arXiv subjects

Pradeep Kumar

Publications and source records attributed to Pradeep Kumar.

At least 37 records · Page 2Linked to original sources

arXiv2024

GNNBENCH: Fair and Productive Benchmarking for Single-GPU GNN System

We hypothesize that the absence of a standardized benchmark has allowed several fundamental pitfalls in GNN System design and evaluation that the community has overlooked. In this work, we propose GNNBench, a plug-and-play benchmarking platform focused on system innovation. GNNBench presents a new protocol to exchange their captive tensor data, supports custom classes in System APIs, and allows automatic integration of the same system module to many deep learning frameworks, such as PyTorch and TensorFlow. To demonstrate the importance of such a benchmark framework, we integrated several GNN systems. Our results show that integration with GNNBench helped us identify several measurement issues that deserve attention from the community.

cs.LG↗

arXiv2024

Single-GPU GNN Systems: Traps and Pitfalls

The current graph neural network (GNN) systems have established a clear trend of not showing training accuracy results, and directly or indirectly relying on smaller datasets for evaluations majorly. Our in-depth analysis shows that it leads to a chain of pitfalls in the system design and evaluation process, questioning the practicality of many of the proposed system optimizations, and affecting conclusions and lessons learned. We analyze many single-GPU systems and show the fundamental impact of these pitfalls. We further develop hypotheses, recommendations, and evaluation methodologies, and provide future directions. Finally, a new reference system is developed to establish a new line of optimizations rooted in solving the system-design pitfalls efficiently and practically. The proposed design can productively be integrated into prior works, thereby truly advancing the state-of-the-art.

cs.LG↗

arXiv2023

Broken weak and strong spin rotational symmetries and tunable interaction between phonon and the continuum in Cr2Ge2Te6

Phase transitions with lowering temperature is a manifestation of decreased entropy and within the Landau theoretical framework these are accompanied by the symmetry breaking. Whenever a symmetry is broken weakly or strongly, it leaves its trail and the same may be captured indirectly using renormalization of the quasi-particle excitations. Cr2Ge2Te6, a quasi-two-dimensional magnetic material, provides a rich playground to probe dynamics of the quasi-particle excitations as well as multiple phase transitions with lowering temperature intimately linked with the lattice and spin degrees of freedom. Here, we report in-depth inelastic light scattering measurements on single crystals of Cr2Ge2Te6 as a function of temperature, from 6 K to 330 K, and polarization. Our measurements reveal the long as well as short range ordering of the spins below Tc (~ 60 K) and T* (~ 180 K), respectively; setting the stage for broken rotational and time reversal symmetry, gauged via the distinct renormalization of the phonon self-energy parameters along with the modes intensity. Our measurements also uncovered an intriguing dependence of the interaction strength between discrete state (phonon here) and the underlying continuum, quantified using the Fano asymmetry parameter, as a function of the scattered light polarization. Our results suggest the possibility of tuning the interaction strength using controlled scattered light and symmetry in this 2D magnet.

cond-mat.str-el↗

arXiv2023

Interplay of topology and antiferromagnetic order in two-dimensional van der Waals crystals of (NixFe1-x)2P2S6

Mermin-Wagner theorem forbid spontaneous symmetry breaking of spins in one/two-dimensional systems at finite temperature and rules out the stabilization of this ordered state. However, it does not apply to all types of phase transitions in low dimensions such as topologically ordered phase rigorously shown by Berezinskii-Kosterlitz-Thouless (BKT) and experimentally realized in very limited systems such as superfluids, superconducting thin films. Quasi 2D van der Waals magnets provide an ideal platform to investigate the fundamentals of low-dimensional magnetism. We explored the 2D honeycomb antiferromagnetic single crystals of (NixFe1-x)2P2S6 with varying spins ( ) using in depth temperature dependent Raman measurements supported by first-principles calculations of the phonon frequencies. As a function of doping, a tunable transition from paramagnetic to antiferromagnetic ordering is shown via phonons reflected in the strong renormalization of the self-energy parameters of the Raman active phonon modes. An anomalously broad magnetic continuum attributed to two-magnon excitations is observed and its coupling with the phonons is revealed in the observation a Fano line asymmetry. Interestingly, the two-magnon continuum is observed only for the finite doping understood invoking underlying nature of insulator these materials belongs to, i.e. exchange interaction between transition metals via surrounding ligands (sulphur) and the resonance involving phonon modes associated with the (P2S6) cage. Quite surprisingly, we also observed renormalization of the phonon modes much below the long-range magnetic ordered temperature attributed to the topological ordered state, namely the BKT phase, which is also found to change as a function of doping. The extracted critical exponent of the order-parameter evince the signature of topologically active state driven by vortex-antivortex excitations.

cond-mat.mtrl-sci↗

arXiv2023

Exciton-exciton Interactions -- A Quantitative Comparison Between Complimentary Phenomenological Models

Many-body interactions (MBIs) such as exciton-exciton interactions significantly affect the optical response of semiconductor nanostructures. These interactions can be rigorously modeled through microscopic calculations. However, these calculations can be computationally intensive and often lack physical insights. An alternative is to use phenomenological many-body interaction models such as the modified optical Bloch equations (MOBEs) and the anharmonic oscillator (AO) model. While both these models have separately been used to interpret experimental data, to the best of our knowledge, an explicit and direct correspondence between these models has not been established. Here, we show the empirical equivalence between these two complimentary MBI models through two-dimensional coherent spectroscopy simulations. A quantitative correspondence between the MBI parameters used in the two models are obtained. We also perform a quantitative comparison of these MBI models with experiments, which highlights the usefulness of these phenomenological models in interpreting experimental results.

cond-mat.mes-hall↗

arXiv2023

Charging capacitors from thermal fluctuations using diodes

We theoretically consider a graphene ripple as a Brownian particle coupled to an energy storage circuit. When circuit and particle are at the same temperature, the second law forbids harvesting energy from the thermal motion of the Brownian particle, even if the circuit contains a rectifying diode. However, when the circuit contains a junction followed by two diodes wired in opposition, the approach to equilibrium may become ultraslow. Detailed balance is temporarily broken as current flows between the two diodes and charges storage capacitors. The energy harvested by each capacitor comes from the thermal bath of the diodes while the system obeys the first and second laws of thermodynamics.

cond-mat.mes-hall↗

arXiv2023

Weakly supervised information extraction from inscrutable handwritten document images

State-of-the-art information extraction methods are limited by OCR errors. They work well for printed text in form-like documents, but unstructured, handwritten documents still remain a challenge. Adapting existing models to domain-specific training data is quite expensive, because of two factors, 1) limited availability of the domain-specific documents (such as handwritten prescriptions, lab notes, etc.), and 2) annotations become even more challenging as one needs domain-specific knowledge to decode inscrutable handwritten document images. In this work, we focus on the complex problem of extracting medicine names from handwritten prescriptions using only weakly labeled data. The data consists of images along with the list of medicine names in it, but not their location in the image. We solve the problem by first identifying the regions of interest, i.e., medicine lines from just weak labels and then injecting a domain-specific medicine language model learned using only synthetically generated data. Compared to off-the-shelf state-of-the-art methods, our approach performs >2.5x better in medicine names extraction from prescriptions.

cs.CV↗

arXiv2023

Load Balanced Demand Distribution under Overload Penalties

Input to the Load Balanced Demand Distribution (LBDD) consists of the following: (a) a set of public service centers (e.g., schools); (b) a set of demand (people) units and; (c) a cost matrix containing the cost of assignment for all demand unit-service center pairs. In addition, each service center is also associated with a notion of capacity and a penalty which is incurred if it gets overloaded. Given the input, the LBDD problem determines a mapping from the set of demand units to the set of service centers. The objective is to determine a mapping that minimizes the sum of the following two terms: (i) the total assignment cost between demand units and their allotted service centers and, (ii) total of penalties incurred. The problem of LBDD finds its application in the domain of urban planning. An instance of the LBDD problem can be reduced to an instance of the min-cost bi-partite matching problem. However, this approach cannot scale up to the real world large problem instances. The current state of the art related to LBDD makes simplifying assumptions such as infinite capacity or total capacity being equal to the total demand. This paper proposes a novel allotment subspace re-adjustment based approach (ASRAL) for the LBDD problem. We analyze ASRAL theoretically and present its asymptotic time complexity. We also evaluate ASRAL experimentally on large problem instances and compare with alternative approaches. Our results indicate that ASRAL is able to scale-up while maintaining significantly better solution quality over the alternative approaches. In addition, we also extend ASRAL to para-ASRAL which uses the GPU and CPU cores to speed-up the execution while maintaining the same solution quality as ASRAL.

cs.DS↗

arXiv2023

Tunable Resonance and Electron-Phonon Coupling in Layered MoS2

Resonance Raman scattering, a very effective and sensitive technique for atomically thin semiconducting transition metal dichalcogenide, can be used to observe the phonons from the entire Brillouin zone. In addition to the significance of resonance effect on the Raman spectrum it may also be used to probe the electron-phonon coupling. Our study is devoted to understand the phonons in layered MoS2, especially for very low frequency range (i.e. below 100 cm-1), as a function of temperature under the resonance effect. Understanding the phonon-phonon and electron-phonon coupling and the effects of temperature on the Raman spectrum are the central points of the present study. We observe the anomalous softening and broadening of a very low frequency phonon mode P3 (~34 cm-1) at low temperature ( i.e below 150 K). We attributed the observed anomalous trend in frequency and linewidth of this low frequency phonon to the electron-phonon coupling. Furthermore, our work also highlights the temperature induced tuning of resonance condition via understanding the intensity of phonon modes as a function of temperature.

cond-mat.mtrl-sci↗

arXiv2023

Estimation of thermal load on the nozzle base plate from small plumes at high temperature

A numerical study is performed to estimate thermal load on the nozzle base plate, which is in the upstream direction to the flow, from three hot plumes of pure (CO2), (H2O) and 50-50 (%) composition of (CO2) and (H2O) expanding through a convergent-divergent (CD) nozzle in a quiescent medium at 1.1 bar pressure and 298K temperature. The base plate of the nozzle heats up due to thermal radiation, emitting from the hot gases in the form of plumes. The spectral radiative properties of major participating gases such as (CO2), (H2O) are calculated from HITEMP-2010 database. A small CD nozzle which is designed for the perfect expansion of air by 1D calculation with nozzle throat diameter 1.98 mm and area ratio 1.5942, is considered as the design of nozzle for present study [1]. All three plumes are in the under-expanded state for this CD nozzle and hence expands rapidly at supersonic speed as the plumes exit from the nozzle and forms a series of expansion and compression waves. The hot plumes emanating from the nozzle develop very high temperature in a small vicinity around the base plate, due to diffusion and develop very high temperature on the base plate. Barring this region, the maximum amount of radiative flux on base plate for these three plumes, i.e., CO2 plume, mixture plume and H2O plume are 4000 W/m2, 2300 W/m2 and 1300 W/m2, respectively and the maximum temperature developed due to these corresponding fluxes are 323 K, 312 K and 308 K, respectively.

physics.comp-ph↗

arXiv2022

Fluctuating Fractionalized Spins in Quasi Two-dimensional Magnetic V0.85PS3

Quantum spin liquid (QSL), a state characterized by exotic low energy fractionalized excitations and statistics is still elusive experimentally and may be gauged via indirect experimental signatures. Remnant of QSL phase may reflect in the spin dynamics as well as quanta of lattice vibrations, i.e., phonons, via the strong coupling of phonons with the underlying fractionalized excitations i.e., Majorana fermions. Inelastic light scattering (Raman) studies on V1-xPS3 single crystals evidences the spin fractionalization into Majorana fermions deep into the paramagnetic phase reflected in the emergence of a low frequency quasielastic response along with a broad magnetic continuum marked by a crossover temperature T* ~ 200 K from a pure paramagnetic state to fractionalized spins regime qualitatively gauged via dynamic Raman susceptibility. We further evidenced anomalies in the phonons self-energy parameters in particular phonon line broadening and line asymmetry evolution at this crossover temperature, attributed to the decaying of phonons into itinerant Majorana fermions. This anomalous scattering response is thus indicative of fluctuating fractionalized spins suggesting a phase proximate to the quantum spin liquid state in this quasi two-dimensional (2D) magnetic system.

cond-mat.str-el↗

arXiv2022

Radiative Heat Transfer Calculations using Full Spectrum k-Distribution Method for Benchmark Test Cases

In the present work, the full spectrum $k$-distribution method (FSK) has been adopted to calculate the radiative heat transfer in the presence of participating gaseous medium within an enclosure. The spectral radiative properties of the gaseous medium is obtained from the HITEMP-2010 database. Further, radiative properties have been assembled into a monotonically increasing function using the full spectrum $k$-distribution method. Moreover, a look-up table has been developed for these properties for different thermodynamic states of gases and a multi-dimensional linear interpolation technique for unavailable thermodynamic states of gases. Furthermore, the FSK method is extended for mixture of gases using different mixing models such as superposition, multiplication and hybrid mixing model. The multiplication mixing model produces most accurate results among the mixture models used here. The results obtained from FSK has been validated against line by line method (LBL). The radiation transfer equation (RTE) is solved by finite volume method to calculate the wall heat fluxes and the divergence of radiative heat flux for various test cases in different category of homogeneous isothermal and isobaric and non-homogeneous non-isothermal non-isobaric media having different conditions of temperature pressure and mole-fraction. The FSK method has been successfully applied to non-homogeneous non-isothermal non-isobaric gaseous media for single gas or mixture of gases with almost LBL accuracy at extremely less computational cost and resource.

physics.comp-ph↗

arXiv2022

Flow Characterization in Triply-Periodic-Minimal-Surface (TPMS) based Porous Geometries: Part 1 -- Hydrodynamics

The modeling of flow and heat transfer in porous media systems have always been a challenge and, the extended Darcy transport models for flow and equilibrium and non-equilibrium energy models for heat transfer are being used for macro-level analysis, however, the limitations of these models are subjected to porous geometry. The forced convective flow of an incompressible viscous fluid through a channel filled with four different types of porous geometries constructed using the Triply-Periodic-Minimal-Surface (or TPMS) model, are presented in this study. Four TPMS lattice shapes namely; Diamond, I-WP, Primitive, and Gyroid are created with identical porosity, and three different types of porous media are further generated for each porous geometry to investigate the relationship of shape-tortuosity, microporosity, and pore size on permeability and inertial drag factors. A pore-scale direct numerical simulation approach is performed for the first two types of porous media by solving the Navier-Stokes equations. The specific microporosity is quantitatively induced in the solid region where Darcy-Forchheimer-Brinkman model is solved, whereas the Navier-Stokes equations is solved for the fluid region in the third type of porous media. The results reveal that the validity of Darcy flow regime is very narrow up to Re ~ 4 for the Primitive lattice (Type 1) while for Diamond lattice (Type 2), it extends up to Re ~ 20. For Re > 20, Darcy regime is not valid for any lattice types. For lower porosity (Type 1, ε = 0.32) the inertial drag is found to be minimum in I-WP lattice and maximum in Gyroid lattice while, for higher porosity ( Type 2, ε ~ 1), Primitive lattice has minimum and I-WP lattice has maximum value of inertial drag, respectively.

physics.flu-dyn↗

arXiv2022

Pressure and temperature dependence of fluorescence anisotropy of Green Fluorescent Protein

We have studied the effect of high hydrostatic pressure and temperature on the steady state fluorescence anisotropy of Green Fluorescent Protein (GFP). We find that the fluorescence anisotropy of GFP at a constant temperature decreases with increasing pressure. At atmospheric pressure, anisotropy decreases with increasing temperature but exhibits a maximum with temperature for pressure larger than 20 MPa. The temperature corresponding to the maximum of anisotropy increases with increasing pressure. By taking into account of the rotational correlation time changes of GFP with the pressure-temperature dependent viscosity of the solvent, we argue that viscosity increase with pressure is not a major contributing factor to the decrease in anisotropy with pressure. Our results suggest that the decrease of fluorescence anisotropy with pressure may result from changes in H-bonding environment around the chromophore.

q-bio.BM↗

arXiv2021

Unravelling the coupling between excitonic quasiparticles-electron-phonon and role of interlayer coupling in vertically and horizontally aligned layered MoS2

Excitonic quasi-particles, excitons/trions/bi-excitons, and their coupling with phonons and charge carriers play a crucial role in controlling the optical properties of atomically thin semiconducting 2D materials. In this work, we unravelled the dynamics of excitons/trions and their coupling with phonons and charge carriers in a few layers vertically and horizontally aligned MoS2. We observed trion signature up to the highest recorded temperature (330 K) in both systems and have shown that the dynamics of excitons/trions and their coupling with phonons and electrons are more affected in vertically aligned MoS2. A homogeneous linewidth broadening is observed with an increase in temperature. The linewidth broadening is attributed mainly to acoustic phonons in a low-temperature regime (<100 K). In contrast, acoustic and longitudinal optical phonons contributions to the linewidth broadening are observed at high temperature. We also observed the significant effects of interlayer coupling in both systems via understanding the temperature-dependent valence band splitting and trion binding energy. A decrease of 22 and 12% in valence band splitting with temperature rise is observed for the vertically and horizontally aligned MoS2, respectively, suggesting that the valence band splitting is affected more in the case of vertically than horizontally aligned. Furthermore, we also notice a significant thermal quenching in the intensity of the trion band than that of exciton bands, attributed to the small binding energy of the trion.

cond-mat.mtrl-sci↗

arXiv2021

Electron-Phonon Coupling, Thermal Expansion Coefficient, Resonance Effect and Phonon Dynamics in High Quality CVD Grown Mono and Bilayer MoSe2

Probing phonons, quasi-particle excitations and their coupling has enriched our understanding of these 2D materials and proved to be crucial for developing their potential applications. Here, we report comprehensive temperature, 4-330 K, and polarization-dependent Raman measurements on mono and bilayer MoSe2. Phonon's modes up to fourth-order are observed including forbidden Raman and IR modes, understood considering Frohlich mechanism of exciton-phonon coupling. Most notably, anomalous variations in the phonon linewidths with temperature pointed at the significant role of electron-phonon coupling in these systems, especially for the out-of-plane (A1g) and shear mode (E22g), which is found to be more prominent in the narrow-gaped bilayer than the large gapped monolayer. Via polarization-dependent measurements, we deciphered the ambiguity in symmetry assignments, especially to the peaks around ~ 170 cm-1 and ~ 350 cm-1. Temperature-dependent thermal expansion coefficient, an important parameter for the device performance, is carefully extracted for both mono and bilayer by monitoring the temperature-dependence of the real-part of the phonon self-energy parameter. Our temperature-dependent in-depth Raman studies provide a pave for uncovering the deeper role of phonons in these 2D layered materials from a fundamental as well as application point of view.

cond-mat.mtrl-sci↗

arXiv2021

Fractional Spin fluctuations and quantum liquid signature in Gd2ZnIrO6

Hitherto, the discrete identification of quantum spin liquid phase, holy grail of condensed matter physics, remains a challenging task experimentally. However, the precursor of quantum spin liquid state may reflect in the spin dynamics even in the paramagnetic phase over a wide temperature range as conjectured theoretically. Here we report comprehensive inelastic light (Raman) scattering measurements on the Ir based double perovskite, Gd2ZnIrO6, as a function of different incident photon energies and polarization in a broad temperature range. Our results evidenced the spin fractionalization within the paramagnetic phase reflected in the emergence of a polarization independent quasi-elastic peak at low energies with lowering temperature. Also, the fluctuating scattering amplitude measured via dynamic Raman susceptibility increases with lowering temperature and decreases mildly upon entering into long-range magnetic ordering phase, below 23 K, suggesting the magnetic origin of these fluctuations. This anomalous scattering response is thus indicative of fluctuating fractional spin evincing the quantum spin liquid phase in a three-dimensional double perovskite system.

cond-mat.str-el↗

arXiv2020

Effects of Semitransparent Window AspectRatio on Interaction of Collimated Beam withNatural Convection: Part I

The effects of the semitransparent winodw's aspect ratio on the interaction of the collimated beam with natural convection have been investigated numerically in the present work. The combination of geometrical parameters of the semitransparent window, i.e., height ratio ($h_r$) and window width ratio ($w_r$) and Planck numbers of the medium have been considered. The other parameters, like flow parameter (Ra$=10^5$), fluid parameter (Pr=0.71), thermal parameter (N), Irradiation (G=1000 $W/m^2$), Angle of incidence ($ϕ=135^0$) and geometrical parameter of the geometry ($A_r$=1) and the wall conditions have been kept constant. A collimated beam is irradiated with irradiation value (G=1000 $W/m^2$) on the semitransparent window at an azimuthal angle ($ϕ) 135^0$. The cavity is convectively heated from the bottom with heat transfer coefficient 50 $W/m^2 K$ and free stream temperature 305 $K$. A semitransparent window is created on the left wall and isothermal conditions (T=296 $K$) is applied on the semitransparent, left and right vertical walls, wherein adiabatic conditions are applied on upper wall of the cavity. The dynamics of two vortices inside the cavity change considerably by combinations these semitransparent window's aspect ratio and Planck number (Pl) of the medium. The left vortex breaks into two parts and remains confined in upper and lower left corners for some combination of aspect ratios and Planck numbers of the medium. The thermal plume flickers depending on the situation of dynamics of two vortices inside the cavity. The localized hating of the fluid happens mostly for large height ratio of semitransparent window. The conduction; radiation and total Nusselt number are also greatly affected by the semitransparent window's aspect ratio and the Planck number of the medium.

physics.flu-dyn↗