arXiv subjects

Philip Richerme

Publications and source records attributed to Philip Richerme.

At least 19 recordsLinked to original sources

arXiv2026

In-Situ Rewiring of Two-Dimensional Ion Lattice Interactions Using Metastable State Shelving

Trapped-ion lattice geometries, which determine the interactions between trapped-ion qubits, are typically governed by the balance of Coulomb repulsion forces with the external trapping potential. Here we demonstrate how the effective ion lattice geometry and resulting qubit-qubit interactions may be reconfigured in-situ, by shelving specific ions in metastable states outside the qubit subspace. Using a triangular lattice of three $^{171}$Yb$^{+}$ ions, we optically pump selected ions into the long-lived $^2F_{7/2}$ state. We then apply a global Ising-like Hamiltonian to the system and verify that the shelved qubits are fully removed from participation in the quantum dynamics. We characterize the metastable state lifetime in the presence of laser-driven ion-ion interactions, finding a deshelving rate that is orders of magnitude slower than the spin-spin interaction rate and scales quadratically with applied laser intensity.

quant-ph↗

arXiv2026

A versatile laser-machined rf trap for arrays of 100+ ions

Large ion crystals in diverse geometries are a key resource for quantum simulation experiments. In this work, we introduce a macroscopic rf trap that supports a wide variety of one-dimensional ion configurations as well as lateral two-dimensional crystals with more than 100 ions. Our design is based on precision-machined fused silica wafers that are stacked to form the trap structure. Ten independently biased electrodes provide flexible control over the axial potential, enabling long one-dimensional crystals, isospaced ion strings, split-well chains, and two-dimensional arrays with tunable aspect ratios. We present the design and fabrication process for this trap and demonstrate the ability to tune the radial secular frequencies, detect and compensate micromotion, rotate the principal axes, and characterize trapped ion heating rates. All trap design and documentation files are freely available alongside this work, to facilitate adoption and further development within the ion trap community.

quant-ph↗

arXiv2026

Tensor-Network-Based Distributed Quantum Dynamics on Independent Quantum Computers

We present an approach based on tensor networks for distributed quantum computing simulation of chemical wavepacket dynamics in a continuous variable representation. The central idea is that the tensor-network representation of the multidimensional time-evolution operator naturally induces an elevated Hilbert space where the dynamics decomposes into a set of independent lower-dimensional propagations. This transformation converts an entangled quantum evolution into a set of parallel computational tasks that can be executed asynchronously across heterogeneous quantum and classical computing architectures. The resulting formalism establishes a direct connection between tensor-network decompositions, uniformly controlled quantum circuits, and asynchronous distributed quantum computing. The approach is developed with a goal towards hybrid quantum/classical implementation, and is appropriate for a general heterogeneous mixture of quantum hardware systems. The experimental realization of the asynchronously distributed quantum processes that arise from the tensor-network decomposition are carried out on the Sandia National Laboratories' trapped-ion quantum computer, where the circuits are compiled using native partial-entangling $XX(θ)$ gates, reducing the expected two-qubit gate infidelity by more than 30\% relative to conventional fully entangling decompositions. We demonstrate the methodology by quantum computing the vibrational spectra of a small protonated water cluster that shows critical quantum nuclear behavior. Such water cluster systems have been found to be challenging for experimental action spectroscopy and for theory, and here, for the first time, we provide results for vibrational spectroscopy that are in agreement with the respective classical results to within 4cm$^{-1}$, thus allowing for the potential for spectroscopic accuracy from quantum computations.

quant-ph↗

arXiv2025

Ion-Based Characterization of Laser Beam Profiles for Quantum Information Processing

Laser-driven operations are a common approach for engineering one- and two-qubit gates in trapped-ion arrays. Measuring key parameters of these lasers, such as beam sizes, intensities, and polarizations, is central to predicting and optimizing gate speeds and stability. Unfortunately, it is challenging to accurately measure these properties at the ion location within an ultra-high vacuum chamber. Here, we demonstrate how the ions themselves may be used as sensors to directly characterize the laser beams needed for quantum gate operations. Making use of the four-photon Stark Shift effect in $^{171}$Yb$^+$ ions, we measure the profiles, alignments, and polarizations of the lasers driving counter-propagating Raman transitions. We then show that optimizing the parameters of each laser individually leads to higher-speed Raman-driven gates with smaller susceptibility to errors. Our approach demonstrates the capability of trapped ions to probe their local environments and to provide useful feedback for improving system performance.

quant-ph↗

arXiv2025

Multi-Mode Global Driving of Trapped Ions for Quantum Circuit Synthesis

We study the use of global drives with multiple frequency components to improve the efficiency of trapped ion quantum simulations and computations. We show that such `multi-mode' global drives, when combined with a linear number of single-qubit rotations, generate universal Ising-type interactions with shorter overall runtimes than corresponding two-qubit gate implementations. Further, we show how this framework may be extended to efficiently generate $n-$body interactions between any subset $n$ of the ion qubits. Finally, we apply these techniques to encode the Quantum Fourier Transform using quadratically-fewer entangling operations, with quadratically smaller runtime, compared with traditional approaches.

quant-ph↗

arXiv2024

Quantum circuit and mapping algorithms for wavepacket dynamics: case study of anharmonic hydrogen bonds in protonated and hydroxide water clusters

The accurate computational study of wavepacket nuclear dynamics is considered to be a classically intractable problem, particularly with increasing dimensions. Here we present two algorithms that, in conjunction with other methods developed by us, will form the basis for performing quantum nuclear dynamics in arbitrary dimensions. For one algorithm, we present a direct map between the Born-Oppenheimer Hamiltonian describing the wavepacket time-evolution and the control parameters of a spin-lattice Hamiltonian that describes the dynamics of qubit states in an ion-trap quantum computer. This map is exact for three qubits, and when implemented, the dynamics of the spin states emulate those of the nuclear wavepacket. However, this map becomes approximate as the number of qubits grow. In a second algorithm we present a general quantum circuit decomposition formalism for such problems using a method called the Quantum Shannon Decomposition. This algorithm is more robust and is exact for any number of qubits, at the cost of increased circuit complexity. The resultant circuit is implemented on IBM's quantum simulator (QASM) for 3-7 qubits. In both cases the wavepacket dynamics is found to be in good agreement with the classical result and the corresponding vibrational frequencies obtained from the wavepacket density time-evolution, are in agreement to within a few tenths of a wavenumbers.

quant-ph↗

arXiv2024

Measurement-Induced Heating of Trapped Ions

We experimentally study the heating of trapped atomic ions during measurement of their internal qubit states. During measurement, ions are projected into one of two basis states and discriminated by their state-dependent fluorescence. We observe that ions in the fluorescing state rapidly scatter photons and heat at a rate of \mbox{$\dot{\bar{n}}\gtrsim 2\times 10^4$ quanta/s}, which is orders of magnitude faster than typical anomalous ion heating rates. We introduce a quantum trajectory-based framework that accurately reproduces the experimental results and provides a unified description of ion heating for both continuous and discrete sources.

quant-ph↗

arXiv2024

Quantum nuclear dynamics on a distributed set of ion-trap quantum computing systems

Quantum nuclear dynamics with wavepacket time-evolution is classically intractable and viewed as a promising avenue for quantum information processing. Here, we use an IonQ 11-qubit trapped-ion quantum computer, Harmony, to study the quantum wavepacket dynamics of a shared-proton within a short-strong hydrogen-bonded system. We also provide the first application of distributed quantum computing for chemical dynamics problems, where the distributed set of quantum processes is constructed using a tensor network formalism. For a range of initial states, we experimentally drive the ion-trap system to emulate the quantum nuclear wavepacket as it evolves along the potential surface generated from electronic structure. Following the experimental creation of the nuclear wavepacket, we extract measurement observables such as its time-dependent spatial projection and its characteristic vibrational frequencies to good agreement with classical results. Vibrational eigenenergies obtained from quantum computational are in agreement with those obtained from classical simulations to within a fraction of a kcal/mol, thus suggesting chemical accuracy. Our approach opens a new paradigm for studying the quantum chemical dynamics and vibrational spectra of molecules and also provides the first demonstration for parallel quantum computation on a distributed set of ion-trap quantum computers.

quant-ph↗

arXiv2024

QDoor: Exploiting Approximate Synthesis for Backdoor Attacks in Quantum Neural Networks

Quantum neural networks (QNNs) succeed in object recognition, natural language processing, and financial analysis. To maximize the accuracy of a QNN on a Noisy Intermediate Scale Quantum (NISQ) computer, approximate synthesis modifies the QNN circuit by reducing error-prone 2-qubit quantum gates. The success of QNNs motivates adversaries to attack QNNs via backdoors. However, naïvely transplanting backdoors designed for classical neural networks to QNNs yields only low attack success rate, due to the noises and approximate synthesis on NISQ computers. Prior quantum circuit-based backdoors cannot selectively attack some inputs or work with all types of encoding layers of a QNN circuit. Moreover, it is easy to detect both transplanted and circuit-based backdoors in a QNN. In this paper, we propose a novel and stealthy backdoor attack, QDoor, to achieve high attack success rate in approximately-synthesized QNN circuits by weaponizing unitary differences between uncompiled QNNs and their synthesized counterparts. QDoor trains a QNN behaving normally for all inputs with and without a trigger. However, after approximate synthesis, the QNN circuit always predicts any inputs with a trigger to a predefined class while still acts normally for benign inputs. Compared to prior backdoor attacks, QDoor improves the attack success rate by $13\times$ and the clean data accuracy by $65\%$ on average. Furthermore, prior backdoor detection techniques cannot find QDoor attacks in uncompiled QNN circuits.

quant-ph↗

arXiv2023

Interaction graph engineering in trapped-ion quantum simulators with global drives

Trapped-ion quantum simulators have demonstrated a long history of studying the physics of interacting spin-lattice systems using globally addressed entangling operations. Here, we seek to broaden and delimit the classes of effective spin-spin interactions achievable using exclusively global driving fields. We find that new categories of interaction graphs become achievable with perfect or near-perfect theoretical fidelity by tailoring the coupling to each vibrational mode of the ion crystal, or by shaping the trapping potential to include specific anharmonic terms. We also derive a rigorous test to determine whether a desired interaction graph is accessible using only globally driven fields. These tools broaden the reach of trapped-ion quantum simulators so that they may more easily address open questions in materials science and quantum chemistry.

quant-ph↗

arXiv2023

Quantum Computation of Hydrogen Bond Dynamics and Vibrational Spectra

Calculating the observable properties of chemical systems is often classically intractable and is widely viewed as a promising application of quantum information processing. Yet one of the most common and important chemical systems in nature - the hydrogen bond - has remained a challenge to study using quantum hardware on account of its anharmonic potential energy landscape. Here, we introduce a framework for solving hydrogen-bond systems and more generic chemical dynamics problems using quantum logic. We experimentally demonstrate a proof-of-principle instance of our method using the QSCOUT ion-trap quantum computer, in which we experimentally drive the ion-trap system to emulate the quantum wavepacket of the shared-proton within a hydrogen bond. Following the experimental creation of the shared-proton wavepacket, we then extract measurement observables such as its time-dependent spatial projection and its characteristic vibrational frequencies to spectroscopic accuracy (3.3 cm$^{-1}$ wavenumbers, corresponding to > 99.9% fidelity). Our approach introduces a new paradigm for studying the quantum chemical dynamics and vibrational spectra of molecules, and when combined with existing algorithms for electronic structure, opens the possibility to describe the complete behavior of complex molecular systems with unprecedented accuracy.

quant-ph↗

arXiv2021

Optimized pulsed sideband cooling and enhanced thermometry of trapped ions

Resolved sideband cooling is a standard technique for cooling trapped ions below the Doppler limit to near their motional ground state. Yet, the most common methods for sideband cooling implicitly rely on low Doppler-cooled temperatures and tightly confined ions, and they cannot be optimized for different experimental conditions. Here we introduce a framework which calculates the fastest possible pulsed sideband cooling sequence for a given number of pulses and set of experimental parameters, and we verify its improvement compared to traditional methods using a trapped $^{171}$Yb$^+$ ion. After extensive cooling, we find that the ion motional distribution is distinctly non-thermal and thus not amenable to standard thermometry techniques. We therefore develop and experimentally validate an improved method to measure ion temperatures after sideband cooling. These techniques will enable more efficient cooling and thermometry within trapped-ion systems, especially those with high initial temperatures or spatially-extended ion wavepackets.

physics.atom-ph↗

arXiv2021

Radial two-dimensional ion crystals in a linear Paul trap

We experimentally study two-dimensional (2D) Coulomb crystals in the "radial-2D" phase of a linear Paul trap. This phase is identified by a 2D ion lattice aligned entirely with the radial plane and is created by imposing a large ratio of axial to radial trapping potentials. Using arrays of up to 19 $^{171}$Yb$^+$ ions, we demonstrate that the structural phase boundaries and vibrational mode frequencies of such crystals are well-described by the pseudopotential approximation, despite the time-dependent ion positions driven by intrinsic micromotion. We further observe that micromotion-induced heating of the radial-2D crystal is confined to the radial plane. Finally, we verify that the transverse motional modes, which are used in most ion-trap quantum simulation schemes, remain decoupled and cold in this geometry. Our results establish radial-2D ion crystals as a robust experimental platform for realizing a variety of theoretical proposals in quantum simulation and computation.

quant-ph↗

arXiv2021

An open-endcap blade trap for radial-2D ion crystals

We present the design and experimental demonstration of an open-endcap radio frequency trap to confine ion crystals in the radial-two dimensional (2D) structural phase. The central axis of the trap is kept free of obstructions to allow for site-resolved imaging of ions in the 2D crystal plane, and the confining potentials are provided by four segmented blade electrodes. We discuss the design challenges, fabrication techniques, and voltage requirements for implementing this open-endcap trap. Finally, we validate its operation by confining up to 29 ions in a 2D triangular lattice, oriented such that both in-plane principal axes of the 2D crystal lie in the radial direction.

quant-ph↗

arXiv2021

Mapping quantum chemical dynamics problems onto spin-lattice simulators

The accurate computational determination of chemical, materials, biological, and atmospheric properties has critical impact on a wide range of health and environmental problems, but is deeply limited by the computational scaling of quantum-mechanical methods. The complexity of quantum-chemical studies arises from the steep algebraic scaling of electron correlation methods, and the exponential scaling in studying nuclear dynamics and molecular flexibility. To date, efforts to apply quantum hardware to such quantum chemistry problems have focused primarily on electron correlation. Here, we provide a framework which allows for the solution of quantum chemical nuclear dynamics by mapping these to quantum spin-lattice simulators. Using the example case of a short-strong hydrogen bonded system, we construct the Hamiltonian for the nuclear degrees of freedom on a single Born-Oppenheimer surface and show how it can be transformed to a generalized Ising model Hamiltonian. We then demonstrate a method to determine the local fields and spin-spin couplings needed to identically match the molecular and spin-lattice Hamiltonians. We describe a protocol to determine the on-site and inter-site coupling parameters of this Ising Hamiltonian from the Born-Oppenheimer potential and nuclear kinetic energy operator. Our approach represents a paradigm shift in the methods used to study quantum nuclear dynamics, opening the possibility to solve both electronic structure and nuclear dynamics problems using quantum computing systems.

physics.chem-ph↗

arXiv2021

Susceptibility of Trapped-Ion Qubits to Low-Dose Radiation Sources

We experimentally study the real-time susceptibility of trapped-ion quantum systems to small doses of ionizing radiation. We expose an ion-trap apparatus to a variety of $α$, $β$, and $γ$ sources and measure the resulting changes in trapped-ion qubit lifetimes, coherence times, gate fidelities, and motional heating rates. We found no quantifiable degradation of ion trap performance in the presence of low-dose radiation sources for any of the measurements performed. This finding is encouraging for the long-term prospects of using ion-based quantum information systems in extreme environments, indicating that much larger doses may be required to induce errors in trapped-ion quantum processors.

quant-ph↗

arXiv2021

Floquet Gauge Pumps as Sensors for Spectral Degeneracies Protected by Symmetry or Topology

We introduce the concept of a Floquet gauge pump whereby a dynamically engineered Floquet Hamiltonian is employed to reveal the inherent degeneracy of the ground state in interacting systems. We demonstrate this concept in a one-dimensional XY model with periodically driven couplings and transverse field. In the high-frequency limit, we obtain the Floquet Hamiltonian consisting of the static XY and dynamically generated Dzyaloshinsky-Moriya interaction (DMI) terms. The dynamically generated magnetization current depends on the phases of complex coupling terms, with the XY interaction as the real and DMI as the imaginary part. As these phases are cycled, the current reveals the ground-state degeneracies that distinguish the ordered and disordered phases. We discuss experimental requirements needed to realize the Floquet gauge pump in a synthetic quantum spin system of interacting trapped ions.

cond-mat.quant-gas↗

arXiv2016

String order via Floquet interactions in atomic systems

We study the transverse-field Ising model with interactions that are modulated in time. In a rotating frame, the system is described by a time-independent Hamiltonian with many-body interactions, similar to the cluster Hamiltonians of measurement-based quantum computing. In one dimension, there is a three-body interaction, which leads to string order instead of conventional magnetic order. We show that the string order is robust to power-law interactions that decay with the cube of distance. In two and three dimensions, there are five- and seven-body interactions. We discuss adiabatic preparation of the ground state as well as experimental implementation with trapped ions, Rydberg atoms, and polar molecules.

cond-mat.quant-gas↗