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R. G. Goodrich

Publications and source records attributed to R. G. Goodrich.

20 records · Page 2Linked to original sources

Magnetization Measurements on Single Crystals of Superconducting Ba0.6K0.4BiO3

Extensive measurements of the magnetization of superconducting single crystal samples of Ba0.6K0.4BiO3} have been made using SQUID and cantilever force magnetometry at temperatures ranging between 1.3 and 350 K and in magnetic fields from near zero to 27 T. Hysteresis curves of magnetization versus field allow a determination of the thermodynamic critical field, the reversibility field, and the upper critical field as a function of temperature. The lower critical field is measured seperately and the Ginzburg-Landau parameter is found to be temperature dependent. All critical fields have higher T = 0 limits than have been previously noted and none of the temperature dependence of the critical fields follow the expected power laws leading to possible alternate interpretation of the thermodynamic nature of the superconducting transition.

cond-mat.supr-con↗

Thermodynamics of the Superconducting Phase Transition in Ba_{0.6}K_{0.4}BiO_3

We suggest that the transition to superconductivity in a single crystal of Ba_{0.6}K_{0.4}BiO_3 with a T_c = 32K, and having critical fields with anomalous temperature dependencies and vanishing discontinuities in specific heat and magnetic susceptibility, may well be an example of a fourth order (in Ehrenfest's sense) phase transition. We have derived a free energy functional for a fourth order transition and calculated (for the temperature range ${T_c/2 < T \simeq T_c}$) the temperature dependence of the critical fields. We find $H_{c1}(T)\propto (1-T/T_c)^3, H_0(T)\propto (1-T/T_c)^2$ and $H_{c2}(T)\propto (1-T/T_c)^{1}$ in general agreement with experiments.

cond-mat.supr-con↗