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S. G. Porsev

Publications and source records attributed to S. G. Porsev.

At least 37 records · Page 2Linked to original sources

Calculation of higher-order corrections to the light shift of the $5s^2\, ^1\!S_0$--$5s5p\,^3\!P_0^o$ clock transition in Cd

In the recent work [A.~Yamaguchi et. al, Phys. Rev. Lett. {\bf 123}, 113201 (2019)] Cd has been identified as an excellent candidate for a lattice clock. Here, we carried out computations needed for further clock development and made an assessment of the higher-order corrections to the light shift of the $5s^2\, ^1\!S_0$--$5s5p\, ^3\!P_0^o$ clock transition. We carried out calculations of the magnetic dipole and electric quadrupole polarizabilities and linear and circular hyperpolarizabilities of the $5s^2\, ^1\!S_0$ and $5s5p\, ^3\!P_0^o$ clock states at the magic wavelength and estimated uncertainties of these quantities. We also evaluated the second-order Zeeman clock transition frequency shift.

physics.atom-ph↗

Accurate prediction of clock transitions in a highly charged ion with complex electronic structure

We have developed a broadly-applicable approach that drastically increases the ability to accurately predict properties of complex atoms. We applied it to the case of Ir$^{17+}$, which is of particular interest for the development of novel atomic clocks with high sensitivity to the variation of the fine-structure constant and dark matter searches. The clock transitions are weak and very difficult to identity without accurate theoretical predictions. In the case of Ir$^{17+}$, even stronger electric-dipole (E1) transitions eluded observation despite years of effort raising the possibility that theory predictions are grossly wrong. In this work, we provide accurate predictions of transition wavelengths and E1 transition rates in Ir$^{17+}$. Our results explain the lack of observation of the E1 transitions and provide a pathway towards detection of clock transitions. Computational advances demonstrated in this work are widely applicable to most elements in the periodic table and will allow to solve numerous problems in atomic physics, astrophysics, and plasma physics.

physics.atom-ph↗

High-precision measurement and ab initio calculation of the $(6s^26p^2)\,^3\!P_0 \rightarrow \, ^3\!P_2$ electric quadrupole transition amplitude in $^{208}$Pb

We have completed a measurement of the $(6s^26p^2)\, ^3\!P_0 \rightarrow \, ^3\!P_2$ 939 nm electric quadrupole ($E2$) transition amplitude in atomic lead. Using a Faraday rotation spectroscopy technique and a sensitive polarimeter, we have measured this very weak $E2$ transition for the first time, and determined its amplitude to be $\langle ^3\!P_2 || Q || ^3\!P_0 \rangle$ = 8.91(9) a.u.. We also present an ab initio theoretical calculation of this matrix element, which agrees with experiment at the 0.5\% level. We heat a quartz vapor cell containing $^{208}$Pb to between 800 and 940 $^{\circ}$C, apply a $\sim \! 10 \, {\rm G}$ longitudinal magnetic field, and use polarization modulation/lock-in detection to measure optical rotation amplitudes of order 1 mrad with noise near 1 $μ$rad. We compare the Faraday rotation amplitude of the $E2$ transition to that of the $^3\!P_0 -\, ^3\!P_1$ 1279 nm magnetic dipole ($M1$) transition under identical sample conditions.

physics.atom-ph↗

Clock-related properties of Lu+

The singly-ionized lutetium has a number of fortuitous properties well suited for a design of an optical clock and corresponding applications. In this work, we study Lu+ properties relevant to a development of the clock using the relativistic high-precision method combining configuration interaction and the linearized coupled-cluster approaches. The systematic effects due to interaction of an external electric-field gradient with the quadrupole moment and the dynamic correction to the blackbody radiation shift are studied and uncertainties are estimated. The value of the 5d6s 1D_2 polarizability is predicted. We also demonstrate that Lu+ is a good candidate to search for variation of the fine-structure constant.

physics.atom-ph↗

Dynamic polarizability measurements in $^{176}$Lu$^+$

We measure the differential polarizability of the $^{176}$Lu$^+$ $^1S_0$ -to- ${^3}D_1$ clock transition at multiple wavelengths. This experimentally characterizes the differential dynamic polarizability for frequencies up to 372 THz and allows an experimental determination of the dynamic correction to the blackbody radiation shift for the clock transition. In addition, measurements at the near resonant wavelengths of 598 and 646 nm determine the two dominant contributions to the differential dynamic polarizability below 372 THz. These additional measurements are carried out by two independent methods to verify the validity of our methodology. We also carry out a theoretical calculation of the polarizabilities using the hybrid method that combines the configuration interaction (CI) and the coupled-cluster approaches, incorporating for the first time quadratic non-linear terms and partial triple excitations in the coupled-cluster calculations. The experimental measurements of the $|\langle ^3D_1|| r || ^3P_J\rangle|$ matrix elements provide high-precision benchmarks for this theoretical approach.

physics.atom-ph↗

Nobelium energy levels and hyperfine structure constants

Advances in laser spectroscopy of superheavy ($Z>100$) elements enabled determination of the nuclear moments of the heaviest nuclei, which requires high-precision atomic calculations of the relevant hyperfine structure (HFS) constants. Here, we calculated the HFS constants and energy levels for a number of nobelium (Z=102) states using the hybrid approach, combining linearized coupled-cluster and configuration interaction methods. We also carried out an extensive study of the No energies using 16-electron configuration interaction method to determine the position of the (5f^{13}7s^2 6d) and (5f^{13}7s^2 7p) levels with a hole in the 5f shell to evaluate their potential effect on the hyperfine structure calculations of the low-lying (5f^{14}7s6d) and (5f^{14}7s7p) levels. We find that unlike the case of Yb, the mixing of the low-lying levels with filled and unfilled f shell is small and does not significantly influence their properties. The resulting HFS constants for the 5f^{14}7s7p 1P1 level, combined with laser-spectroscopy measurement, were used to extract nobelium nuclear properties [S. Raeder et al., Phys. Rev. Lett. 120, 232503 (2018)]

physics.atom-ph↗

Nuclear charge radii of $^{229}$Th from isotope and isomer shifts

The isotope $^{229}$Th is unique in that it possesses an isomeric state of only a few eV above the ground state, suitable for nuclear laser excitation. An optical clock based on this transition is expected to be a very sensitive probe for variations of fundamental constants, but the nuclear properties of both states have to be determined precisely to derive the actual sensitivity. We carry out isotope shift calculations in Th$^+$ and Th$^{2+}$ including the specific mass shift, using a combination of configuration interaction and all-order linearized coupled-cluster methods and estimate the uncertainty of this approach. We perform experimental measurements of the hyperfine structure of Th$^{2+}$ and isotopic shift between $^{229}$Th$^{2+}$ and $^{232}$Th$^{2+}$ to extract the difference in root-mean-square radii as $δ\langle r^{2} \rangle^{232,229}=0.299(15)$ fm$^2$. Using the recently measured values of the isomer shift of lines of $^{229\textrm{m}}$Th, we derive the value for the mean-square radius change between $^{229}$Th and its low lying isomer $^{229\textrm{m}}$Th to be $δ\langle r^2 \rangle^{229\textrm{m},229} = 0.0105(13)\,{\rm fm}^2$.

physics.atom-ph↗

Two clock transitions in neutral Yb for the highest sensitivity to variations of the fine-structure constant

We propose a new frequency standard based on a $4f^{14} 6s6p~ ^3\!P_0 - 4f^{13} 6s^2 5d ~(J=2)$ transition in neutral Yb. This transition has a potential for high stability and accuracy and the advantage of the highest sensitivity among atomic clocks to variation of the fine-structure constant $α$. We find its dimensionless $α$-variation enhancement factor to be $K=-15$, in comparison to the most sensitive current clock (Yb$^+$ E3, $K=-6$), and it is 18 times larger than in any neutral-atomic clocks (Hg, $K=0.8$). Combined with the unprecedented stability of an optical lattice clock for neutral atoms, this high sensitivity opens new perspectives for searches for ultralight dark matter and for tests of theories beyond the standard model of elementary particles. Moreover, together with the well-established $^1\!S_0 -\, ^3\!P_0$ transition one will have two clock transitions operating in neutral Yb, whose interleaved interrogations may further reduce systematic uncertainties of such clock-comparison experiments.

physics.atom-ph↗

Multipolar polarizabilities and hyperpolarizabilities in the Sr optical lattice clock

We address the problem of the lattice Stark shifts in the Sr clock caused by the multipolar $M1$ and $E2$ atom-field interactions and by the term nonlinear in lattice intensity and determined by the hyperpolarizability. We have developed an approach to calculate hyperpolarizabilities for atoms and ions based on a solution of the inhomogeneous equation which allows to effectively and accurately carry out complete summations over intermediate states. We applied our method to the calculation of the hyperpolarizabilities for the clock states in Sr. We also carried out an accurate calculation of the multipolar polarizabilities for these states at the magic frequency. Understanding these Stark shifts in optical lattice clocks is crucial for further improvement of the clock accuracy.

physics.atom-ph↗

Relativistic all-order many-body calculation of energies, wavelengths, and $M1$ and $E2$ transition rates for the $3d^n$ configurations in tungsten ions

Energy levels, wavelengths, magnetic-dipole and electric-quadrupole transition rates between the low-lying states are evaluated for W$^{51+}$ to W$^{54+}$ ions with $3d^n$ (n = 2 to 5) electronic configurations using an approach combining configuration interaction with linearized coupled-cluster single-double method. The QED corrections are directly incorporated into the calculations and their effect is studied in detail. Uncertainties of the calculations are discussed. This first study of such highly charged ions with the present method opens the way for future applications allowing an accurate prediction of properties for a very wide range of highly charged ions aimed at providing precision benchmarks for various applications.

physics.atom-ph↗

A theoretical study of the g-factor of the 6s6p 3P0 state of mercury

We calculate the g-factor of the 6s6p 3P0 state of 199 and 201 mercury isotopes using a relativistic high-precision all-order method that combines the configuration interaction and the coupled-cluster approaches. Our values $g(199Hg) = -0.9485(49)*10^{-3}$ and $g(201Hg) = -0.3504(18)*10^{-3}$ are in agreement with the experimental measurements within the 0.5% theoretical uncertainty. We also calculate the hyperfine quenching rate of the 6s6p 3P0 state in 199Hg and 201Hg and determine its lifetime to be 1.3 and 1.9 s, respectively.

physics.atom-ph↗

Effective three particle forces in polyvalent atoms

We study effective three-particle interactions between valence electrons, which are induced by the core polarization. Such interactions are enhanced when valence orbitals have strong overlap with the outermost core shell, in particular for the systems with partially filled f-shell. We find that in certain cases the three-particle contributions are large, affecting the order of energy levels, and need to be included in high-precision calculations.

physics.atom-ph↗

Atomic Properties of Lu$^+$

Singly ionised Lutetium has recently been suggested as a potential clock candidate. Here we report a joint experimental and theoretical investigation of \ce{Lu^+}. Measurements relevant to practical clock operation are made and compared to atomic structure calculations. Calculations of scalar and tensor polarizabilities for clock states over a range of wavelengths are also given. These results will be useful for future work with this clock candidate.

physics.atom-ph↗

A development of the CI + all-order method and application to the parity-nonconserving amplitude and other properties of Pb

We have further developed and extended a method for calculation of atomic properties based on a combination of the configuration interaction and coupled-cluster approach. We have applied this approach to the calculation of different properties of atomic lead, including the energy levels, hyperfine structure constants, electric-dipole transition amplitudes, and E1 parity nonconserving (PNC) amplitude for the (6p^2) ^3P_0 - (6p^2) ^3P_1 transition. The uncertainty of the E1 PNC amplitude was reduced by a factor of two in comparison with the previous most accurate calculation [V.~A.~Dzuba et.al., Europhys. Lett. 7, 413 (1988)]. Our value for the weak charge Q_W=-117(5) is in agreement with the standard model prediction.

physics.atom-ph↗

Observation of an unexpected negative isotope shift in 229Th+ and its theoretical explanation

We have measured the hyperfine structure and isotope shifts of the 402.0 nm and 399.6 nm resonance lines in 229Th+. These transitions could provide pathways towards the 229Th isomeric nuclear state excitation. An unexpected negative isotope shift relative to 232Th+ is observed for the 399.6 nm line, indicating a strong Coulomb coupling of the excited state to the nucleus. We have developed a new all-order approach to the isotope shift calculations that is generally applicable to heavy atoms and ions with several valence electrons. The theoretical calculations provide an explanation for the negative isotope shift of the 399.6 nm transition and yield a corrected classification of the excited state. The calculated isotope shifts are in good agreement with experimental values.

physics.atom-ph↗

Towards a Mg lattice clock: Observation of the $^1S_{0}-$$^3P_{0}$ transition and determination of the magic wavelength

We optically excite the electronic state $3s3p~^3P_{0}$ in $^{24}$Mg atoms, laser-cooled and trapped in a magic-wavelength lattice. An applied magnetic field enhances the coupling of the light to the otherwise strictly forbidden transition. We determine the magic wavelength, the quadratic magnetic Zeeman shift and the transition frequency to be 468.463(207)$\,$nm, -206.6(2.0)$\,$MHz/T$^2$ and 655 058 646 691(101)$\,$kHz, respectively. These are compared with theoretical predictions and results from complementary experiments. We also developed a high-precision relativistic structure model for magnesium, give an improved theoretical value for the blackbody radiation shift and discuss a clock based on bosonic magnesium.

physics.atom-ph↗

Strongly enhanced effects of Lorentz symmetry violation in entangled Yb+ ions

Lorentz symmetry is one of the cornerstones of modern physics. However, a number of theories aiming at unifying gravity with the other fundamental interactions including string field theory suggest violation of Lorentz symmetry [1-4]. While the energy scale of such strongly Lorentz symmetry-violating physics is much higher than that currently attainable by particle accelerators, Lorentz violation may nevertheless be detectable via precision measurements at low energies [2]. Here, we carry out a systematic theoretical investigation of the sensitivity of a wide range of atomic systems to violation of local Lorentz invariance (LLI). Aim of these studies is to identify which atom shows the biggest promise to detect violation of Lorentz symmetry. We identify the Yb+ ion as an ideal system with high sensitivity as well as excellent experimental controllability. By applying quantum information inspired technology to Yb+, we expect tests of LLI violating physics in the electron-photon sector to reach levels of $10^{-23}$, five orders of magnitude more sensitive than the current best bounds [5-7]. Most importantly, the projected sensitivity of $10^{-23}$ for the Yb+ ion tests will allow for the first time to probe whether Lorentz violation is minimally suppressed at low energies for photons and electrons.

physics.atom-ph↗

A Michelson-Morley Test of Lorentz Symmetry for Electrons

All evidence so far suggests that the absolute spatial orientation of an experiment never affects its outcome. This is reflected in the Standard Model of physics by requiring all particles and fields to be invariant under Lorentz transformations. The most well-known test of this important cornerstone of physics are Michelson-Morley-type experiments\cite{MM, Herrmann2009,Eisele2009} verifying the isotropy of the speed of light. Lorentz symmetry also implies that the kinetic energy of an electron should be independent of the direction of its velocity, \textit{i.e.,} its dispersion relation should be isotropic in space. In this work, we search for violation of Lorentz symmetry for electrons by performing an electronic analogue of a Michelson-Morley experiment. We split an electron-wavepacket bound inside a calcium ion into two parts with different orientations and recombine them after a time evolution of 95ms. As the Earth rotates, the absolute spatial orientation of the wavepackets changes and anisotropies in the electron dispersion would modify the phase of the interference signal. To remove noise, we prepare a pair of ions in a decoherence-free subspace, thereby rejecting magnetic field fluctuations common to both ions\cite{Roos2006}. After a 23 hour measurement, we limit the energy variations to $h\times 11$ mHz ($h$ is Planck's constant), verifying that Lorentz symmetry is preserved at the level of $1\times10^{-18}$. We improve on the Lorentz-violation limits for the electron by two orders of magnitude\cite{Hohensee2013c}. We can also interpret our result as testing the rotational invariance of the Coloumb potential, improving limits on rotational anisotropies in the speed of light by a factor of five\cite{Herrmann2009,Eisele2009}. Our experiment demonstrates the potential of quantum information techniques in the search for physics beyond the Standard Model.

quant-ph↗