arXiv subjects

R. Kadono

Publications and source records attributed to R. Kadono.

At least 37 records · Page 2Linked to original sources

arXiv2022

Ambipolar Property of Isolated Hydrogen in Oxide Materials Revealed by Muon

The study on the electronic state of muon as pseudo-hydrogen (represented by the elemental symbol Mu) has long been appreciated as one of the few methods to experimentally access the electronic state of dilute hydrogen (H) in semiconductors and dielectrics. Meanwhile, theoretical predictions on the electronic state of H in these materials by first-principles calculations using density functional theory (DFT) do not always agree with the observed states of Mu, standing as an obstacle to integrating the findings of both Mu and H. In this paper, we provide resolution to this problem by a semi-quantitative model that enables systematic understanding of the electronic states of Mu in most oxides.

cond-mat.mtrl-sci↗

arXiv2021

Anomalous diamagnetism of electride electrons in transition metal silicides

Intermetallic silicide compounds, LaScSi and Y$_5$Si$_3$, known for being hydrogen (H) storage materials, are drawing attention as candidates for electrides in which anions are substituted by unbound electrons. It is inferred from a muon spin rotation experiment that the local field at the muon site (which is the same site as that for H) in these compounds exhibits a large negative shift under an external magnetic field, which is mostly independent of temperature. Such anomalous diamagnetism signals a unique property of electride electrons associated with transition metals. Moreover, the diamagnetic shift decreases with increasing H content, suggesting that the electride electrons existing coherently in the hollow interstitial positions are adsorbed by H to form hydride ions (H$^-$)

cond-mat.mtrl-sci↗

arXiv2020

Magnetism behavior of $T^{\prime}$-type Eu$_2$CuO$_4$ revealed by muon spin rotation/relaxation measurements

We performed muon spin rotation/relaxation measurements to investigate the magnetic behavior of $T^{\prime}$-type Eu$_2$CuO$_4$ (ECO), which is the parent compound of electron-doped cuprate superconductors, and the effects of oxygen-reduction annealing on its magnetism. In as-sintered (AS) ECO, we clarified the development of magnetic correlations upon cooling below $T_\mathrm{N1}$ (= 265 K) as well as the coexistence of a dominant fluctuating spin state and partially ordered spin state in the temperature range between $\sim$150 K and $T_\mathrm{N1}$. Upon further cooling, uniform long-range magnetic order was observed below $T_\mathrm{N2} = 110$ K, which is close to the ordering temperature of 115 K in $T^{\prime}$-type La$_2$CuO$_4$ (LCO) [Phys. Rev. B {\bf 82}, 180508(R) (2010)]. For oxygen-reduction-annealed ECO, a similar ordering sequence with the same $T_\mathrm{N2}$ was observed but without the partially ordered spin state. Therefore, the fluctuating spin state over a wide temperature range and a $T_\mathrm{N2}$ less than the N{é}el temperature ($T_\mathrm{N2} \approx T_\mathrm{N1}$) in $T$-type LCO are common features of the $T^{\prime}$-type parent $R_2$CuO$_4$ ($R$CO, $R$: rare-earth ion). The origin of the partially ordered spin state in AS ECO is discussed from the viewpoint of chemical defect. Furthermore, we discuss the roles of electron doping and repairing defect in the observed effect of annealing on the magnetism of $T^{\prime}$-type $R$CO.

cond-mat.str-el↗

arXiv2020

Electronic charge transfer driven by spin cycloidal structure

Muon spin rotation and resonant soft X-ray scattering experiments on prototype multiferroics RMn2O5 (R = Y, Sm) are used to demonstrate that the local electric displacements are driven by the spin-current (SC) mechanism. Small local electric displacements were evaluated by observing spin polarization at ligand O ions, for which implanted muons served as an extremely sensitive probe. Our results for YMn2O5 provide evidence that the spin polarization of O ions forming a spin cycloid chain with Mn spins increases in proportion to the vector spin chirality (Si x Sj ) of the Mn ions. This relationship strongly indicates that the charge transfer between O and Mn ions is driven by the SC mechanism, which leads to the ferroelectricity accompanying O spin polarization.

cond-mat.str-el↗

arXiv2020

Magnetism driven by strong electronic correlation in the heavily carrier-doped iron oxypnictide LaFeAsO$_{0.49}$H$_{0.51}$

The magnetism of the second antiferromagnetic phase (AF2) arising in the iron-based LaFeAsO$_{1-x}$H$_{x}$ superconductor for $x\gtrsim0.4$ was investigated by muon spin rotation measurements under hydrostatic pressure up to 2.6 GPa. The Néel temperature ($T_{\rm N}$) obtained for a sample with $x=0.51$ exhibits considerably greater sensitivity to pressure than that in the pristine antiferromagnetic phase (AF1, $x\lesssim0.06$). Moreover, while the AF1 phase is always accompanied by the structural transition (from tetragonal to orthorhombic) at a temperature ($T_{\rm s}$) which is slightly higher than $T_{\rm N}$, the AF2 phase prevails at higher pressures above $\sim$1.5 GPa where the structural transition is suppressed ($T_{\rm s}=0$). These features indicate that the microscopic origin of the AF2 phase is distinct from that of AF1, suggesting that electronic correlation plays important role in the former phase. We argue that the orbital-selective Mott transition is a plausible scenario to account for the observed pressure dependence of $T_{\rm N}$ and $T_{\rm s}$ in the AF2 phase.

cond-mat.str-el↗

arXiv2019

Coupled Spin-Charge-Phonon Fluctuation in the All-In/All-Out Antiferromagnet Cd$_2$Os$_2$O$_7$

We report on a novel spin-charge fluctuation in the all-in-all-out pyrochlore magnet Cd$_2$Os$_2$O$_7$, where the spin fluctuation is driven by the conduction of thermally excited electrons/holes and associated fluctuation of Os valence. The fluctuation exhibits an activation energy significantly greater than the spin-charge excitation gap and a peculiar frequency range of $10^{6}$--$10^{10}$ s$^{-1}$. These features are attributed to the hopping motion of carriers as small polarons in the insulating phase, where the polaron state is presumably induced by the magnetoelastic coupling via the strong spin-orbit interaction. Such a coupled spin-charge-phonon fluctuation manifests as a part of the metal-insulator transition that is extended over a wide temperature range due to the modest electron correlation comparable with other interactions characteristic for 5$d$-subshell systems.

cond-mat.str-el↗

arXiv2019

A New Approach for Measuring the Muon Anomalous Magnetic Moment and Electric Dipole Moment

This paper introduces a new approach to measure the muon magnetic moment anomaly $a_μ = (g-2)/2$, and the muon electric dipole moment (EDM) $d_μ$ at the J-PARC muon facility. The goal of our experiment is to measure $a_μ$ and $d_μ$ using an independent method with a factor of 10 lower muon momentum, and a factor of 20 smaller diameter storage-ring solenoid compared with previous and ongoing muon $g-2$ experiments with unprecedented quality of the storage magnetic field. Additional significant differences from the present experimental method include a factor of 1,000 smaller transverse emittance of the muon beam (reaccelerated thermal muon beam), its efficient vertical injection into the solenoid, and tracking each decay positron from muon decay to obtain its momentum vector. The precision goal for $a_μ$ is statistical uncertainty of 450 part per billion (ppb), similar to the present experimental uncertainty, and a systematic uncertainty less than 70 ppb. The goal for EDM is a sensitivity of $1.5\times 10^{-21}~e\cdot\mbox{cm}$.

physics.ins-det↗

arXiv2019

Quantum magnetisms in uniform triangular lattices Li2AMo3O8 (A = In, Sc)

Molecular based spin-1/2 triangular lattice systems such as LiZn$_2$Mo$_3$O$_8$ have attracted research interest. Distortions, defects, and intersite disorder are suppressed in such molecular-based magnets, and intrinsic geometrical frustration gives rise to unconventional and unexpected ground states. Li$_2$$A$Mo$_3$O$_8$ ($A$ = In or Sc) is such a compound where spin-1/2 Mo$_3$O$_{13}$ clusters in place of Mo ions form the uniform triangular lattice. Their ground states are different according to the $A$ site. Li$_2$InMo$_3$O$_8$ undergoes conventional $120^\circ$ long-range magnetic order below $T_\text{N}=12$~K whereas isomorphic Li$_2$ScMo$_3$O$_8$ exhibits no long-range magnetic order down to 0.5~K. Here, we report exotic magnetisms in Li$_2$InMo$_3$O$_8$ and Li$_2$ScMo$_3$O$_8$ investigated by muon spin rotation ($μ$SR) and inelastic neutron scattering (INS) spectroscopies using polycrystalline samples. Li$_2$InMo$_3$O$_8$ and Li$_2$ScMo$_3$O$_8$ show completely different behaviors observed in both $μ$SR and INS measurements, representing their different ground states. Li$_2$InMo$_3$O$_8$ exhibits spin wave excitation which is quantitatively described by the nearest neighbor anisotropic Heisenberg model based on the $120^\circ$ spin structure. In contrast, Li$_2$ScMo$_3$O$_8$ undergoes short-range magnetic order below 4~K with quantum-spin-liquid-like magnetic fluctuations down to the base temperature. Origin of the different ground states is discussed in terms of anisotropies of crystal structures and magnetic interactions.

cond-mat.str-el↗

arXiv2019

Successive magnetic ordering sequence observed from muon spin rotation in T'-structured R2CuO4 (R = Eu, Nd)

The magnetic behavior and effects of oxygen-reduction annealing on the magnetism of T'-structured R2CuO4 (R = Eu and Nd), which is the parent compound of electron-doped cuprate superconductors, have been investigated from muon spin rotation (muSR) measurements. In the muon time spectra of as-sintered R2CuO4, an oscillation component with a small amplitude and a dominant exponential-type decay component were observed for the temperature range between 150 K and TN1 (=250-270 K). This observation suggests an inhomogeneous magnetic phase of a fluctuating spin state and a locally ordered spin state at these temperatures. With decreasing temperature,the small oscillation component disappears, and the exponential one develops below 150 K. Upon further cooling, well-defined oscillation spectra corresponding to uniform long-ranged magnetic order emerge below TN2 = 110 K. Except for the absence of the small oscillation component, similar magnetic behavior is confirmed for the annealed compounds. Therefore, the successive development of magnetism characterized by the fluctuating spin state over a wide temperature range is a common feature for T'-R2CuO4. We discuss a possible picture for the ordering sequence in T'-R2CuO4 and the origin of the small oscillation component in the as-sintered compounds from the viewpoint of local defects.

cond-mat.str-el↗

arXiv2018

Metallic Spin Liquid-like Behavior of LiV$_2$O$_4$

LiV$_2$O$_4$ spinel is known to exhibit heavy fermion-like behavior below a characteristic temperature $T_K\simeq 20$ K, while it preserves a paramagnetic state down to $T\sim10^{-2}$ K due to geometrical frustration. Here, it is shown that the dynamical spin susceptibility $χ({\bf q},ω)$ in LiV$_2$O$_4$ exhibits anomalous duality which is modeled as a sum of itinerant ($χ_{\rm F}$) and local ($χ_{\rm L}$) components,and that the local spin dynamics inferred from $χ_{\rm L}({\bf q},ω)$ is qualitatively different from that expected from time-averaged bulk properties. The anomaly coexists with the marginal Fermi liquid behavior inferred from the $-\ln T$ dependence of the electronic specific heat over a wide temperature range below $T_K$. We argue that such unusual properties of LiV$_2$O$_4$ can be attributed to the putative metallic spin liquid state emerging near the quantum critical point between spin glass and Fermi liquid states.

cond-mat.str-el↗

arXiv2018

Local Electronic Structure of Interstitial Hydrogen in Iron Disulfide

The electronic structure of interstitial hydrogen in a compound semiconductor FeS$_2$ (naturally $n$-type) is inferred from a muon study. An implanted muon (Mu, a pseudo-hydrogen) forms electronically different defect centers discerned by the hyperfine parameter ($ω_{\rm hf}$). A body of evidence indicates that one muon is situated at the center of an iron-cornered tetrahedron with nearly isotropic $ω_{\rm hf}$ (Mu$_{\rm p}$), and that the other exists as a diamagnetic state (Mu$_{\rm d}$, $ω_{\rm hf}\simeq 0$). Their response to thermal agitation indicates that the Mu$_{\rm d}$ center accompanies a shallow level (donor or acceptor) understood by effective mass model while the electronic structure of Mu$_{\rm p}$ center is more isolated from host than Mu$_{\rm d}$ to form a deeper donor level. These observations suggest that interstitial hydrogen also serves as an electronically active impurity in FeS$_2$. Based on earlier reports on the hydrogen diffusion in FeS$_2$, possibility of fast diffusion for Mu$_{\rm p}$ leading to formation of a complex defect state (Mu$^*_{\rm d}$, $T\le 100$ K) or to motional narrowing state (Mu$^*_{\rm p}$, $T\ge 150$ K) is also discussed.

cond-mat.mtrl-sci↗

arXiv2018

Electronic correlation in the quasi-two-dimensional electride Y$_2$C

Magnetic properties of the electride compound Y$_2$C were investigated by muon spin rotation and magnetic susceptibility on two samples with different form (poly- and single-crystalline), to examine the theoretically-predicted Stoner ferromagnetism for the electride bands. There was no evidence of static magnetic order in both samples even at temperatures down to 0.024 K. For the poly-crystalline sample, the presence of a paramagnetic moment at Y sites was inferred from the Curie-Weiss behavior of the muon Knight shift and susceptibility, whereas no such tendency was observed in the single-crystalline sample. These observations suggest that the electronic ground state of Y$_2$C is at the limit between weak-to-strong electronic correlation, where onsite Coulomb repulsion is sensitive to a local modulation of the electronic state or a shift in the Fermi level due to the presence of defects/impurities.

cond-mat.mtrl-sci↗

arXiv2016

Repolarization of Negative Muons by Polarized $^{209}$Bi Nuclei

A large $μ^-$ polarization was achieved in muonic Bi atoms with the help of the strong hyperfine field in a polarized nuclear target. Using $^{209}$Bi nuclei polarized to ($59\pm9$)% in ferromagnetic BiMn, we observed a $μ$-$e$ decay asymmetry of ($13.1\pm3.9$)%, which gives $μ^-$ polarization per nuclear polarization equal to $-1.07\pm 0.35$. This value is almost consistent with $-0.792$ calculated for nuclei with spin $I= \frac{9}{2}$ and a positive magnetic moment under the assumption that the hyperfine interaction becomes effective in the lowest muonic states.

nucl-ex↗

arXiv2016

Metal-Insulator Transition and Pseudogap in Bi$_{1.76}$Pb$_{0.35}$Sr$_{1.89}$CuO$_{6+δ}$ High-$T_c$ Cuprates

It is inferred from bulk-sensitive muon Knight shift measurement for a Bi$_{1.76}$Pb$_{0.35}$Sr$_{1.89}$CuO$_{6+δ}$ single-layer cuprate that metal-insulator (MI) transition (in the low temperature limit, $T\rightarrow0$) occurs at the critical hole concentration $p=p_{\rm MI}=0.09(1)$, where the electronic density of states (DOS) at the Fermi level is reduced to zero by the pseudogap irrespective of the Néel order or spin glass magnetism. Superconductivity also appears for $p>p_{\rm MI}$, suggesting that this feature is controlled by the MI transition. More interestingly, the magnitude of the DOS reduction induced by the pseudogap remains unchanged over a wide doping range ($0.1\le p\le0.2$), indicating that the pseudogap remains as a hallmark of the MI transition for $p>p_{\rm MI}$.

cond-mat.str-el↗

arXiv2016

Cage Electron-Hydroxyl Complex State as Electron Donor in Mayenite

It is inferred from the chemical shift of muon spin rotation ($μ$SR) spectra that muons implanted in pristine (fully oxidized) mayenite, [Ca$_{12}$Al$_{14}$O$_{32}]^{2+}$[$\square_5$O$^{2-}$] (C12A7, with $\square$ referring to the vacant cage), are bound to O$^{2-}$ at the cage center to form OMu$^-$ (where Mu represents muonium, a muonic analog of the H atom). However, an isolated negatively charged state (Mu$^-$, an analog of H$^-$) becomes dominant when the compound approaches the state of electride [Ca$_{12}$Al$_{14}$O$_{32}]^{2+}$[$\square_4$2e$^{-}$] as a result of the reduction process. Moreover, the OMu$^-$ state in the pristine specimen exhibits depolarization of paramagnetic origin at low temperatures (below $\sim$30~K), indicating that OMu$^-$ accompanies a loosely bound electron in the cage that can be thermally activated. This suggests that interstitial muons (and hence H) forming a "cage electron-hydroxyl" complex can serve as electron donors in C12A7.

cond-mat.mtrl-sci↗

arXiv2015

Strong electron correlation behind the superconductivity in Ce-free and Ce-underdoped high-Tc T'-cuprates

In order to investigate the electronic state of Ce-free and Ce-underdoped high-Tc cuprates with the so-called T' structure, we have performed muon-spin-relaxation (muSR) and specific-heat measurements of Ce-free T'-La_1.8_Eu_0.2_CuO_4+d_ (T'-LECO) polycrystals and Ce-underdoped T'-Pr_1.3-x_La_0.7_Ce_x_CuO_4+d_ (T'-PLCCO) single crystals with x=0.10. The muSR spectra of the reduced superconducting samples of both T'-LECO with Tc=15K and T'-PLCCO with x=0.10 and Tc=27K have revealed that a short-range magnetic order coexists with the superconductivity in the ground state. The formation of a short-range magnetic order due to a tiny amount of excess oxygen in the reduced superconducting samples strongly suggest that the Ce-free and Ce-underdoped T'-cuprates are regarded as strongly correlated electron systems.

cond-mat.supr-con↗

arXiv2015

Electronic structure of shallow donor state associated with muonium in rutile TiO$_2$

The hyperfine structure of the interstitial muonium (Mu) center in rutile (TiO$_2$, weakly $n$-type) has been identified by means of muon spin rotation technique. The angle-resolved hyperfine parameter has a tetragonal anisotropy within the $ab$ plane and axial anisotropy along the $c$ axis, strongly suggesting that Mu simulates the known local structure of interstitial hydrogen (H) located at an off-center position within a channel along $c$ axis, and the electron wave function bound to Mu is highly delocalized (~1.5 nm along $c$ axis, ~0.8 nm for $a$ axis). The ionization energy of Mu ($\rightarrow μ^+ + e^-$) due to thermal activation is deduced to be 1.2(4) meV, as is directly inferred from the disappearance of Mu signal above ~8 K. These observations suggest that electronic level associated with Mu (as well as H) is situated near the bottom of the conduction band, serving as a shallow donor state in rutile.

cond-mat.mtrl-sci↗

arXiv2015

Evidence for ordered magnetic moments at oxygen sites in antiferromagnetic Sr$_2$IrO$_4$ and Sr$_3$Ir$_2$O$_7$

In this study, the magnetic ground state of iridium perovskites (Sr$_{n+1}$Ir$_{n}$O$_{3n+1}$, where $n=1$, 2, and $\infty$) was considered using muon spin spectroscopy ($μ$SR). When probed by muons in Sr$_2$IrO$_4$ and Sr$_3$Ir$_2$O$_7$ ($n=1,2$), the internal field ($B_{\rm loc}$) showed clear sign of a magnetic order in two stages at transition temperatures $T_{\rm N}\simeq 230$ K and $T_{\rm m}\simeq 90$ K in Sr$_2$IrO$_4$ and $T_{\rm N}\simeq 280$ K and $T_{\rm m}\simeq 70$ K in Sr$_3$Ir$_2$O$_7$, respectively. In contrast, no long-range magnetic order was observed in orthorhombic SrIrO$_3$ ($n=\infty$). Based on the known magnetic structure in Sr$_2$IrO$_4$ and Sr$_3$Ir$_2$O$_7$, we successfully identified muon sites in these compounds from the magnitude of $B_{\rm loc}$ in the first stage ($T_{\rm m}\le T\le T_{\rm N}$). Below $T_{\rm m}$, $B_{\rm loc}$ probed by a fraction of muons occupying sites near the apical oxygen of IrO$_6$ octahedra exhibited a further increase but remained mostly unchanged for sites close to the in-plane oxygen. While such behavior cannot be explained by the alteration of the Ir spin structure, it is consistent with the selective appearance of ordered magnetic moments on the apical oxygen. The oxygen polarization was also in line with the reported magnetization anomalies in these compounds below $\sim T_{\rm m}$. A possible link between the oxygen polarization and ferroelectric (multiferroic) behavior in Sr$_2$IrO$_4$ was considered.

cond-mat.str-el↗