arXiv subjects

R. Rossignoli

Publications and source records attributed to R. Rossignoli.

At least 19 recordsLinked to original sources

arXiv2026

Fermionic entanglement and quantum correlation measures in molecules

We analyze fermionic entanglement and correlation measures in the ground and the low temperature thermal state of the water molecule as a function of the internuclear distance in the context of the full configuration interaction approach. The aim is to obtain a general entanglement based characterization of the electronic eigenstates. We consider first the spin-up - spin-down partition and the associated Schmidt decomposition, examining the total up-down entanglement of the electronic wave function. We then consider the one- and two-body entanglement derived from the one- and two-body reduced density matrices (DMs), which measure both the deviation of the state from a Slater Determinant (SD) as well as the up-down correlation at the two-body level. All blocks of these DMs are examined. We also introduce and analyze new measures like the up-down two-body mutual information and two types of two-body negativities, the latter measuring the "inner" entanglement of the reduced two-body DMs, i.e., their deviation from a convex mixture of SDs. Finally, the dissociation limit is also analyzed, considering both the exact ground state (GS) as well as the thermal state in the zero temperature limit, representing the projector onto the "GS band" of almost degenerate lowest lying eigenstates.

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arXiv2026

History state formalism for time series with application to finance

We present a method for analyzing general time series by employing the history state formalism of quantum mechanics. This formalism allows us to describe a complete evolution based on a single quantum state, the history state, which simultaneously includes -also as a quantum system- the reference clock. It naturally leads to the concept of system-time entanglement, with the ensuing entanglement entropy constituting a measure of the effective number of distinguishable states visited in the history. Through a quantum coherent state embedding of the time series data, it is then possible to associate a quantum history state to the series. The gaussian overlap between these coherent states provides thus a smooth measure of distinguishability between the series data. The eigenvalues of the corresponding overlap matrix determine in fact the entanglement spectrum and entropy of the history state, which provide a rigorous characterization of the evolution. As illustration, the formalism is applied to typical financial time-series data. Through the entanglement entropy and spectrum, different evolution regimes can be identified. Entanglement based volatility indicators are also derived, and compared with standard volatility measures.

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arXiv2025

Spacetime quantum mechanics for bosonic and fermionic systems

We provide a Hilbert space approach to quantum mechanics where space and time are treated on an equal footing. Our approach replaces the standard dependence on an external classical time parameter with a spacetime-symmetric algebraic structure, thereby unifying the axioms that traditionally distinguish the treatment of spacelike and timelike separations. Standard quantum evolution can be recovered from timelike correlators, defined by means of a quantum action operator, a quantum version of the action of classical mechanics. The corresponding map also provides a novel perspective on the path integral formulation, which, in the case of fermions, yields an alternative to the use of Grassmann variables. In addition, the formalism can be interpreted in terms of generalized quantum states, codifying both the conventional information of a quantum system at a given time and its evolution. We show that these states are solutions to a quantum principle of stationary action grounded in timelike correlations and pseudo-entropies

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arXiv2025

Conserved operators and exact conditions for pair condensation

We determine the necessary and sufficient conditions which ensure that an $N=2m$-particle fermionic or bosonic state has the form $|\Psi\rangle\propto(A^{\dagger})^{m}|0\rangle$, where $A^{\dagger}=\tfrac{1}{2}\sum_{i,j}A_{ij}c_{i}^{\dagger}c_{j}^{\dagger}$ is a general pair creation operator. These conditions can be cast as an eigenvalue equation for a modified two-body density matrix, and enable an exact reconstruction of the operator $A^\dag$, providing as well a measure of the proximity of a given state to an exact pair condensate. Through a covariance-based formalism, it is also shown that such states are fully characterized by a set of $L$ "conserved" one-body operators which have $|\Psi\rangle$ as exact eigenstate, with $L$ determined just by the single particle space dimension involved. The whole set of two-body Hamiltonians having $|\Psi\rangle$ as exact eigenstate is in this way determined, while a general subset having $|\Psi\rangle$ as nondegenerate ground state is also identified. Extension to states $\propto f(A^\dag)|0\rangle$ with $f$ an arbitrary function is also discussed.

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arXiv2024

Bipartite representations and many-body entanglement of pure states of $N$ indistinguishable particles

We analyze a general bipartite-like representation of arbitrary pure states of $N$ indistinguishable particles, valid for both bosons and fermions, based on $M$- and $(N-M)$-particle states. It leads to exact $(M,N-M)$ Schmidt-like expansions of the state for any $M<N$ and is directly related to the isospectral reduced $M$- and $(N-M)$-body density matrices $\rho^{(M)}$ and $\rho^{(N-M)}$. The formalism also allows for reduced yet still exact Schmidt-like decompositions associated with blocks of these densities, in systems having a fixed fraction of the particles in some single particle subspace. Monotonicity of the ensuing $M$-body entanglement under a certain set of quantum operations is also discussed. Illustrative examples in fermionic and bosonic systems with pairing correlations are provided, which show that in the presence of dominant eigenvalues in $\rho^{(M)}$, approximations based on a few terms of the pertinent Schmidt expansion can provide a reliable description of the state. The associated one- and two-body entanglement spectrum and entropies are also analyzed.

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arXiv2023

Spacetime quantum and classical mechanics with dynamical foliation

The conventional phase space of classical physics treats space and time differently, and this difference carries over to field theories and quantum mechanics (QM). In this paper, the phase space is enhanced through two main extensions. First, we promote the time choice of the Legendre transform to a dynamical variable. Second, we extend the Poisson brackets of matter fields to a spacetime symmetric form. The ensuing "spacetime phase space" is employed to obtain an explicitly covariant version of Hamilton equations for relativistic field theories. A canonical-like quantization of the formalism is then presented in which the fields satisfy spacetime commutation relations and the foliation is quantum. In this approach, the classical action is also promoted to an operator and retains explicit covariance through its non-separability in the matter-foliation partition. The problem of establishing a correspondence between the new noncausal framework (where fields at different times are independent) and conventional QM is solved through a generalization of spacelike correlators to spacetime. In this generalization, the Hamiltonian is replaced by the action, and conventional particles by off-shell particles. When the foliation is quantized, the previous map is recovered by conditioning on foliation eigenstates, in analogy with the Page and Wootters mechanism. We also provide an interpretation of the correspondence in which the causal structure of a given theory emerges from the quantum correlations between the system and an environment. This idea holds for general quantum systems and allows one to generalize the density matrix to an operator containing the information of correlators both in space and time.

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arXiv2023

Covariance-based method for eigenstate factorization and generalized singlets

We derive a general method for determining the necessary and sufficient conditions for exact factorization $|\Psi\rangle=\otimes_p |\psi_p\rangle$ of an eigenstate of a many-body Hamiltonian $H$, based on the quantum covariance matrix of the relevant local operators building the Hamiltonian. The "site" $p$ can be either a single component or a group of subsystems. The formalism is then used to derive exact dimerization and clusterization conditions in spin systems, covering from spin-$s$ singlets and clusters coupled to $0$ total spin to general nonmaximally entangled spin-$s$ dimers (generalized singlets). New results for field induced dimerization in anisotropic $XYZ$ arrays under a magnetic field are obtained.

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arXiv2023

Parallel-in-time quantum simulation via Page and Wootters quantum time

In the past few decades, researchers have created a veritable zoo of quantum algorithms by drawing inspiration from classical computing, information theory, and even from physical phenomena. Here we present quantum algorithms for parallel-in-time simulations that are inspired by the Page and Wootters formalism. In this framework, and thus in our algorithms, the classical time-variable of quantum mechanics is promoted to the quantum realm by introducing a Hilbert space of ``clock'' qubits which are then entangled with the ``system'' qubits. We show that our algorithms can compute temporal properties over $N$ different times of many-body systems by only using $\log(N)$ clock qubits. As such, we achieve an exponential trade-off between time and spatial complexities. In addition, we rigorously prove that the entanglement created between the system qubits and the clock qubits has operational meaning, as it encodes valuable information about the system's dynamics. We also provide a circuit depth estimation of all the protocols, showing a running time advantage in computation times over traditional sequential-in-time algorithms. In particular, for the case when the dynamics are determined by the Aubry--Andre model, we present a hybrid method for which our algorithms have a depth that only scales as $\mathcal{O}(\log(N)n)$. As a by-product, we can relate the previous schemes to the problem of equilibration of an isolated quantum system, thus indicating that our framework enables a new dimension for studying dynamical properties of many-body systems.

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arXiv2022

History states of one-dimensional quantum walks

We analyze the application of the history state formalism to quantum walks. The formalism allows one to describe the whole walk through a pure quantum history state, which can be derived from a timeless eigenvalue equation. It naturally leads to the notion of system-time entanglement of the walk, which can be considered as a measure of the number of orthogonal states visited in the walk. We then focus on one-dimensional discrete quantum walks, where it is shown that such entanglement is independent of the initial spin orientation for real Hadamard-type coin operators and real initial states (in the standard basis) with definite site parity. Moreover, in the case of an initially localized particle it can be identified with the entanglement of the unitary global operator that generates the whole history state, which is related to its entangling power and can be analytically evaluated. Besides, it is shown that the evolution of the spin subsystem can also be described through a spin history state with an extended clock. A connection between its average entanglement (over all initial states) and that of the operator generating this state is also derived. A quantum circuit for generating the quantum walk history state is provided as well.

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arXiv2022

Ground state separability and criticality in interacting many-particle systems

We analyze exact ground state (GS) separability in general $N$ particle systems with two-site couplings. General necessary and sufficient conditions for full separability, in the form of one and two-site eigenvalue equations, are first derived. The formalism is then applied to a class of $SU(n)$-type interacting systems, where each constituent has access to $n$ local levels, and where the total number parity of each level is preserved. Explicit factorization conditions for parity-breaking GS's are obtained, which generalize those for $XYZ$ spin systems and correspond to a fundamental GS multilevel parity transition where the lowest $2^{n-1}$ energy levels cross. We also identify a multicritical factorization point with exceptional high degeneracy proportional to $N^{n-1}$, arising when the total occupation number of each level is preserved, in which any uniform product state is an exact GS. Critical entanglement properties (like full range pairwise entanglement) are shown to emerge in the immediate vicinity of factorization. Illustrative examples are provided.

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arXiv2021

Path Integrals from Spacetime Quantum Actions

The possibility of extending the canonical formulation of quantum mechanics (QM) to a space-time symmetric form has recently attracted wide interest. In this context, a recent proposal has shown that a spacetime symmetric many-body extension of the Page and Wootters mechanism naturally leads to the so-called Quantum Action (QA) operator, a quantum version of the action of classical mechanics. In this work, we focus on connecting the QA with the well-established Feynman's Path Integral (PI). In particular, we present a novel formalism which allows one to identify the "sum over histories" with a quantum trace, where the role of the classical action is replaced by the corresponding QA. The trace is defined in the extended Hilbert space resulting from assigning a conventional Hilbert space to each time slice and then taking their tensor product. The formalism opens the way to the application of quantum computation protocols to the evaluation of PIs and general correlation functions, and reveals that different representations of the PI arise from distinct choices of basis in the evaluation of the same trace expression. The Hilbert space embedding of the PIs also discloses a new approach to their continuum time limit. Finally, we discuss how the ensuing canonical-like version of QM inherits many properties from the PI formulation, thus allowing an explicitly covariant treatment of spacetime symmetries.

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arXiv2021

Many-body entanglement in fermion systems

We introduce a general bipartite-like representation and Schmidt decomposition of an arbitrary pure state of $N$ indistinguishable fermions, based on states of $M<N$ and $(N-M)$ fermions. It is directly connected with the reduced $M$- and $(N-M)$-body density matrices (DMs), which have the same spectrum in such states. The concept of $M$-body entanglement emerges naturally in this scenario, generalizing that of one-body entanglement. Rigorous majorization relations satisfied by the normalized $M$-body DM are then derived, which imply that the associated entropy will not increase, on average, under a class of operations which have these DMs as post-measurement states. Moreover, such entropy is an upper bound to the average bipartite entanglement entropy generated by a class of operations which map the original state to a bipartite state of $M$ and $N-M$ effectively distinguishable fermions. Analytic evaluation of the spectrum of $M$-body DMs in some strongly correlated fermionic states is also provided.

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arXiv2021

Spacetime Quantum Actions

We propose a formulation of quantum mechanics in an extended Fock space in which a tensor product structure is applied to time. Subspaces of histories consistent with the dynamics of a particular theory are defined by a direct quantum generalization of the corresponding classical action. The diagonalization of such quantum actions enables us to recover the predictions of conventional quantum mechanics and reveals an extended unitary equivalence between all physical theories. Quantum correlations and coherent effects across time and between distinct theories acquire a rigorous meaning, which is encoded in the rich temporal structure of physical states. Connections with modern relativistic schemes and the path integral formulation also emerge.

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arXiv2020

One-body entanglement as a quantum resource in fermionic systems

We show that one-body entanglement, which is a measure of the deviation of a pure fermionic state from a Slater determinant (SD) and is determined by the mixedness of the single-particle density matrix (SPDM), can be considered as a quantum resource. The associated theory has SDs and their convex hull as free states, and number conserving fermion linear optics operations (FLO), which include one-body unitary transformations and measurements of the occupancy of single-particle modes, as the basic free operations. We first provide a bipartitelike formulation of one-body entanglement, based on a Schmidt-like decomposition of a pure $N$-fermion state, from which the SPDM [together with the $(N-1)$-body density matrix] can be derived. It is then proved that under FLO operations, the initial and postmeasurement SPDMs always satisfy a majorization relation, which ensures that these operations cannot increase, on average, the one-body entanglement. It is finally shown that this resource is consistent with a model of fermionic quantum computation which requires correlations beyond antisymmetrization. More general free measurements and the relation with mode entanglement are also discussed.

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arXiv2020

Nonlinear effects on the dynamics of quantum harmonic modes coupled through angular momentum

We investigate nonlinear effects on the dynamics of entanglement and other quantum observables in a system of two harmonic modes coupled through angular momentum. The nonlinearity arises from a quartic anharmonic term in each mode. The emergence and evolution of entanglement, non-gaussianity, photon number, photon antibunching and squeezing are examined for different initial product coherent states and couplings, through exact diagonalization in a truncated basis. It is shown that the anharmonic terms, even if weak, can lead to very significant effects for such initial states, considerably enhancing and stabilizing entanglement and leading to a non negligible non-gaussianity of the evolved states. They also affect other observables, stabilizing the dynamics after an initial transient regime, for not too small initial average populations of each mode. Analytic short-time approximate expressions are also provided.

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arXiv2020

Separability and parity transitions in $XYZ$ spin systems under nonuniform fields

We examine the existence of completely separable ground states (GS) in finite spin-$s$ arrays with anisotropic $XYZ$ couplings, immersed in a non-uniform magnetic field along one of the principal axes. The general conditions for their existence are determined. The analytic expressions for the separability curve in field space, and for the ensuing factorized state and GS energy, are then derived for alternating solutions, valid for any spin and size. They generalize results for uniform fields and show that nonuniform fields can induce GS factorization also in systems which do not exhibit this phenomenon in a uniform field. It is also shown that such curve corresponds to a fundamental $S_z$-parity transition of the GS, present for any spin and size, and that two different types of GS parity diagrams can emerge, according to the anisotropy. The role of factorization in the magnetization and entanglement of these systems is also analyzed, and analytic expressions at the borders of the factorizing curve are provided. Illustrative examples for spin pairs and chains are as well discussed.

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arXiv2019

History state formalism for scalar particles

We present a covariant quantum formalism for scalar particles based on an enlarged Hilbert space. The particular physical theory can be introduced through a timeless Wheeler DeWitt-like equation, whose projection onto four-dimensional coordinates leads to the Klein Gordon equation. The standard quantum mechanical product in the enlarged space, which is invariant and positive definite, implies the usual Klein Gordon product when applied to its eigenstates. Moreover, the standard three-dimensional invariant measure emerges naturally from the flat measure in four dimensions when mass eigenstates are considered, allowing a rigorous identification between definite mass history states and the standard Wigner representation. Connections with the free propagator of scalar field theory and localized states are subsequently derived. The formalism also allows the superposition of different theories and remains valid in the presence of a fixed external field, revealing special orthogonality relations. Other details such as extended identities for the current density, the quantization of parameterized theories and the nonrelativistic limit, with its connection to the Page and Wootters formalism, are discussed. A related consistent second quantization formulation is also introduced.

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arXiv2019

Fermionic entanglement in the Lipkin model

We examine the fermionic entanglement in the ground state of the fermionic Lipkin model and its relation with bipartite entanglement. It is first shown that the one-body entanglement entropy, which quantifies the minimum distance to a fermionic Gaussian state, behaves similarly to the mean-field order parameter and is essentially proportional to the total bipartite entanglement between the upper and lower modes, a quantity meaningful only in the fermionic realization of the model. We also analyze the entanglement of the reduced state of four single-particle modes (two up-down pairs), showing that its fermionic concurrence is strongly peaked at the phase transition and behaves differently from the corresponding up-down entanglement. We finally show that the first measures and the up-down reduced entanglement can be correctly described through a basic mean-field approach supplemented with symmetry restoration, whereas the concurrence requires at least the inclusion of RPA-type correlations for a proper prediction. Fermionic separability is also discussed.

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