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Sagnick Mukherjee

Publications and source records attributed to Sagnick Mukherjee.

At least 19 recordsLinked to original sources

A JWST transiting survey of FGK stellar limb darkening: empirical evidence for quadratic laws and atmospheric model comparisons

We present a study of stellar limb-darkening using JWST transit observations of seven exoplanets orbiting FGK host stars, spanning 4200-6800 K. The wide wavelength coverage and high S/N of NIRISS/SOSS and NIRSpec/PRISM enable precise constraints on the wavelength-dependent limb-darkening. Using Bayesian model selection, we find that the quadratic limb-darkening law is statistically preferred over higher-order laws for most FGK stars, recovers consistent intensity profiles for $>$95% of the stellar disk area, and introduces a minimal bias in the derived transit depths of only $\sim$14 ppm (1$\sigma$) for 6/7 targets. This contrasts with previous studies relying on stellar models. We compare the empirically derived quadratic coefficients to predictions from the PHOENIX, MPS-ATLAS, MURaM, and Stagger stellar atmosphere grids. We introduce a quadratic limb-darkening parameterization in terms of limb intensity ($\ell$) and curvature at mid-$\mu$ ($\delta$), finding that empirical FGK limb darkening is generally more linear than models predict ($\delta \lesssim 0.1$). We identify wavelength-independent offsets between data and model quadratic coefficients, minimized by adopting $\mu_{\rm min} = 0.2$ in intensity calculations; we attribute this in part to models overpredicting limb-darkening near the limb where the plane-parallel approximation breaks down. For spherical PHOENIX models, we derive a $\mu$ rescaling method using a $\tau = 1$ photospheric radius. With these corrections, residual offsets are minimized and all stellar models achieve statistically acceptable fits. We provide recommended limb-darkening offset priors for use in JWST transit analyses, enabling more accurate constraints on exoplanet transmission spectra while accounting for residual stellar model uncertainties.

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A Clearer View of HAT-P-1 b: JWST NIRSpec G395H Reveals Water, Carbon Dioxide, and Possibly Hydrogen Sulfide

As part of JWST's Exoplanet Grand Tour Survey, we use panchromatic transmission spectroscopy to connect HAT-P-1 b's previously studied optical and near-infrared atmosphere to the longer-wavelength molecular bands accessible with JWST. We present JWST NIRSpec G395H transmission spectroscopy of the hot Jupiter HAT-P-1 b over 2.7--5.3~$\mu$m, and combine the new spectrum with archival HST STIS and WFC3 observations for a 0.3--5.3~$\mu$m atmospheric analysis. We independently reduce the JWST data with the Eureka!, FIREFLy, and Tswift pipelines, finding mutually consistent transmission spectra across the G395H bandpass. Atmospheric retrievals yield strong evidence for H$_2$O and CO$_2$ with Bayes factors of $\log_{10}B_{\mathrm{H_2O}}=8.9$ and $\log_{10}B_{\mathrm{CO_2}}=52.3$, while providing tentative evidence for H$_2$S ($\log_{10}B_{\mathrm{H_2S}}=1.4$). The joint H$_2$O and CO$_2$ constraints favor an atmosphere near chemical equilibrium, with $\log_{10} \text{M/H}=0.99^{+0.19}_{-0.14}$, corresponding to $\sim10\times$ Solar or $\sim9\times$ relative to the near-solar metallicity host star, and a 3$\sigma$ upper limit of C/O $<0.52$. Because H$_2$O and CO$_2$ provide a metallicity comparatively insensitive to vertical mixing in this temperature regime, their combined detection suggests the composition is dominated by bulk enrichment rather than strong disequilibrium transport. We find no significant evidence for clouds; instead, the persistence of molecular structure across the spectrum argues against strong cloud muting. The tentative H$_2$S signal, if confirmed, would further suggest limited photochemical processing at the pressures probed. Together, the molecular inventory, enriched metallicity, and low C/O ratio point to an oxygen-rich atmosphere and establish HAT-P-1 b as a benchmark for comparative studies of hot-Jupiter atmospheric composition.

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JWST color sequence of transiting exoplanets and directly imaged substellar objects

Color-magnitude diagrams (CMDs) have been foundational across astrophysics, from galaxies and stars to brown dwarfs, and JWST now extends them to transiting exoplanets and self-luminous substellar objects at overlapping temperatures. We compile JWST dayside emission spectra for 13 transiting giant planets, 57 self-luminous objects, and the irradiated brown dwarf ZTF J0038+2030 B, spanning ~350-2600 K and log g = 2.5-5.5, plus ~2150 SPHEREx ultracool dwarfs, converted to synthetic photometry in 2MASS J/Ks and five NIRCam medium bands isolating H2O, CH4, CO2, and CO. Low gravity and inflated radii make transiting planets resemble young substellar objects, with shallower features and redder colors from high-altitude clouds that raise the photosphere. Transiting planets follow the L-dwarf sequence on the J versus J-K CMD, with WASP-80 b (T_eq~800 K) showing no T-dwarf-like blueward turn, suggesting a delayed or suppressed L/T transition in irradiated, low-gravity atmospheres. Methane onset is delayed from substellar to transiting-planet atmospheres, and cloudy radiative-convective models indicate that lower gravity and cloud back-warming shift atmospheres toward CO-dominated chemistry, suppressing photospheric CH4. The irradiated but old, high-gravity brown dwarf ZTF J0038+2030 B (T_day = 1049 K, log g = 5.4) shows a deep, field-T-dwarf-like dayside methane band, implicating gravity rather than irradiation as the dominant control. CO2-to-CO diagnostics place transiting and directly imaged planetary-mass companions at stronger relative CO2 absorption than field brown dwarfs, consistent with metallicity enhancement from planetesimal accretion. These CMD sequences provide a unified, model-testable map for self-luminous and irradiated atmospheres.

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Asymmetric Aerosol Distribution on the Terminators of the Warm Saturn WASP-69 b Revealed by JWST NIRISS/SOSS

How aerosols form, are transported, and cycle between condensation and evaporation across exoplanet temperature regimes remains poorly understood. Recent models and observations suggest that warm giant planets near $800$--$1000$ K may span a transition between homogeneous and longitudinally heterogeneous aerosol distributions. We present a robust detection of aerosol asymmetry in a giant planet with $T_{\rm eq}\lesssim1000$ K, using the $0.86$--$2.82~\mu$m JWST NIRISS/SOSS transmission spectrum of WASP-69 b. The evening limb shows prominent 1.4 $\mu$m H$_2$O absorption ($\Delta\mathrm{BIC}_{\rm H_2O}=+22.7$), whereas H$_2$O is not detected on the morning limb ($\Delta\mathrm{BIC}_{\rm H_2O}=-8.7$). Atmospheric retrievals reveal significant aerosol opacity on both limbs, with high-altitude, optically thick clouds muting molecular features on the morning limb and lower cloud opacity allowing H$_2$O to emerge on the evening limb. The evening terminator is hotter by $304^{+62}_{-91}$ K, consistent with morning-limb condensates partially evaporating during transport toward the evening limb. This mechanism is independently verified with 3D general circulation models. Stellar contamination or aerosols dominated by photochemical haze do not readily explain the asymmetry. From a limb-resolved analysis, we infer a stellar-to-superstellar atmospheric metallicity, with $\rm[M/H]=0.11^{+0.40}_{-0.46}$ from the equilibrium retrieval and [O/H]$=1.38^{+0.44}_{-0.79}$ from the free retrieval. We also detect an escaping metastable-helium tail extending to $3.08^{+0.50}_{-0.45}\,R_p$. WASP-69 b anchors the cooler edge of the emerging population of planets with asymmetric aerosol distributions and suggests that substantial aerosol opacity may persist on both limbs across this transition.

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JWST/NIRSpec Spectra for Three Ultracool Brown Dwarfs Detected in Extragalactic Surveys: Further Evidence for Phosphine Absorption

We present JWST NIRSpec prism spectra for three ultracool brown dwarfs discovered in extragalactic survey data, two from the JWST Advanced Deep Extragalactic Survey (JADES), and one from Public Release IMaging for Extragalactic Research (PRIMER) survey observed as part of the Mirage or Miracle (MoM) program. The spectra for these sources indicate that one is a T6 dwarf (JADES-GS-BD-11, T$_{\mathrm{eff}} = \sim 700$ K) and two are Y0-Y1 dwarfs (JADES-GS-BD-5, T$_{\mathrm{eff}} = \sim 400$ K, and MoM-239450, T$_{\mathrm{eff}} = \sim 500$ K). Model atmospheric fits with $\texttt{NIFTY}$ to the spectra are consistent with this classification, and indicate that JADES-GS-BD-5 is only $\sim 150$ pc from the Sun, MoM-239450 is $\sim 700 - 800$ pc from the Sun, and JADES-GS-BD-11 is $\sim 1$ kpc from the Sun, with these latter two more distant sources being best fit at sub-solar metallicities. JADES-GS-BD-5 has an observed spectrum with significantly weaker J and H band emission than Y dwarf atmospheric models, potentially indicating the presence of water ice clouds in the brown dwarf. The spectrum for JADES-GS-BD-11 has a feature at 4.3$\mu$m consistent with absorption from the rarely seen phosphine molecule at $2.6\sigma$ confidence. Given the low metallicity for this source ([M/H] $ = -0.7$), our finding supports the theory that detecting phosphine in brown dwarf atmospheres is tied to atmospheric metallicity. JWST/NIRSpec spectroscopy continues to be a powerful tool for understanding the properties of these distant, and very cold brown dwarfs.

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The Sonora Substellar Atmosphere Models. VII. Flame Skimmer: Cloud-free Atmospheric and Evolutionary Models for the Coldest Substellar Objects

JWST has provided unprecedented access to ultra-cool brown dwarfs and has pushed the boundaries of directly imaging temperate giant planets. As we continue to push toward detecting sub-Saturn and Neptune-like planets, it is crucial to develop atmospheric and evolutionary models that better capture the complexity and diversity of planetary atmospheres similar to the gas and ice giants in our Solar System. We present Sonora Flame Skimmer, the next suite of cloud-free 1D atmospheric and evolutionary models in chemical equilibrium and disequilibrium probing colder temperatures (down to 50 K), smaller objects (down to log(g) = 2), and a wide range of metallicities (10x sub-solar to 100x super-solar) and C/O ratios (solar to 2.5x solar). Beyond expanding the physical parameter space of previous Sonora models, we update the opacities and evolutionary model framework from Sonora Bobcat, as well as the chemical treatment of volatiles (H$_2$O, CH$_4$, NH$_3$) and carbon species such as CO$_2$ from Sonora Elf Owl. For the evolution of these substellar objects, we find that high-metallicity atmospheres lead to slower cooling compared to solar metallicity, while the strength of vertical mixing ($K_{\rm zz}$) has a negligible impact on the evolutionary tracks. At the highest metallicity explored here (100$\times$ solar), the deuterium-burning and hydrogen-burning minimum masses fall to 5.39 and 45.03 $M_{\rm J}$, respectively. All the models presented here, including the atmospheric structure, chemical profiles, spectra, synthetic photometry, and evolutionary models, are publicly available.

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The JWST Early Release Science Program for Direct Observations of Exoplanetary Systems VIII: patchy forsterite and enstatite clouds in the atmosphere of VHS 1256 b, retrieval lessons learned and outlook to the future

JWST defines a new era for the data-driven approach of retrieval modelling, which has become a cornerstone tool for the statistical inference of exoplanetary and brown dwarf properties. The Early Release Science program #1386 observations of VHS 1256 b represent a huge jump in data quality, data quantity and spectral coverage for such objects. VHS 1256 b is a young, planetary mass and extremely variable companion that populates the enigmatic L/T cohort of substellar atmospheres. In this first retrieval analysis of the full 1 - 18 micron dataset, we apply the Brewster retrieval framework to the NIRSpec and MIRI spectroscopic observations of VHS 1256 b, exploring a variety of cloud species and structures. Using Delta(BIC) we find that the data is best described by a forsterite (Mg$_{2}$SiO$_{4}$) and enstatite (MgSiO$_{3}$) cloud combination. Our analysis shows a strong preference for patchy silicate cloud coverage, which aligns with VHS 1256 b's extensive and well documented spectral variability. Our retrieval is able to place constraints on the abundances of H$_{2}$O, CO, CO$_{2}$, CH$_{4}$ as well as NH$_{3}$. We also show that the retrieved parameters are sensitive to the data used and the relative signal-to-noise ratios between data from different instruments. We conclude with the next steps for the wider retrieval community to better understand young and cloudy exoplanetary atmospheres.

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Mitigating Charge Migration in JWST NIRISS Reveals That KELT-7 b is a Metal-enriched Ultra-hot Jupiter Orbiting a Young Metal-rich Star

We present the first panchromatic JWST transmission spectrum of an ultra-hot Jupiter, combining NIRISS and NIRSpec observations to constrain KELT-7\,b's atmospheric properties. We show evidence for charge migration in our NIRISS SOSS observation between 1--1.5~$\mu$m, a wavelength range crucial to test for enhanced H$^-$ previously inferred from HST WFC3/IR G141 observations. We mitigate charge migration by fitting the ramp after extracting 1D stellar spectra at the group level. This ``late-ramp-fit'' method accurately calculates KELT-7\,b's transmission spectrum between 1--1.5~$\mu$m at higher signal-to-noise. Using the transit-derived stellar mean density during stellar property inference reveals that KELT-7 is a $640\pm100$ Myr-old, $[\text{Fe}/\text{H}]=0.46\pm0.02$ star. Combined with NIRSpec and re-reduced WFC3/UVIS G280 data, our free retrieval analysis shows strong evidence for H$_2$O, CO$_2$, and TiO among high-temperature species, but not H$^-$ or clouds. Unaccounted-for systematics may therefore bias longer-wavelength WFC3/IR G141 transit depths shallower. Our free retrieval, two equilibrium retrievals, and self-consistent grid fit all prefer a high metallicity but find discrepant C/O ratios. Agglomerated together, we constrain a super-stellar $\text{M/H}=92^{+24}_{-23}\times$~Solar and C/O~$\leq0.9$, suggesting enhanced metal accretion in the later stages of KELT-7\,b's formation. Our GCMs explain the observed lack of limb asymmetry with superrotating jet-driven efficient horizontal mixing. The stark contrast between our panchromatic analysis and prior analyses on subsets of these data demonstrates the value of broad wavelength coverage for the comprehensive study of exoplanet atmospheres.

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KRONOS I: The $1{-}2.8\mu$m JWST Transmission Spectrum of the 23 Myr V1298 Tau c

While recent JWST observations of mature super-Earths and sub-Neptunes have frequently revealed featureless transmission spectra, their inflated progenitors offer a unique window into understanding their primordial compositions. As part of the Keys to Revealing the Origin and Nature Of sub-neptune Systems (KRONOS) JWST program, we present the NIRISS/SOSS transmission spectrum of V1298 Tau c, a $\sim$23 Myr super-Earth progenitor orbiting a young Solar analog. We detect H$_2$O in V1298 Tau c's atmosphere with a $\log_{10}$ volume mixing ratio of $-1.83^{+0.68}_{-0.77}$, but no additional molecules from these data alone. We find consistent results for the planetary atmospheric properties in both retrievals with and without informed priors on stellar heterogeneities based on the observed stellar spectrum. We infer an atmospheric metallicity [O/H] of $14.8^{+56.0}_{-12.28}\times$ the solar value. This metallicity is similar to literature measurements for other young planets, including its massive outer companion V1298~Tau~b. In contrast, this measured metallicity is systematically lower than the metallicities of mature planets of similar mass and temperature. Altogether, these results provide tentative but growing evidence that the exoplanet mass--metallicity relation evolves with planetary age.

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Photochemical CS$_2$ Gas Detected on a 20-Myr-old Exoplanet

Probing the atmospheres of young exoplanets offers a powerful window into how planetary systems evolve and the physical and chemical processes that drive those early evolutions. We present JWST/NIRSpec transmission spectroscopy of V1298 Tau e, a $\sim$20-Myr-old, $\sim$15-$M_\oplus$ planet with a Jupiter-like radius orbiting a young Sun-like star. We identified carbon disulfide (CS$_2$) in its atmosphere at $>$8$\sigma$ significance based on spectral features between 4.3 and 4.7~$\mu$m. Photochemical forward models show that the inferred CS$_2$ abundance is physically plausible in an H/He-dominated atmosphere exposed to intense ultraviolet irradiation. The atmosphere of V1298 Tau e is strikingly different from its nearest neighboring planet b, whose atmosphere shows SO$_2$ rather than CS$_2$. These observations demonstrate that even planets within the same system can occupy distinct photochemical regimes. Our results further provide empirical evidence for complex sulfur photochemistry in exoplanet atmospheres in general and may also point to divergent formation or evolutionary pathways within the same planetary system.

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Impact of Clouds on the Atmosphere-Mantle Interface of Sub-Neptunes

Sub-Neptunes are among the most common type of close-in planets found in our galaxy, yet their bulk composition remains largely uncertain; H-rich envelopes overlaying rocky cores, volatile-rich planets, and carbon-rich interiors all remain viable configurations for members of this population. Atmospheric characterization has been proposed as a means of distinguishing between these scenarios, but growing evidence suggests that sub-Neptunes may host molten atmosphere-mantle interfaces which could alter the composition of their atmosphere. We use the PICASO 1D climate model, coupled to interior-structure and magma-atmosphere chemistry frameworks to quantify how clouds alter the atmospheric and interior structure of sub-Neptunes. For temperate sub-Neptunes like TOI-270 d, we find that clouds can lead to $\ge{1000}$ K heating at depth (${\sim}10^{4}$ bar) and $\sim{600}$ K cooling at shallow pressures ($\sim$1 bar). This heating is very sensitive to the cloud sedimentation efficiency and, to a lesser extent, to metallicity. Most sub-Neptunes in our sample should have a molten atmosphere-mantle interface, except TOI-1231 b and GJ 1214 b. For these two planets, cloudy models have a molten interface whereas clear models can allow a solid boundary. Clouds can heat the atmosphere-mantle interfaces by a temperature difference between $\sim{1400}-2600$ K for most sub-Neptunes in our sample. Such cloud-driven heating can substantially change the composition of the interface with abundances of O$_2$, SiH$_4$, and SiO showing a $\ge{36}$\% increase between cloudy and clear models of TOI-270 d. We discuss the implications of our results for the thermal evolution and measurements of intrinsic heat flux for this population.

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The tale of the 3 planets: 3D cloud feedback enhances the spectral diversity of warm Jupiters

JWST has shown a large diversity in warm Jupiter spectra, despite only small variations in the planetary parameters. However, the main driver of this diversity remains unclear. We aim to identify the mechanisms responsible for the spectral difference of three warm Jupiter-size exoplanets observed by JWST: whereas WASP-80b appears mostly cloud-free, both WASP-107b and WASP-69b have spectra dominated by clouds. We model each planet using the same framework, ADAM (formerly SPARC/MITgcm), which solves for the interactions among cloud transport, radiative transfer, and atmospheric circulation in 3D. We investigate the role of three condensate species, Na$_2$S, KCl, and MgSiO$_3$, and four particle sizes (0.1, 1, 5, and 10 $\mu$m). Clouds settle deeper in the atmosphere of the higher-gravity planet WASP-80b than in WASP-107b, reproducing their spectral difference naturally. For WASP-107b, three clouds can reproduce the NIRCam observations: 5 $\mu$m Na$_2$S, 1 $\mu$m KCl, and 5 $\mu$m MgSiO$_3$ models. However, these cannot match the scattering slope observed at shorter wavelengths in NIRISS and the possible silicate feature in the MIRI bandpass, suggesting a multi-modal distribution of clouds. Our model predicts that small silicate particles should be homogeneously distributed and thus cannot account for the difference between the two limb spectra in the MIRI bandpass. Finally, applying the same model to WASP-69b does not yield a partially cloudy dayside solution that fits the emission spectra, as proposed in a previous study. Coupling among 3D circulation, clouds, and radiative transfer can enhance the spectral diversity of warm Jupiter exoplanets, particularly through changes in cloudiness with gravity. The combination of multi-phase, wide-wavelength coverage and models that couple clouds, circulation, and radiative transfer is key to advancing our understanding of these new objects.

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The Identification of CS2 and Evidence for Carbon-Sulfur Chemical Coupling in a Warm Giant Exoplanet Atmosphere

Transmission spectroscopy with the James Webb Space Telescope (JWST) is revealing growing chemical complexity in giant exoplanet atmospheres. Of particular interest is sulfur, which had essentially no observational constraints before JWST. Recent work has shown that a planet's atmospheric sulfur content traces its refractory budget and is therefore a sensitive indicator of formation pathways. But despite the growing library of JWST data, the sulfur inventory of giant exoplanets remains poorly constrained: sulfur-bearing species are governed by disequilibrium chemistry and by kinetic networks that are still being revised. Here we present a transmission spectrum of the warm giant planet WASP-80 b obtained with JWST/NIRCam and MIRI over 2.4 $\mu$m--10$\mu$m in three transits. We uniquely identify CS$_2$ in our transmission spectrum using the combination of the two absorption features in NIRCam and MIRI at a significance of $\ln (B)=17.89$ ($\sigma = 6.3$). Our grid-based retrievals yield $\mathrm{[M/H] = \:} 0.54^{+0.17}_{-0.12}$ and $\mathrm{C/O =\:}0.43^{+0.12}_{-0.08}$ which result in $\log(\mathrm{X_{CS_2}})$ abundances of $\sim-4.5$. The latest carbon-sulfur kinetics networks produce substantially greater amounts of CS$_2$ than past works, enabling good fits ($\chi^2/\mathrm{N_{data}}\sim1.2$) to the data without invoking extreme abundance patterns. These results identify CS$_2$ as an observable tracer of sulfur disequilibrium chemistry and provide observational support for theoretically predicted carbon-sulfur chemical coupling in giant exoplanet atmospheres.

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PICASO 4.0: Clouds and Photochemistry in Climate Models of Brown Dwarfs and Exoplanets

We present a major update to the open-source atmospheric modeling package \texttt{PICASO}, designed for simulating the thermal structure and spectra of hydrogen-rich atmospheres of brown dwarfs and exoplanets. This release, \texttt{PICASO 4.0}, expands upon the existing radiative-convective equilibrium model framework by incorporating several new capabilities. Key additions include the integration of \texttt{Virga} for self-consistent cloud modeling, new flexible treatments for rainout and cold trapping of volatile species, and support for photochemistry. We also introduce a parameterized energy injection scheme to simulate additional external or internal heating processes. These features are motivated by lessons from recent JWST observations that reveal the prevalence of non-equilibrium chemistry and clouds. We benchmark the new functionalities against previously published results in the literature, including the Sonora Diamondback grid, energy injected atmospheres, patchy cloud models, and other photochemical models of WASP-39b. \texttt{PICASO} continues to be actively developed as an open-source package aimed at enabling reproducible, community-driven atmospheric modeling of all substellar objects.

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The Role of Intrinsic Temperature and Vertical Mixing in Characterizing Sub-Neptune Atmospheres

Sub-Neptune planets are often modeled with a dense rocky or metal-rich interior beneath a thick hydrogen/helium (H/He) atmosphere; though their bulk densities could also be explained by a water-rich interior with a thin H/He atmosphere. Atmospheric composition provides a key mechanism to break this degeneracy between competing interior models. However, the overall composition of sub-Neptunes inferred from spectra obtained with the James Webb Space Telescope, remains debated in part due to differences in modeling assumptions. While previous studies explored parameter spaces such as stellar spectra, atmospheric metallicities, and carbon-to-oxygen ratios, they often assumed fixed intrinsic temperatures (Tint) and vertical eddy diffusion coefficients (Kzz) - two critical, yet poorly constrained, drivers of atmospheric chemistry. To address this, we present a self-consistent grid of models that covers the full plausible range of Tint (60 - 450 K) and Kzz (10^{5} - 10^{12} cm^2/s) using the open-source PICASO and VULCAN packages to better characterize sub-Neptune atmospheres. Focusing on K2-18b analogs, we demonstrate that Tint and Kzz significantly impact CH4, CO2, CO, NH3 and HCN abundances, with H2O being largely unaffected. Our work demonstrates that comprehensive parameter space exploration of thermal and mixing parameters is essential for accurate interpretation of sub-Neptune spectra, and that single-parameter assumptions can lead to misclassification of planetary interiors. We provide a diagnostic framework using multi-molecule observations to distinguish between competing atmospheric models and advance robust characterization of sub-Neptunes.

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Uniform Forward-Modeling Analysis of Ultracool Dwarfs. IV. Benchmarking the Sonora Diamondback and Saumon & Marley (2008) Atmospheric Models Across Late-M, L, and T types with Low-Resolution 0.8-2.5 $\mu$m Spectroscopy

(Abridged) We present a systematic assessment of two major cloudy atmospheric model grids -- SM08 (Saumon & Marley 2008) and Sonora Diamondback -- when applied to low-resolution near-infrared (0.8-2.5 $\mu$m) spectroscopy. Our analysis focuses on a uniform sample of 142 age-benchmark brown dwarfs and planetary-mass objects spanning late-M, L, and T spectral types, with independently determined ages from 10 Myr to 10 Gyr. We perform forward-model spectral fitting for all benchmarks' IRTF/SpeX spectra ($R\sim$80-250) using both SM08 and Sonora Diamondback atmospheric models to infer effective temperatures, surface gravities, metallicities, radii, and cloud sedimentation efficiencies. The two model grids yield broadly consistent results. Among L4-L9 dwarfs, we identify a statistically significant, population-level age dependence of the cloud parameter $f_{\rm sed}$, with young benchmarks ($<300$ Myr) exhibiting systematically lower $f_{\rm sed}$ values than older counterparts. This trend is absent across L0-T5 and T0-T5, demonstrating that cloud properties vary with age and surface gravity and offering explanations for the observed gravity-dependent photometric properties at the late-L end of the L/T transition. By comparing spectroscopically inferred parameters with predictions from evolution models, we quantify systematic errors in the fitted atmospheric parameters and establish empirical calibrations to anchor future studies using these atmospheric models. Stacked residuals of the sample reveal wavelength-dependent data-model mismatches associated with key atomic and molecular absorption bands, highlighting the need for improved opacities and rainout chemistry. Finally, we show that including an interstellar-medium-like extinction term significantly improves the spectral fits, confirming and broadening previous findings and suggesting missing opacity sources in current cloudy models.

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The Impact of Irradiation on the Radius and Thermal Evolution of Transiting Brown Dwarfs

Masses and radii of transiting brown dwarfs can be measured directly in contrast to isolated field brown dwarfs, whose mass and radius inferences are model dependent. Therefore, transiting brown dwarfs are a testbed for the interior and evolutionary models of brown dwarfs and giant exoplanets. We have developed atmospheric and evolutionary models for this emerging population. We show that intense stellar irradiation can cause a large enhancement in the radius of transiting brown dwarfs at all masses, especially if the incident flux exceeds $log_{10}(F/cgs)\ge$9 ($T_{\rm eq}\ge 1450$ K). Stellar irradiation can significantly alter rates of nuclear burning in irradiated brown dwarfs, making the Deuterium-burning and Hydrogen-burning minimum masses strong functions of incident stellar flux. We show that the D-burning and H-burning minimum masses can decrease by 16% and 13%, respectively, between isolated and strongly irradiated brown dwarfs ( $log_{10}(F/cgs)\ge$10 ($T_{\rm eq}\ge 2570$ K)). This shows that stellar irradiation has a larger impact on the planet-brown dwarf-star mass boundaries than metallicity or clouds. We show that metal cores or migration affect their evolution to a much lesser extent, whereas low mass highly irradiated old sources can help us test the physics of hot Jupiter radius anomaly. We fit the observed radii of 46 transiting brown dwarfs and show that our irradiated evolutionary models fit their radii better than models that ignore the host star, especially for highly irradiated objects. However, the measured radii of 10 objects are still inconsistent at $>3\sigma$ level, indicating residual gaps in our irradiated evolutionary model.

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The Sonora Substellar Atmosphere Models VI. Red Diamondback: Extending Diamondback with SPHINX for Brown Dwarf Early Evolution

We extend the Sonora Diamondback brown dwarf evolution models to higher effective temperatures to treat the evolution of younger, higher mass objects. Due to an upper temperature limit of $T_\mathrm{eff}=$2400 K in the original Sonora Diamondback model grid, high mass objects ($M\geq$ 0.05 $M_\mathrm{\odot}=$ 52.4 $M_\mathrm{J}$) were limited to ages of $\gtrsim$ 100 Myr. To include the early evolution of brown dwarfs at $T_\mathrm{eff}>$ 2400 K, we use existing and new SPHINX cloud-free model atmosphere calculations of temperature structures of M-type atmospheres. These atmospheres range from $T_\mathrm{eff}$ 2000--4000 K, log($g$) 3.0--5.5, and metallicity [M/H] $-$0.5 to $+$0.5. This combination of Diamondback and SPHINX atmospheres, with a transition across $T_\mathrm{eff}$ 2000--2400 K, allows us to calculate evolution tracks, and infrared photometry and colors, for ages $>$ 1 Myr and masses from above the hydrogen burning minimum mass down to planetary masses. The Hayashi phase of massive brown dwarf evolution (ages $<$ 10--100 Myr) at low surface gravity leads to nearly constant $T_\mathrm{eff}$ values, at effective temperatures much lower than would be obtained from simply extrapolating backwards from evolution tracks at older ages.

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