arXiv subjects

Robert J Cava

Publications and source records attributed to Robert J Cava.

12 recordsLinked to original sources

arXiv2025

van der Waals Nanoreactors

Advancing the chemical synthesis of crystals is important for both fundamental research and practical applications of quantum materials. While established bulk-phase and thin-film growth methods have enabled enormous progress, synthesizing single crystals suitable for quantum electronic discoveries remains challenging for many emerging materials. Here, we introduce van der Waals (vdW) stacks as nanochemical reactors for single-crystal synthesis and demonstrate their broad applicability in growing both elemental and compound crystals at the micrometer scale. By encapsulating atomically thin reactants that are stacked compactly with inert vdW layers such as hexagonal boron nitride (hBN), we achieve nanoconfined synthesis with the resulting crystals remaining encapsulated. As proof of concept, we synthesized isolated single crystals of elemental tellurium and distinct types of Pd-Te compounds. Structural characterization, including atomic-resolution scanning transmission electron microscopy, confirms the high crystalline quality of the products. We confirm the intrinsic semiconducting gap of tellurium and observe that non-stoichiometric PdTe1-x with a significantly reduced Te content (x ~ 0.18, a regime not previously achieved) retains uniform crystallinity and exhibits superconductivity below a critical temperature of 3.8 K. This nanochemical synthesis is broadly generalizable, chip-integrable, well-suited to a wide range of processing conditions, and compatible with nanofabrication routines for constructing devices. The concept of vdW nanoreactors offers a powerful and versatile pathway to expand the accessible landscape of quantum materials.

cond-mat.mtrl-sci↗

arXiv2023

The breakdown of both strange metal and superconducting states at a pressure-induced quantum critical point in iron-pnictide superconductors

The strange metal (SM) state, characterized by a linear-in-temperature resistivity, is often seen in the normal state of high temperature superconductors. It is believed that the SM state is one of the keys to understand the underlying mechanism of high-Tc superconductivity. Here we report the first observation of the concurrent breakdown of the SM normal state and superconductivity at a pressure-induced quantum critical point in an iron-pnictide superconductor, Ca10(Pt4As8)((Fe0.97Pt0.03)2As2)5. We find that, upon suppressing the superconducting state by applying pressure, the power exponent changes from 1 to 2, and the corresponding coefficient A, the slope of the temperature-linear resistivity per FeAs layer, gradually diminishes. At a critical pressure (12.5 GPa), A and Tc go to zero concurrently,where a quantum phase transition (QPT) from a superconducting state with a SM normal state to a non-superconducting Fermi liquid state takes place. Scaling analysis on the results obtained from the pressurized 1048 superconductor reveals that A and Tc have a positive relation, which exhibits a similarity with that is seen in other chemically-doped unconventional superconductors, regardless of the type of the tuning method (doping or pressurizing), the crystal structure, the bulk or film superconductors and the nature of dopant. These results suggest that there is a simple but powerful organizational principle of connecting the SM normal state with the high-Tc superconductivity.

cond-mat.supr-con↗

arXiv2022

Observation of three superconducting transitions in the pressurized CDW-bearing compound TaTe2

Transition metal dichalcogenides host a wide variety of lattice and electronic structures, as well as corresponding exotic physical properties, especially under certain tuning conditions. Here, we are the first to report the observation of pressure-induced three superconducting transitions in TaTe2, a charge density wave (CDW) - bearing layered transition-metal dichalcogenide that is metallic but not superconducting at ambient pressure. We find that its CDW state can be easily suppressed upon increasing pressure up to ~ 1 GPa. A superconducting state then emerges from the suppressed CDW state and persists to the pressure about 7 GPa. Unexpectedly, another superconducting state appears at ~ 11 GPa within the same monoclinic (M) structure of its ambient-pressure one. Upon further compression to 21 GPa, a third superconducting state with higher Tc appears from a high-pressure (HP) phase. Our experimental results suggest that the pressure-induced three superconducting transitions in TaTe2 are respectively driven by the suppression of the CDW state, the change of the angle in the M phase and the transition of M-to-HP phase. These results demonstrate not only the versatile nature of this correlated electron system, but also the first experimental example that shows the pressure-induced evolution from a CDW state to three superconducting states driven by different mechanisms.

cond-mat.supr-con↗

arXiv2021

Erbium-Implanted Materials for Quantum Communication Applications

Erbium-doped materials can serve as spin-photon interfaces with optical transitions in the telecom C-band, making them an exciting class of materials for long-distance quantum communication. However, the spin and optical coherence times of Er3+ ions are limited by currently available host materials, motivating the development of new Er3+-containing materials. Here, we demonstrate the use of ion implantation to efficiently screen prospective host candidates, and show that disorder introduced by ion implantation can be mitigated through post-implantation thermal processing to achieve inhomogeneous linewidths comparable to bulk linewidths in as-grown samples. We present optical spectroscopy data for each host material, which allows us to determine the level structure of each site, allowing us to compare the environments of Er3+ introduced via implantation and via doping during growth. We demonstrate that implantation can generate a range of local environments for Er3+, including those observed in bulk-doped materials, and that the populations of these sites can be controlled with thermal processing.

cond-mat.mtrl-sci↗

arXiv2019

Record-High Superconductivity in Niobium-Titanium Alloy

Here we report the observation of extraordinary superconductivity in a pressurized commercial niobium-titanium alloy. We find that its zero-resistance superconductivity persists from ambient pressure to the pressure as high as 261.7 GPa, a record high pressure up to which a known superconducting state can continuously survives. Remarkably, at such an ultra-high pressure, although the ambient pressure volume is shrunk by 45% without structural phase transition, the superconducting transition temperature (TC) increases to ~19.1 K from ~9.6 K, and the critical magnetic field (HC2) at 1.8 K has been enhanced to 19 T from 15.4 T. These results set new records for both of the TC and the HC2 among all the known alloy superconductors composed of only transition metal elements. The remarkable high pressure superconducting properties observed in the NbTi alloy not only expand our knowledge on this important commercial superconductor but also are helpful for a better understanding on the superconducting mechanism.

cond-mat.supr-con↗

arXiv2018

Universal superconductivity phase diagram for pressurized tetradymite topological insulators

We show that two different superconducting phases exist at high pressures in the optimized tetradymite topological insulators Bi2Te2Se (BTS) and Bi1.1Sb0.9Te2S (BSTS). The superconducting phases emerge at structural phase transitions, the first at 8.4 GPa for BTS and 12.4 GPa for BSTS, and the second at 13.6 GPa for BTS and 20.4 GPa, for BSTS. Electronic structure calculations show that these phases do not have topological character. Comparison of our results with prior work on Bi2Se3, Bi2Te3 and (Bi,Sb)2(Se,Te)3 allows us to uncover a universal phase diagram for pressure-induced superconductivity in tetradymites, providing a basis for understanding the relationships between topological behavior, crystal structure, and superconductivity for these materials.

cond-mat.supr-con↗

arXiv2018

Independence of topological surface state and bulk conductances in three-dimensional topological insulators

The archetypical 3D topological insulators Bi2Se3, Bi2Te3 and Sb2Te3 commonly exhibit high bulk conductivities, hindering the characterization of the surface state charge transport. The optimally doped topological insulators Bi2Te2Se and Bi2-xSbxTe2S, however, allow for such characterizations to be made. Here we report the first experimental comparison of the topological surface states and bulk conductances of Bi2Te2Se and Bi1.1Sb0.9Te2S, based on temperature-dependent high-pressure measurements. We find that the surface state conductance at low temperatures remains constant in the face of orders of magnitude increase in the bulk state conductance, revealing in a straightforward way that the topological surface states and bulk states are decoupled at low temperatures, consistent with theoretical models, and confirming topological insulators to be an excellent venue for studying charge transport in 2D Dirac electron systems.

cond-mat.str-el↗

arXiv2017

Pressure-induced melting of magnetic order and emergence of new quantum state in alpha-RuCl3

Here we report the observation of pressure-induced melting of antiferromagnetic (AFM) order and emergence of a new quantum state in the honeycomb-lattice halide alpha-RuCl3, a candidate compound in the proximity of quantum spin liquid state. Our high-pressure heat capacity measurements demonstrate that the AFM order smoothly melts away at a critical pressure (Pc) of 0.7 GPa. Intriguingly, the AFM transition temperature displays an increase upon applying pressure below the Pc, in stark contrast to usual phase diagrams, for example in pressurized parent compounds of unconventional superconductors. Furthermore, in the high-pressure phase an unusual steady of magnetoresistance is observed. These observations suggest that the high-pressure phase is in an exotic gapped quantum state which is robust against pressure up to ~140 GPa.

cond-mat.str-el↗

arXiv2017

Zero resistance from one atmosphere to the pressure of earth's outer core in a superconducting high entropy alloy

We report the observation of extraordinarily robust zero-resistance superconductivity in the pressurized (TaNb)0.67(HfZrTi)0.33 high entropy alloy - a new kind of material with a body-centered cubic crystal structure made from five randomly distributed transition metal elements. The transition to superconductivity (TC) increases from an initial temperature of 7.7 K at ambient pressure to 10 K at ~ 60 GPa, and then slowly decreases to 9 K by 190.6 GPa, a pressure that falls within that of the outer core of the earth. We infer that the continuous existence of the zero-resistance superconductivity from one atmosphere up to such a high pressure requires a special combination of electronic and mechanical characteristics. This high entropy alloy superconductor thus may have a bright future for applications under extreme conditions, and also poses a challenge for understanding the underlying quantum physics.

cond-mat.supr-con↗

arXiv2016

Pressuring the low-temperature orthorhombic phase with a non-trivial topological state of Ru2Sn3 to room temperature

We report high pressure studies of the structural stability of Ru2Sn3, a new type of three dimensional topological insulator (3D-TI) with unique quasi-one dimensional Dirac electron states throughout the surface Brillouin zone of its one-atmosphere low temperature orthorhombic form. Our in-situ high-pressure synchrotron x-ray diffraction and electrical resistance measurements reveal that upon increasing pressure the tetragonal to orthorhombic shifts to higher temperature. We find that the stability of the orthorhombic phase that hosts the non-trivial topological ground state can be pushed up to room temperature by an applied pressure of ~ 20 GPa. This is in contrast to the commonly known 3D-TIs whose ground state is usually destroyed under pressure. Our results indicate that pressure provides a possible pathway for realizing a room-temperature topological insulating state in Ru2Sn3.

cond-mat.str-el↗

arXiv2016

The vital role of hole-carriers for superconductivity in pressurized black phosphorus

The influence of carrier type on superconductivity has been an important issue for understanding both conventional and unconventional superconductors [1-7]. For elements that superconduct, it is known that hole-carriers govern the superconductivity for transition and main group metals [8-10]. The role of hole-carriers in elements that are not normally conducting but can be converted to superconductors, however, remains unclear due to the lack of experimental data. Here we report the first in-situ high pressure Hall effect measurements on single crystal black phosphorus, measured up to ~ 50 GPa, and find a correlation between the Hall coefficient and the superconducting transition temperature (TC). Our results reveal that hole-carriers play a vital role in developing superconductivity and enhancing TC. Importantly, we also find a Lifshitz transition in the high-pressure cubic phase at ~17.2GPa, which uncovers the origin of a puzzling valley in the superconducting TC-pressure phase diagram. These results offer insight into the role of hole-carriers in developing superconductivity in simple semiconducting solids under pressure.

cond-mat.supr-con↗

arXiv2014

Evidence for SrHo2O4 and SrDy2O4 as model J1-J2 zig-zag chain materials

Neutron diffraction and inelastic spectroscopy is used to characterize the magnetic Hamiltonian of SrHo2O4 and SrDy2O4. Through a detailed computation of the crystal-field levels we find site- dependent anisotropic single-ion magnetism in both materials and diffraction measurements show the presence of strong one-dimensional spin correlations. Our measurements indicate that competing interactions of the zig-zag chain, combined with frustrated interchain interactions, play a crucial role in stabilizing spin-liquid type correlations in this series.

cond-mat.str-el↗