2 b

We use a high signal-to-noise MIRI-LRS spectrum (5.45 - 11 $μ$m, R$_λ$ $\sim100$) of COCONUTS-2~b revealing prominent molecular features of H$_2$O, CH$_4$ and NH$_3$. This dataset is combined with spectra from Gemini/FLAMINGOS-2 and JWST/NIRSpec (G395H), as well as photometry from WISE and Spitzer, resulting in almost continuous wavelength coverage from 1 to 15 $μ$m. We analyze the data using five grids of self-consistent atmospheric models, spanning a wide range of T$_\text{eff}$, log(g), and [M/H]. We also investigate the use of Gaussian Processes to account for correlated noise either caused by the spectrograph or by systematic departures of models in the inversion framework. All models manage to fit the overall combined observations but predict fainter flux in Y- and N-bands. Classical model comparison suggests that the ATMO2020++ synthetic specra (with and without PH$_3$) are statistically preferred. Fitting for the correlated noise of the three spectroscopic instruments, ATMO2020++ models yields constraints consistent with previous studies and evolutionary models predictions: T$_\text{eff}$ $=496^{+5}_{-3}$ K, log(g) $=4.30^{+0.04}_{-0.02}$ dex, [M/H] $=-0.02^{+0.03}_{-0.02}$ dex, and R $=1.03^{+0.01}_{-0.02}$ R$_\text{jup}$. The extended wavelength coverage provided by MIRI (accounting for 41% of the bolometric flux) completes the SED, yielding a precise luminosity estimation of log(L/L$_{\odot}$) $=-6.166\pm0.002$ dex. Combined with a previous estimate of the system age ($414\pm23$ Myr), cooling models predict a mass of M $=7.3\pm0.3$ M$_\text{jup}$.

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arXiv2025

The bulk metal content of WASP-80 b from joint interior-atmosphere retrievals: Breaking degeneracies and exploring biases with panchromatic spectra

WASP-80 b is an unusually low-density exoplanet in tension with the metal-rich composition expected for a planet of its mass. We aim to derive precise constraints on WASP-80 b's bulk metal mass fraction, atmospheric composition, and thermal structure. We conducted a suite of retrievals using three approaches: traditional interior-only, atmosphere-only, and joint interior-atmosphere retrievals. We coupled the open-source models GASTLI and petitRADTRANS, which describe planetary structure and thermal evolution, and atmospheric chemistry and clouds, respectively. Our retrievals combine mass and age with panchromatic spectra from JWST and HST in both transmission (0.5-4 $μ$m) and emission (1-12 $μ$m) as observational constraints. We identify two fiducial scenarios. In the first, WASP-80 b has an internal temperature consistent with its age in the absence of external heating sources, and its atmosphere is in chemical equilibrium, with an atmospheric metallicity M/H = 2.75$^{+0.88}_{-0.56}$x solar, a bulk metal mass fraction $Z_{planet}=0.12\pm0.02$, and a core mass $M_{core}=3.49^{+3.49}_{-1.59} \ M_{\oplus}$. In the second scenario, WASP-80 b may be inflated by an additional heat source - possibly induced by magnetic fields - with an atmospheric metallicity M/H = 10.00$^{+8.20}_{-4.75}$x solar, $Z_{planet}=0.28\pm0.11$, and $M_{core}=31.8^{+21.3}_{-17.5} \ M_{\oplus}$. The super-solar M/H and sub-solar C/O ratios in both scenarios suggest late pebble or planetesimal accretion, while additional heating is required to reconcile the data with the more massive core predicted by the core accretion paradigm. In general, joint retrievals are inherently affected by a degeneracy between atmospheric chemistry and internal structure. Together with flexible cloud treatment and an unweighted likelihood, this leads to larger uncertainties in bulk and atmospheric compositions than previously claimed.

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arXiv2025

BOWIE-ALIGN: Weak spectral features in KELT-7b's JWST NIRSpec/G395H transmission spectrum imply a high cloud deck or a low-metallicity atmosphere

Hot Jupiters and their atmospheres are prime targets for transmission spectroscopy due to their extended atmospheres and the corresponding large signal-to-noise, providing the best possible constraints for the atmospheric carbon-to-oxygen (C/O) ratio and metallicity of exoplanets. Within BOWIE-ALIGN, we aim to compare JWST spectra of a sample of orbitally aligned and misaligned hot Jupiters orbiting F-type stars to probe the link between hot Jupiter atmospheres and planet formation history. Here, we present a near-infrared transmission spectrum of the aligned planet KELT-7b using one transit observed with JWST NIRSpec/G395H. We find weak features, only tentative evidence for H$_2$O and CO$_2$ in the atmosphere of KELT-7b. This poses a challenge to constrain the atmospheric properties of KELT-7b and two possible scenarios emerge from equilibrium chemistry and free chemistry retrievals: a high-altitude cloud deck muting all features or an extremely low metallicity atmosphere, respectively. The retrieved C/O ratios from our data reductions range from $0.43 - 0.74$, while the atmospheric metallicity is suggested to be solar to super-solar ($1-16 \times$ solar). Although these wide constraints prevent detailed conclusions about KELT-7b's formation history, a solar-to-super-solar metallicity would imply the accretion of solid material during its formation, which is valuable information for the survey's wider goals of understanding the relative importance of gaseous to solid accretion.

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arXiv2025

SO2, silicate clouds, but no CH4 detected in a warm Neptune

WASP-107b is a warm (~740 K) transiting planet with a Neptune-like mass of ~30.5 Earth masses and Jupiter-like radius of ~0.94 Jupiter radius, whose extended atmosphere is eroding. Previous observations showed evidence for water vapour and a thick high-altitude condensate layer in WASP-107b's atmosphere. Recently, photochemically produced sulphur dioxide (SO2) was detected in the atmosphere of a hot (~1200 K) Saturn-mass planet from transmission spectroscopy near 4.05 microns, but for temperatures below 1000 K sulphur is predicted to preferably form sulphur allotropes instead of SO2. Here we report the 9-sigma detection of two fundamental vibration bands of SO2, at 7.35 microns and 8.69 microns, in the transmission spectrum of WASP-107b using the Mid-Infrared Instrument (MIRI) of the JWST. This discovery establishes WASP-107b as the second irradiated exoplanet with confirmed photochemistry, extending the temperature range of exoplanets exhibiting detected photochemistry from ~1200 K down to ~740 K. Additionally, our spectral analysis reveals the presence of silicate clouds, which are strongly favoured (~7-sigma) over simpler cloud setups. Furthermore, water is detected (~12-sigma), but methane is not. These findings provide evidence of disequilibrium chemistry and indicate a dynamically active atmosphere with a super-solar metallicity.

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arXiv2025

The SPACE Program. I. The featureless spectrum of HD 86226 c challenges sub-Neptune atmosphere trends

Sub-Neptune exoplanets are the most abundant type of planet known today. As they do not have a Solar System counterpart, many open questions exist about their composition and formation. Previous spectroscopic studies rule out aerosol-free hydrogen-helium-dominated atmospheres for many characterized sub-Neptunes but are inconclusive about their exact atmospheric compositions. Here we characterize the hot (Teq=1311K) sub-Neptune HD 86226 c, which orbits its G-type host star. Its high equilibrium temperature prohibits methane-based haze formation, increasing the chances for a clear atmosphere on this planet. We use HST data taken with WFC3 and STIS from the Sub-neptune Planetary Atmosphere Characterization Experiment (SPACE) Program to perform near-infrared 1.1-1.7micrometer transmission spectroscopy and UV characterization of the host star. We report a featureless transmission spectrum that is consistent within 0.4 sigma with a constant transit depth of 418+-14ppm. The amplitude of this spectrum is only 0.01 scale heights for a H/He-dominated atmosphere, excluding a cloud-free solar-metallicity atmosphere on HD 86226 c with a confidence of 6.5 sigma. Based on an atmospheric retrieval analysis and forward models of cloud and haze formation, we find that the featureless spectrum could be due to a metal enrichment [M/H] above 2.3 (3 sigma confidence lower limit) of a cloudless atmosphere, or silicate (MgSiO3), iron (Fe), or manganese sulfide (MnS) clouds. For these species, we perform an investigation of cloud formation in high-metallicity, high-temperature atmospheres. Our results highlight that HD 86226c does not follow the aerosol trend of sub-Neptunes found by previous studies. Follow-up observations with the JWST could determine whether this planet aligns with the recent detections of metal-enriched atmospheres or if it harbors a cloud species otherwise atypical for sub-Neptunes.

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arXiv2025

X-SHYNE: X-Shooter spectra of young exoplanet analogs II. Presentation and analysis of the full library

The X-SHYNE library is a homogeneous sample of 43 medium-resolution (R=8000) infrared (0.3-2.5um) spectra of young (<500Myr), low-mass (<20Mjup), and cold (Teff=600-2000K) isolated brown dwarfs and wide-separation companions observed with the VLT/X-Shooter instrument. To characterize our targets, we performed a global comparative analysis. We first applied a semi-empirical approach. By refining their age and bolometric luminosity, we derived key atmospheric and physical properties, such as Teff, mass, surface gravity (g), and radius, using the evolutionary model COND03. These results were then compared with the results from a synthetic analysis based on three self-consistent atmospheric models. To compare our spectra with these grids we used the Bayesian inference code ForMoSA. We found similar Lbol estimates between both approaches, but an underestimated Teff from the cloudy models, likely due to a lack of absorbers that could dominate the J and H bands of early L. We also observed a discrepancy in the log(g) estimates, which are dispersed between 3.5 and 5.5 dex for mid-L objects. We interpreted this as a bias caused by a range of rotational velocities leading to cloud migration toward equatorial latitudes, combined with a variety of viewing angles that result in different observed atmospheric properties (cloud column densities, atmospheric pressures, etc.). Finally, while providing robust estimates of [M/H] and C/O for individual objects remains challenging, the X-SHYNE library globally suggests solar values, which are consistent with a formation via stellar formation mechanisms. This study highlights the strength of homogeneous datasets in performing comparative analyses, reducing the impact of systematics, and ensuring robust conclusions while avoiding over-interpretation.

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arXiv2025

ELemental abundances of Planets and brown dwarfs Imaged around Stars (ELPIS): II. The Jupiter-like Inhomogeneous Atmosphere of the First Directly Imaged Planetary-Mass Companion 2MASS 1207 b

2MASS 1207 b, the first directly imaged planetary-mass companion, has been instrumental in advancing our understanding of exoplanets and brown dwarfs over the past 20 years. We have performed extensive atmospheric retrieval analyses of 2MASS 1207 b's JWST/NIRSpec spectrum using petitRADTRANS and a new atmospheric inhomogeneity framework, which characterizes homogeneous atmospheres, patchy clouds, cloud-free hot spots, or the combination of patchy clouds and spots. Among 24 retrieval runs with various assumptions, the most statistically preferred model corresponds to the patchy cloud scheme, with Teff$=1174^{+4}_{-3}$ K, log(g)=$3.62^{+0.03}_{-0.02}$ dex, and R$=1.399^{+0.008}_{-0.010}$ R$_{\rm Jup}$, along with near-solar atmospheric compositions of [M/H]$=-0.05\pm0.03$ dex and C/O$=0.440\pm0.012$. This model suggests ~9% of 2MASS 1207 b's atmosphere is covered by thin iron clouds, producing L-dwarf-like spectra, while the remaining 91% consists of thick silicate and iron clouds, emitting blackbody-like spectra. These thin-cloud and thick-cloud regions resemble Jupiter's belts and zones, respectively; this scenario is consistently supported by other retrieval runs incorporating inhomogeneous atmospheres. We demonstrate that 2MASS 1207 b's weak CO absorption can be explained by the veiling effects of patchy thick clouds; the absence of 3.3um CH4 absorption is attributed to its hot thermal structure, which naturally leads to a CO-dominant, CH4-deficient atmosphere. The retrieved atmospheric models also match the observed variability amplitudes of 2MASS 1207 b. Our analysis reveals that the inferred atmospheric properties show significant scatter in less statistically preferred retrieval runs but converge to consistent values among the preferred ones. This underscores the importance of exploring diverse assumptions in retrievals to avoid biased interpretations of atmospheres and formation.

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arXiv2025

HCN and C2H2 in the atmosphere of a T8.5+T9 brown dwarf binary

T-type brown dwarfs present an opportunity to explore atmospheres teeming with molecules such as H2O, CH4 and NH3, which exhibit a wealth of absorption features in the mid-infrared. With JWST, we can finally explore this chemistry in detail, including for the coldest brown dwarfs that were not yet discovered in the Spitzer era. This allows precise derivations of the molecular abundances, which in turn informs our understanding of vertical transport in these atmospheres and can provide clues about the formation of cold brown dwarfs and exoplanets. This study presents the first JWST/MRS mid-IR spectrum (R ~ 1500-3000) of a T-dwarf: the T8.5+T9 brown dwarf binary WISE J045853.90+643451.9. We fit the spectrum using a parameterized P-T profile and free molecular abundances (i.e., a retrieval analysis), treating the binary as unresolved. We find a good fit with a cloud-free atmosphere and identify H2O, CH4 and NH3 features. Moreover, we make the first detections of HCN and C2H2 (at 13.4$σ$ and 9.5$σ$ respectively) in any brown dwarf atmosphere. The detection of HCN suggests intense vertical mixing ($K_{zz}\sim10^{11}$cm$^2$s$^{-1}$), challenging previous literature derivations of $K_{zz}$ values for T-type brown dwarfs. Even more surprising is the C2H2 detection, which cannot be explained with existing atmospheric models for isolated objects. This result challenges model assumptions about vertical mixing, and/or our understanding of the C2H2 chemical network, or might hint towards a more complex atmospheric processes such as magnetic fields driving aurorae, or lightning driving ionization. These findings open a new frontier in studying carbon chemistry within brown dwarf atmospheres.

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arXiv2024

easyCHEM: A Python package for calculating chemical equilibrium abundances in exoplanet atmospheres

For modeling the spectra of exoplanets one must know their atmospheric composition. This is necessary because the abundance of molecules, atoms, ions and condensates is needed to construct the total cross-section for the interaction between electro-magnetic radiation and matter. In addition, when solving for the temperature structure of an atmosphere the so-called adiabatic temperature gradient must be known, which describes the pressure-temperature dependence in convectively unstable regions well. Depending on the planetary properties, the composition and adiabatic gradients may be well described by equilibrium chemistry, which means that chemical reactions occur faster than any other relevant processes in the atmosphere, such as mixing. What is more, the equilibrium assumption often serves as a useful starting point for non-equilibrium calculations. Efficient and easy-to-use codes for determining equilibrium abundances are therefore needed. Here we report on our easyCHEM Python package that calculates atmospheric compositions and adiabatic temperature gradients in chemical equilibrium for any user-specified elemental composition.

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arXiv2024

The ESO SupJup Survey III: Confirmation of 13CO in YSES 1 b and Atmospheric Detection of YSES 1 c with CRIRES+

High-resolution spectroscopic characterization of young super-Jovian planets enables precise constraints on elemental and isotopic abundances of their atmospheres. As part of the ESO SupJup Survey, we present high-resolution spectral observations of two wide-orbit super-Jupiters in YSES 1 (or TYC 8998-760-1) using the upgraded VLT/CRIRES+ (R~100,000) in K-band. We carry out free atmospheric retrieval analyses to constrain chemical and isotopic abundances, temperature structures, rotation velocities, and radial velocities. We confirm the previous detection of 13CO in YSES 1 b at a higher significance of 12.6σ, but point to a higher 12CO/13CO ratio of 88+/-13 (1σ confidence interval), consistent with the primary's isotope ratio 66+/-5. We retrieve a solar-like composition in YSES 1 b with a C/O=0.57+/-0.01, indicating a formation via gravitational instability or core accretion beyond the CO iceline. Additionally, the observations lead to detections of H2O and CO in the outer planet YSES 1 c at 7.3σ and 5.7σ, respectively. We constrain the atmospheric C/O ratio of YSES 1 c to be either solar or subsolar (C/O=0.36+/-0.15), indicating the accretion of oxygen-rich solids. The two companions have distinct vsini, 5.34+/-0.14 km/s for YSES 1 b and 11.3+/-2.1 km/s for YSES 1 c, despite their similar natal environments. This may indicate different spin axis inclinations or effective magnetic braking by the long-lived circumplanetary disk around YSES 1 b. YSES 1 represents an intriguing system for comparative studies of super-Jovian companions and linking present atmospheres to formation histories.

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arXiv2024

Standing on the Shoulders of Giants: A Comprehensive Spectroscopic Survey of Transiting & High-Contrast Giant Planets

We propose a comprehensive survey of giant planets ranging from close-in highly irradiated hot Jupiters to young, wide-orbit directly imaged planets. The combination of two established techniques for probing planetary atmospheric compositions (time-series transit observations and high-contrast spectroscopy) will provide an unprecedented window into gaseous planet compositions across a range of equilibrium temperatures (100-2000 K), orbital separations (0.1-100 au), and system ages (10 Myr-1 Gyr). To-date, compositional measurements of both transiting and directly imaged planets suggest two distinct formation pathways: star-like formation for directly imaged planets and planet-like formation for transiting planets. By leveraging the combined technical and theoretical expertise of the transiting and direct imaging communities, we can obtain a holistic view of giant planet formation, migration, accretion, and evolution. From the results of this comprehensive program, we will begin to answer one of the fundamental outstanding questions in our understanding of giant planets: where and how in the protoplanetary disk do giant planets form?

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arXiv2024

GASTLI: An open-source coupled interior-atmosphere model to unveil gas giant composition

The metal mass fractions of gas giants are a powerful tool to constrain their formation mechanisms and evolution. The metal content is inferred by comparing mass and radius measurements with interior structure and evolution models. In the midst of the JWST, CHEOPS, TESS, and the forthcoming PLATO era, we are at the brink of obtaining unprecedented precision in radius, age and atmospheric metallicity measurements. To prepare for this wealth of data, we present the GAS gianT modeL for Interiors (GASTLI), an easy-to-use, publicly available Python package. The code is optimized to rapidly calculate mass-radius relations, and radius and luminosity thermal evolution curves for a variety of envelope compositions and core mass fractions. Its applicability spans planets with masses $17 \ M_{\oplus} < M < 6 \ M_{Jup}$, and equilibrium temperatures $T_{eq} < 1000$ K. The interior model is stratified in a core composed of water and rock, and an envelope constituted by H/He and metals (water). The interior is coupled to a grid of self-consistent, cloud-free atmospheric models to determine the atmospheric and boundary interior temperature, as well as the contribution of the atmosphere to the total radius. We successfully validate GASTLI by comparing it to previous work and data of the Solar System's gas giants and Neptune. We also test GASTLI on the Neptune-mass exoplanet HAT-P-26 b, finding a bulk metal mass fraction between 0.60-0.78 and a core mass of 8.5-14.4 $M_{\oplus}$. Finally, we explore the impact of different equations of state and assumptions, such as C/O ratio and transit pressure, in the estimation of bulk metal mass fraction. These differences between interior models entail a change in radius of up to 2.5% for Jupiter-mass planets, but more than 10\% for Neptune-mass. These are equivalent to variations in core mass fraction of 0.07, or 0.10 in envelope metal mass fraction.

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arXiv2024

Are these planets or brown dwarfs? Broadly solar compositions from high-resolution atmospheric retrievals of ~10-30 $M_\textrm{Jup}$ companions

Using Keck Planet Imager and Characterizer (KPIC) high-resolution ($R$~35000) spectroscopy from 2.29-2.49 $μ$m, we present uniform atmospheric retrievals for eight young substellar companions with masses of ~10-30 $M_\textrm{Jup}$, orbital separations spanning ~50-360 au, and $T_\textrm{eff}$ between ~1500-2600 K. We find that all companions have solar C/O ratios, and metallicities, to within the 1-2$σ$ level, with the measurements clustered around solar composition. Stars in the same stellar associations as our systems have near-solar abundances, so these results indicate that this population of companions is consistent with formation via direct gravitational collapse. Alternatively, core accretion outside the CO snowline would be compatible with our measurements, though the high mass ratios of most systems would require rapid core assembly and gas accretion in massive disks. On a population level, our findings can be contrasted with abundance measurements for directly imaged planets with m<10 $M_\textrm{Jup}$, which show tentative atmospheric metal enrichment. In addition, the atmospheric compositions of our sample of companions are distinct from those of hot Jupiters, which most likely form via core accretion. For two companions with $T_\textrm{eff}$~1700-2000 K (kap And b and GSC 6214-210 b), our best-fit models prefer a non-gray cloud model with >3$σ$ significance. The cloudy models yield 2-3$σ$ lower $T_\textrm{eff}$ for these companions, though the C/O and [C/H] still agree between cloudy and clear models at the $1σ$ level. Finally, we constrain 12CO/13CO for three companions with the highest S/N data (GQ Lup b, HIP 79098 b, and DH Tau b), and report $v$sin($i$) and radial velocities for all companions.

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arXiv2024

Atmospheric retrievals with petitRADTRANS

petitRADTRANS (pRT) is a fast radiative transfer code used for computing emission and transmission spectra of exoplanet atmospheres, combining a FORTRAN back end with a Python based user interface. It is widely used in the exoplanet community with 222 references in the literature to date, and has been benchmarked against numerous similar tools. The spectra calculated with pRT can be used as a forward model for fitting spectroscopic data using Monte Carlo techniques, commonly referred to as an atmospheric retrieval. The new retrieval module combines fast forward modelling with nested sampling codes, allowing for atmospheric retrievals on a large range of different types of exoplanet data. Thus it is now possible to use pRT to easily and quickly infer the atmospheric properties of exoplanets in both transmission and thermal emission.

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