arXiv subjects

S. Aswartham

Publications and source records attributed to S. Aswartham.

At least 73 records · Page 4Linked to original sources

arXiv2015

Decoupling of the Antiferromagnetic and Insulating States in Tb doped Sr2IrO4

Sr2IrO4 is a spin-orbit coupled insulator with an antiferromagnetic (AFM) transition at TN=240 K. We report results of a comprehensive study of single-crystal Sr2Ir1-xTbxO4. This study found that mere 3% (x=0.03) tetravalent Tb4+(4f7) substituting for Ir4+ (rather than Sr2+) completely suppresses the long-range collinear AFM transition but retains the insulating state, leading to a phase diagram featuring a decoupling of magnetic interactions and charge gap. The insulating state at x=0.03 is characterized by an unusually large specific heat at low temperatures and an incommensurate magnetic state having magnetic peaks at (0.95, 0, 0) and (0, 0.95, 0) in the neutron diffraction, suggesting a spiral or spin density wave order. It is apparent that Tb doping effectively changes the relative strength of the SOI and the tetragonal CEF and enhances the Hund's rule coupling that competes with the SOI, and destabilizes the AFM state. However, the disappearance of the AFM accompanies no metallic state chiefly because an energy level mismatch for the Ir and Tb sites weakens charge carrier hopping and renders a persistent insulating state. This work highlights an unconventional correlation between the AFM and insulating states in which the magnetic transition plays no critical role in the formation of the charge gap in the iridate.

cond-mat.str-el↗

arXiv2015

Ground state tuning of the metal-insulator transition by compositional variations in BaIr1-xRuxO3(0<x<1)

BaIrO3 is a magnetic insulator driven by the spin-orbit interaction (SOI), whereas BaRuO3 is a paramagnet and exhibits a crossover from a metallic to an insulating regime. Our investigation of structural, magnetic, transport and thermal properties reveals that substitution of Ru4+ (4d4) ions for Ir5+ (5d5) ions in BaIrO3 reduces the magnitudes of the SOI and a monoclinic structural distortion, and rebalances the competition between the SOC and the lattice degrees freedom to generate a rich phase diagram for BaIr1-xRuxO3 (0< x <1). There are two major effects of Ru additions: (1) Light Ru doping (0 < x < 0.15) prompts simultaneous, precipitous drops in both the magnetic ordering temperature TN and the electrical resistivity, which exhibits a crossover behavior from a metallic to an insulating state near TN. (2) Heavier Ru doping (0.41< x < 0.9) induces a robust metallic state with a strong spin frustration generated by competing antiferromagnetic and ferromagnetic interactions.

cond-mat.str-el↗

arXiv2015

From Jeff=1/2 insulator to p-wave superconductor in single-crystal Sr2Ir1-xRuxO4 (0 < x< 1)

Sr2IrO4 is a magnetic insulator assisted by strong spin-orbit coupling (SOC) whereas the Sr2RuO4 is a p-wave superconductor. The contrasting ground states have been shown to result from the critical role of the strong SOC in the iridate. Our investigation of structural, transport, and magnetic properties reveals that substituting 4d Ru4+ (4d4) ions for 5d Ir4+(5d5) ions in Sr2IrO4 directly adds holes to the t2g bands, reduces the SOC and thus rebalances the competing energies in single-crystal Sr2Ir1-xRuxO4. A profound effect of Ru doping driving a rich phase diagram is a structural phase transition from a distorted I41/acd to a more ideal I4/mmm tetragonal structure near x=0.50 that accompanies a phase transition from an antiferromagnetic-insulating state to a paramagnetic-metal state. We also make a comparison drawn with Rh doped Sr2IrO4, highlighting important similarities and differences.

cond-mat.str-el↗

arXiv2015

Coexisting charge and magnetic orders in the dimer-chain iridate Ba5AlIr2O11

We have synthesized and studied single-crystal Ba5AlIr2O11 that features dimer chains of two inequivalent octahedra occupied by tetravalent and pentavalent ions, respectively. Ba5AlIr2O11 is a Mott insulator that undergoes a subtle structural phase transition near 210 K and a magnetic transition at 4.5 K; the latter transition is surprisingly resistant to applied magnetic fields up to 12 T, but sensitive to modest applied pressure. All results indicate that the phase transition at 210 K signals an enhanced charge order that induces electrical dipoles and strong dielectric response near 210 K. It is clear that the strong covalency and spin-orbit interaction (SOI) suppress double exchange in Ir dimers and stabilize a novel magnetic state. The behavior of Ba5AlIr2O11 therefore provides unique insights into the physics of SOI along with strong covalency in competition with double exchange interactions of comparable strength.

cond-mat.str-el↗

arXiv2015

Evolution of Magnetism in Single-Crystal Ca2Ru1-xIrxO4 (0< x <0.65)

We report structural, magnetic, transport and thermal properties of single-crystal Ca2Ru1-xIrxO4 (0 < x< 0.65). Ca2RuO4 is a structurally-driven Mott insulator with a metal-insulator transition at TMI = 357 K, which is well separated from antiferromagnetic order at TN = 110 K. Substitution of 5d element, Ir, for Ru enhances spin-orbit coupling (SOC) and locking between the structural distortions and magnetic moment canting. In particular, Ir doping intensifies the distortion or rotation of Ru/IrO6 octahedra and induces weak ferromagnetic behavior along the c-axis. Moreover, the magnetic ordering temperature TN increases from 110 K at x = 0 to 215 K with enhanced magnetic anisotropy at x = 0.65. The effect of Ir doping sharply contrasts with that of 3d-element doping such as Cr, Mn and Fe, which suppresses TN and induces unusual negative volume thermal expansion. The stark difference between 3d- and 5d-element doping underlines a strong magnetoelastic coupling inherent in the Ir-rich oxides.

cond-mat.str-el↗

arXiv2014

Lattice-Tuned Magnetism of Ru4+(4d4) Ions in Single-Crystals of the Layered Honeycomb Ruthenates: Li2RuO3 and Na2RuO3

We synthesize and study single crystals of the layered honeycomb lattice Mott insulators Na2RuO3 and Li2RuO3 with magnetic Ru4+(4d4) ions. The newly found Na2RuO3 features a nearly ideal honeycomb lattice and orders antiferromagnetically at 30 K. Single-crystals of Li2RuO3 adopt a honeycomb lattice with either C2/m or more distorted P21/m below 300 K, depending on detailed synthesis conditions. We find that Li2RuO3 in both structures hosts a well-defined magnetic state, in contrast to the singlet ground state found in polycrystalline Li2RuO3. A phase diagram generated based on our results uncovers a new, direct correlation between the magnetic ground state and basal-plane distortions in the honeycomb ruthenates.

cond-mat.str-el↗

arXiv2014

Superconducting properties of K$_{1-x}$Na$_x$Fe$_2$As$_2$ under pressure

The effect of hydrostatic pressure and partial Na substitution on the normal-state properties and the superconducting transition temperature ($T_c$) of K$_{1-x}$Na$_x$Fe$_2$As$_2$ single crystals were investigated. It was found that a partial Na substitution leads to a deviation from the standard $T^2$ Fermi-liquid behavior in the temperature dependence of the normal-state resistivity. It was demonstrated that non-Fermi liquid like behavior of the resistivity for K$_{1-x}$Na$_{x}$Fe$_2$As$_2$ and some KFe$_2$As$_2$ samples can be explained by disorder effect in the multiband system with rather different quasiparticle effective masses. Concerning the superconducting state our data support the presence of a shallow minimum around 2 GPa in the pressure dependence of $T_c$ for stoichiometric KFe$_2$As$_2$. The analysis of $T_c$ in the K$_{1-x}$Na$_{x}$Fe$_2$As$_2$ at pressures below 1.5 GPa showed, that the reduction of $T_c$ with Na substitution follows the Abrikosov-Gor'kov law with the critical temperature $T_{c0}$ of the clean system (without pair-breaking) which linearly depends on the pressure. Our observations, also, suggest that $T_c$ of K$_{1-x}$Na$_x$Fe$_2$As$_2$ is nearly independent of the lattice compression produced by the Na substitution. Further, we theoretically analyzed the behavior of the band structure under pressure within the generalized gradient approximation (GGA). A qualitative agreement between the calculated and the recently in de Haas-van Alphen experiments [T. Terashima et al., Phys.Rev.B89, 134520(2014)] measured pressure dependencies of the Fermi-surface cross-sections has been found. These calculations, also, indicate that the observed minimum around 2~GPa in the pressure dependence of $T_c$ may occur without a change of the pairing symmetry.

cond-mat.supr-con↗

arXiv2014

Josephson effect and Andreev reflection in Ba(1-x)NaxFe2As2 (x=0.25 and 0.35) point contacts

I(V) characteristics and their first derivatives of ScS and ScN-type (S-superconductor, c-constriction, N-normal metal) point-contacts (PCs) based on Ba{1-x}NaxFe2As2 ($x$=0.25 and 0.35) were studied. ScS-type PCs with S=Nb,Ta and Pb show Josephson-like resistively shunted I(V) curves with microwave induced Shapiro steps which satisfy relation 2eV=hw. The I_cR_N product (I_c-critical current, R_N-- normal state PC resistance) in these PCs is found to be up to 1.2mV. All this data with the observed dependence of the I_c on the microwave power of ScS PCs with Pb counterelectrode indicates the presence of the singlet s-wave type pairing in Ba(1-x)NaxFe2As2. From the dV/dI(V) curves of ScN-type PCs demonstrating Andreev-reflection like features, the superconducting gap ratio 2Δ/k_BT_c = 3.6 \pm 1 for the compound with x=0.35 was evaluated. Analysis of these dV/dI(V) at high biases V, that is well above Δ, testifies transition to the thermal regime in PCs with a voltage increase.

cond-mat.supr-con↗

arXiv2014

Single 20meV boson mode in KFe2As2 detected by point-contact spectroscopy

We report an experimental and theoretical investigation of the electron-boson interaction in KFe2As2 by point-contact (PC) spectroscopy, model, and ab-initio LDA-based calculations for the standard electron-phonon Eliashberg function. The PC spectrum viz. the second derivative of the I - V characteristic of representative PC exhibits a pronounced maximum at about 20meV and surprisingly a featureless behavior at lower and higher energies. We discuss phonon and non-phonon (excitonic) mechanisms for the origin of this peak. Analysis of the underlying source of this peak may be important for the understanding of serious puzzles of superconductivity in this type of compounds.

cond-mat.supr-con↗

arXiv2014

Spin reorientation in Na-doped BaFe$_2$As$_2$ studied by neutron diffraction

We have studied the magnetic ordering in Na doped BaFe$_2$As$_2$ by unpolarized and polarized neutron diffraction using single crystals. Unlike previously studied FeAs-based compounds that magnetically order, Ba$_{1-x}$Na$_x$Fe$_2$As$_2$ exhibits two successive magnetic transitions: For x=0.35 upon cooling magnetic order occurs at $\sim$70\ K with in-plane magnetic moments being arranged as in pure or Ni, Co and K-doped BaFe$_2$As$_2$ samples. At a temperature of $\sim$46\ K a second phase transition occurs, which the single-crystal neutron diffraction experiments can unambiguously identify as a spin reorientation. At low temperatures, the ordered magnetic moments in Ba$_{0.65}$Na$_{0.35}$Fe$_2$As$_2$ point along the $c$ direction. Magnetic correlations in these materials cannot be considered as Ising like, and spin-orbit coupling must be included in a quantitative theory.

cond-mat.supr-con↗

arXiv2014

Specific heat of K071Na0.29Fe2As2 at very low temperatures

A commercially available calorimeter has been used to investigate the specific heat of a high-quality \kn\ single crystal. The addenda heat capacity of the calorimeter is determined in the temperature range $0.02 \, \mathrm{K} \leq T \leq 0.54 \, \mathrm{K}$. The data of the \kn\ crystal imply the presence of a large $T^2$ contribution to the specific heat which gives evidence of $d$-wave order parameter symmetry in the superconducting state. To improve the measurements, a novel design for a calorimeter with a paramagnetic temperature sensor is presented. It promises a temperature resolution of $ΔT \approx 0.1 \, \mathrm{μK}$ and an addenda heat capacity less than $200 \, \mathrm{pJ/K}$ at $ T < 100 \, \mathrm{mK}$.

cond-mat.supr-con↗

arXiv2014

Superconducting specific heat jump $ΔC_{\rm el} \propto T_c^β\ (β\approx 2)$ for K$_{1-x}$Na$_x$Fe$_2$As$_2$

We present a systematic study of the electronic specific heat jump ($ΔC_{\rm el}$) at the superconducting transition temperature $T_c$ of K$_{1-x}$Na$_x$Fe$_2$As$_2$. Both $T_c$ and $ΔC_{\rm el}$ monotonously decrease with increasing $x$. The specific heat jump scales approximately with a power-law, $ΔC_{\rm el} \propto T_c^β$, with $β\approx 2$ determined by the impurity scattering rate, in contrast to most iron-pnictide superconductors, where the remarkable Bud'ko-Ni-Canfield (BNC) scaling $ΔC_{\rm el} \propto T^3$ has been found. Both the $T$ dependence of $C_{\rm el}(T)$ in the superconducting state and the nearly quadratic scaling of $ΔC_{\rm el}$ at $T_c$ are well described by the Eliashberg-theory for a two-band $d$-wave superconductor with weak pair-breaking due to nonmagnetic impurities. The disorder induced by the Na substitution significantly suppresses the small gaps leading to gapless states in the slightly disordered superconductor, which results in a large observed residual Sommerfeld coefficient in the superconducting state for $x > 0$.

cond-mat.supr-con↗

arXiv2014

Exploring of point-contact spectra of Ba1-xNaxFe2As2 in the normal and superconducting state

We present study of derivatives of current-voltage I(V) characteristics of point-contacts (PCs) based on Ba{1-x}Na{x}Fe2As2 (x=0.25) in the normal and superconducting state. The detailed analysis of dV/dI(V) data (also given in Appendix A) shows that the thermal regime, when temperature increases with a voltage at a rate of about 1.8 K/mV, is realized in the investigated PCs at least at high biases V above the superconducting (SC) gap Δ. In this case, specific resistivity ρ(T) in PC core is responsible for a peculiar dV/dI(V) behavior, while a pronounced asymmetry of dV/dI(V) is caused by large value of thermopower in this material. A reproducible zero-bias minima detected on dV/dI(V) at low biases in the range \pm(6--9)mV well below the SC critical temperature T_c could be connected with the manifestation of the SC gap Δ. Evaluation of these Andreev-reflection-like structures on dV/dI(V) points out to the preferred value of 2Δ/kT_c \approx 6. The expected second gap features on dV/dI(V) are hard to resolve unambiguously, likely due to impurity scattering, spatial inhomogeneity and transition to the mentioned thermal regime as the bias further increases. Suggestions are made how to separate spectroscopic features in dV/dI(V) from those caused by the thermal regime.

cond-mat.supr-con↗

arXiv2013

Evidence for a vortex-glass transition in superconducting Ba(Fe$_{0.9}$Co$_{0.1}$)$_{2}$As$_{2}$

Measurements of magneto-resistivity and magnetic susceptibility were performed on single crystals of superconducting Ba(Fe$_{0.9}$Co$_{0.1}$)$_{2}$As$_{2}$ close to the conditions of optimal doping. The high quality of the investigated samples allows us to reveal a dynamic scaling behaviour associated with a vortex-glass phase transition in the limit of weak degree of quenched disorder. Accordingly, the dissipative component of the ac susceptibility is well reproduced within the framework of Havriliak-Negami relaxation, assuming a critical power-law divergence for the characteristic correlation time $τ$ of the vortex dynamics. Remarkably, the random disorder introduced by the Fe$_{1-x}$Co$_{x}$ chemical substitution is found to act on the vortices as a much weaker quenched disorder than previously reported for cuprate superconductors such as, e.g., Y$_{1-x}$Pr$_{x}$Ba$_{2}$Cu$_{3}$O$_{7-δ}$.

cond-mat.supr-con↗

arXiv2013

Evidence of d-wave Superconductivity in K_(1-x)Na_xFe_2As_2 (x = 0, 0.1) Single Crystals from Low-Temperature Specific Heat Measurements

From the measurement and analysis of the specific heat of high-quality K_(1-x)Na_xFe_2As_2 single crystals we establish the presence of large T^2 contributions with coefficients alpha_sc ~ 30 mJ/mol K^3 at low-T for both x=0 and 0.1. Together with the observed square root field behavior of the specific heat in the superconducting state both findings evidence d-wave superconductivity on almost all Fermi surface sheets with an average gap amplitude of Delta_0 in the range of 0.4 - 0.8 meV. The derived Delta_0 and the observed T_c agree well with the values calculated within the Eliashberg theory, adopting a spin-fluctuation mediated pairing in the intermediate coupling regime.

cond-mat.supr-con↗

arXiv2012

Electronic band structure and momentum dependence of the superconducting gap in (Ca, Na)Fe2As2 from angle-resolved photoemission spectroscopy

Electronic structure of newly synthesized single crystals of calcium iron arsenide doped with sodium with Tc ranging from 33 to 14 K has been determined by angle-resolved photoemission spectroscopy (ARPES). The measured band dispersion is in general agreement with theoretical calculations, nonetheless implies absence of Fermi surface nesting at antiferromagnetic vector. A clearly developing below Tc strongly band-dependant superconducting gap has been revealed for samples with various doping levels. BCS ratio for optimal doping, $2Δ/k_{\rm B}T_{\rm c}=5.5$, is substantially smaller than the numbers reported for related compounds, implying a non-trivial relation between electronic dispersion and superconducting gap in iron arsenides.

cond-mat.supr-con↗

arXiv2012

Observation of charge accumulation and onsite Coulomb repulsion at transition metal impurities in the iron pnictides

We report a combined valence band photoemission and Auger spectroscopy study of single crystalline Ca(Fe,Co)2As2 and Ba(Fe,TM)2As2 with TM=Ni or Cu. The valence band photoemission data show directly that the TM-states move to higher binding energies with increasing atomic number, contributing less and less to the states close to the Fermi level. Furthermore, the 3d8 final state of the LVV Auger decay, which is observed for Ni and Cu, unambiguously reveals the accumulation of charge at these impurities. We also show that the onsite Coulomb interaction on the impurity strongly increases when moving from Co over Ni to Cu. Our results quantify the impurity potentials and imply that the superconducting state is robust against impurity scattering.

cond-mat.supr-con↗

arXiv2012

Disordered magnetism in superconducting KFe2As2 single crystals

High-quality KFe2As2 (K122) single crystals synthesized by different techniques have been studied by magnetization and specific heat (SH) measurements. There are 2 types of samples both affected by disordered magnetic phases: (i) cluster-glass (CG) like or (ii) Griffiths phase (G) like. For (i) at low applied magnetic fields the T-dependence of the zero field cooled (ZFC) linear susceptibility (chi_l) exhibits an anomaly with an irreversible behavior in ZFC and field cooled (FC) data. This anomaly is related to the freezing temperature T_f. The extrapolated T_f to B=0 varies between 50 K and 90 K. Below T_f we observed a magnetic hysteresis in the field dependence of the isothermal magnetization (M(B)). The frequency shift of the freezing temperature delta T_f=Delta T_f/[T_fΔ(\ln ν)]\sim 0.05$ has an intermediate value, which provides evidence for the formation of a CG-like state in the K122 samples of type (i). The frequency dependence of their T_f follows a conventional power-law divergence of critical slowing down: tau=tau_0 [T_f(nu)/T_f(0)-1]^{-zν^{'}} with the critical exponent zν^{'}=10(2) and a relatively long characteristic time constant tau_0 =6.9 x10^{-11}$s also supporting a CG behavior. The large value of the Sommerfeld coefficient was related to magnetic contribution from a CG. Samples from (ii) did not show a hysteresis behavior for chi_l(T) and M(B). Below a crossover temperature T^* sim 40 K a power-law dependence in the chi_l propto T^[lambda_G-1}], with a non-universal lambda_G was observed, suggesting a quantum G-like behavior. In this case chi_l and M(B) can be scaled using the scaling function M_s(T,B)= B^{1-λ_{\tiny G}}Y(mu B/k_BT) with the scaling moment mu of the order of 3.5mu_b. The same non-universal exponent was found also in SH measurements, where the magnetic contribution C/T propto T^(lambda_G-1).

cond-mat.dis-nn↗