Impact of Oxygen Diffusion on Superconductivity in YBa$_2$Cu$_3$O$_{7-δ}$ Thin Films Studied by Positron Annihilation Spectroscopy
The oxygen deficiency $δ$ in YBa$_2$Cu$_3$O$_{7-δ}$ (YBCO) plays a crucial role for affecting high-temperature superconductivity. We applied (coincident) Doppler broadening spectroscopy of the electron-positron annihilation line to study in situ the temperature dependence of the oxygen concentration and its depth profile in single crystalline YBCO film grown on SrTiO$_3$ (STO) substrates. The oxygen diffusion during tempering was found to lead to a distinct depth dependence of $δ$, which is not accessible using X-ray diffraction. A steady-state reached within a few minutes is defined by both, the oxygen exchange at the surface and at the interface to the STO substrate. Moreover, we revealed the depth dependent critical temperature $T_{\mathrm{c}}$ in the as prepared and tempered YBCO film.