arXiv subjects

Sebastien Michelin

Publications and source records attributed to Sebastien Michelin.

At least 19 recordsLinked to original sources

arXiv2025

Marangoni swimmer pushing particle raft under 1D confinement

Active matter systems, due to their spontaneous self-propulsion ability, hold potential for future applications in healthcare and environmental sustainability. Marangoni swimmers, a type of synthetic active matter, are a common model system for understanding the underlying physics. Existing studies of the interactions of active matter with passive particles have mostly focused on the modification of the behavior of the passive particles. In contrast, we analyse here experimentally the impact on the self-propulsion of camphor-infused agarose disks (active) of their interactions with floating hollow glass microspheres (passive) within an annular channel. Two distinct regimes are observed: a steady regime with uni-directional motion of the swimmer at low packing fractions (\phi_{\textrm{ini}} \lesssim 0.45) and an oscillatory regime with to-and-fro motion at higher packing fractions (\phi_{\textrm{ini}} \gtrsim 0.45). In the former, the swimmer pushes nearly the entire particle raft together with it, like a towing cargo, causing a decrease in swimmer speed with increasing packing fraction due to the additional drag from the particle raft. A simplified force-balance model is finally proposed that captures the experimental trend in swimmer speed reasonably well.

cond-mat.soft↗

arXiv2023

Self-organisation of auto-phoretic suspensions in confined shear flows

Janus phoretic particles exploit chemical energy stored in their environment to self-propel. These active particles modify and respond to their hydrodynamic and chemical environments, thus giving them a sensibility to external flows and other particles. Furthermore, experimental observations and analysis on biological or synthetic active suspensions indicate that hydro-chemical interparticle interactions lead to non-trivial collective behaviour (e.g., cluster formation of phoretic particles or bacterial swarming) and that the response of the suspensions to shear flows is non-trivial. In fact, it can lead to significant reductions in viscosity due to the energy conversion at microscopic scales. In this work, using simulations of a continuum kinetic model, we analyse the dynamics and response to shear and confinement of dilute suspensions of chemotactic phoretic particles that reorient and drift toward the chemical solutes released by their neighbours. We show that a 1D transient steady distribution driven by the effect of confinement is a common feature considered and analyse its stability for varying confinement strength and shear rate. In the second step, we consider and discuss, more specifically, the feedback effect on the flow by the particle and the resulting effective viscosity of the suspension.

cond-mat.soft↗

arXiv2022

Steady state propulsion of isotropic active colloids along a wall

Active drops emit/absorb chemical solutes, whose concentration gradients cause interfacial flows driving their own transport and the propulsion of the droplet. Such non-linear coupling enables active drops to achieve directed self-propulsion despite their isotropy, if the ratio of advective-to-diffusive solute transport, i.e. the Peclet number Pe, is larger than a finite critical threshold. In most experimental situations, active drops are non-neutrally buoyant and thus swim along rigid surfaces; yet theoretical descriptions of their non-linear motion focus almost exclusively on unbounded domains to circumvent geometric complexity. To overcome this gap in understanding, we investigate the spontaneous emergence and nonlinear saturation of propulsion of an isotropic phoretic colloid along a rigid wall, to which it is confined by a constant external force (e.g., gravity). This phoretic particle model is considered here as a limiting case for a viscous active drop. We show that, for moderate Pe, the particle motion and associated chemical transport reduce the chemically-induced wall repulsion, thereby causing the particle to swim progressively closer to the wall as Pe increases. Far from hindering self-propulsion, this reduction in the particle-wall separation is accompanied by a wall-induced efficient rearrangement of the solute concentration gradients driving the particle, thus augmenting its swimming speed.

physics.flu-dyn↗

arXiv2022

Collective dynamics and rheology of confined phoretic suspensions

Similarly to their biological counterparts, suspensions of chemically-active autophoretic swimmers exhibit nontrivial dynamics involving self-organization processes as a result of inter-particle interactions. Using a kinetic model for a dilute suspension of autochemotactic Janus particles, we analyse the effect of a confined pressure-driven flow on these collective behaviours and the impact of chemotactic aggregation on the effective viscosity of the active fluid. Four dynamic regimes are identified when increasing the strength of the imposed pressure-driven flow, each associated with a different collective behaviour resulting from the competition of flow- and chemically-induced reorientation of the swimmers together with the constraints of confinement. Interestingly, we observe that the effect of the pusher (resp. puller) hydrodynamic signature, which is known to reduce (resp. increase) the effective viscosity of a sheared suspension, is inverted upon the emergence of autochemotactic aggregation. Our results provide new insights on the role of collective dynamics in complex environments, which are relevant to synthetic as well as biological systems.

cond-mat.soft↗

arXiv2022

Self-propulsion of chemically-active droplets

Microscopic active droplets are able to swim autonomously in viscous flows: this puzzling feature stems from solute exchanges with the surrounding fluid via surface reactions or their spontaneous solubilisation, and the interfacial flows resulting from these solutes' gradients. Contrary to asymmetric active colloids, these isotropic droplets swim spontaneously by exploiting the nonlinear coupling of solute transport with self-generated Marangoni flows, which is also responsible for secondary transitions to more complex individual and collective dynamics. Thanks to their simple design and their sensitivity to physico-chemical signals, they are fascinating physicists, chemists, biologists and fluid dynamicists alike to analyse viscous self-propulsion and collective dynamics in active matter systems, to develop synthetic cellular models or to perform targeted biomedical or engineering applications. I review here the most recent and significant developments of this rapidly-growing field, focusing on the mathematical and physical modelling of these intringuing droplets, together with its experimental design and characterisation.

physics.flu-dyn↗

arXiv2021

Confined self-propulsion of an isotropic active colloid

To spontaneously break their intrinsic symmetry and self-propel at the micron scale, isotropic active colloidal particles and droplets exploit the non-linear convective transport of chemical solutes emitted/consumed at their surface by the surface-driven fluid flows generated by these solutes. Significant progress was recently made to understand the onset of self-propulsion and non-linear dynamics. Yet, most models ignore a fundamental experimental feature, namely the spatial confinement of the colloid, and its effect on propulsion. In this work, the self-propulsion of an isotropic colloid inside a capillary tube is investigated numerically. A flexible computational framework is proposed based on a finite-volume approach on adaptative octree-grids and embedded boundary methods. This method is able to account for complex geometric confinement, the nonlinear coupling of chemical transport and flow fields, and the precise resolution of the surface boundary conditions, that drive the system's dynamics. Somewhat counter-intuitively, spatial confinement promotes the colloid's spontaneous motion by reducing the minimum advection-to-diffusion ratio or P\'clet number, Pe, required to self-propel; furthermore, self-propulsion velocities are significantly modified as the colloid-to-capillary size ratio $\kappa$ is increased, reaching a maximum at fixed Pe for an optimal confinement $0<\kappa<1$. These properties stem from a fundamental change in the dominant chemical transport mechanism with respect to the unbounded problem : with diffusion now restricted in most directions by the confining walls, the excess solute is predominantly convected away downstream from the colloid, enhancing front-back concentration contrasts. These results are confirmed quantitatively using conservation arguments and lubrication analysis of the tightly-confined limit, $\kappa\rightarrow 1$.

cond-mat.soft↗

arXiv2021

Instability and self-propulsion of active droplets along a wall

Active droplets can swim spontaneously in viscous flows as a result of the non-linear convective transport of a chemical solute produced at their surface by the Marangoni and/or phoretic flows generated by this solute's inhomogeneous distribution, provided the ratio of convective-to-diffusive solute transport, or P\'eclet number $\mbox{Pe}$ is large enough. As the result of their net buoyancy, active drops typically evolve at a small finite distance $d$ from rigid boundaries. Yet, existing models systematically focus on unbounded flows, ignoring the effect of the wall proximity on the intrisically-nonlinear nature of their propulsion mechanism. In contrast, we obtain here a critical insight on the propulsion of active drops near walls by analysing their stability to non-axisymmetric perturbations and the resulting emergence of self-propulsion along the wall with no limiting assumption on the wall-distance $d$. Dipolar or quadrupolar axisymmetric (levitating) base states are identified depending on $d$ and $\mbox{Pe}$. Perhaps counter-intuitively, a reduction in the drop-wall separation $d$ is observed to destabilize these modes and to promote self-propulsion, as a result from the confinement-induced localisation of the chemical gradients driving the motion. In addition, quadrupolar states are more unstable than their dipolar counterparts due to the redistribution of the chemical perturbation by the base flow, favouring the emergence of stronger slip forcing on the drop surface.

physics.flu-dyn↗

arXiv2021

Hydrochemical interactions of phoretic particles: a regularized multipole framework

Chemically-active colloids modify the concentration of chemical solutes surrounding them in order to self-propel. In doing so, they generate long-ranged hydrodynamic flows and chemical gradients that modify the trajectories of other particles. As a result, the dynamics of reactive suspensions is fundamentally governed by hydro-chemical interactions. A full solution of the detailed hydro-chemical problem with many particles is challenging and computationally expensive. Most current methods rely on the Green's functions of the Laplace and Stokes operators to approximate the particle signatures in the far-field, which is only valid in the very dilute limit in simple geometries. To overcome these limitations, we propose a regularized mutipole framework, directly inspired by the Force Coupling Method (FCM), to model phoretic suspensions. Our approach, called Diffusio-phoretic FCM (DFCM), relies on grid-based volume averages of the concentration field to compute the particle surface concentration moments. These moments define the chemical multipoles of the diffusion (Laplace) problem and provide the swimming forcing of the Stokes equations. Unlike far-field models based on singularity superposition, DFCM accounts for mutually-induced dipoles. The accuracy of the method is evaluated against exact and accurate numerical solutions for a few canonical cases. We also quantify its improvements over far-field approximations for a wide range of inter-particle distances. The resulting framework can readily be implemented into efficient CFD solvers, allowing for large scale simulations of semi-dilute diffusio-phoretic suspensions.

physics.flu-dyn↗

arXiv2020

Alignment and scattering of colliding active droplets

Active droplets emit a chemical solute at their surface that modifies their local interfacial tension. They exploit the nonlinear coupling of the convective transport of solute to the resulting Marangoni flows to self-propel. Such swimming droplets are by nature anti-chemotactic and are repelled by their own chemical wake or their neighbours. The rebound dynamics resulting from pairwise droplet interactions was recently analysed in detail for purely head-on collisions using a specific bispherical approach. Here, we extend this analysis and propose a reduced model of a generic collision to characterise the alignment and scattering properties of oblique droplet collisions and their potential impact on collective droplet dynamics. A systematic alignment of the droplets' trajectories is observed for symmetric collisions, when the droplets interact directly, and arises from the finite-time rearrangement of the droplets' chemical wake during the collision. For more generic collisions, complex and diverse dynamical regimes are observed, whether the droplets interact directly or through their chemical wake, resulting in a significant scattering.

physics.flu-dyn↗

arXiv2020

Hydro-chemical interactions in dilute phoretic suspensions: from individual particle properties to collective organization

Janus phoretic colloids (JPs) self-propel as a result of self-generated chemical gradients and exhibit spontaneous nontrivial dynamics within phoretic suspensions, on length scales much larger than the microscopic swimmer size. Such collective dynamics arise from the competition of (i) the self-propulsion velocity of the particles, (ii) the attractive/repulsive chemically-mediated interactions between particles and (iii) the flow disturbance they introduce in the surrounding medium. These three ingredients are directly determined by the shape and physico-chemical properties of the colloids' surface. Owing to such link, we adapt a recent and popular kinetic model for dilute suspensions of chemically-active JPs where the particles' far-field hydrodynamic and chemical signatures are intrinsically linked and explicitly determined by the design properties. Using linear stability analysis, we show that self-propulsion can induce a wave-selective mechanism for certain particles' configurations consistent with experimental observations. Numerical simulations of the complete kinetic model are further performed to analyze the relative importance of chemical and hydrodynamic interactions in the nonlinear dynamics. Our results show that regular patterns in the particle density are promoted by chemical signaling but prevented by the strong fluid flows generated collectively by the polarized particles, regardless of their chemotactic or antichemotactic nature (i.e. for both puller and pusher swimmers).

physics.flu-dyn↗

arXiv2020

Acoustic propulsion of a small bottom-heavy sphere

We present here a comprehensive derivation for the speed of a small bottom-heavy sphere forced by a transverse acoustic field and thereby establish how density inhomogeneities may play a critical role in acoustic propulsion. The sphere is trapped at the pressure node of a standing wave whose wavelength is much larger than the sphere diameter. Due to its inhomogeneous density, the sphere oscillates in translation and rotation relative to the surrounding fluid. The perturbative flows induced by the sphere's rotation and translation are shown to generate a rectified inertial flow responsible for a net mean force on the sphere that is able to propel the particle within the zero-pressure plane. To avoid an explicit derivation of the streaming flow, the propulsion speed is computed exactly using a suitable version of the Lorentz reciprocal theorem. The propulsion speed is shown to scale as the inverse of the viscosity, the cube of the amplitude of the acoustic field and is a non trivial function of the acoustic frequency. Interestingly, for some combinations of the constitutive parameters (fluid to solid density ratio, moment of inertia and centroid to center of mass distance), the direction of propulsion is reversed as soon as the frequency of the forcing acoustic field becomes larger than a certain threshold. The results produced by the model are compatible with both the observed phenomenology and the orders of magnitude of the measured velocities.

physics.flu-dyn↗

arXiv2020

Bouncing, chasing or pausing: asymmetric collisions of active droplets

Chemically-active droplets exhibit complex avoiding trajectories. While heterogeneity is inevitable in active matter experiments, it is mostly overlooked in their modelling. Exploiting its geometric simplicity, we fully-resolve the head-on collision of two swimming droplets of different radii and demonstrate that even a small contrast in size critically conditions their collision and subsequent dynamics. We identify three fundamentally-different regimes. The resulting high sensitivity of pairwise collisions is expected to profoundly affect their collective dynamics.

physics.flu-dyn↗

arXiv2019

Modeling chemo-hydrodynamic interactions of phoretic particles: a unified framework

Phoretic particles exploit local self-generated physico-chemical gradients to achieve self-propulsion at the micron scale. The collective dynamics of a large number of such particles is currently the focus of intense research efforts, both from a physical perspective to understand the precise mechanisms of the interactions and their respective roles, as well as from an experimental point of view to explain the observations of complex dynamics as well as formation of coherent large-scale structures. However, an exact modelling of such multi-particle problems is difficult and most efforts so far rely on the superposition of far-field approximations for each particle's signature, which are only valid asymptotically in the dilute suspension limit. A systematic and unified analytical framework based on the classical Method of Reflections (MoR) is developed here for both Laplace and Stokes' problems to obtain the higher-order interactions and the resulting velocities of multiple phoretic particles, up to any order of accuracy in the radius-to-distance ratio $\varepsilon$ of the particles. Beyond simple pairwise chemical or hydrodynamic interactions, this model allows us to account for the generic chemo-hydrodynamic couplings as well as $N$-particle interactions ($N\geq 3$). The $\varepsilon^5$-accurate interaction velocities are then explicitly obtained and the resulting implementation of this MoR model is discussed and validated quantitatively against exact solutions of a few canonical problems.

physics.flu-dyn↗

arXiv2019

Orientational instability and spontaneous rotation of active nematic droplets

In experiments, an individual chemically active liquid crystal (LC) droplet submerged in the bulk of a surfactant solution may self-propel along a straight, helical, or random trajectory. In this paper, we develop a minimal model capturing all three types of self-propulsion trajectories of a drop in the case of a nematic LC with homeotropic anchoring at LC-fluid interface. We emulate the director field within the drop by a single preferred polarization vector that is subject of two reorientation mechanisms, namely, the internal flow-induced displacement of the hedgehog defect and the droplet's rotation. Within this reduced-order model, the coupling between the nematic ordering of the drop and the surfactant transport is represented by variations of the droplet's interfacial properties with nematic polarization. Our analysis reveals that a novel mode of orientational instability emerges from the competition of the two reorientation mechanisms and is characterized by a spontaneous rotation of the self-propelling drop responsible for helical self-propulsion trajectories. In turn, we also show that random trajectories in isotropic and nematic drops alike stem from the advection-driven transition to chaos. The succession of the different propulsion modes is consistent with experimentally-reported transitions in the shape of droplet trajectories as the drop size is varied.

cond-mat.soft↗

arXiv2019

Universal optimal geometry of minimal phoretic pumps

Unlike pressure-driven flows, surface-mediated phoretic flows provide efficient means to drive fluid motion on very small scales. Colloidal particles covered with chemically-active patches with nonzero phoretic mobility (e.g. Janus particles) swim using self-generated gradients, and similar physics can be exploited to create phoretic pumps. Here we analyse in detail the design principles of phoretic pumps and show that for a minimal phoretic pump, consisting of 3 distinct chemical patches, the optimal arrangement of the patches maximizing the flow rate is universal and independent of chemistry.

physics.flu-dyn↗

arXiv2019

The flow field around a confined active droplet

We present here first-of-a-kind experimental measurements of the flow field around a swimming water droplet, using confocal PIV in three dimensions. The droplet is denser than the continuous oil phase, and swims close and parallel to the bottom wall. The measured flow field is first quantitatively characterized and compared to the flow field obtained for an axisymmetric swimmer in unbounded flow. Important qualitative differences are observed, in particular the emergence of a strong isotropic radial flow field in the planes parallel to the wall. These fundamental differences stress the critical impact of confinement on the flow field around the swimming droplet. We then propose an analytical formulation, based on a reduced order description of the swimming droplet in terms of fundamental hydrodynamic singularities as well as the classical method of images. This model is able to account exactly for the effect of the wall and provides a simplified description of the flow field as the superposition of axisymmetric dipole and quadrupole singularities. We demonstrate that this simplified description quantitatively captures the effect of the wall on the dipolar and quadrupolar components of the flow field. Further including the confinement-induced asymmetry of the concentration field responsible for the droplet's Marangoni propulsion, our model is also able to account for the monopolar contribution to the experimental flow field which drives the dominant far-field signature of the droplet.

physics.flu-dyn↗

arXiv2019

Stresslets induced by active swimmers

Active particles disturb the fluid around them as force dipoles, or stresslets, which govern their collective dynamics. Unlike swimming speeds, the stresslets of active particles are rarely determined due to the lack of a suitable theoretical framework for arbitrary geometry. We propose a general method, based on the reciprocal theorem of Stokes flows, to compute stresslets as integrals of the velocities on the particle's surface, which we illustrate for spheroidal chemically-active particles. Our method will allow tuning the stresslet of artificial swimmers and tailoring their collective motion in complex environments.

physics.flu-dyn↗

arXiv2019

Nonlinear dynamics of a chemically-active drop: from steady to chaotic self-propulsion

Individual chemically active drops suspended in a surfactant solution were observed to self-propel spontaneously with straight, helical, or chaotic trajectories. To elucidate how these drops can exhibit such strikingly different dynamics and `decide' what to do, we propose a minimal axisymmetric model of a spherical active drop, and show that simple and linear interface properties can lead to both steady self-propulsion of the droplet as well as chaotic behavior. The model includes two different mobility mechanisms, namely, diffusiophoresis and the Marangoni effect, that convert self-generated gradients of surfactant concentration into the flow at the droplet surface. In turn, surface-driven flow initiates surfactant advection that is the only nonlinear mechanism and, thus, the only source of dynamical complexity in our model. Numerical investigation of the fully-coupled hydrodynamic and advection diffusion problems reveals that strong advection (e.g., large droplet size) may destabilize a steadily self-propelling drop; once destabilized, the droplet spontaneously stops and a symmetric extensile flow emerges. If advection is strengthened even further in comparison with molecular diffusion, the droplet may perform chaotic oscillations. Our results indicate that the thresholds of these instabilities depend heavily on the balance between diffusiophoresis and the Marangoni effect. Using linear stability analysis, we demonstrate that diffusiophoresis promotes the onset of high-order modes of monotonic instability of the motionless drop. We argue that diffusiophoresis has a similar effect on the instabilities of a moving drop.

physics.flu-dyn↗