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Rafael M. Fernandes

Publications and source records attributed to Rafael M. Fernandes.

At least 19 recordsLinked to original sources

Direct Evidence of Unconventional Superconductivity in Doped Kagome system RV$_3$Sb$_5$

The superconducting pairing symmetry of kagome metals remains a central unresolved question largely because phase-sensitive experiments capable of distinguishing between different possible order parameters have been difficult to implement. The spatial and energetic characteristics of impurity bound states measured by spectroscopic-imaging scanning tunneling microscopy encode information on the superconducting order parameter. Here, we use impurity-bound state spectroscopy to investigate optimally doped RbV$_3$Sb$_{5}$ where the charge-density wave instability is fully suppressed. We find that the superconducting state is fully gapped and exhibits two distinct energy scales, consistent with a multiband order parameter. Atomic-scale spectroscopy around nonmagnetic defects reveals pronounced particle-hole asymmetric bound states. Comparison with theoretical calculations demonstrates that these bound states are incompatible with conventional $s$-wave and sign-changing $s^{\pm}$ pairing. Our calculations also show that the data are fully consistent with a chiral order parameter. Our results establish impurity-bound-state spectroscopy as a powerful phase-sensitive probe of superconductivity in kagome materials and provide strong evidence that optimally doped RbV$_3$Sb$_{5}$ realizes a fully gapped chiral superconducting state.

cond-mat.supr-con

Symmetries of Spin-Splitting Induced by Spin-Orbit Coupling in Non-magnetic Crystals

Spin-orbit coupling (SOC) leads to splitting of otherwise spin-degenerate bands in noncentrosymmetric materials, even if time-reversal symmetry is present. While this gives rise to well-known phenomena such as the Rashba and Dresselhaus effects, various other terms are allowed based on the point group of the crystal and the electronic Hamiltonian. In this study, we utilize point group representations to illustrate that four different types of SOC terms (Rashba, Dresselhaus, Weyl, and Ising) can emerge in periodic solids. We construct reciprocal-space energy expressions for each type of SOC-induced splitting of opposite-spin bands, and follow a similar procedure to also obtain minimal tight-binding models that capture all types of spin-splittings for subgroups of two high-symmetry groups $m\bar{3}m$ and $6/mmm$. Furthermore, we also obtain a complete list of nodal features in the electronic band structure in these systems, distinguishing between crystallographic-symmetry-imposed nodal lines and those imposed by time-reversal-symmetry only. Finally, we conclude by presenting a list of materials that host each type of inversion-breaking SOC effects. Our classification of the spin-splitting symmetries in non-magnetic systems with SOC is the counterpart of the recent classification of spin-splitting symmetries in unconventional magnetic systems without SOC, such as altermagnets and odd-parity magnets. More broadly, our work provides a basis for studying superconductivity and other collective electronic phenomena that are impacted by SOC-induced band splittings in noncentrosymmetric materials.

cond-mat.mtrl-sci

Observation of mirror-odd and mirror-even spin texture in ultrathin epitaxially strained RuO2 films

Recently, rutile ruthenium dioxide (RuO$_2$) has attracted renewed interest due to expectations of prominent altermagnetic spin splitting. However, accumulating experimental evidence suggests that, in its bulk and thick-film forms, RuO$_2$ does not display any form of magnetic ordering. Despite this, the spin structure of RuO$_2$ remains largely unexplored in the ultrathin limit, where substrate-imposed epitaxial strain can be substantial. Here, we use spin-resolved angle-resolved photoemission spectroscopy, supported by ab initio calculations, to reveal the electronic structure of 2-nanometer-thick epitaxial RuO$_2$ heterostructures. We observe an unconventional spin texture characterized by the coexistence of mirror-even and mirror-odd momentum-dependent components. A comprehensive symmetry analysis rules out nonmagnetic origins of this spin texture. These findings suggest an emergent nonrelativistic spin structure enabled by epitaxial strain in the ultrathin limit, marking a distinct departure from the behavior of relaxed or bulk RuO$_2$. Our work opens previously unexplored perspectives for exploring symmetry-breaking mechanisms and spin textures in oxide heterostructures.

cond-mat.mtrl-sci

Probing multipolar order in the candidate altermagnet MnF$_2$ through the elastocaloric effect under strain

Altermagnets break a combination of time-reversal and rotational symmetries without generating a net magnetization. As such, the order parameter of $d$-wave altermagnets has the same symmetry as magnetic multipoles, and couples to the product of a magnetic field and uniaxial strain. We combine elastocaloric experiments, free-energy modeling, and first-principles calculations on MnF$_2$ to establish a thermodynamic probe of the predicted finite-temperature altermagnetic critical point. These results pave the way to explore altermagnetic quantum criticality in $d$-wave materials and beyond.

cond-mat.str-el

Anomalous Hall viscosity of altermagnets

We show that the phonon Hall viscosity at zero magnetic field is a natural probe of altermagnetism. First, we demonstrate that the finite elements of the Hall viscosity tensor unambiguously distinguish altermagnets from ferromagnets and conventional antiferromagnets. We then microscopically compute the Hall viscosity in models for d-wave and g-wave altermagnets, and find a strong sensitivity to electronic spectrum features such as gapped Dirac points and Lifshitz transitions. This sensitivity reflects a strain-space Berry curvature monopole, which contrast to the multipolar character of the standard momentum-space Berry curvature in altermagnets. Since the Hall viscosity can be probed experimentally through magneto-acoustic measurements, it provides a compelling method to probe the broken symmetries and topology of insulating altermagnets.

cond-mat.mes-hall

All-In-All-Out Pyrochlore Iridates as Noncollinear Spin-Orbit Coupled Counterparts of Altermagnets

Altermagnets are collinear magnetically ordered states that exhibit momentum-dependent spin splitting in the absence of net magnetization and spin-orbit coupling (SOC). Related spin-splitting patterns, however, can also emerge in noncollinear magnetic systems with large SOC. Here we show, via a microscopic model, that the all-in-all-out (AIAO) state in pyrochlore iridates constitutes a noncollinear counterpart of a $d$-wave altermagnet stabilized by strong SOC. Starting from a microscopic $j_{\mathrm{eff}} = 1/2$ tight-binding model on the pyrochlore lattice, we demonstrate that electronic interactions favor the AIAO phase and analyze its symmetry properties. We show that the AIAO order parameter transforms as an $A_{2g}^{-}$ octupolar magnetic moment, breaking time-reversal symmetry while preserving inversion and zero net magnetization. Using group-theory analysis and mean-field calculations, we demonstrate that this symmetry enforces both a spin-polarized momentum-dependent lifting of band degeneracies that is similar to that of a collinear $d$-wave cubic altermagnet, but also a band splitting at zero-momentum. We show that the latter feature is captured by a low-energy model similar to the Luttinger-Kohn model for cubic semiconductors. Our results identify pyrochlore iridates as a platform for noncollinear counterparts of altermagnetism and provide a general symmetry framework for spin-split phenomena in spin-orbit coupled materials.

cond-mat.str-el

Orbital altermagnetism on the kagome lattice and possible application to $A$V$_3$Sb$_5$

Altermagnets, which encompass a broad landscape of materials, are compensated collinear magnetic phases in which the antiparallel magnetic moments are related by a crystalline rotation. Here, we argue that collinear altermagnetic-like states can also be realized in lattices with an odd number of sublattices, provided that the electronic interactions promote non-uniform magnetic moments. We demonstrate this idea for a kagome metal whose band filling places the Fermi level close to the van Hove singularity. Combining phenomenological and microscopic modeling, we show that the intertwined charge density-wave and loop-current instabilities of this model lead to a wide parameter range in which orbital ferromagnetic, antiferromagnetic, and altermagnetic phases emerge inside the charge-ordered state. In the presence of spin-orbit coupling, their electronic structures display the usual spin-split fingerprints associated with the three types of collinear magnetic order. We discuss the possible realization of orbital altermagnetic phases in the $A$V$_3$Sb$_5$ family of kagome metals.

cond-mat.str-el

Superconductivity in kagome metals due to soft loop-current fluctuations

We demonstrate that soft fluctuations of translation symmetry-breaking loop currents provide a mechanism for unconventional superconductivity in kagome metals that naturally addresses the multiple superconducting phases observed under pressure. Focusing on the rich multi-orbital character of these systems, we show that loop currents involving both vanadium and antimony orbitals generate low-energy collective modes that couple efficiently to electrons near the Fermi surface and mediate attractive interactions in two distinct unconventional pairing channels. While loop-current fluctuations confined to vanadium orbitals favor chiral $d+id$ superconductivity, which spontaneously breaks time-reversal symmetry, the inclusion of antimony orbitals stabilizes an $s^{\pm}$ state that is robust against disorder. We argue that these two states are realized experimentally as pressure increases and the antimony-dominated Fermi surface sheet undergoes a Lifshitz transition.

cond-mat.supr-con

Unbiased large-$N$ approach to competing vestigial orders of density-wave and superconducting instabilities

When a primary order breaks multiple symmetries, partially ordered phases that only break a subset of those symmetries, known as vestigial phases, may onset at a higher temperature. This concept has been applied to a wide range of systems, including iron pnictides, cuprates, van der Waals antiferromagnets, doped topological insulators, and twisted bilayer graphene. In general, a multi-component primary order parameter (OP) supports multiple vestigial channels, each described by a quadratic (or higher-order) composite OP. However, the standard large-$N$ approach to the Ginzburg-Landau action of the primary OP has an intrinsic ambiguity in how one decouples the composite OPs, leading to situations in which one can seemingly enhance or eliminate altogether any vestigial instability. Here, we show that this ambiguity is a direct consequence of redundancy relations, such as Fierz identities, that relate different composite OPs, reflecting the fact that different vestigial channels interfere with each other and thus cannot be treated separately. To resolve this ambiguity, we propose an unbiased large-$N$ approach that respects both the redundancy relations and the underlying symmetry-group structure, and that gives unique values for the effective interactions of all vestigial channels. Our analysis reveals the generic existence of regions in the parameter space of quartic Landau coefficients where no vestigial order is stable, in contrast to the standard large-$N$ approach, but in agreement with weak-coupling and variational approaches. We illustrate our results by analyzing the vestigial orders of charge-density waves, spin-density waves, and multi-component superconductors in tetragonal, hexagonal, and cubic systems, respectively, revealing the presence of exotic vestigial phases describing spin-quadrupolar, charge-$4e$ superconducting, and altermagnetic orders.

cond-mat.str-el

Compatible Instability: Gauge Constraints of Elasticity Inherited by Electronic Nematic Criticality

Electronic nematicity is widely observed in quantum materials with varying degrees of electronic correlation, manifesting through charge, spin, orbital, or superconducting degrees of freedom. A phenomenological model capable of describing this broad set of systems must also account for nemato-elasticity, by which nematic and elastic degrees of freedom become intertwined. However, being a tensor gauge field theory, elasticity must satisfy the compatibility relations which guarantee the integrability of lattice deformations. Here, we develop a formalism for nemato-elasticity that manifestly respects the elastic compatibility relations. We show that these constraints bifurcate the phase space of nematic fluctuations into two orthogonal sectors: one compatible and thus critical, the other incompatible and therefore gapped. The suppression of the latter leads to universal direction-selective nematic criticality in any crystal lattice. Moreover, the critical nematic modes are protected from pinning effects induced by microscopic defect strains, which necessarily induce both longitudinal and transverse correlated random fields. Finally, our results also reconcile seemingly contradictory nematic phenomena, such as the mean-field character of the nematic transition and the widespread presence of domain formation.

cond-mat.str-el

Topological surface states revealed by the Zeeman effect in superconducting UTe2

Intrinsic topological superconductors with protected boundary modes obeying non-Abelian statistics constitute a vanishingly small class of quantum materials. A defining spectroscopic signature of such phases is the presence of in-gap topological surface states (TSS). However, despite extensive theoretical proposals, their unambiguous experimental identification has remained elusive. Here we use vector magnetic-field scanning tunnelling microscopy to obtain direct spectroscopic evidence of TSS in the spin-triplet superconductor UTe2. Atomic-scale spectroscopy reveals striking site-dependent superconductivity: Te sites host a large in-gap density of states that nearly fills the superconducting gap, whereas neighboring atomic sites remain gapped. Upon application of a magnetic field, the in-gap states on the Te sites are selectively suppressed, yielding a spatially homogeneous superconducting state with a markedly deeper gap relative to zero field. This site-selective gap evolution is in quantitative agreement with theoretical predictions for TSS in UTe2 that possess dominant Te-orbital character. Spectral-function calculations incorporating the Zeeman coupling reproduce the observed magnetic-field response. Our results provide a spectroscopic fingerprint of the long-sought TSS in superconductors and establish UTe2 as a compelling system for exploring intrinsic topological superconductivity.

cond-mat.supr-con

Evidence for ferroaxial order in 1T-TiSe$_2$ via elastoresistivity measurements

The study of spontaneous symmetry breaking and electronic order is fundamental in condensed matter physics. Hidden order, symmetry-breaking states that elude conventional probes, potentially plays a crucial role in understanding complex quantum phases in a wide range of materials. Ferroaxial order, a state characterized by broken mirror symmetries while maintaining time-reversal and inversion symmetries, is one of the hidden orders that have proven most challenging to detect experimentally. Here, we demonstrate a new approach for investigating both the ferroaxial order parameter and ferroaxial susceptibility using elastoresistivity measurements. We do this for 1T-TiSe$_{2}$, a material that exhibits charge density wave order that has eluded comprehensive understanding for a long time. These measurements reveal an anomalous off-diagonal linear elastoresistivity in the CDW state. We discuss why this provides a smoking gun for ferroaxial order. Furthermore, we construct an appropriate combination of the symmetry-breaking strains $ε_{x^2-y^2}$ and $ε_{xy}$ that acts as an effective conjugate field for the ferroaxial order, and demonstrate how sweeping this effective field in the CDW state results in a hysteretic behavior of the elastoresistivity, associated with the movement of ferroaxial domain walls. Finally, we reveal a divergence of certain nonlinear elastoresistivity coefficients above the critical temperature, and discuss how this is consistent with a divergence of the ferroaxial susceptibility near T$_{\rm{CDW}}$ $\sim$ 200K. Our study also includes detailed elastocaloric measurements, which reveal the presence of an additional phase transition several tens of Kelvin below T$_{\rm{CDW}}$. Our results provide new insight into the symmetry of the ordered state in 1T-TiSe$_2$ and establish elastoresistivity as a powerful probe of hidden order and its symmetry.

cond-mat.str-el

Ferroaxial and nematic transitions in the charge density wave phase of 1T-TiSe$_2$

Charge density waves (CDWs) with multi-component order parameters can break unexpected symmetries through the interplay of nearly degenerate instabilities. In the widely investigated material 1T-TiSe$_2$, a central question is whether the observed CDW has a chiral character, which would manifest as the spontaneous breaking of mirror and inversion symmetries. Previous experiments have reported conflicting results about the broken symmetries in the CDW phase of 1T-TiSe$_2$. Here, we resolve this controversy by identifying the bulk broken symmetry as ferroaxial, corresponding to the breaking of vertical mirrors while preserving inversion symmetry. Using symmetry-resolved elastoresistivity, we detect the spontaneous emergence of intrinsic off-diagonal elastoresistivity coefficients that satisfy an antisymmetric relation ($m_{xx-yy,xy} \approx -m_{xy,xx-yy}$), providing an unambiguous bulk transport signature of a macroscopic electric toroidal moment. Simultaneous elastocaloric measurements reveal that the onset of ferroaxial order occurs just below the CDW transition. As the temperature is lowered further, a diverging nematic susceptibility signals a distinct rotational symmetry-breaking instability inside the ferroaxial CDW state. Our findings demonstrate that the proposed ``chiral'' CDW in 1T-TiSe$_2$ is actually a centrosymmetric ferroaxial state, reconciling previous surface-sensitive observations with bulk symmetry constraints.

cond-mat.str-el

Microscopic origin of the nemato-elastic coupling and dynamics of hybridized collective nematic-phonon excitations

Electronically-driven nematic order breaks the rotational symmetry of a system, e.g., through a Pomeranchuk instability of the Fermi surface, with a concomitant distortion of the lattice. As a result, in a metal, the nematic collective mode interacts with two different sets of gapless excitations: the particle-hole excitations of the metal and the lattice fluctuations that become soft at the induced structural transition, namely, the transverse acoustic phonons. However, the \textit{dynamics} of these hybridized collective modes formed by the transverse acoustic phonons and the metallic electronic-nematic fluctuations has remained largely unexplored. Here we address this problem by developing a formalism in which the nemato-elastic coupling is obtained microscopically from the direct coupling between electrons and transverse acoustic phonons enabled by impurities present in the crystal. We then demonstrate the emergence of hybrid nemato-elastic modes that mix the characteristics of the transverse phonons and of the nematic fluctuations. Near the nematic quantum critical point in a metal, two massless modes emerge with intertwined dynamic behaviors, implying that neither mode dominates the response of the system. We systematically study the non-trivial dependence of these collective modes on the longitudinal and transverse momenta, revealing a rich landscape of underdamped and overdamped modes as the proximity to the quantum critical point and the strength of the electron-phonon coupling are changed. Since dynamics play an important role for determining superconducting instabilities, our results have implications for the study of pairing mediated by electronic nematic fluctuations.

cond-mat.str-el

Strain-tunable anomalous Hall effect in hexagonal MnTe

The ability to control and manipulate time-reversal ($T$) symmetry-breaking phases with near-zero net magnetization is a sought-after goal in spintronic devices. The recently discovered hexagonal altermagnet manganese telluride ($α$-MnTe) is a prime example. It has a compensated altermagnetic ground state where the magnetic moments are aligned in each layer and stacked antiparallel along the $c$ axis, yet it exhibits a spontaneous anomalous Hall effect (AHE) that breaks the $T$-symmetry with a vanishingly small $c$-axis ferromagnetic (FM) moment. However, the presence of three 120$^\circ$ separated in-plane magnetic domains presents a challenge in understanding the origin of the AHE and the effective control of the altermagnetic state. Here we use neutron scattering to show that symmetry breaking anisotropic strain, induced by compressive uniaxial pressure along the nearest-neighbor (NN) Mn-Mn bond directions, detwins $α$-MnTe into a single in-plane magnetic domain. This control over in-plane domains allows us to unambiguously establish that the in-plane moments are aligned along the NNN Mn-Mn bond direction, irrespective of the applied strain directions. Mounting the sample on a piezoelectric strain cell along both NN and NNN directions can drive the sample into a single-domain state that significantly sharpens the AHE hysteresis loop and extends the AHE to lower temperatures. Furthermore, tuning the uniaxial strain reverses the sign of the AHE near room temperature. Remarkably, this is achieved without altering the altermagnetic phase-transition temperature or substantially changing the small $c$-axis FM moment. Combined with our phenomenological model, we argue that these effects result from the modification of the electronic Berry curvature by a combination of both spin-orbit coupling and strain. (See the full abstract in the PDF.)

cond-mat.str-el

Superconducting States and Intertwined Orders in Metallic Altermagnets

Altermagnets are a newly identified class of magnets with nodal spin-split band structures, providing a fertile platform for studying unconventional superconductivity and intertwined orders. Here we investigate multicomponent superconductivity and fluctuation-induced intertwined orders in an interacting $d$-wave metallic altermagnet that is invariant under a combination of a fourfold rotation $C_4$ and time-reversal symmetry $T$. Within mean-field theory, the superconducting ground-state manifold is described in terms of two equal-spin two-component $p$-wave gap functions $(Δ_A^x,Δ_B^y)$ and $(Δ_A^y,Δ_B^x)$, where $A$ and $B$ refer to the two spin-polarized Fermi surfaces related by $C_4T$ symmetry. Because these two sets of gap functions condense at different temperatures, a rich phase diagram with multiple superconducting phase transitions emerges. Distinct fluctuations of sub-leading normal-state instabilities that compete with altermagnetism lift the degeneracy of the multicomponent pairing state in different ways. While nematic fluctuations enhance competition between distinct superconducting components and stabilize nematic superconducting phases, spin current-loop fluctuations promote coexistence and select a pair of chiral states. Our results uncover the pairing structure and elucidate how intertwined sub-leading fluctuations shape superconducting order in altermagnetic metals, suggesting a route toward realizing nematic and topological superconductivity.

cond-mat.supr-con

Theory of Electronic Nematic Criticality Constrained by Elastic Compatibility

The defining property of electronic nematicity -- the spontaneous breaking of rotational symmetry -- implies an unavoidable coupling between the nematic order parameter and elastic strain fields, known as nemato-elasticity. While both quantities are rank-2 tensors, the strain tensor is constrained through the Saint Venant compatibility relations. These three coupled second-order partial differential equations arise from the lattice displacement vector's role as a potential field, and they reflect the underlying gauge invariance of geometric deformations which are violated only in the presence of crystalline defects. In this work, we develop a theory of nemato-elasticity that incorporates elastic compatibility explicitly through a co-rotating helical basis. With our formalism, we show elasticity bestows tensor compatibility upon the nematic order parameter by suppressing incompatible nematic fluctuations. As a result, nemato-elasticity is markedly different from bare nematicity. In ideal media devoid of defects, we show the suppression of incompatible nematicity underlies direction-selective criticality, even in the absence of crystalline anisotropy. In systems with defects, meanwhile, we show that elastic pinning fields emanate from quenched defects, generating random longitudinal and transverse conjugate fields for the local nematic order parameter. The coexistence of direction-selective nematic criticality with pinning effects from random fields is explained within our theory from the transformation to the helical basis, implying that local experimental probes of nematicity will be influenced by a linear -- but nonlocal -- combination of long-ranged and short-ranged helical nematic modes. Because the compatibility relations are gauge constraints endowed in the isotropic medium, our results constitute universal features of nemato-elastic criticality present in all crystalline systems.

cond-mat.str-el

Magnetic field-induced momentum-dependent symmetry breaking in a kagome superconductor

When multiple degrees of freedom share similar energy scales in quantum materials, intertwined electronic orders, which exhibit broken symmetries, are often strongly coupled. Recent studies on kagome superconductors such as CsV$_3$Sb$_5$ report rotational and time-reversal symmetry breaking linked to a charge density wave. Here, we observe a momentum-selective response of the electronic structure of CsV$_3$Sb$_5$ to an external magnetic field. By performing angle-resolved photoemission spectroscopy in a tuneable magnetic field, we demonstrate that the response of the electronic structure is compatible with piezomagnetism along with strong orbital selectivity. Our results show that the origin of the time-reversal symmetry breaking is associated with the vanadium Van Hove singularities at the onset of the charge density wave order. We also demonstrate the presence of fluctuations beyond the charge ordering temperature. Our results reveal that magnetic fields can be used as tuning knobs for disentangling intertwined orders in the momentum space for quantum materials.

cond-mat.str-el