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Sachin Gupta

Publications and source records attributed to Sachin Gupta.

At least 19 recordsLinked to original sources

Optimization of magneto-electric properties in Lead-free (x)Co1.2Ti0.2Fe1.6O4 - (100-x)BaTiO3 based composites

This work presents a systematic study of lead-free multiferroic composites of (x)Co1.2Ti0.2Fe1.6O4 - (100-x)BaTiO3 (x = 10, 20, 30), which were synthesized by a solid-state reaction method to investigate the effects of composition and sintering temperature on their structural , electrical, magnetic, and magnetoelectric (ME) properties. X-ray diffraction along with Rietveld refinement confirms the coexistence of tetragonal BaTiO3 (BTO) and cubic spinel Co1.2Ti0.2Fe1.6O4 (CTFO) phases. Microstructural analysis shows that densification and grain growth are better at higher sintering temperatures, leading to better coupling between the two phases. Dielectric and ferroelectric studies indicate lossy polarization-electric field (P-E) behaviour due to leakage from the conductive phase, while magnetic properties show increased magnetization with increasing ferrite content. All composites exhibit ME coefficients, which depend on the composition and sintering conditions; the highest ME coefficient (~1.28 mV/cm.Oe) was observed for the 30CTFO - 70BTO composite sintered at 1200 °C. This improvement is due to the optimal balance between magnetostrictive and piezoelectric responses and improved interfacial strain transfer. These results demonstrate that simultaneous optimization of dopant-modified composition and sintering conditions is essential for achieving improved magnetoelectric coupling in bulk multiferroic composites. Moreover, the results demonstrate the potential of lead-free composites for multifunctional device applications in next-generation, low-power technologies, including high-density non-volatile memory (e.g. FeRAM/MRAM), magnetic field sensors, spintronic devices, and actuators.

cond-mat.mtrl-sci

Quantum correlations in QBism's reconstruction program

QBism recasts quantum theory as a normative framework for an agent's probability assignments, with the Born rule taking the form of a consistency condition known as the Urgleichung. Motivated by this perspective, qplex theories provide a broader class of probabilistic models in which the sets of valid states and measurements are constrained by QBist-inspired geometric conditions. While qplexes have been extensively studied for single systems, their implications for bipartite correlations remain largely unexplored. In this work, we investigate bipartite correlations in qplex theories by expressing joint expectation values as inner products between suitably defined $C$-vectors. This geometric formulation allows Bell-type inequalities to be studied as optimization problems over qplex-compatible probability assignments. We first analyze the CHSH scenario and show that the shared inner-product structure of the $C$-vectors restricts the maximal value to the Tsirelson bound $2\sqrt{2}$. We then turn to the three-outcome CGLMP inequality $I_{2233}$ and find that the same qplex-derived norm and inner-product constraints allow a violation of up to $\leq 2+2\sqrt(3)/3 \approx 3.1547$ versus the quantum maximum of $\approx 2.8729$, thereby exhibiting super-quantum correlations. These results show that qplex geometry captures enough structure to reproduce an important quantum bound in the two-outcome case, but not enough to recover the full set of quantum correlation constraints. The analysis therefore suggests that additional principles are needed to complete the QBist reconstruction of quantum theory.

quant-ph

A Proposed Biomedical Data Policy Framework to Reduce Fragmentation, Improve Quality, and Incentivize Sharing in Indian Healthcare in the era of Artificial Intelligence and Digital Health

India generates vast biomedical data through postgraduate research, government hospital services and audits, government schemes, private hospitals and their electronic medical record (EMR) systems, insurance programs and standalone clinics. Unfortunately, these resources remain fragmented across institutional silos and vendor-locked EMR systems. The fundamental bottleneck is not technological but economic and academic. There is a systemic misalignment of incentives that renders data sharing a high-risk, low-reward activity for individual researchers and institutions. Until India's academic promotion criteria, institutional rankings, and funding mechanisms explicitly recognize and reward data curation as professional work, the nation's AI ambitions will remain constrained by fragmented, non-interoperable datasets. We propose a multi-layered incentive architecture integrating recognition of data papers in National Medical Commission (NMC) promotion criteria, incorporation of open data metrics into the National Institutional Ranking Framework (NIRF), adoption of Shapley Value-based revenue sharing in federated learning consortia, and establishment of institutional data stewardship as a mainstream professional role. Critical barriers to data sharing, including fear of data quality scrutiny, concerns about misinterpretation, and selective reporting bias, are addressed through mandatory data quality assessment, structured peer review, and academic credit for auditing roles. The proposed framework directly addresses regulatory constraints introduced by the Digital Personal Data Protection Act 2023 (DPDPA), while constructively engaging with the National Data Sharing and Accessibility Policy (NDSAP), Biotech-PRIDE Guidelines, and the Anusandhan National Research Foundation (ANRF) guidelines.

cs.AI

Low magnetic moment and unconventional magneto-transport in half-Heusler alloy CoVGe

In the present work, we experimentally realize CoVGe for the first time and investigate its structural, magnetic, and transport properties, supported by theoretical calculations. The material crystallizes in a cubic structure and exhibits a very low magnetic moment of 0.13 μB per formula unit at 5 K. The temperature dependence of electrical resistivity suggests half-metallic behaviour. Magnetoresistance shows a positive, non-saturating linear field dependence at low temperature that gradually weakens with increasing temperature. The combination of low magnetic moment and unusual magnetotransport behaviour positions CoVGe as a promising platform for exploring spin-dependent transport in Heusler-based materials.

cond-mat.mtrl-sci

Transport spin polarization in RuO$_2$ films

Altermagnets host spin-split electronic bands without net magnetization, enabling spin-polarized transport in the absence of conventional ferromagnetism. RuO$_2$ has been proposed as a candidate altermagnet, yet experimental reports remain conflicting, particularly between bulk-sensitive probes and thin-film measurements. Here we investigate the electronic transport properties of epitaxial RuO$_2$ thin films using anomalous Hall effect measurements and point-contact Andreev reflection spectroscopy. We observe transport spin polarization and a strongly orientation-dependent anomalous Hall response, while magnetometry reveals no detectable net magnetization. The anomalous Hall effect appears only in ultrathin (110)-oriented films, consistent with symmetry-driven Néel-vector physics, and the measured transport spin polarization is systematically higher for (110)-oriented films than for (001)-oriented films, consistent with the crystallographic anisotropy of the spin-split bands. These results are consistent with altermagnetic behavior in RuO$_2$, with the experimentally accessible signatures confined to near-surface regions. They also establish superconducting transport spectroscopy as a metrology for identifying and characterizing altermagnet candidates.

cond-mat.mes-hall

A simple realization of Weyl-Heisenberg covariant measurements

Informationally complete (IC) measurements are fundamental tools in quantum information processing, yet their physical implementation remains challenging. By the Naimark extension theorem, an IC measurement may be realized by a von Neumann measurement on an extended system after a suitable interaction. In this work, we elaborate on a simple algorithm for realizing Naimark extensions for rank-one Weyl-Heisenberg covariant informationally complete measurements in arbitrary finite dimensions. Exploiting Weyl-Heisenberg covariance, we show that the problem reduces to determining a $d \times d$ unitary from which the full $d^2 \times d^2$ unitary interaction can be constructed. The latter unitary enjoys a block-circulant structure which allows e.g., for an elegant optical implementation. We illustrate the procedure with explicit calculations for qubit, qutrit, and ququart SIC-POVMs. Finally, we show that from another point of view, this method amounts to preparing an ancilla system according to a so-called fiducial state, followed by a generalized Bell-basis measurement on the system and ancilla. These results provide a straightforward framework for implementing informationally complete measurements in the laboratory suitable for both qubit and qudit based systems.

quant-ph

CoRuTiGe: A Possible Spin Gapless Semiconductor

We report experimental and theoretical investigations on the quaternary Heusler alloy CoRuTiGe, synthesized using the arc melting technique. Crystal structure analysis reveals a tetragonal structure at room temperature. Magnetization measurements as a function of temperature and magnetic field indicate ferromagnetic nature with a saturation magnetization of 0.681 mB/f.u. at 5 K. The temperature dependence of electrical resistivity shows a nearly linear decrease in the high-temperature range, indicating the spin gapless semiconductor like behavior of the material. This SGS nature is further supported by the temperature-independent carrier concentration and mobility. Hall effect analysis reveals that the anomalous Hall effect in CoRuTiGe arises from both intrinsic and extrinsic mechanisms. Additionally, a well-defined symmetric negative magnetoresistance is observed at low temperatures. These findings suggest that CoRuTiGe holds significant promise for spintronic applications.

cond-mat.mtrl-sci

Novel Heusler Materials for Spintronic Applications: Growth, Characterizations and Applications

Spintronics is a rapidly evolving technology that utilizes the spin of electrons along with their charge to enable high speed, low power and non volatile electronic devices. The development of novel materials with tailored magnetic and electronic properties is critical to exploit the full potential of spintronic applications. Among these, Heusler alloys stand out due to their tunable multifunctional properties. This review presents a comprehensive overview of various Heusler based materials including half metallic ferromagnets, spin gapless semiconductors, magnetic semiconductors, spin semimetals, and nearly zero moment materials focusing on their synthesis, structural and magnetic characterizations, and transport behavior. The role of crystal structure, and structural disorder in governing their magnetic and electronic properties is discussed in detail. Emphasis is placed on experimental results and their implications for spintronic devices. By bringing together recent advancements, the review highlights the critical role of Heusler alloys in advancing the next-generation spintronic technologies and outlines future directions for their integration in practical applications.

cond-mat.mtrl-sci

Low-Moment Semiconducting Properties of Quaternary Heusler Alloy CoRuTiSn

We investigate structural, magnetic and transport properties of CoRuTiSn equiatomic quaternary Heusler alloy. CoRuTiSn was synthesized by arc-melt technique. The room temperature powder XRD pattern was analyzed, and it was found that CoRuTiSn has a tetragonal crystal structure. Magnetic measurements show non-zero but small hysteresis indicating CoRuTiSn as a soft ferromagnetic with a Curie temperature of ~200 K. The magnetic moment determined from magnetization data is found to be 0.84 μB/f.u. at 4 K, which is close to the value, calculated using first principles calculations. Electrical resistivity decreases with temperatures, indicating semiconducting nature of CoRuTiSn. Hall effect measurements show anomalous behavior, consistent with the ferromagnetic nature of the sample. The low moment ferromagnetic semiconducting nature of CoRuTiSn could make this material promising for semiconducting spintronics.

cond-mat.mtrl-sci

Interplay of structure, magnetism, and magneto-thermal effects in Gadolinium-based intermetallic compound

We study structural, magnetic and magneto-thermal properties of GdRhIn compound. The room temperature X-ray diffraction measurements show hexagonal crystal structure. Temperature and field dependence of magnetization suggest two magnetic transitions antiferromagnetic to ferromagnetic at 16 K and ferromagnetic to paramagnetic at 34. The heat capacity measurements confirm both the magnetic transitions in GdRhIn. The magnetization data was used to calculate isothermal magnetic entropy change and refrigerant capacity in GdRhIn, which was found to be 10.3 J/Kg-K for the field change of 70 kOe and 282 J/Kg for the field change of 50 kOe, respectively. The large magnetocaloric effect in GdRhIn suggests that the material could be used for magnetic refrigeration at low temperatures.

cond-mat.mtrl-sci

Exotic rare earth-based materials for emerging spintronic technology

The progress in materials science has always been associated with the development of functional materials systems, which enables us to design proof-of-concept devices. To advance further, theoretical predictions of new novel materials and their experimental realization is very important. This chapter reviews the intriguing properties of rare earth-based materials and their applications in spintronics. Spintronics is an emerging technology, which exploits spin degree of freedom of an electron along with its charge property. Discovery of various physical phenomena and their industrial applications in the field of magnetic sensors, magnetic recording and non-volatile memories such as magnetic random access memory (MRAM) and spin-transfer torque (STT) MRAM opens several new directions in this field. Materials with large spin polarization, strong spin-orbit coupling, and tunable electronic and magnetic properties offer an excellent platform for the spintronics technology. Combination of rare earths with other elements such as transition metals show broad range of structural, electronic, and magnetic properties which make them excellent candidates for various spintronic applications. This chapter discusses many such materials ranging from Heusler alloys, topological insulators to two-dimensional ferromagnets and their potential applications. The review gives an insight of how rare-earth materials can play a key role in emerging future technology and have great potential in many new spintronic related applications.

cond-mat.mtrl-sci

Magnetic phenomena in equiatomic ternary rare earth compounds

The chapter discusses the structural and magnetic properties of equiatomic ternary RTX compounds, where R represents rare earth, T is transition metal, and X belongs to the p block elements. RTX compounds exhibit a variety of crystal structures, which leads to a range of magnetic phenomenon ranging from long range antiferromagnetic-ferromagnetic ordering, unconventional superconductivity, magnetic frustration to spin ices. Coexistence of various magnetic phenomenon result in many exotic properties, which make these materials promising for next generation technological applications. In RTX family of compounds, most transition metals, except manganese, Mn do not contribute significantly to the magnetic moment and behave as non-magnetic. The lack of magnetic behaviour in the transition metal sublattices of these ternary compounds may be attributed to hybridization between p electron states of X atom and d electron states of the transition metal, resulting in the filling of the d band. The dominant interaction in these compounds is of Ruderman Kittel Kasuya Yosida type due to the localized nature of the 4f electrons in the rare earths. The magnetic transition temperature in these materials varies from ultra-low to high temperatures, making them suitable for integration into devices operating at room temperature. The RTX series discussed here encompasses all rare earth elements, a range of transition metals, and various p-block elements such as Al, Ga, In, Si, Ge, Sn, Sb, and Bi. Most of the materials studied are arc melted polycrystalline materials with some in the form of single crystal or thin films.

cond-mat.str-el

Experimental realization of a high Curie temperature CoFeRuSn quaternary Heusler alloy for spintronic applications

We synthesize CoFeRuSn equiatomic quaternary Heusler alloy using arc-melt technique and investigate its structural, magnetic and transport properties. The room temperature powder X-ray diffraction analysis reveals that CoFeRuSn crystallizes in cubic crystal structure with small amount of DO3 - disorder. The field dependence of magnetization shows non-zero but small hysteresis and saturation behavior up to room temperature, indicating soft ferromagnetic nature of CoFeRuSn. The magnetic moment estimated from the magnetization data is found to be 4.15 μB / f.u., which is slightly less than the expected Slater-Pauling rule. The deviation in the value of experimentally observed moment from the theoretical value might be due to small disorder in the crystal. The low temperature fit to electrical resistivity data show absence of quadratic temperature dependence of resistivity, suggesting half-metallic behavior of CoFeRuSn. The high Curie temperature and possible half-metallic behavior of CoFeRuSn make it a highly promising candidate for room temperature spintronic applications.

cond-mat.mtrl-sci

Carbon Emission Prediction on the World Bank Dataset for Canada

The continuous rise in CO2 emission into the environment is one of the most crucial issues facing the whole world. Many countries are making crucial decisions to control their carbon footprints to escape some of their catastrophic outcomes. There has been a lot of research going on to project the amount of carbon emissions in the future, which can help us to develop innovative techniques to deal with it in advance. Machine learning is one of the most advanced and efficient techniques for predicting the amount of carbon emissions from current data. This paper provides the methods for predicting carbon emissions (CO2 emissions) for the next few years. The predictions are based on data from the past 50 years. The dataset, which is used for making the prediction, is collected from World Bank datasets. This dataset contains CO2 emissions (metric tons per capita) of all the countries from 1960 to 2018. Our method consists of using machine learning techniques to take the idea of what carbon emission measures will look like in the next ten years and project them onto the dataset taken from the World Bank's data repository. The purpose of this research is to compare how different machine learning models (Decision Tree, Linear Regression, Random Forest, and Support Vector Machine) perform on a similar dataset and measure the difference between their predictions.

cs.LG

MAG-Net: Multi-task attention guided network for brain tumor segmentation and classification

Brain tumor is the most common and deadliest disease that can be found in all age groups. Generally, MRI modality is adopted for identifying and diagnosing tumors by the radiologists. The correct identification of tumor regions and its type can aid to diagnose tumors with the followup treatment plans. However, for any radiologist analysing such scans is a complex and time-consuming task. Motivated by the deep learning based computer-aided-diagnosis systems, this paper proposes multi-task attention guided encoder-decoder network (MAG-Net) to classify and segment the brain tumor regions using MRI images. The MAG-Net is trained and evaluated on the Figshare dataset that includes coronal, axial, and sagittal views with 3 types of tumors meningioma, glioma, and pituitary tumor. With exhaustive experimental trials the model achieved promising results as compared to existing state-of-the-art models, while having least number of training parameters among other state-of-the-art models.

eess.IV

Monolayer MoS2 field effect transistor with low Schottky barrier height with ferromagnetic metal contacts

Two-dimensional MoS2 has emerged as promising material for nanoelectronics and spintronics due to its exotic properties. However, high contact resistance at metal semiconductor MoS2 interface still remains an open issue. Here, we report electronic properties of field effect transistor devices using monolayer MoS2 channels and permalloy (Py) as ferromagnetic (FM) metal contacts. Monolayer MoS2 channels were directly grown on SiO2/Si substrate via chemical vapor deposition technique. The increase in current with back gate voltage shows the tunability of FET characteristics. The Schottky barrier height (SBH) estimated for Py/MoS2 contacts is found to be +28.8 meV (zero-bias), which is the smallest value reported so-far for any direct metal (magnetic or non-magnetic)/monolayer MoS2 contact. With the application of gate voltage (+10 V), SBH shows a drastic reduction down to a value of -6.8 meV. The negative SBH reveals ohmic behavior of Py/MoS2 contacts. Low SBH with controlled ohmic nature of FM contacts is a primary requirement for MoS2 based spintronics and therefore using directly grown MoS2 channels in the present study can pave a path towards high performance devices for large scale applications.

physics.app-ph

Magnetic and transport properties of Sb2Te3 doped with high concentration of Cr

We report on molecular beam epitaxy and properties of a magnetic topological insulator, Cr doped Sb2Te3. The composition analysis reveals that Cr replaces Sb site, and x-ray diffraction confirms that single phase textured crystal structure can be obtained for (CrxSb1-x)2Te3 with x up to 0.44. Further increase in x results in phase separation or precipitates in the material. The Curie temperature TC increases with x up to 0.44, and reaches to 250 K, which is the highest TC observed till now in magnetically doped topological insulators.

cond-mat.mtrl-sci

Competing magnetic and spin gap-less semiconducting behaviour in fully compensated ferrimagnet CrVTiAl: Theory and Experiment

We report the structural, magnetic and transport properties of polycrystalline CrVTiAl alloy along with first principles calculations. It crystallizes in the LiMgPdSn type structure with lattice parameter 6.14 Å at room temperature. Absence of (111) peak along with the presence of a weak (200) peak indicates the antisite disorder of Al with Cr and V atoms. The magnetization measurements reveal a ferrimagnetic transition near 710 K and a coercive field of 100 Oe at 3 K. Very low moment and coercive field indicate fully compensated ferrimagnetism in the alloy. Temperature coefficient of resistivity is found to be negative, indicating a characteristic of semiconducting nature. Absence of exponential dependence of resistivity on temperature indicates a gapless/spin-gapless semiconducting behaviour. Electronic and magnetic properties of CrVTiAl for three possible crystallograpic configurations are studied theoretically. All the three configurations are found to be different forms of semiconductors. Ground state configuration is a fully compensated ferrimagnet with band gaps 0.58 eV and 0.30 eV for up and down spin bands respectively. The next higher energy configuration is also ferrimagnetic, but has spin-gapless semiconducting nature. The highest energy configuration corresponds to a non-magnetic gapless semiconductor. The energy differences among these configurations are quite small ($<$ 1 $\mathrm{mRy/atom}$) which hints that at finite temperatures, the alloy exists in a disordered phase, which is a mixture of the three configurations. By taking into account the theoretical and the experimental findings, we conclude that CrVTiAl is a fully compensated ferrimagnet with predominantly spin gap-less semiconductor nature.

cond-mat.mtrl-sci