arXiv subjects

Ryan J. MacDonald

Publications and source records attributed to Ryan J. MacDonald.

83 records · Page 5Linked to original sources

arXiv2020

Evidence of a Clear Atmosphere for WASP-62b: the Only Known Transiting Gas Giant in the JWST Continuous Viewing Zone

Exoplanets with cloud-free, haze-free atmospheres at the pressures probed by transmission spectroscopy represent a valuable opportunity for detailed atmospheric characterization and precise chemical abundance constraints. We present the first optical to infrared (0.3-5 microns) transmission spectrum of the hot Jupiter WASP-62b, measured with Hubble/STIS and Spitzer/IRAC. The spectrum is characterized by a 5.1-sigma detection of Na I absorption at 0.59 microns, in which the pressure-broadened wings of the Na D-lines are observed from space for the first time. A spectral feature at 0.4 microns is tentatively attributed to SiH at 2.1-sigma confidence. Our retrieval analyses are consistent with a cloud-free atmosphere without significant contamination from stellar heterogeneities. We simulate James Webb Space Telescope (JWST) observations, for a combination of instrument modes, to assess the atmospheric characterization potential of WASP-62b. We demonstrate that JWST can conclusively detect Na, H2O, FeH, and SiH within the scope of its Early Release Science (ERS) program. As the only transiting giant planet currently known in the JWST Continuous Viewing Zone, WASP-62b could prove a benchmark giant exoplanet for detailed atmospheric characterization in the James Webb era.

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arXiv2020

Into the UV: The Atmosphere of the Hot Jupiter HAT-P-41b Revealed

For solar-system objects, ultraviolet spectroscopy has been critical in identifying sources for stratospheric heating and measuring the abundances of a variety of hydrocarbon and sulfur-bearing species, produced via photochemical mechanisms, as well as oxygen and ozone. To date, less than 20 exoplanets have been probed in this critical wavelength range (0.2-0.4 um). Here we use data from Hubble's newly implemented WFC3 UVIS G280 grism to probe the atmosphere of the hot Jupiter HAT-P-41b in the ultraviolet through optical in combination with observations at infrared wavelengths. We analyze and interpret HAT-P-41b's 0.2-5.0 um transmission spectrum using a broad range of methodologies including multiple treatments of data systematics as well as comparisons with atmospheric forward, cloud microphysical, and multiple atmospheric retrieval models. Although some analysis and interpretation methods favor the presence of clouds or potentially a combination of Na, VO, AlO, and CrH to explain the ultraviolet through optical portions of HAT-P-41b's transmission spectrum, we find that the presence of a significant H- opacity provides the most robust explanation. We obtain a constraint for the abundance of H-, log(H-) = -8.65 +/- 0.62 in HAT-P-41b's atmosphere, which is several orders of magnitude larger than predictions from equilibrium chemistry for a 1700 - 1950 K hot Jupiter. We show that a combination of photochemical and collisional processes on hot hydrogen-dominated exoplanets can readily supply the necessary amount of H- and suggest that such processes are at work in HAT-P-41b and many other hot Jupiter atmospheres.

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arXiv2020

The White Dwarf Opportunity: Robust Detections of Molecules in Earth-like Exoplanet Atmospheres with the James Webb Space Telescope

The near-term search for life beyond the solar system currently focuses on transiting planets orbiting small M dwarfs, and the challenges of detecting signs of life in their atmospheres. However, planets orbiting white dwarfs (WDs) would provide a unique opportunity to characterize rocky worlds. The discovery of the first transiting giant planet orbiting a white dwarf, WD 1856+534b, showed that planetary-mass objects can survive close-in orbits around WDs. The large radius ratio between WD planets and their host renders them exceptional targets for transmission spectroscopy. Here, we explore the molecular detectability and atmospheric characterization potential for a notional Earth-like planet, evolving in the habitable zone of WD 1856+534, with the James Webb Space Telescope (JWST). We establish that the atmospheric composition of such Earth-like planets orbiting WDs can be precisely retrieved with JWST. We demonstrate that robust > 5$σ$ detections of H$_2$O and CO$_2$ can be achieved in a 5 transit reconnaissance program, while the biosignatures O$_3$ + CH$_4$, and O$_3$ + N$_2$O can be detected to > 4$σ$ in as few as 25 transits. N$_2$ and O$_2$ can be detected to > 5$σ$ within 100 transits. Given the short transit duration of WD habitable zone planets (~ 2 minutes for WD 1856+534), conclusive molecular detections can be achieved in a small or medium JWST transmission spectroscopy program. Rocky planets in the WD habitable zone therefore represent a promising opportunity to characterize terrestrial planet atmospheres and explore the possibility of a second genesis on these worlds.

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arXiv2020

Why is it so Cold in Here?: Explaining the Cold Temperatures Retrieved from Transmission Spectra of Exoplanet Atmospheres

Transmission spectroscopy is a powerful technique widely used to probe exoplanet terminators. Atmospheric retrievals of transmission spectra are enabling comparative studies of exoplanet atmospheres. However, the atmospheric properties inferred by retrieval techniques display a significant anomaly: most retrieved temperatures are far colder than expected. In some cases, retrieved temperatures are ~1000 K colder than T_eq. Here, we provide an explanation for this conundrum. We demonstrate that erroneously cold temperatures result when 1D atmospheric models are applied to spectra of planets with differing morning-evening terminator compositions. Despite providing an acceptable fit, 1D retrieval techniques artificially tune atmospheric parameters away from terminator-averaged properties. Retrieved temperature profiles are hundreds of degrees cooler and have weaker temperature gradients than reality. Retrieved abundances are mostly biased by > 1$σ$ and sometimes by > 3$σ$, with the most extreme biases for ultra-hot Jupiters. When morning-evening compositional differences manifest for prominent opacity sources, H$_2$O abundances retrieved by 1D models can be biased by over an order of magnitude. Finally, we demonstrate that these biases provide an explanation for the cold retrieved temperatures reported for WASP-17b and WASP-12b. To overcome biases associated with 1D atmospheric models, there is an urgent need to develop multidimensional retrieval techniques.

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arXiv2020

Understanding the atmospheric properties and chemical composition of the ultra-hot Jupiter HAT-P-7b II. Mapping the effects of gas kinetics

The atmospheres of ultra-hot Jupiters are commonly considered to be at thermochemical equilibrium. We aim to provide disequilibrium chemistry maps for a global understanding of the chemistry in HAT-P-7b's atmosphere and assess the importance of disequilibrium chemistry on UHJs. We apply a hierarchical modelling approach utilising 97 1D atmospheric profiles from 3D GCM of HAT-P-7b. For each 1D profile, we evaluate our kinetic cloud formation model consistently with the local gas-phase composition in chemical equilibrium. We then evaluate quenching results from a zeroth-order approximation in comparison to a kinetic gas-phase approach. We find that the zeroth-order approach of estimating quenching points agrees well with the full gas-kinetic modeling results. Chemical disequilibrium has the greatest effect on the nightside and morning abundance of species such as H, H$_2$O, CH$_4$, CO$_2$, HCN, and all C$_n$H$_m$ molecules; heavier C$_n$H$_m$ molecules are more affected by disequilibrium processes. CO abundance, however, is affected only marginally. While dayside abundances also notably change, those around the evening terminator of HAT-P-7b are the least affected by disequilibrium processes. The latter finding may partially explain the consistency of observed transmission spectra of UHJs with atmospheres in thermochemical equilibrium. Photochemistry only negligibly affects molecular abundances and quenching levels. In general, the quenching points of HAT-P-7b's atmosphere are at much lower pressures in comparison to the cooler hot-jupiters. We propose several avenues to look for the effect of disequilibrium processes on UHJs that are, in general, based on abundance and opacity measurements at different local times. It remains a challenge to completely disentangle this from the chemical effects of clouds and that of a primordial non-solar abundance.

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arXiv2019

The Metal-Rich Atmosphere of the Neptune HAT-P-26b

Transmission spectroscopy is enabling precise measurements of atmospheric H2O abundances for numerous giant exoplanets. For hot Jupiters, relating H2O abundances to metallicities provides a powerful probe of their formation conditions. However, metallicity measurements for Neptune-mass exoplanets are only now becoming viable. Exo-Neptunes are expected to possess super-solar metallicities from accretion of H2O-rich and solid-rich planetesimals. However, initial investigations into the exo-Neptune HAT-P-26b suggested a significantly lower metallicity than predicted by the core-accretion theory of planetary formation and solar system expectations from Uranus and Neptune. Here, we report an extensive atmospheric retrieval analysis of HAT-P-26b, combining all available observations, to reveal its composition, temperature structure, and cloud properties. Our analysis reveals an atmosphere containing 1.5(+2.1)(-0.9)% H2O, an O/H of 18.1(+25.9)(-11.3)x solar, and C/O < 0.33 (to 2$σ$). This updated metallicity, the most precise exo-Neptune metallicity reported to date, suggests a formation history with significant planetesimal accretion, albeit below that of Uranus and Neptune. We additionally report evidence for metal hydrides at 4.1$σ$ confidence. Potential candidates are identified as TiH (3.6$σ$), CrH (2.1$σ$), or ScH (1.8$σ$). Maintaining gas-phase metal hydrides at the derived temperature (~560 K) necessitates strong disequilibrium processes or external replenishment. Finally, we simulate the JWST Guaranteed Time Observations for HAT-P-26b. Assuming a composition consistent with current observations, we predict JWST can detect H2O (at 29$σ$), CH4 (6.2$σ$), CO2 (13$σ$), and CO (3.7$σ$), improving metallicity and C/O precision to 0.2 dex and 0.35 dex. Furthermore, NIRISS observations could detect several metal hydrides at >5$σ$ confidence.

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arXiv2018

H$_2$O abundances and cloud properties in ten hot giant exoplanets

Transmission spectroscopy of exoplanets has the potential to provide precise measurements of atmospheric chemical abundances, in particular of hot Jupiters whose large sizes and high temperatures make them conducive to such observations. To date, several transmission spectra of hot Jupiters have revealed low amplitude features of water vapour compared to expectations from cloud-free atmospheres of solar metallicity. The low spectral amplitudes in such atmospheres could either be due to the presence of aerosols that obscure part of the atmosphere or due to inherently low abundances of H$_2$O in the atmospheres. A recent survey of transmission spectra of ten hot Jupiters used empirical metrics to suggest atmospheres with a range of cloud/haze properties but with no evidence for H$_2$O depletion. Here, we conduct a detailed and homogeneous atmospheric retrieval analysis of the entire sample and report the H$_2$O abundances, cloud properties, terminator temperature profiles, and detection significances of the chemical species. Our present study finds that the majority of hot Jupiters have atmospheres consistent with sub-solar H$_2$O abundances at their day-night terminators. The best constrained abundances range from $\mathrm{log(H_2O)}$ of $-5.04^{+0.46}_{-0.30}$ to $-3.16^{+0.66}_{-0.69}$, which compared to expectations from solar-abundance equilibrium chemistry correspond to $0.018^{+0.035}_{-0.009}\times$ solar to $1.40^{+4.97}_{-1.11}\times$ solar. Besides H$_2$O we report statistical constraints on other chemical species and cloud/haze properties, including cloud/haze coverage fractions which range from $0.18^{+0.26}_{-0.12}$ to $0.76^{+0.13}_{-0.15}$. The retrieved H$_2$O abundances suggest sub-solar oxygen and/or super-solar C/O ratios, and can provide important constraints on the formation and migration pathways of hot giant exoplanets.

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arXiv2018

Exploring H$_2$O Prominence in Reflection Spectra of Cool Giant Planets

The H2O abundance of a planetary atmosphere is a powerful indicator of formation conditions. Inferring H2O in the solar system giant planets is challenging, due to condensation depleting the upper atmosphere of water vapour. Substantially warmer hot Jupiter exoplanets readily allow detections of H2O via transmission spectroscopy, but such signatures are often diminished by the presence of clouds made of other species. In contrast, highly scattering H2O clouds can brighten planets in reflected light, enhancing molecular signatures. Here, we present an extensive parameter space survey of the prominence of H2O absorption features in reflection spectra of cool (Teff<400K) giant exoplanetary atmospheres. The impact of effective temperature, gravity, metallicity, and sedimentation efficiency is explored. We find prominent H2O features around 0.94um, 0.83um, and across a wide spectral region from 0.4-0.73um. The 0.94um feature is only detectable where high-altitude water clouds brighten the planet: T~150K, g>~20m/s^2, fsed>~3, m<~10xsolar. In contrast, planets with g<~20m/s^2 and T>~180K display prominent H2O features embedded in the Rayleigh slope from 0.4-0.73um. High fsed enhances H2O features around 0.94um, and enables them to be detected at lower temperatures. High m results in dampened H2O absorption features, due to H2O vapour condensing to form bright optically thick clouds that dominate the continuum. We verify these trends via self-consistent modelling of the low gravity exoplanet HD 192310c, revealing that its reflection spectrum is expected to be dominated by H2O absorption from 0.4-0.73um for m<~10xsolar. Our results demonstrate that H2O is manifestly detectable in reflected light spectra of cool giant planets only marginally warmer than Jupiter, providing an avenue to directly constrain the C/O and O/H ratios of a hitherto unexplored population of exoplanetary atmospheres.

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arXiv2017

Signatures of Nitrogen Chemistry in Hot Jupiter Atmospheres

Inferences of molecular compositions of exoplanetary atmospheres have generally focused on C, H, and O-bearing molecules. Recently, additional absorption in HST WFC3 transmission spectra around 1.55$μ$m has been attributed to nitrogen-bearing chemical species: NH$_3$ or HCN. These species, if present in significant abundance, would be strong indicators of disequilibrium chemical processes -- e.g. vertical mixing and photochemistry. The derived N abundance, in turn, could also place important constraints on planetary formation mechanisms. Here, we examine the detectability of nitrogen chemistry in exoplanetary atmospheres. In addition to the WFC3 bandpass (1.1-1.7$μ$m), we find that observations in K-band at $\sim$2.2$μ$m, achievable with present ground-based telescopes, sample a strong NH$_3$ feature, whilst observations at $\sim$3.1$μ$m and $\sim$4.0$μ$m sample strong HCN features. In anticipation of such observations, we predict absorption feature amplitudes due to nitrogen chemistry in the 1-5$μ$m spectral range possible for a typical hot Jupiter. Finally, we conduct atmospheric retrievals of 9 hot Jupiter transmission spectra in search of near-infrared absorption features suggestive of nitrogen chemistry. We report weak detections of NH$_3$ in WASP-31b (2.2$σ$), HCN in WASP-63b (2.3$σ$), and excess absorption that could be attributed to NH$_3$ in HD 209458b. High-precision observations from 1-5$μ$m (e.g., with the James Webb Space Telescope), will enable definitive detections of nitrogen chemistry, in turn serving as powerful diagnostics of disequilibrium atmospheric chemistry and planetary formation processes.

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arXiv2017

Detection of titanium oxide in the atmosphere of a hot Jupiter

As an exoplanet transits its host star, some of the light from the star is absorbed by the atoms and molecules in the planet's atmosphere, causing the planet to seem bigger; plotting the planet's observed size as a function of the wavelength of the light produces a transmission spectrum. Measuring the tiny variations in the transmission spectrum, together with atmospheric modelling, then gives clues to the properties of the exoplanet's atmosphere. Chemical species composed of light elements$-$such as hydrogen, oxygen, carbon, sodium and potassium$-$have in this way been detected in the atmospheres of several hot giant exoplanets, but molecules composed of heavier elements have thus far proved elusive. Nonetheless, it has been predicted that metal oxides such as titanium oxide (TiO) and vanadium oxide occur in the observable regions of the very hottest exoplanetary atmospheres, causing thermal inversions on the dayside. Here we report the detection of TiO in the atmosphere of the hot-Jupiter planet WASP-19b. Our combined spectrum, with its wide spectral coverage, reveals the presence of TiO (to a confidence level of 7.7σ), a strongly scattering haze (7.4σ) and sodium (3.4σ), and confirms the presence of water (7.9σ) in the atmosphere.

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arXiv2017

HD 209458b in New Light: Evidence of Nitrogen Chemistry, Patchy Clouds and Sub-Solar Water

Interpretations of exoplanetary transmission spectra have been undermined by apparent obscuration due to clouds/hazes. Debate rages on whether weak H$_2$O features seen in exoplanet spectra are due to clouds or inherently depleted oxygen. Assertions of solar H$_2$O abundances have relied on making a priori model assumptions, e.g. chemical/radiative equilibrium. In this work, we attempt to address this problem with a new retrieval paradigm for transmission spectra. We introduce POSEIDON, a two-dimensional atmospheric retrieval algorithm including generalised inhomogeneous clouds. We demonstrate that this prescription allows one to break vital degeneracies between clouds and prominent molecular abundances. We apply POSEIDON to the best transmission spectrum presently available, for the hot Jupiter HD 209458b, uncovering new insights into its atmosphere at the day-night terminator. We extensively explore the parameter space with an unprecedented 10$^8$ models, spanning the continuum from fully cloudy to cloud-free atmospheres, in a fully Bayesian retrieval framework. We report the first detection of nitrogen chemistry (NH$_3$ and/or HCN) in an exoplanet atmosphere at 3.7-7.7$σ$ confidence, non-uniform cloud coverage at 4.5-5.4$σ$, high-altitude hazes at $>$3$σ$, and sub-solar H$_2$O at $\gtrsim$3-5$σ$, depending on the assumed cloud distribution. We detect NH$_3$ at 3.3$σ$ and 4.9$σ$ for fully cloudy and cloud-free scenarios, respectively. For the model with the highest Bayesian evidence, we constrain H$_2$O at 5-15 ppm (0.01-0.03$\times$ solar) and NH$_3$ at 0.01-2.7 ppm, strongly suggesting disequilibrium chemistry and cautioning against equilibrium assumptions. Our results herald new promise for retrieving cloudy atmospheres using high-precision HST and JWST spectra.

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