arXiv subjects

Pradeep Kumar

Publications and source records attributed to Pradeep Kumar.

At least 55 records · Page 3Linked to original sources

arXiv2020

Davydov Splitting, Resonance Effect and Phonon Dynamics in CVD grown Layered MoS2

We present a comprehensive temperature dependent Raman measurements for horizontally aligned CVD grown layered MoS2 in a temperature range of 4 to 330 K under resonance condition. Our analysis of temperature dependent phonon frequency shift and linewidth suggest a finite role of three and four phonon anharmonic effect. We observed Davydov splitting of the out-of-plane (A1g ) and in-plane (E12g ) modes, attributed to the weak interlayer interaction, and reflected in the appearance of additional modes with decreasing temperature for both 3 layers and few layers system. We also observed that the number of Davydov splitting components are more in few layers as compared to 3L MoS2, suggesting it increases with increasing number of layers. Temperature evaluation of the Raman spectra shows that the Davydov splitting, especially for A1g mode, is very strong and well resolved at low temperature. We note that A1g mode shows splitting at low temperature, while E12g mode is splitted even at room temperature, and that suggests to prominent role of A1g mode to the interlayer interaction. Further, the temperature dependence tuning of resonance effect is observed, via almost sixty fold increase in the intensity of the phonon modes at low temperature.

cond-mat.mtrl-sci↗

arXiv2020

Investigations of Non-Gray/Gray Radiative Heat Transfer Effect on Natural Convection in Tall Cavities at Low Operating Temperature

The present work numerically investigates the influence of radiation on the natural convection in differentially heated slender and square-base tall cavities at low operating temperature range of 288.1-307.7 K. The atmospheric air which has the composition of $N_2$, $O_2$, $CO_2$ and $H_2O$ in the molar mass proportion of 75.964%, 21%, 0.036% and 3%, respectively, has been considered as the working fluid in the cavities. The non-gray and gray Planck mean absorption coefficients for whole spectrum of the air at the atmospheric pressure and average temperature of the cavity have been calculated from HITEMP-2010 database by Line-By-Line (LBL) approach. The flow and heat transfer simulations for combined radiation and natural convection have been performed for four different scenarios, i.e., pure convection, radiation in transparent, gray, and non-gray radiation medium. First, the numerical results are compared with the experimental results of Betts and Bukhari [1] for the slender cavity case, subsequently a comprehensive analysis of the fluid flow and heat transfer are presented to demonstrate the influence of the radiation on natural convection inside both the cavities. The flow structure has been visualized by Q-criterion - a vortex identification technique. The results reveal that the fluid flow and thermal characteristics change significantly at the top and the bottom of both the cavities with the inclusion of radiation. Moreover, the radiation in gray medium has significant effect on these characteristics. The fluid flow and heat transfer are only happening in a narrow regions near to the active walls. The radiative flux is in the same order of the conductive flux in these cavities and these fluxes are almost same in all four scenarios of the radiation modeling.

physics.flu-dyn↗

arXiv2020

Investigation of Thermal Adiabatic Boundary Condition on Semitransparent Wall in Combined Radiation and Natural Convection

Two thermal adiabatic boundary conditions arise on the semitransparent window owing to the fact that whether semitransparent window allows the energy to leave the system by radiation mode of heat transfer. It is assumed that being low conductivity of semitransparent material, energy does not leave by conduction mode of heat transfer. This does mean that the semitransparent window may behave as only conductively adiabatic (qc = 0) or combinedly conductively and radiatively adiabatic (qc + qr = 0). In the present work, the above two thermal adiabatic boundary conditions have been investigated in natural convection problem for the Rayleigh number (Ra) 10^5 and Prandtl number(Pr) 0.71 in a cavity, whose left vertical wall has been divided into upper and lower parts in the ratio of 4:6. The upper section is semitransparent window, while lower section is isothermal wall at a temperature of 296K. A collimated beam is irradiated with different value (0, 100, 500 and 1000 W/m2) on the semitransparent window at an angle of 45^0 . The cavity is heated from the bottom by convective heating with free stream temperature of 305K and heat transfer coefficient of 50 W/m2K while right wall is also isothermal at same temperature as of lower left wall and upper wall is adiabatic. All walls are opaque for radiation except semitransparent window. The results reveal that the dynamics of both the vortices inside the cavity change drastically with irradiation value and also with the boundary conditions on the semitransparent window. The temperature and Nusselt number increase inside the cavity multifold for combinedly conductively and radiatively adiabatic condition than the only conductively adiabatic condition on the semitransparent window.

physics.flu-dyn↗

arXiv2020

Effects of Diffuse and Collimated Beam Radiation on a Symmetrical Cooling Case of Natural Convection

In the present work, the effects of diffuse and collimated radiation on the symmetrical cooling case of natural convection in a two-dimensional cavity heated from the bottom have been investigated, numerically. The cavity is convectively heated from the bottom with heat transfer coefficient of 50 W/m2K and free stream temperature 305 K, while both vertical walls of cavity are isothermal at temperature of 296 K. The top wall is adiabatic and all walls are opaque for radiation heat transfer. For collimated case, a small semitransparent window of non-dimensional width of 0.05 at height of 0.7 has been created on the left wall and a collimated irradiation of value 1000 W/m2 at an angle 45 is applied on this semitransparent window. The results reveal that the diffuse radiation has little effect on the dynamics of two rolls inside the cavity, however, collimated beam irradiation changes the dynamics of two rolls significantly and also the heat transfer characteristics. This further changes with the optical thickness of the fluid. The left vortex is bigger in size than the right vortex for collimated beam in transparent fluid, whereas, reverse trend is seen for collimated beam in non-zero optical thickness of the fluid.

physics.flu-dyn↗

arXiv2020

Coupling of lattice, spin and intra-configurational excitations of Eu3+ in Eu2ZnIrO6

In Eu2ZnIrO6, effectively two atoms are active i.e. Ir is magnetically active, which results in complex magnetic ordering within the Ir sublattice at low temperature. On the other hand, although Eu is a van-vleck paramagnet, it is active in the electronic channels involving 4f 6 crystal-field split levels. Phonons, quanta of lattice vibration, involving vibration of atoms in the unit cell, are intimately coupled with both magnetic and electronic degrees of freedom (DoF). Here, we report a comprehensive study focusing on the phonons as well as intra-configurational excitations in double-perovskite Eu2ZnIrO6. Our studies reveal strong coupling of phonons with the underlying magnetic DoF reflected in the renormalization of the phonon self-energy parameters well above the spin-solid phase (TN ~ 12 K) till temperature as high as ~ 3TN, evidences broken spin rotational symmetry deep into the paramagnetic phase. In particular, all the observed first-order phonon modes show softening of varying degree below ~3TN, and low-frequency phonons become sharper, while the high-frequency phonons show broadening attributed to the additional available magnetic damping channels. We also observed a large number of high-energy modes, 39 in total, attributed to the electronic transitions between 4f-levels of the rare-earth Eu3+ ion and these modes shows anomalous temperature evolution as well as mixing of the crystal-field split levels attributed to the strong coupling of electronic and lattice DoF.

cond-mat.str-el↗

arXiv2020

Topology of atomically thin soft ferroelectric membranes at finite temperature

One account of two-dimensional (2D) structural transformations in 2D ferroelectrics predicts an evolution from a structure with Pnm2$_1$ symmetry into a structure with square P4/nmm symmetry and is consistent with experimental evidence, while another argues for a transformation into a structure with rectangular Pnmm symmetry. An analysis of the assumptions made in these models is provided here, and six fundamental results concerning these transformations are contributed as follows: (i) Softened phonon modes produce rotational modes in these materials. (ii) The transformation to a structure with P4/nmm symmetry occurs at the lowest critical temperature $T_c$. (iii) The hypothesis that one unidirectional optical vibrational mode underpins the 2D transformation is unwarranted. (iv) Being successively more constrained, a succession of critical temperatures ($T_c<T_c'<T_c''$) occurs in going from molecular dynamics calculations with the NPT and NVT ensembles onto the model with unidirectional oscillations. (v) The choice of exchange-correlation functional impacts the estimate of the critical temperature. (vi) Crucially, the correct physical picture of these transformations is one in which rotational modes confer a topological character to the 2D transformation via the proliferation of vortices.

cond-mat.soft↗

arXiv2020

Kramer doublets, phonons, crystal-field excitations and their coupling in Nd2ZnIrO6

We report comprehensive Raman-scattering measurements on a single crystal of double-perovskite Nd2ZnIrO6 in temperature range of 4-330 K, and spanning a broad spectral range from 20 cm-1 to 5500 cm-1. The paper focuses on lattice vibrations and electronic transitions involving Kramers doublets of the rare-earth Nd3+ ion with local C1 site symmetry. Temperature evolution of these quasi-particle excitations have allowed us to ascertain the intricate coupling between lattice and electronic degrees of freedom in Nd2ZnIrO6. Strong coupling between phonons and crystal-field excitation is observed via renormalization of the self-energy parameter of the phonons i.e. peak frequency and line-width. The phonon frequency shows abrupt hardening and line-width narrowing below ~ 100 K for the majority of the observed first-order phonons. We observed splitting of the lowest Kramers doublets of ground state (4I9/2) multiplets i.e. lifting of the Kramers degeneracy, prominently at low-temperature (below ~ 100 K), attributed to the Nd-Nd/Ir exchange interactions and the intricate coupling with the lattice degrees of freedom. The observed splitting is of the order of ~ 2-3 meV and is consistent with the estimated value. We also observed a large number of high-energy modes, 46 in total, attributed to the intra-configurational transitions between 4f3 levels of Nd3+ coupled to the phonons reflected in their anomalous temperature evolution.

cond-mat.str-el↗

arXiv2020

Pressure and temperature dependence of solubility and surface adsorption of nitrogen in the liquid hydrocarbon bodies on Titan

We have studied the pressure and temperature dependence of solubility of nitrogen in methane and ethane using vapor-liquid equilibrium simulations of binary mixtures of nitrogen in methane and ethane for a range of pressures between 1.5 atm and 3.5 atm and temperatures between 90 K and 110 K, thermodynamic conditions that may exist on the Saturn's moon, Titan. We find that the solubility of nitrogen in methane increases linearly with pressure while the solubility of nitrogen in ethane increases exponentially with pressure at temperature 90 K. Solubility of nitrogen in both methane and ethane exhibits an exponential decrease with temperature at a pressure of 3 atm. The solubility of nitrogen in methane is much larger compared to that in ethane in the range of pressure and temperature studied here. Our results are in quantitative agreement with the available experimental measurements of the solubility of nitrogen in methane and ethane. Furthermore, we find that the surface adsorption of nitrogen increases with increasing pressure at temperature 90 K, while the adsorption free energy increases with increasing pressure. Moreover, we find that the surface tension decreases linearly with pressure for both nitrogen-methane and nitrogen-ethane systems. The rate of decrease of surface tension with pressure for nitrogen-ethane system is much larger as compared to the nitrogen-methane system. Finally, we find that the absorption of a nitrogen molecule into the liquid-phase from the interface is diffusive and does not involve any appreciable energy barrier. Our results suggest that homogeneous nucleation of bubbles is unlikely on Titan and the bubble formation in the lakes on Titan must arise from heterogeneous nucleation of bubbles.

cond-mat.soft↗

arXiv2020

Anomalous Phonon Renormalization in Single Crystal of Silicon

The temperature dependence of the first-order phonon mode of single crystal of Silicon (Si) is determined by Raman scattering in a broad temperature range of 4-623 K. Our studies reveal the anomalous red-shift of the Raman active phonon mode at temperature (~ 50 K) attributed to the anomalous expansion of Si in the low temperature region. Silicon shows negative thermal expansion below 120 K, however, odd behaviour is also observed at very low temperatures i.e., softening of the Si crystal is detected below 40 K. This peculiar behaviour of Si is described by the anomalous phonon anharmonicity observed at low temperature.

cond-mat.mtrl-sci↗

arXiv2020

Anisotropic Electron-Photon-Phonon Coupling in Layered MoS2

Transition metal dichalcogenide, especially MoS2 has attracted lot of attention recently owing to its tunable visible range band gap and anisotropic electronic and transport properties. Here, we report a comprehensive inelastic light scattering measurements on CVD grown (horizontally and vertically aligned flakes) as well as single crystal flakes of MoS2, probing the anisotropic optical response via studying the polarization dependence intensity of the Raman active phonon modes as a function of different incident photon energy and flake thickness. Our polarization dependent Raman studies intriguingly revealed strong anisotropic behavior reflected in the anomalous renormalization of the modes intensity as a function of flake thickness, phonons and photon energy. Our observations reflects the strong anisotropic light-matter interaction in this high crystalline symmetric layered MoS2 system especially for the in-plane vibrations, which is crucial for understanding as well application of these materials for future application such as optoelectronic applications.

cond-mat.mtrl-sci↗

arXiv2019

Kitaev Magnetism and Fractionalized Excitations in Double Perovskite Sm2ZnIrO6

The quest for Kitaev spin liquids in particular three dimensional solids is long sought goal in condensed matter physics, as these states may give rise to exotic new types of quasi-particle excitations carrying fractional quantum numbers namely Majorana Fermionic excitations. Here we report the experimental signature of this characteristic feature of the Kitaev spin liquid via Raman measurements. Sm2ZnIrO6 is a strongly spin orbit coupled Mott insulator, where Jeff = 1/2 controls the physics, which provide striking evidence for this characteristic feature of the Kitaev spin liquid. As the temperature is lowered, we find that the spin excitations form a continuum in contrast to the conventional sharp modes expected in ordered antiferromagnets. Our observation of a broad magnetic continuum and anomalous renormalization of the phonon self-energy parameters evidence the existence of Majorana fermions from spin fractionalization in double perovskites structure as theoretically conjectured in a Kitaev-Heisenberg geometrically frustrated double perovskite systems.

cond-mat.str-el↗

arXiv2019

Solubility of nitrogen in methane, ethane, and mixtures of methane and ethane at Titan-like conditions: A molecular dynamics study

We have studied the temperature dependence of the solubility of nitrogen in methane, ethane, and mixtures of methane and ethane using vapor-liquid equilibrium simulations of binary and ternary mixtures of nitrogen, methane and ethane for a range of temperatures between 90K and 110K at a pressure of 1.5 atm, thermodynamic conditions that may exist on the Saturn's giant moon, Titan. We find that --(i) the solubility of nitrogen in both methane and ethane decreases with increasing temperature; (ii) the solubility of nitrogen in methane is much larger compared to that in ethane at low temperatures, (iii) solubility of nitrogen in a ternary mixture of methane, ethane, and nitrogen increases upon increasing mole-fraction of methane. Our results are in quantitative agreement with the recent experimental measurement of the solubility of nitrogen in methane, ethane, and a mixture of methane and ethane. Furthermore, we find a strong temperature-dependent surface adsorption of nitrogen at the nitrogen-hydrocarbon interface, previously unknown. We have also investigated surface tension of the gas-liquid interface and find that it decreases upon decreasing temperature. Moreover, we find that the interfacial layer of adsorbed nitrogen and ethane show a preferential orientational ordering at the interface.

physics.chem-ph↗

arXiv2019

A model field theory with $(ψ\ln ψ)^2$ potential: Kinks with super-exponential profiles

We study a (1+1)-dimensional field theory based on $(ψ\ln ψ)^2$ potential. There are three degenerate minima at $ψ= 0$ and $ψ=\pm1$. There are novel, asymmetric kink solutions of the form $ψ= \mp\exp (-\exp(\pm x))$ connecting the minima at $ψ= 0$ and $ψ= \mp 1$. The domains with $ψ= 0$ repel the linear excitations, the waves (e.g. phonons). Topology restricts the domain sequences and therefore the ordering of the domain walls. Collisions between domain walls are rich for properties such as transmission of kinks and particle conversion, etc. To our knowledge this is the first example of kinks with super-exponential profiles and super-exponential tails. Finally, we provide a comparison of these results with the $ϕ^6$ model and its half-kink solution.

nlin.PS↗

arXiv2019

Deep Learning to Address Candidate Generation and Cold Start Challenges in Recommender Systems: A Research Survey

Among the machine learning applications to business, recommender systems would take one of the top places when it comes to success and adoption. They help the user in accelerating the process of search while helping businesses maximize sales. Post phenomenal success in computer vision and speech recognition, deep learning methods are beginning to get applied to recommender systems. Current survey papers on deep learning in recommender systems provide a historical overview and taxonomy of recommender systems based on type. Our paper addresses the gaps of providing a taxonomy of deep learning approaches to address recommender systems problems in the areas of cold start and candidate generation in recommender systems. We outline different challenges in recommender systems into those related to the recommendations themselves (include relevance, speed, accuracy and scalability), those related to the nature of the data (cold start problem, imbalance and sparsity) and candidate generation. We then provide a taxonomy of deep learning techniques to address these challenges. Deep learning techniques are mapped to the different challenges in recommender systems providing an overview of how deep learning techniques can be used to address them. We contribute a taxonomy of deep learning techniques to address the cold start and candidate generation problems in recommender systems. Cold Start is addressed through additional features (for audio, images, text) and by learning hidden user and item representations. Candidate generation has been addressed by separate networks, RNNs, autoencoders and hybrid methods. We also summarize the advantages and limitations of these techniques while outlining areas for future research.

cs.IR↗

arXiv2019

Correlated Paramagnetism and Interplay of Magnetic and Phononic Degrees of Freedom in 3d-5d Coupled La2CuIrO6

Conventional Paramagnetism - a state with finite magnetic moment per ion sans long range magnetic ordering, but with lowering temperature the moment on each ion picks up a particular direction, breaking rotational symmetry, and results into long range magnetic ordering. However, in systems with competing multiple degrees of freedom this conventional notion may easily breaks and results into short range correlation much above the global magnetic transition temperature. La2CuIrO6 with complex interplay of spins (s =1/2) on Cu site and pseudo-spin (j =1/2) on Ir site owing to strong spin-orbit coupling provides fertile ground to observe such correlated phenomena. By a comprehensive temperature dependent Raman study, we have shown the presence of such a correlated paramagnetic state in La2CuIrO6 much above the long range magnetic ordering temperature (TN ). Our observation of strong interactions of phonons, associated with Cu/Ir octahedra, with underlying magnetic degrees of freedom mirrored in the observed Fano asymmetry, which remarkably persists as high as ~ 3.5TN clearly signals the existence of correlated paramagnetism hence broken rotational symmetry. Our detailed analysis also reveals anomalous changes in the self-energy parameters of the phonon modes, i.e. mode frequencies and linewidth, below TN, providing a useful gauge for monitoring the strong coupling between phonons and magnetic degrees of freedom.

cond-mat.str-el↗

arXiv2019

Thermal Expansion Coefficient and Phonon Dynamics in Coexisting Allotropes of Monolayer WS2 Probed by Raman Scattering

We report a comprehensive temperature dependent Raman measurements on three different phases of monolayer WS2 from 4K to 330K in a wide spectral range. Our studies revels the anomalous nature of the first as well as the higher order combination modes reflected in the disappearance of the few modes and anomalous temperature evaluation of the phonon self-energy parameters attributed to the detuning of resonance condition and development of strain due to thermal expansion mismatch with the underlying substrate. Our detailed temperature dependence studies also decipher the ambiguity about assignment of the two modes in literature near ~ 297 cm-1 and 325 cm-1. Mode near 297 cm-1 is assigned as first order Raman mode, which is forbidden in the backscattering geometry and 325 cm-1 is assigned to the combination of and mode. We also estimated thermal expansion coefficient by systematically disentangling the substrate effect in the temperature range of 4K to 330K and probed its temperature dependence in 1H, 1T and 1T' phases.

cond-mat.mtrl-sci↗

arXiv2019

Broken translational and rotational symmetries in LiMn1.5Ni0.5O4 spinel

In condensed matter physics broken symmetries and emergence of quasi-particles are intimately linked to each other. Whenever a symmetry is broken, it leaves its fingerprints, and that may be observed indirectly via its influence on the other quasi-particles. Here, we report the strong signature of broken rotational symmetry induced due to long range-ordering of spins in Mn - sublattice of LiMn1.5Ni0.5O4 below Tc ~ 113 K reflected with the marked changes in the lattice vibrations using Raman scattering. In particular, the majority of the observed first-order phonon modes show a sharp shift in frequency in the vicinity of long range magnetic-ordering temperature. Phonons exist in a crystalline system because of broken translational symmetry, therefore any renormalization in the phonon-spectrum could be a good gauge for broken translational symmetry. Anomalous evolution of the few modes associated with stretching of Mn/NiO6 octahedra in the intermediate temperature range (~ 60-260 K) marked the broken translational symmetry attributed to the charge ordering. Interestingly same modes also show strong coupling with magnetic degrees of freedom, suggesting that charge-ordering and magnetic transition may be linked to each other.

cond-mat.mtrl-sci↗

arXiv2019

Evolution of elastic moduli through a two-dimensional structural transformation

We use a classical analytical and separable elastic energy landscape describing SnO monolayers to estimate the softening of elastic moduli through a mechanical instability occurring at finite temperature in this material. Although not strictly applicable to this material due to its low energy barrier $J$ that leads to a quantum paraelastic phase, the present exercise is relevant as it establishes a conceptual procedure to estimate such moduli straight from a two-dimensional elastic energy landscape. As additional support for the existence of a quantum paraelastic phase, we carry a qualitative WKB analysis to estimate escape times from an individual well on the landscape; escape times increase exponentially with the height of the barrier $J$. We also provide arguments against an additional transformation onto a planar lattice due to its high energy cost. These results continue to establish a case for the usefulness of soft matter concepts in two-dimensional materials, and of the potential lurking of quantum effects into soft matter.

cond-mat.soft↗