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Saar Rahav

Publications and source records attributed to Saar Rahav.

At least 19 recordsLinked to original sources

Piston-Like Information Engine II: Boundary-Controlled Optimum in Active Matter

Information engines convert information into extractable work through measurements and feedback. We realize an engine that employs information to compress a gas of self-propelled bristle bots. Its work per measurement, $\bar{W}$, is controlled by the size of the detection region $\Delta x$ and the probability $p_1$ that this region is vacant. In thermal systems, $\bar{W}$ follows the universal form $-p_1 \ln p_1$, whereas the active engine shows a qualitatively modified relation. As particle density increases, the maximum of $\bar{W}(\Delta x)$ switches between two distinct operating regimes. Notably, this transition is also found in the solutions that maximize power output for finite-time cycles with dynamics affected by dry friction. We attribute this nonequilibrium feature to the accumulation of active particles near the boundaries.

cond-mat.stat-mech

Fluctuation theorems for autonomous work

Classical fluctuation theorems for work have been obtained theoretically, and verified experimentally, within a non-autonomous framework in which work is performed on a system of interest, ${\cal S}$, by the external manipulation of a work parameter, such as a piston's position. Here we obtain fluctuation theorems within an autonomous framework in which ${\cal S}$ exchanges energy with a reversible work source, ${\cal R}$. The two subsystems, ${\cal R}$ and ${\cal S}$, interact with one another as they evolve under Hamiltonian or stochastic dynamics, without external intervention. In this setting, we must account for the back-action of ${\cal S}$ on ${\cal R}$, which is absent in the non-autonomous setting. We obtain autonomous versions of standard fluctuation theorems for work and entropy production. In each case, we argue, the autonomous fluctuation theorem reduces to its non-autonomous counterpart when ${\cal R}$'s inertia becomes infinitely large.

cond-mat.stat-mech

Piston-Like Information Engine I: Universal Features in Equilibrium

The ability to measure the stochastic degrees of freedom of a thermal system enables the extraction of energy from an equilibrium heat bath. This is the underlying principle of Maxwell's demon and subsequent information engines. Here, we experimentally realize a microscopic information engine configured as a compressible piston containing a thermalized colloidal suspension. The particle positions are recorded to identify when a predefined region near the wall is empty, allowing the piston to compress the colloidal suspension without applying work on the system. We find that the stored compression energy is universally set by the probability of a positive measurement outcome, which in turn is controlled by parameters such as density and compression step size. We further demonstrate that mechanical work can be extracted during the decompression of the piston, thereby closing the engine's operating cycle.

cond-mat.stat-mech

Experimental Realizations of Information Engines: Beyond Proof of Concept

Gathering information about a system enables greater control over it. This principle lies at the core of information engines, which use measurement-based feedback to rectify thermal noise and convert information into work. Originating from Maxwell's and Szil\'ard's thought experiments, the thermodynamics of information engines has steadily advanced, with recent experimental realizations both confirming established results and pushing the field forward. Coupled with technological advances and developments in nonequilibrium thermodynamics, novel implementations of information engines continue to challenge theoretical understanding. In this perspective, we discuss recent progress and highlight new opportunities, such as applying information engines to active, many-body, and inertial systems, and leveraging tools like optimal control to design their driving protocols.

cond-mat.stat-mech

Acceleration of enzymatic reactions due to nearby inactive binding sites

Many biological molecular motors and machines are driven by chemical reactions that occur in specific catalytic sites. We study whether the arrival of molecules to such an active site can be accelerated by the presence of a nearby inactive site. Our approach is based on comparing the steady-state current in simple models to reference models without an inactive site. We identify two parameter regimes in which the reaction is accelerated. We then find the transition rates that maximize this acceleration, and use them to determine the underlying mechanisms in each region. In the first regime, the inactive site stores a molecule in order to release it following a reaction, when the neighboring catalytic site is empty. In the second regime, the inactive site releases a molecule when the catalytic site is full, in order to impede the molecules from leaving the active site before they react. For the storage mechanism, which is more likely to be biologically relevant, the acceleration can reach up to 15%, depending on parameters.

cond-mat.stat-mech

A many-body Szilard engine with giant number fluctuations

Szil\'ard's information engine is a canonical example in the field of thermodynamics of information. We realize experimentally a macroscopic many-particle Szil\'ard engine that consists of active particles and use it to lift a mass against gravity. We show that the extractable work per cycle increases when the raised weight is changed more gradually during the process. Interestingly, we find that the ideal extractable work grows with the number of particles due to giant number fluctuations. This is in contrast to the calculated behavior of a similar engine operating on thermal particles.

cond-mat.stat-mech

Singular optimal driving cycles of stochastic pumps

The investigation of optimal processes has a long history in the field of thermodynamics. It is well known that finite-time processes that minimize dissipation often exhibit discontinuities. We use a combination of numerical and analytical approaches to study the driving cycle that maximizes the output in a simple model of a stochastic pump: a system driven out of equilibrium by a cyclic variation of external parameters. We find that this optimal solution is singular, with an infinite rate of switching between sets of parameters. The appearance of such singular solutions in thermodynamic processes is surprising, but we argue that such solutions are expected to be quite common in models whose dynamics exhibit exponential relaxation, as long as the driving period is not externally fixed, and is allowed to be arbitrarily short. Our results have implications to artificial molecular motors that are driven in a cyclic manner.

cond-mat.stat-mech

Non-Uniform Convergence in Moment Expansions of Integral Work Relations

Exponential averages that appear in integral fluctuation theorems can be recast as a sum over moments of thermodynamic observables. We use two examples to show that such moment series can exhibit non-uniform convergence in certain singular limits. The first example is a simple model of a process with measurement and feedback. In this example, the limit of interest is that of error-free measurements. The second system we study is an ideal gas particle inside an (infinitely) fast expanding piston. Both examples show qualitative similarities; the low order moments are close to their limiting value, while high order moments strongly deviate from their limit. As the limit is approached the transition between the two groups of moments is pushed toward higher and higher moments. Our findings highlight the importance of the ordering of limits in certain non-equilibrium related calculations.

cond-mat.stat-mech

Thermodynamic uncertainty relation for first-passage times on Markov chains

We derive a thermodynamic uncertainty relation (TUR) for first-passage times (FPTs) on continuous time Markov chains. The TUR utilizes the entropy production coming from bidirectional transitions, and the net flux coming from unidirectional transitions, to provide a lower bound on FPT fluctuations. As every bidirectional transition can also be seen as a pair of separate unidirectional ones, our approach typically yields an ensemble of TURs. The tightest bound on FPT fluctuations can then be obtained from this ensemble by a simple and physically motivated optimization procedure. The results presented herein are valid for arbitrary initial conditions, out-of-equilibrium dynamics, and are therefore well suited to describe the inherently irreversible first-passage event. They can thus be readily applied to a myriad of first-passage problems that arise across a wide range of disciplines.

cond-mat.stat-mech

Thermodynamic uncertainty relation for systems with unidirectional transitions

We derive a thermodynamic uncertainty relation (TUR) for systems with unidirectional transitions. The uncertainty relation involves a mixture of thermodynamic and dynamic terms. Namely, the entropy production from bidirectional transitions, and the net flux of unidirectional transitions. The derivation does not assume a steady-state, and the results apply equally well to transient processes with arbitrary initial conditions. As every bidirectional transition can also be seen as a pair of separate unidirectional ones, our approach is equipped with an inherent degree of freedom. Thus, for any given system, an ensemble of valid TURs can be derived. However, we find that choosing a representation that best matches the systems dynamics over the observation time will yield a TUR with a tighter bound on fluctuations. More precisely, we show a bidirectional representation should be replaced by a unidirectional one when the entropy production associated with the transitions between two states is larger than the sum of the net fluxes between them. Thus, in addition to offering TURs for systems where such relations were previously unavailable, the results presented herein also provide a systematic method to improve TUR bounds via physically motivated replacement of bidirectional transitions with pairs of unidirectional transitions. The power of our approach and its implementation are demonstrated on a model for random walk with stochastic resetting and on the Michaelis-Menten model of enzymatic catalysis.

cond-mat.stat-mech

The Passivity Deformation Approach for the Thermodynamics of Isolated Quantum Setups

Recently implemented quantum devices such as quantum processors and quantum simulators combine highly complicated quantum dynamics with high-resolution measurements. We present a passivity deformation methodology that sets thermodynamic constraints on the evolution of such quantum devices. This framework enhances the thermodynamic predictive power by simultaneously resolving four of the cardinal deficiencies of the second law in microscopic setups: i) It yields tight bounds even when the environment is microscopic; ii) The ultra-cold catastrophe is resolved; iii) It enables to integrate conservation laws into thermodynamic inequalities for making them tighter; iv) it bounds observables that are not energy-based, and therefore do not appear in the second law of thermodynamics. Furthermore, this framework provides insights to non-thermal environments, correlated environments, and to coarse-graining in microscopic setups. Our findings can be explored and used in physical setups such as trapped ions, superconducting circuits, neutral atoms in optical lattices and more.

quant-ph

Global passivity in microscopic thermodynamics

The main thread that links classical thermodynamics and the thermodynamics of small quantum systems is the celebrated Clausius inequality form of the second law. However, its application to small quantum systems suffers from two cardinal problems: (i) The Clausius inequality does not hold when the system and environment are initially correlated - a commonly encountered scenario in microscopic setups. (ii) In some other cases, the Clausius inequality does not provide any useful information (e.g. in dephasing scenarios). We address these deficiencies by developing the notion of global passivity and employing it as a tool for deriving thermodynamic inequalities on observables. For initially uncorrelated thermal environments the global passivity framework recovers the Clausius inequality. More generally, global passivity provides an extension of the Clausius inequality that holds even in the presences of strong initial system-environment correlations. Crucially, the present framework provides additional thermodynamic bounds on expectation values. To illustrate the role of the additional bounds we use them to detect unaccounted heat leaks and weak feedback operations ("Maxwell's demons") that the Clausius inequality cannot detect. In addition, it is shown that global passivity can put practical upper and lower bounds on the buildup of system-environment correlation for dephasing interactions. Our findings are highly relevant for experiments in various systems such as ion traps, superconducting circuits, atoms in optical cavities and more.

quant-ph

Integral Fluctuation Theorems for Stochastic Resetting Systems

We study the stochastic thermodynamics of resetting systems. Violation of microreversibility means that the well known derivations of fluctuations theorems break down for dynamics with resetting. Despite that we show that stochastic resetting systems satisfy two integral fluctuation theorems. The first is the Hatano-Sasa relation describing the transition between two steady states. The second integral fluctuation theorem involves a functional that includes both dynamical and thermodynamic contributions. We find that the second law-like inequality found by Fuchs et al. for resetting systems [EPL, 113, (2016)] can be recovered from this integral fluctuation theorem with the help of Jensen's inequality.

cond-mat.stat-mech

Nonequilibrium free energy estimation conditioned on measurement outcomes

The Jarzynski equality is one of the most influential results in the field of non equilibrium statistical mechanics. This celebrated equality allows to calculate equilibrium free energy differences from work distributions of nonequilibrium processes. In practice, such calculations often suffer from poor convergence due to the need to sample rare events. Here we examine if the inclusion of measurement and feedback can improve the convergence of nonequilibrium free energy calculations. A modified version of the Jarzynski equality in which realizations with a given outcome are kept, while others are discarded, is used. We find that discarding realizations with unwanted outcomes can result in improved convergence compared to calculations based on the Jarzynski equality. We argue that the observed improved convergence is closely related to Bennett's acceptance ratio method, which was developed without any reference to measurements or feedback.

cond-mat.stat-mech

Kinetic discrimination of a polymerase in the presence of obstacles

One of the causes of high fidelity of copying in biological systems is kinetic discrimination. In this mechanism larger dissipation and copying velocity result in improved copying accuracy. We consider a model of a polymerase which simultaneously copies a single stranded RNA and opens a single- to double-stranded junction serving as an obstacle. The presence of the obstacle slows down the motor, resulting in a change of its fidelity, which can be used to gain information about the motor and junction dynamics. We find that the motor's fidelity does not depend on details of the motor-junction interaction, such as whether the interaction is passive or active. Analysis of the copying fidelity can still be used as a tool for investigating the junction kinetics.

q-bio.SC

The validity of the no-pumping theorem in systems with finite-range interactions between particles

The no-pumping theorem states that seemingly natural driving cycles of stochastic machines fail to generate directed motion. Initially derived for single particle systems, the no-pumping theorem was recently extended to many-particle systems with zero-range interactions. Interestingly, it is known that the theorem is violated by systems with exclusion interactions. These two paradigmatic interactions differ by two qualitative aspects: the range of interactions, and the dependence of branching fractions on the state of the system. In this work two different models are studied in order to identify the qualitative property of the interaction that leads to breakdown of no-pumping. A model with finite-range interaction is shown analytically to satisfy no-pumping. In contrast, a model in which the interaction affects the probabilities of reaching different sites, given that a particle is making a transition, is shown numerically to violate the no-pumping theorem. The results suggest that systems with interactions that lead to state-dependent branching fractions do not satisfy the no-pumping theorem.

cond-mat.stat-mech

The quantum-classical correspondence principle for work distributions

For closed quantum systems driven away from equilibrium, work is often defined in terms of projective measurements of initial and final energies. This definition leads to statistical distributions of work that satisfy nonequilibrium work and fluctuation relations. While this two-point measurement definition of quantum work can be justified heuristically by appeal to the first law of thermodynamics, its relationship to the classical definition of work has not been carefully examined. In this paper we employ semiclassical methods, combined with numerical simulations of a driven quartic oscillator, to study the correspondence between classical and quantal definitions of work in systems with one degree of freedom. We find that a semiclassical work distribution, built from classical trajectories that connect the initial and final energies, provides an excellent approximation to the quantum work distribution when the trajectories are assigned suitable phases and are allowed to interfere. Neglecting the interferences between trajectories reduces the distribution to that of the corresponding classical process. Hence, in the semiclassical limit, the quantum work distribution converges to the classical distribution, decorated by a quantum interference pattern. We also derive the form of the quantum work distribution at the boundary between classically allowed and forbidden regions, where this distribution tunnels into the forbidden region. Our results clarify how the correspondence principle applies in the context of quantum and classical work distributions, and contribute to the understanding of work and nonequilibrium work relations in the quantum regime.

cond-mat.stat-mech

Interpretation of surface diffusion data with Langevin simulations - a quantitative assessment

Diffusion studies of adsorbates moving on a surface are often analyzed using 2D Langevin simulations. These simulations are computationally cheap and offer valuable insight into the dynamics, however, they simplify the complex interactions between the substrate and adsorbate atoms, neglecting correlations in the motion of the two species. The effect of this simplification on the accuracy of observables extracted using Langevin simulations was previously unquantified. Here we report a numerical study aimed at assessing the validity of this approach. We compared experimentally accessible observables which were calculated using a Langevin simulation with those obtained from explicit molecular dynamics simulations. Our results show that within the range of parameters we explored Langevin simulations provide a good alternative for calculating the diffusion procress, i.e. the effect of correlations is too small to be observed within the numerical accuracy of this study and most likely would not have a significant effect on the interpretation of experimental data. Our comparison of the two numerical approaches also demonstrates the effect temperature dependent friction has on the calculated observables, illustrating the importance of accounting for such a temperature dependence when interpreting experimental data.

cond-mat.mtrl-sci