arXiv subjects

Sagnick Mukherjee

Publications and source records attributed to Sagnick Mukherjee.

At least 37 records · Page 2Linked to original sources

arXiv2026

The Role of Intrinsic Temperature and Vertical Mixing in Characterizing Sub-Neptune Atmospheres

Sub-Neptune planets are often modeled with a dense rocky or metal-rich interior beneath a thick hydrogen/helium (H/He) atmosphere; though their bulk densities could also be explained by a water-rich interior with a thin H/He atmosphere. Atmospheric composition provides a key mechanism to break this degeneracy between competing interior models. However, the overall composition of sub-Neptunes inferred from spectra obtained with the James Webb Space Telescope, remains debated in part due to differences in modeling assumptions. While previous studies explored parameter spaces such as stellar spectra, atmospheric metallicities, and carbon-to-oxygen ratios, they often assumed fixed intrinsic temperatures (Tint) and vertical eddy diffusion coefficients (Kzz) - two critical, yet poorly constrained, drivers of atmospheric chemistry. To address this, we present a self-consistent grid of models that covers the full plausible range of Tint (60 - 450 K) and Kzz (10^{5} - 10^{12} cm^2/s) using the open-source PICASO and VULCAN packages to better characterize sub-Neptune atmospheres. Focusing on K2-18b analogs, we demonstrate that Tint and Kzz significantly impact CH4, CO2, CO, NH3 and HCN abundances, with H2O being largely unaffected. Our work demonstrates that comprehensive parameter space exploration of thermal and mixing parameters is essential for accurate interpretation of sub-Neptune spectra, and that single-parameter assumptions can lead to misclassification of planetary interiors. We provide a diagnostic framework using multi-molecule observations to distinguish between competing atmospheric models and advance robust characterization of sub-Neptunes.

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arXiv2026

Uniform Forward-Modeling Analysis of Ultracool Dwarfs. IV. Benchmarking the Sonora Diamondback and Saumon & Marley (2008) Atmospheric Models Across Late-M, L, and T types with Low-Resolution 0.8-2.5 $μ$m Spectroscopy

(Abridged) We present a systematic assessment of two major cloudy atmospheric model grids -- SM08 (Saumon & Marley 2008) and Sonora Diamondback -- when applied to low-resolution near-infrared (0.8-2.5 $μ$m) spectroscopy. Our analysis focuses on a uniform sample of 142 age-benchmark brown dwarfs and planetary-mass objects spanning late-M, L, and T spectral types, with independently determined ages from 10 Myr to 10 Gyr. We perform forward-model spectral fitting for all benchmarks' IRTF/SpeX spectra ($R\sim$80-250) using both SM08 and Sonora Diamondback atmospheric models to infer effective temperatures, surface gravities, metallicities, radii, and cloud sedimentation efficiencies. The two model grids yield broadly consistent results. Among L4-L9 dwarfs, we identify a statistically significant, population-level age dependence of the cloud parameter $f_{\rm sed}$, with young benchmarks ($<300$ Myr) exhibiting systematically lower $f_{\rm sed}$ values than older counterparts. This trend is absent across L0-T5 and T0-T5, demonstrating that cloud properties vary with age and surface gravity and offering explanations for the observed gravity-dependent photometric properties at the late-L end of the L/T transition. By comparing spectroscopically inferred parameters with predictions from evolution models, we quantify systematic errors in the fitted atmospheric parameters and establish empirical calibrations to anchor future studies using these atmospheric models. Stacked residuals of the sample reveal wavelength-dependent data-model mismatches associated with key atomic and molecular absorption bands, highlighting the need for improved opacities and rainout chemistry. Finally, we show that including an interstellar-medium-like extinction term significantly improves the spectral fits, confirming and broadening previous findings and suggesting missing opacity sources in current cloudy models.

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arXiv2025

Challenges in the detection of gases in exoplanet atmospheres

Claims of detections of gases in exoplanet atmospheres often rely on comparisons between models including and excluding specific chemical species. However, the space of molecular combinations available for model construction is vast and highly degenerate. Only a limited subset of these combinations is typically explored for any given detection. As a result, apparent detections of trace gases risk being artifacts of incomplete modeling rather than robust identification of atmospheric constituents, especially in the low signal-to-noise regime. Using the sub-Neptune K2-18 b as a case study, we show that recent biosignature claims vanish when the model space is expanded, with numerous alternatives providing equally good or better fits. We demonstrate that the significance of a claimed detection relies on the choice of models being compared, and that model preference does not in itself imply the presence of a specific gas. We recommend treating model comparisons instead as relative adequacy tests, which should be supported by theoretical predictions and complementary metrics of statistical significance in order to attribute a signal to a particular gas.

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arXiv2025

The Impact of Irradiation on the Radius and Thermal Evolution of Transiting Brown Dwarfs

Masses and radii of transiting brown dwarfs can be measured directly in contrast to isolated field brown dwarfs, whose mass and radius inferences are model dependent. Therefore, transiting brown dwarfs are a testbed for the interior and evolutionary models of brown dwarfs and giant exoplanets. We have developed atmospheric and evolutionary models for this emerging population. We show that intense stellar irradiation can cause a large enhancement in the radius of transiting brown dwarfs at all masses, especially if the incident flux exceeds $log_{10}(F/cgs)\ge$9 ($T_{\rm eq}\ge 1450$ K). Stellar irradiation can significantly alter rates of nuclear burning in irradiated brown dwarfs, making the Deuterium-burning and Hydrogen-burning minimum masses strong functions of incident stellar flux. We show that the D-burning and H-burning minimum masses can decrease by 16% and 13%, respectively, between isolated and strongly irradiated brown dwarfs ( $log_{10}(F/cgs)\ge$10 ($T_{\rm eq}\ge 2570$ K)). This shows that stellar irradiation has a larger impact on the planet-brown dwarf-star mass boundaries than metallicity or clouds. We show that metal cores or migration affect their evolution to a much lesser extent, whereas low mass highly irradiated old sources can help us test the physics of hot Jupiter radius anomaly. We fit the observed radii of 46 transiting brown dwarfs and show that our irradiated evolutionary models fit their radii better than models that ignore the host star, especially for highly irradiated objects. However, the measured radii of 10 objects are still inconsistent at $>3σ$ level, indicating residual gaps in our irradiated evolutionary model.

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arXiv2025

The Sonora Substellar Atmosphere Models VI. Red Diamondback: Extending Diamondback with SPHINX for Brown Dwarf Early Evolution

We extend the Sonora Diamondback brown dwarf evolution models to higher effective temperatures to treat the evolution of younger, higher mass objects. Due to an upper temperature limit of $T_\mathrm{eff}=$2400 K in the original Sonora Diamondback model grid, high mass objects ($M\geq$ 0.05 $M_\mathrm{\odot}=$ 52.4 $M_\mathrm{J}$) were limited to ages of $\gtrsim$ 100 Myr. To include the early evolution of brown dwarfs at $T_\mathrm{eff}>$ 2400 K, we use existing and new SPHINX cloud-free model atmosphere calculations of temperature structures of M-type atmospheres. These atmospheres range from $T_\mathrm{eff}$ 2000--4000 K, log($g$) 3.0--5.5, and metallicity [M/H] $-$0.5 to $+$0.5. This combination of Diamondback and SPHINX atmospheres, with a transition across $T_\mathrm{eff}$ 2000--2400 K, allows us to calculate evolution tracks, and infrared photometry and colors, for ages $>$ 1 Myr and masses from above the hydrogen burning minimum mass down to planetary masses. The Hayashi phase of massive brown dwarf evolution (ages $<$ 10--100 Myr) at low surface gravity leads to nearly constant $T_\mathrm{eff}$ values, at effective temperatures much lower than would be obtained from simply extrapolating backwards from evolution tracks at older ages.

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arXiv2025

Bayesian Model Comparison and Significance: Widespread Errors and how to Correct Them

Bayes factors have become a popular tool in exoplanet spectroscopy for testing atmosphere models against one another. We show that the commonly used method for converting these values into significance "sigmas" is invalid. The formula is neither justified nor recommended by its original paper, and overestimates the confidence of results. We use simple examples to demonstrate the invalidity and prior sensitivity of this approach. We review the standard Bayesian interpretation of the Bayes factor as an odds ratio and recommend its use in conjunction with the Akaike Information Criterion (AIC) or Bayesian Predictive Information Criterion Simplified (BPICS) in future analyses (Python implementations are included) . As a concrete example, we refit the WASP-39 b NIRSpec transmission spectrum to test for the presence of SO$_2$. The prevalent, incorrect significance calculation gives $3.67σ$ whereas the standard Bayesian interpretation yields a null model probability $p(\mathcal{B}|y)=0.0044$. Surveying the exoplanet atmosphere literature, we find widespread use of the erroneous formula. In order to avoid overstating observational results and estimating observation times too low, the community should return to the standard Bayesian interpretation.

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arXiv2025

Condensation Clouds in Substellar Atmospheres with Virga

Here we present an open-source cloud model for substellar atmospheres, called Virga. The Virga-v0 series has already been widely adopted in the literature. It is written in Python and has heritage from the Ackerman & Marley (2001) model (often referred to as eddysed), used to study clouds on both exoplanets and brown dwarfs. In the development of the official Virga-v1 we have retained all the original functionality of eddysed and updated/expanded several components including the back-end optical constants data, calculations of the Mie properties, available condensate species, saturation vapor pressure curves and formalism for fall speeds calculations. Here we benchmark Virga by reproducing key results in the literature, including the SiO2 cloud detection in WASP-17 b and the brown dwarf Diamondback-Sonora model series. Development of Virga is ongoing, with future versions already planned and ready for release. We encourage community feedback and collaborations within the GitHub code repository.

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arXiv2025

A metal-poor atmosphere with a hot interior for a young sub-Neptune progenitor: JWST/NIRSpec transmission spectrum of V1298 Tau b

We present the JWST/NIRSpec G395H transmission spectrum of the young (10 - 20 Myr old) transiting planet V1298 Tau b (9.85+/-0.35 Re, Teq=670K). Combined HST and JWST observations reveal a haze free, H/He dominated atmosphere with a large scale height (~1500km), allowing detection of CO2 (35 sigma), H2O (30 sigma), CO (10 sigma), CH4 (6 sigma), SO2 (4 sigma) and OCS (3.5 sigma). Our observations probe several scale heights (~4.4 in the CO2 4.3 microns and ~3 in the 2.7 micron water band). The planet's mass, inferred from atmospheric scale height using free retrieval and grid modelling is 12+/-1 and 15+/-1.7Me respectively which is significantly lower than previous radial velocity estimates and confirm it as a 'gas-dwarf' sub-Neptune progenitor. We find an atmospheric super-solar metallicity (logZ=0.6^+0.4_-0.6 x solar) and a sub-solar C/O ratio (0.22^+0.06_-0.05). The atmospheric metallicity is low compared to matured sub-Neptunes by an order of magnitude. The CH4 abundance ([CH4]=-6.2^+0.3_-0.5) is ~7 sigma lower than equilibrium chemistry prediction. To adjust for the low methane abundance, the self-consistent grids favour a high internal temperature (~500K) and vertical mixing (Kzz ~10^7-10^8 cm2/s). These internal temperatures are inconsistent with predictions from evolutionary models, which expect ~100 - 200K at the current system age. We estimate a gas-to-core mass fraction between 0.1 - 8 %, with a core mass of 11 - 12 Me, consistent with in-situ gas dwarf formation. A deep atmospheric metallicity gradient may explain both the high internal temperature and low observable metallicity. Over time, mass loss from such an atmosphere could enhance its metallicity, potentially reconciling V1298 Tau b with mature sub-Neptunes.

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arXiv2025

Overcast mornings and clear evenings in hot Jupiter exoplanet atmospheres

Aerosols is an old topic in the young field of exoplanet atmospheres. Understanding what they are, how they form, and where they go has long provided a fertile playground for theorists. For observers, however, aerosols have been a multi-decade migraine, as their chronic presence hides atmospheric features. For hot Jupiters, the large day-night temperature contrast drives inhomogeneous thermal structures and aerosol distribution, leading to different limb properties probed by transit spectra. We present JWST NIRISS/SOSS spectra of morning and evening limbs for nine gas giants with equilibrium temperatures of ~800-1700 K. By measuring feature size of the 1.4 $μ$m water band for both limbs, we found three planets (WASP-39 b, WASP-94 Ab, and WASP-17 b) show prominent ($>$5$σ$) limb-limb atmospheric opacity difference with muted morning and clear evening limbs. The heavily muted water features on morning limbs indicate high-altitude (0.1 to 0.01 mbar) aerosols. To simultaneously have clear evening limbs requires processes with timescales ($\sim$day) comparable to advection to remove these lofted grains, and we found that both downwelling flow and dayside cloud evaporation could be plausible mechanisms. We hypothesize an empirical boundary--termed the "asymmetry horizon"--in temperature-gravity space that marks the transition where inhomogeneous aerosol coverage begins to emerge. Heterogeneous aerosol coverage is common among hot Jupiters. If unrecognized, limb averaging suppresses spectral features, mimicking high-mean-molecular-weight atmospheres, inflating inferred metallicity by up to 2 dex, and underestimating limb temperatures by as much as half. Finally, we introduce the Limb Spectroscopy Metric (LSM) to predict limb spectral feature size based on planet parameters.

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arXiv2025

A Precise Metallicity and Carbon-to-Oxygen Ratio for a Warm Giant Exoplanet from its Panchromatic JWST Emission Spectrum

WASP-80 b, a warm sub-Jovian (equilibrium temperature ~820 K, 0.5 Jupiter masses), presents an opportunity to characterize a rare gas giant exoplanet around a low-mass star. In addition, its moderate temperature enables its atmosphere to host a range of carbon and oxygen species (H$_2$O, CH$_4$, CO, CO$_2$, NH$_3$). In this paper, we present a panchromatic emission spectrum of WASP-80 b, the first gas giant around a late K/early M-dwarf star and the coolest planet for which the James Webb Space Telescope has obtained a complete emission spectrum spanning 2.4-12 $μ$m, including NIRCam F322W2 (2.4-4 $μ$m) and F444W (4-5 $μ$m), and MIRI LRS (5-12 $μ$m). We report confident detections of H$_2$O, CH$_4$, CO, and CO$_2$, and a tentative detection of NH$_3$. We estimate WASP-80 b's atmospheric metallicity and carbon-to-oxygen ratio and compare them with estimates for other gas giants. Despite the relative rarity of giant planets around low-mass stars, we find that WASP-80 b's composition is consistent with other hot gas giants, suggesting that the formation pathway of WASP-80 b may not be dissimilar from hot gas giants around higher-mass stars.

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arXiv2025

A 1.48-2.48 $\mathrmμ$m R=28000 spectroscopic atlas of the L7.5 and T0.5 components of the nearest pair of brown dwarfs: Luhman 16AB

We present a high signal-to-noise (SNR $\sim$ 450), high-dispersion ($R \equiv λ/ Δλ\sim 28\,000$) H- and K-band spectroscopic atlas of the L7.5 and T0.5 components of the Luhman 16AB binary (WISE J104915.57$-$531906.1AB): the closest pair of brown dwarfs, and one of the best substellar benchmarks. The spectra were combined from a 70-day spectroscopic monitoring campaign of the binary with IGRINS on Gemini South. We fit model photospheres to the combined high-quality spectra to estimate atmospheric parameters. The model is based on the Sonora model atmosphere further incorporating the effects of clouds and disequilibrium. We detect ammonia (NH3) lines in both binary components, making Luhman 16A the warmest object where individual NH3 lines were identified. We discover hydrogen (H2), hydrogen sulfide (H2S), and hydrogen fluoride (HF) lines in both components, following recent reports of these species in either cooler (H2, H2S in a T6 dwarf) or warmer (HF in young late-M or mid-L dwarfs) objects. Methane (CH4) shows a small contribution, with lines sensitive to the slight temperature difference spanning the L/T transition. Against model expectations, we do not detect FeH lines, implying more efficient iron rainout than incorporated in the models. We find various unidentified features in water-dominated regions, likely the result of residual inaccuracies in the water line lists. We searched for planetary-mass companions by periodogram analysis of radial velocities over 70 days but detected no significant signal. The upper limits of projected planetary mass are $M\sin{i}=$ 0.2 $M_{\mathrm{J}}$ and 0.3 $M_{\mathrm{J}}$ at P $\sim$ 1 day, and 0.4 $M_{\mathrm{J}}$ and 0.7 $M_{\mathrm{J}}$ at P $\sim$ 10 days for Luhman 16A and B, respectively.

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arXiv2025

A Panchromatic Characterization of the Evening and Morning Atmosphere of WASP-107 b: Composition and Cloud Variations, and Insight into the Effect of Stellar Contamination

Limb-resolved transmission spectroscopy has the potential to transform our understanding of exoplanetary atmospheres. By separately measuring the transmission spectra of the evening and morning limbs, these atmospheric regions can be individually characterized, shedding light into the global distribution and transport of key atmospheric properties from transit observations alone. In this work, we follow up the recent detection of limb asymmetry on the exoplanet WASP-107 b (Murphy et al. 2024) by reanalyzing literature observations of WASP-107 b using all of JWST's science intruments (NIRISS, NIRCam, NIRSpec, and MIRI) to measure its limb transmission spectra from $\sim$1-12 $μ$m. We confirm the evening--morning temperature difference inferred previously and find that it is qualitatively consistent with predictions from global circulation models. We find evidence for evening--morning variation in SO$_2$ and CO$_2$ abundance, and significant cloud coverage only on WASP-107 b's morning limb. We find that the NIRISS and NIRSpec observations are potentially contaminated by occulted starspots, which we leverage to investigate stellar contamination's impact on limb asymmetry measurements. We find that starspot crossings can significantly bias the inferred evening and morning transmission spectra depending on when they occur during the transit, and develop a simple correction model which successfully brings these instruments' spectra into agreement with the uncontaminated observations.

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arXiv2025

The Sonora Substellar Atmosphere Models. V: A Correction to the Disequilibrium Abundance of CO$_2$ for Sonora Elf Owl

To aid the interpretation of observations of substellar atmospheres, Mukherjee et al. (2024) created the Sonora Elf Owl grid of model atmospheres, simulations that accounted for disequilibrium quench chemistry. However, Sonora Elf Owl did not accurately estimate CO$_2$ quenching because the models quenched the gas with respect to the full atmosphere equilibrium, but CO$_2$ should have instead been quenched with respect to the disequilibrium (i.e., quenched) abundance of CO. As a result, Sonora Elf Owl under-predicted the CO$_2$ abundance by several order of magnitude in some instances, an amount that JWST is sensitive to. Here, we release version two of the Sonora Elf Owl grid which has corrected CO$_2$ concentrations. Additionally, in version two we remove PH$_3$ as a spectral contributor since our spectra consistently contained too much PH$_3$ absorption. The new spectra can be found as an update to the original Zenodo postings.

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arXiv2025

A JWST Panchromatic Thermal Emission Spectrum of the Warm Neptune Archetype GJ 436b

GJ 436b is the archetype warm Neptune exoplanet. The planet's thermal emission spectrum was previously observed via intensive secondary eclipse campaigns with Spitzer. The atmosphere has long been interpreted to be extremely metal-rich, out of chemical equilibrium, and potentially tidally heated. We present the first panchromatic emission spectrum of GJ 436b observed with JWST's NIRCAM (F322W2 and F444W) and MIRI (LRS) instruments between 2.4 and 11.9 $μ$m. Surprisingly, the JWST spectrum appears significantly fainter around 3.6 $μ$m than that implied by Spitzer photometry. The molecular absorption features in the spectrum are relatively weak, and we only find tentative evidence of CO$_2$ absorption at 2$σ$ significance. Under the assumption of a day-side blackbody, we find $T_{\rm day}$=662.8$\pm$5.0 K, which is similar to the zero Bond albedo equilibrium temperature. We use it to obtain a 3$σ$ upper limit on the Bond albedo of $A_B{\le}$0.66. To understand the spectrum we employ 1D radiative-convective models but find that atmospheric constraints depend strongly on model assumptions. If thermochemical equilibrium is assumed, we find a cloudy metal-enriched atmosphere (metallicity $\ge$ 300$\times$solar). We employ 1D photochemical modeling to show that the observed spectrum is also consistent with a cloud-free, relatively lower-metallicity atmosphere (metallicity $\ge$ 80$\times$solar) with a cold internal temperature ($T_{\rm int}$$\sim$60 K). These are much lower metallicities and internal temperatures than inferences from Spitzer photometry. The low $T_{\rm day}$ and non-detection of transmission features at high spectral resolution does suggest a role for cloud opacity, but this is not definitive.

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arXiv2025

Atmospheric abundances and bulk properties of the binary brown dwarf Gliese 229 Bab from JWST/MIRI spectroscopy

We present JWST/MIRI low-resolution spectroscopy ($4.75-14~μ$m) of the first known substellar companion, Gliese 229 Bab, which was recently resolved into a tight binary brown dwarf. Previous atmospheric retrieval studies modeling Gliese 229 B as a single brown dwarf have reported anomalously high carbon-to-oxygen ratios (C/O) of $\approx 1.1$ using $1-5~μ$m ground-based spectra. Here, we fit the MIRI spectrum of Gliese 229 Bab with a two-component binary model using the Sonora Elf Owl grid and additionally account for the observed $K$ band flux ratio of the binary brown dwarf. Assuming the two brown dwarfs share the same abundances, we obtain $\rm C/O=0.65\pm0.05$ and $\rm [M/H]=0.00^{+0.04}_{-0.03}$ as their abundances ($2σ$ statistical errors), which are fully consistent with the host star abundances. We also recover the same abundances if we fit the MIRI spectrum with a single brown dwarf model, indicating that binarity does not strongly affect inferred abundances from mid-infrared data when the $T_\rm{eff}$ are similar between components of the binary. We measure $T_\rm{eff}=900^{+78}_{-29}~$K and $T_\rm{eff}=775^{+20}_{-33}~$K for the two brown dwarfs. We find that the vertical diffusion coefficients of $\log{K_\rm{zz}} \approx4.0$ are identical between the two brown dwarfs and in line with $\log{K_\rm{zz}}$ values inferred for isolated brown dwarfs with similar $T_\rm{eff}$. Our results demonstrate the power of mid-infrared spectroscopy in providing robust atmospheric abundance measurements for brown dwarf companions and by extension, giant planets.

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arXiv2025

The JWST Early Release Science Program for Direct Observations of Exoplanetary Systems III: Aperture Masking Interferometric Observations of the star HIP 65426 at 3.8 um

We present aperture masking interferometry (AMI) observations of the star HIP 65426 at $3.8\,\rm{μm}$ as a part of the JWST Direct Imaging Early Release Science (ERS) program obtained using the Near Infrared Imager and Slitless Spectrograph (NIRISS) instrument. This mode provides access to very small inner working angles (even separations slightly below the Michelson limit of $0.5λ/D$ for an interferometer), which are inaccessible with the classical inner working angles of the JWST coronagraphs. When combined with JWST's unprecedented infrared sensitivity, this mode has the potential to probe a new portion of parameter space across a wide array of astronomical observations. Using this mode, we are able to achieve a $5σ$ contrast of $Δm{\sim}7.62{\pm}0.13$ mag relative to the host star at separations ${\gtrsim}0.07{"}$, and the contrast deteriorates steeply at separations ${\lesssim}0.07{"}$. However, we detect no additional companions interior to the known companion HIP 65426 b (at separation ${\sim}0.82{"}$ or, $87^{+108}_{-31}\,\rm{au}$). Our observations thus rule out companions more massive than $10{-}12\,\rm{M_{Jup}}$ at separations ${\sim}10{-}20\,\rm{au}$ from HIP 65426, a region out of reach of ground or space-based coronagraphic imaging. These observations confirm that the AMI mode on JWST is sensitive to planetary mass companions at close-in separations (${\gtrsim}0.07{"}$), even for thousands of more distant stars at $\sim$100 pc, in addition to the stars in the nearby young moving groups as stated in previous works. This result will allow the planning and successful execution of future observations to probe the inner regions of nearby stellar systems, opening an essentially unexplored parameter space.

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arXiv2025

Statistical trends in JWST transiting exoplanet atmospheres

Our brains are hardwired for pattern recognition as correlations are useful for predicting and understanding nature. As more exoplanet atmospheres are being characterized with JWST, we are starting to unveil their properties on a population level. Here we present a framework for comparing exoplanet transmission spectroscopy from 3 to 5$μ$m with four bands: L (2.9 - 3.7$μ$m), SO$_2$ (3.95 - 4.1$μ$m), CO$_2$ (4.25 - 4.4$μ$m) and CO (4.5 - 4.9$μ$m). Together, the four bands cover the major carbon, oxygen, nitrogen, and sulfur-bearing molecules including H$_2$O, CH$_4$, NH$_3$, H$_2$S, SO$_2$, CO$_2$, and CO. Among the eight high-precision gas giant exoplanet planet spectra we collected, we found strong correlations between the SO$_2$-L index and planet mass (r=-0.41$\pm$0.09) and temperature (r=-0.64$\pm$0.08), indicating SO$_2$ preferably exists (SO$_2$-L$>$-0.5) among low mass ($\sim<$0.3M$_J$) and cooler ($\sim<$1200K) targets. We also observe strong temperature dependency for both CO$_2$-L and CO-L indices. Under equilibrium chemistry and isothermal thermal structure assumptions, we find that the planet sample favors super-solar metallicity and low C/O ratio ($<$0.7). In addition, the presence of a mass-metallicity correlation is favored over uniform metallicity with the eight planets. We further introduce the SO$_2$-L versus CO$_2$-L diagram alike the color-magnitude diagram for stars and brown dwarfs. All reported trends here will be testable and be further quantified with existing and future JWST observations within the next few years.

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arXiv2024

Disequilibrium Chemistry, Diabatic Thermal Structure, and Clouds in the Atmosphere of COCONUTS-2b

Located 10.888 pc from Earth, COCONUTS-2b is a planetary-mass companion to a young (150-800 Myr) M3 star, with a wide orbital separation (6471 au) and a low companion-to-host mass ratio ($0.021\pm0.005$). We have studied the atmospheric properties of COCONUTS-2b using newly acquired 1.0-2.5 $μ$m spectroscopy from Gemini/Flamingos-2. The spectral type of COCONUTS-2b is refined to T$9.5 \pm 0.5$ based on comparisons with T/Y dwarf spectral templates. We have conducted an extensive forward-modeling analysis, comparing the near-infrared spectrum and mid-infrared broadband photometry with sixteen state-of-the-art atmospheric model grids developed for brown dwarfs and self-luminous exoplanets near the T/Y transition. The PH$_{3}$-free ATMO2020++, ATMO2020++, and Exo-REM models best match the specific observations of COCONUTS-2b, regardless of variations in the input spectrophotometry. This analysis suggests the presence of disequilibrium chemistry, along with a diabatic thermal structure and/or clouds, in the atmosphere of COCONUTS-2b. All models predict fainter $Y$-band fluxes than observed, highlighting uncertainties in the alkali chemistry models and opacities. We determine a bolometric luminosity of $\log{(L_{\rm bol}/L_{\odot})}=-6.18$ dex, with a 0.5 dex-wide range of $[-6.43,-5.93]$ dex that accounts for various assumptions of models. Using thermal evolution models, we derive an effective temperature of $T_{\rm eff}=483^{+44}_{-53}$ K, a surface gravity of $\log{(g)}=4.19^{+0.18}_{-0.13}$ dex, a radius of $R=1.11^{+0.03}_{-0.04}$ R$_{\rm Jup}$, and a mass of $M=8 \pm 2$ M$_{\rm Jup}$. Various atmospheric model grids consistently indicate that COCONUTS-2b's atmosphere has sub- or near-solar metallicity and C/O. These findings provide valuable insights into COCONUTS-2b's formation history and the potential outward migration to its current wide orbit.

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