arXiv subjects

Pradeep Kumar

Publications and source records attributed to Pradeep Kumar.

At least 73 records · Page 4Linked to original sources

arXiv2019

Non-Markovian evolution: a quantum walk perspective

Quantum non-Markovianity of a quantum noisy channel manifests typically as information backflow, characterized by the departure of the intermediate map from complete positivity, though we indicate certain noisy channels that don't exhibit this behavior. In complex systems, non-Markovianity becomes more involved on account of subsystem dynamics. Here we study various facets of non-Markovian evolution, in the context of coined quantum walks, with particular stress on disambiguating the internal vs. environmental contributions to non-Markovian backflow. For the above problem of disambiguation, we present a general power-spectral technique based on a distinguishability measure such as trace-distance or correlation measure such as mutual information. We also study various facets of quantum correlations in the transition from quantum to classical random walks, under the considered non-Markovian noise models. The potential for the application of this analysis to the quantum statistical dynamics of complex systems is indicated.

quant-ph↗

arXiv2018

Orbiton-Phonon coupling in Ir5+(5d4) double perovskite Ba2YIrO6

Ba2YIrO6, a Mott insulator, with four valence electrons in Ir5+ d-shell (5d4) is supposed to be non-magnetic, with Jeff = 0, within the atomic physics picture. However, recent suggestions of non-zero magnetism have raised some fundamental questions about its origin. Focussing on the phonon dynamics, probed via Raman scattering, as a function of temperature and different incident photon energies, as an external perturbation. Our studies reveal strong renormalization of the phonon self-energy parameters and integrated intensity for first-order modes, especially redshift of the few first-order modes with decreasing temperature and anomalous softening of modes associated with IrO6 octahedra, as well as high energy Raman bands attributed to the strong anharmonic phonons and coupling with orbital excitations. The distinct renormalization of second-order Raman bands with respect to their first-order counterpart suggest that higher energy Raman bands have significant contribution from orbital excitations. Our observation indicates that strong anharmonic phonons coupled with electronic/orbital degrees of freedom provides a knob for tuning the conventional electronic levels for 5d-orbitals, and this may give rise to non-zero magnetism as postulated in recent theoretical calculations with rich magnetic phases.

cond-mat.str-el↗

arXiv2018

(Pb1-xBix)(Ti1-xMnx)O3: Competing mechanism of Tetragonal-Cubic phase on A/B site modifications

Structural, vibrational and dielectric properties of (Pb1-xBix)(Ti1-xMnx)O3 (PBTM) (0 x 0.50) polycrystalline ceramics have been examined as a function of temperature. Synchrotron-based powder x-ray diffraction was employed to confirm phase purity and crystal structure of samples. Tetragonality (c/a ratio) of the PBTM system exhibit an increase 1.065, 1.066 for x = 0.06 and 0.09 compositions respectively, compare to 1.064 for x = 0 sample. Curie point was found ~763 K and 773 K for x = 0.06 and 0.09 samples respectively. Though, tetragonality start to decreasing from samples with x 0.18, Curie point of the samples started decreasing for x 0.12. Temperature-dependent x-ray diffraction reveals the structural change from tetragonal to cubic structure. Unit cell volume was found to decrease with increasing temperature; indicate these materials are negative thermal expansion type until phase transition temperature, with negative thermal coefficients are -1.571*10-5 /K, -2.44*10-5 /K, and -5.025*10-6 /K for x = 0, 0.06, and 0.09 samples respectively. Raman spectra showed softening of the transverse optical phonon modes and increase in the full width at half maxima with the increase in composition. Field-emission scanning electron microscope equipped with energy dispersive x-ray spectrometer (EDS) confirmed compositional homogeneity and dense type microstructure.

cond-mat.mtrl-sci↗

arXiv2017

Diverse Trends of Electron Correlation Effects for Properties with Different Radial and Angular Factors in an Atomic System: A case study in Ca$^{+}$

Atomic properties such as field shift constants, magnetic dipole and electric quadrupole hyperfine structure constants, Landé $g_J$ factors, and electric quadrupole moments that are described by electronic operators with different ranks and radial behaviors are studied and the role of electron correlation effects in their determination are investigated. We have adopted the Dirac-Hartree-Fock method, the second- and third-order relativistic many-body perturbation theories, and an all-order relativistic many-body method in the coupled-cluster theory framework considering only the linearized terms and also all the non-linearized terms in the singles and doubles with partial triples excitations approximation to carry out these analyses. Variations in the propagation of electron correlation effects with operators having same angular factors but different radial behaviors and with different ranks are highlighted. Corrections from the higher-order relativistic corrections due to the Breit and quantum electrodynamics interactions to all these properties are also estimated. Understanding of trends of electron correlation effects in these properties can be useful to establish accuracies in the theoretical results of different atomic properties and to substantiate validity of an approximated many-body method.

physics.atom-ph↗

arXiv2017

Tuning the ferro- to para-electric transition temperature and dipole orientation of group-IV monochalcogenide monolayers

Coordination-related, two-dimensional (2D) structural phase transitions are a fascinating and novel facet of two-dimensional materials with structural degeneracies. Nevertheless, a unified theoretical account of these transitions remains absent, and the following points are established through {\em ab-initio} molecular dynamics and 2D discrete clock models here: Group-IV monochalcogenide (GeSe, SnSe, SnTe, ...) monolayers have four degenerate structural ground states, and a 2D phase transition from a three-fold coordinated onto a five-fold coordinated structure takes place at finite temperature. On unstrained samples, the 2D phase transition requires lattice parameters to freely evolve. A fundamental energy scale permits understanding this transition. The transition temperature $T_c$ and the orientation of the in-plane intrinsic electric dipole can be controlled by moderate uniaxial tensile strain, and a modified discrete clock model describes the transition on strained samples. These results establish a general underlying theoretical background to understand structural phase transitions in 2D materials and their effects on material properties.

cond-mat.mes-hall↗

arXiv2017

Temperature Dependence of Nonlinear Susceptibilities in an Infinite Range Interaction Model

We present a model to probe metamagnetic properties in systems with an arbitrary number of interacting spins. Thermodynamic properties such as the magnetization per particle $m(B,T,N)$, linear susceptibility $χ_1(T)$, nonlinear susceptibilities $χ_3(T)$ and $χ_5(T)$, specific heat $C(B,T,N)$, and pressure $P(B,T,N)$ were calculated. The model produces a different magnetic response for $N$ particles when comparing to $N - 1$ particles for small $N \sim 1$. For an even number of particles, the susceptibilities show maxima in their temperature dependence. An odd number produces an additional free spin response that dominates at low temperatures. This free spin response for odd $N$ also produces a step in the magnetization per particle at $B = 0$. The magnetization shows $N/2$ steps at $γB_c/J = n$ with integer $n$ for even $N$ and $(N-1)/2$ additional steps at half-integer $n$ starting at 3/2 for odd $N$. Small clusters respond with metamagnetism in an otherwise isotropic spin space, while the large clusters show no metamagnetism.

cond-mat.stat-mech↗

arXiv2017

Relativistic coupled-cluster theory analysis of unusually large correlation effects in the determination of $g_j$ factors in Ca$^+$

We investigate roles of electron correlation effects in the determination of the $g_j$ factors of the $4s ~ ^2S_{1/2}$, $4p ~ ^2P_{1/2}$, $4p ~ ^2P_{3/2}$, $3d ~ ^2D_{3/2}$, and $3d ~ ^2D_{5/2}$ states, representing to different parities and angular momenta, of the Ca$^+$ ion. Correlation contributions are highlighted with respect to the mean-field values evaluated using the Dirac-Hartree-Fock method, relativistic second order many-body theory, and relativistic coupled-cluster (RCC) theory with the singles and doubles approximation considering only the linear terms and also accounting for all the non-linear terms. This shows that it is difficult to achieve reasonably accurate results employing an approximated perturbative approach. We also find that contributions through the non-linear terms and higher-level excitations such as triple excitations, estimated perturbatively in the RCC method, are found to be crucial to attain precise values of the $g_j$ factors in the considered states of Ca$^+$ ion.

physics.atom-ph↗

arXiv2017

Morphology, cell division, and viability of Saccharomyces cerevisiae at high hydrostatic pressure

High hydrostatic pressure is commonly encountered in many environments, but the effects of high pressure on eukaryotic cells have been understudied. To understand the effects of hydrostatic pressure in the model eukaryote, Saccharomyces cerevisiae, we have performed quantitative experiments of cell division, cell morphology, and cell death under a wide range of pressures. We developed an automated image analysis method for quantification of the yeast budding index - a measure of cell cycle state - as well as a continuum model of budding to investigate the effect of pressure on cell division and cell morphology. We find that the budding index, the average cell size, and the eccentricity - a measure of how much the cell morphology varies from the being elliptical - of the cells decrease with increasing pressure. Furthermore, high hydrostatic pressure led to the small but finite probability of cell death via both apoptosis and necrosis. Our experiments suggest that decrease of budding index arises from cellular arrest or death at the cell cycle checkpoints during different stages of cell division.

q-bio.CB↗

arXiv2016

Structural phase transition and material properties of few-layer monochalcogenides

GeSe and SnSe monochalcogenide monolayers and bilayers undergo a two-dimensional phase transition from a rectangular unit cell to a square unit cell at a temperature $T_c$ well below the melting point. Its consequences on material properties are studied within the framework of Car-Parrinello molecular dynamics and density-functional theory. No in-gap states develop as the structural transition takes place, so that these phase-change materials remain semiconducting below and above $T_c$. As the in-plane lattice transforms from a rectangle onto a square at $T_c$, the electronic, spin, optical, and piezo-electric properties dramatically depart from earlier predictions. Indeed, the $Y-$ and $X-$points in the Brillouin zone become effectively equivalent at $T_c$, leading to a symmetric electronic structure. The spin polarization at the conduction valley edge vanishes, and the hole conductivity must display an anomalous thermal increase at $T_c$. The linear optical absorption band edge must change its polarization as well, making this structural and electronic evolution verifiable by optical means. Much excitement has been drawn by theoretical predictions of giant piezo-electricity and ferroelectricity in these materials, and we estimate a pyroelectric response of about $3\times 10^{-12}$ $C/K m$ here. These results uncover the fundamental role of temperature as a control knob for the physical properties of few-layer group-IV monochalcogenides

cond-mat.mtrl-sci↗

arXiv2016

Significance of Mobility on Received Signal Strength: An Experimental Investigation

In this paper, estimation of mobility using received signal strength is presented. In contrast to standard methods, speed can be inferred without the use of any additional hardware like accelerometer, gyroscope or position estimator. The strength of Wi-Fi signal is considered herein to compute the time-domain features such as mean, minimum, maximum, and autocorrelation. The experiments are carried out in different environments like academic area, residential area and in open space. The complexity of the algorithm in training and testing phase are quadratic and linear with the number of Wi-Fi samples respectively. The experimental results indicate that the average error in the estimated speed is 12 % when the maximum signal strength features are taken into account. The proposed method is cost-effective and having a low complexity with reasonable accuracy in a Wi-Fi or cellular environment. Additionally, the proposed method is scalable that is the performance is not affected in a multi-smartphones scenario.

cs.NI↗

arXiv2016

Finite frequency Seebeck coefficient of metals: A memory function approach

We study the dynamical thermoelectric transport in metals subjected to the electron-impurity and the electron-phonon interactions using the memory function formalism. We introduce a generalized Drude form for the Seebeck coefficient in terms of thermoelectric memory function and calculate the later in various temperature and frequency limits. In the zero frequency and high temperature limit, we find that our results are consistent with the experimental findings and with the traditional Boltzmann equation approach. In the low temperature limit, we find that the Seebeck coefficient is quadratic in temperature. In the finite frequency regime, we report new results: In the electron-phonon interaction case, we find that the Seebeck coefficient shows frequency independent behavior both in the high frequency regime ($ω\gg ω_{D}$, where $ω_{D}$ is the Debye frequency) and in the low frequency regime ($ω\ll ω_{D}$), whereas in the intermediate frequencies, it is a monotonically increasing function of frequency. In the case of the electron-impurity interaction, first it decays and then after passing through a minimum it increases with the increase in frequency and saturates at high frequencies.

cond-mat.str-el↗

arXiv2016

Iron Isotope Effect in SmFeAsO0.65 and SmFeAsO0.77H0.12 Superconductors: A Raman Study

We report the inelastic light scattering studies on SmFeAsO0.65 and SmFeAsO0.77H0.12 with iron isotopes namely 54Fe and 57Fe. In both of these systems under investigation we observed a significant shift in the frequency of the phonon modes associated with the displacement of Fe atoms around ~ 200 cm-1. The observed shift in the Fe mode (B1g) for SmFeAsO0.65 is ~ 1.4 % and lower in case of SmFeAsO0.77H0.12, which is ~ 0.65 %, attributed to the lower percentage of isotopic substitution in case of SmFeAsO0.77H0.12. Our study reveals the significant iron isotope effect in these systems hinting towards the crucial role of electron-phonon coupling in the pairing mechanism of iron based superconductors.

cond-mat.str-el↗

arXiv2016

Theory of the Dynamical Thermal conductivity of Metals

The Mori's projection method, known as memory function method is an important theoretical formalism to study various transport coefficients. In the present work, we calculate the dynamical thermal conductivity in the case of metals using the memory function formalism. We introduce thermal memory functions for the first time and discuss the behavior of thermal conductivity in both zero frequency limit and in the case of non-zero frequencies. We compare our results for the zero frequency case with the results obtained by the Bloch-Boltzmann kinetic approach and find that both approaches agree with each other. Motivated by some recent experimental advancements, we obtain several new results for the ac or the dynamical thermal conductivity.

cond-mat.str-el↗

arXiv2016

Two-dimensional disorder in black phosphorus and monochalcogenide monolayers

Ridged, orthorhombic two-dimensional atomic crystals with a bulk {\em Pnma} structure such as black phosphorus and monochalcogenide monolayers are an exciting and novel material platform for a host of applications. Key to their crystallinity, monolayers of these materials have a four-fold degenerate structural ground state, and a single energy scale $E_C$ (representing the elastic energy required to switch the longer lattice vector along the $x-$ or $y-$direction) determines how disordered these monolayers are at finite temperature. Disorder arises when nearest neighboring atoms become gently reassigned as the system is thermally excited beyond a critical temperature $T_c$ that is proportional to $E_C/k_B$. $E_C$ is tunable by chemical composition and it leads to a classification of these materials into two categories: (i) Those for which $E_C\ge k_BT_m$, and (ii) those having $k_BT_m>E_C\ge 0$, where $T_m$ is a given material's melting temperature. Black phosphorus and SiS monolayers belong to category (i): these materials do not display an intermediate order-disorder transition and melt directly. All other monochalcogenide monolayers with $E_C>0$ belonging to class (ii) will undergo a two-dimensional transition prior to melting. $E_C/k_B$ is slightly larger than room temperature for GeS and GeSe, and smaller than 300 K for SnS and SnSe monolayers, so that these materials transition near room temperature. The onset of this generic atomistic phenomena is captured by a planar Potts model up to the order-disorder transition. The order-disorder phase transition in two dimensions described here is at the origin of the {\em Cmcm} phase being discussed within the context of bulk layered SnSe.

cond-mat.mes-hall↗

arXiv2015

The CeMIn5 (M = Rh, Ir and Co) System and the Single Energy Scale Model of Metamagnetism

For a decade and a half, CeCoIn$_5$ and related alloys have served as a rich playground to explore the interplay between magnetism and unconventional superconductivity. Despite this extended study, the presence/absence of metamagnetism (MM) in this ternary system remains as an unresolved issue. Here we show that the linear and non-linear magnetic response in CeMIn$_5$ (M = Rh, Ir and Co) can be understood within the context of the recently proposed single energy scale (SES) model of MM. New measurements of the third-order susceptibility, $χ_3$, in CeCoIn$_5$ are presented and together with the known systematics of the linear susceptibility in all three compounds, are shown to be consistent with the SES model. Predictions are made for the MM critical field in CeCoIn$_5$ and the fifth-order susceptibility, $χ_5$.

cond-mat.str-el↗

arXiv2015

Proximate transition temperatures amplify linear magnetoelectric coupling in strain-disordered multiferroic BiMnO3

We report a giant linear magnetoelectric coupling in strained BiMnO3 thin films in which the disorder associated with an islanded morphology gives rise to extrinsic relaxor ferroelectricity that is not present in bulk centrosymmetric ferromagnetic crystalline BiMnO3. Strain associated with the disorder is treated as a local variable which couples to the two ferroic order parameters, magnetization M and polarization P. A straightforward "gas under a piston" thermodynamic treatment explains the observed correlated temperature dependencies of the product of susceptibilities and the magnetoelectric coefficient together with the enhancement of the coupling by the proximity of the ferroic transition temperatures close to the relaxor freezing temperature. Our interpretation is based on a trilinear coupling term in the free energy of the form L(PXM) where L is a hidden antiferromagnetic order parameter, previously postulated by theory for BiMnO3. This phenomenological invariant not only preserves inversion and time reversal symmetry of the strain-induced interactions but also explains the pronounced linear magnetoelectric coupling without using the more conventional higher order biquadratic interaction proportional to (PM)^2.

cond-mat.mtrl-sci↗

arXiv2015

Hypersurfaces of a Projective Randers conformal change

In the year 1984 Shibata investigated the theory of a change which is called a $ β$-change of a Finsler metric. On the other hand in 1985 a systematic study of geometry of hypersurfaces in Finsler spaces was given by Matsumoto. In the present paper is to devoted to the study of a condition for a Randers conformal change to be projective and find out when a totally geodesic hypersurface $ F^{n-1} $ remains to be a totally geodesic hypersurface $ F^{n-1} $ under the projective Randers conformal change. Further obatined the condition under which a Finslerian hypersurfaces given by the projective Randers conformal change are projectively flat.

math.DG↗

arXiv2015

High Field Ultrasound Measurements in UPt3 and the Single Energy Scale Model of Metamagnetism

We report longitudinal ultrasound velocity measurements for magnetic fields up to 33 T applied parallel to the a-axis of the heavy electron compound UPt$_{3}$. A characteristic dip in the sound velocity at the metamagnetic critical field, $H_{c}=20$ T, reported in earlier work is reproduced and shown to be independent of temperature at very low temperatures. We show that the single energy scale model (B.S. Shivaram et al., Phys. Rev. B89, 241107(R), 2014) captures the observed key features of the field dependence in the sound velocity shift, $δv_{s}$. The shift $δv_{s}$ at $H_{c}$ is found to be inversely dependent on temperature above 3\thinspace K and assumes a fixed value at low T. This saturation in $δv_{s}$ below 3 K is accounted for by level broadening of the Uranium spin states.

cond-mat.str-el↗