arXiv subjects

Shin-ichi Sasa

Publications and source records attributed to Shin-ichi Sasa.

At least 37 records · Page 2Linked to original sources

arXiv2023

Rigorous proof of a phase transition of parallelizability in a one-dimensional structure assembly

In this paper, we prove the existence of a phase transition of parallelizability in the assembly of one-dimensional chains. By introducing the parallel efficiency that measures how efficiently the parallel assembly works, the parallelizable phase is defined by its positive value. The parallelizable/unparallelizable transition is then identified by the non-analytic change in the parallel efficiency from a positive value to zero. By evaluating the parallel efficiency on each side of the transition point, we show the existence of a phase transition in this system.

cond-mat.stat-mech↗

arXiv2023

Growth of self-integrated atomic quantum wires and junctions of a Mott semiconductor

Continued advances in quantum technologies rely on producing nanometer-scale wires. Although several state-of-the-art nanolithographic technologies and bottom-up synthesis processes have been used to engineer such wires, critical challenges remain in growing uniform atomic-scale crystalline wires and constructing their network structures. Here we discover a simple method to fabricate atomic-scale wires with various arrangements, including stripes, X-, Y-junctions, and nanorings. Single-crystalline atomic-scale wires of a Mott insulator, whose band gap is comparable to those of wide-gap semiconductors, are spontaneously grown on graphite substrates \DEL{and epitaxial monolayer graphene on SiC }by pulsed-laser deposition. These wires are one-unit-cell-thick and have an exact width of two- and four-unit-cells (1.4 and 2.8\,nm) and lengths up to a few $μm$. We show that the non-equilibrium reaction-diffusion processes may play an essential role in atomic pattern formation. Our findings offer a new perspective on the non-equilibrium self-organization phenomena on an atomic scale, paving a unique way for the quantum architecture of nano-network.

cond-mat.mes-hall↗

arXiv2023

Divergent stiffness of one-dimensional growing interfaces

When a spatially localized stress is applied to a growing one-dimensional interface, the interface deforms. This deformation is described by the effective surface tension representing the stiffness of the interface. We present that the stiffness exhibits divergent behavior in the large system size limit for a growing interface with thermal noise, which has never been observed for equilibrium interfaces. Furthermore, by connecting the effective surface tension with a space-time correlation function, we elucidate the mechanism that anomalous dynamical fluctuations lead to divergent stiffness.

cond-mat.stat-mech↗

arXiv2023

Thermodynamic bounds on correlation times

We derive a variational expression for the correlation time of physical observables in steady-state diffusive systems. As a consequence of this variational expression, we obtain lower bounds on the correlation time, which provide speed limits on the self-averaging of observables. In equilibrium, the bound takes the form of a tradeoff relation between the long- and short-time fluctuations of an observable. Out of equilibrium, the tradeoff can be violated, leading to an acceleration of self-averaging. We relate this violation to the steady-state entropy production rate, as well as the geometric structure of the irreversible currents, giving rise to two complementary speed limits. One of these can be formulated as a lower estimate on the entropy production from the measurement of time-symmetric observables. Using an illustrating example, we show the intricate behavior of the correlation time out of equilibrium for different classes of observables and how this can be used to partially infer dissipation even if no time-reversal symmetry breaking can be observed in the trajectories of the observable.

cond-mat.stat-mech↗

arXiv2022

Phase growth with heat diffusion in a stochastic lattice model

When a stable phase is adjacent to a metastable phase with a planar interface, the stable phase grows. We propose a stochastic lattice model describing the phase growth accompanying heat diffusion. The model is based on an energy-conserving Potts model with a kinetic energy term defined on a two-dimensional lattice, where each site is sparse-randomly connected in one direction and local in the other direction. For this model, we calculate the stable and metastable phases exactly using statistical mechanics. Performing numerical simulations, we measure the displacement of the interface $R(t)$. We observe the scaling relation $R(t)=L_x \bar{\mathcal{R}} (Dt/L_x^2)$, where $D$ is the thermal diffusion constant and $L_x$ is the system size between the two heat baths. The scaling function $\bar{\mathcal{R}}(z)$ shows $\bar{\mathcal{R}}(z) \simeq z^{0.5}$ for $z \ll z_c$ and $\bar{\mathcal{R}}(z) \simeq z^α$ for $z \gg z_c$, where the cross-over value $z_c$ and exponent $α$ depend on the temperatures of the baths, and $0.5\leα\le 1$. We then confirm that a deterministic phase-field model exhibits the same scaling relation. Moreover, numerical simulations of the phase-field model show that the cross-over value $\bar{\mathcal{R}}(z_c)$ approaches zero when the stable phase becomes neutral.

cond-mat.stat-mech↗

arXiv2022

Unique extension of the maximum entropy principle to phase coexistence in heat conduction

The maximum entropy principle determines the values of thermodynamic variables in thermally isolated equilibrium systems. This paper extends the principle to a variational principle that applies to liquid-gas coexistence in heat conduction. We show the uniqueness of the extension under the assumption that the variational principle and the fundamental thermodynamic relation are simultaneously extended in the linear response regime with the total energy fixed. Using the extended variational principle, we calculate the thermodynamic quantities in this steady state and find that the temperature of the liquid-gas interface deviates from the equilibrium transition temperature, which should be verified in experiments.

cond-mat.stat-mech↗

arXiv2022

Geometric decomposition of entropy production into excess, housekeeping and coupling parts

For a generic overdamped Langevin dynamics driven out of equilibrium by both time-dependent and nonconservative forces, the entropy production rate can be decomposed into two positive terms, termed excess and housekeeping entropy. However, this decomposition is not unique: There are two distinct decompositions, one due to Hatano and Sasa, the other one due to Maes and Netočny. Here, we establish the connection between these two decompositions and provide a simple, geometric interpretation. We show that this leads to a decomposition of the entropy production rate into three positive terms, which we call excess, housekeeping and coupling part, respectively. The coupling part characterizes the interplay between the time-dependent and nonconservative forces. We also derive thermodynamic uncertainty relations for the excess and housekeeping entropy in both the Hatano-Sasa and Maes-Netočny-decomposition and show that all quantities obey integral fluctuation theorems. We illustrate the decomposition into three terms using a solvable example of a dragged particle in a nonconservative force field.

cond-mat.stat-mech↗

arXiv2022

Quasi-static decomposition and the Gibbs factorial in small thermodynamic system

For small thermodynamic systems in contact with a heat bath, we determine the free energy by imposing the following two conditions. First, the quasi-static work in any configuration change is equal to the free energy difference. Second, the temperature dependence of the free energy satisfies the Gibbs-Helmholtz relation. We find that these prerequisites uniquely lead to the free energy of a classical system consisting of $N$-interacting identical particles, up to an additive constant proportional to $N$. The free energy thus determined contains the Gibbs factorial $N!$ in addition to the phase space integration of the Gibbs-Boltzmann factor. The key step in the derivation is to construct a quasi-static decomposition of small thermodynamic systems.

cond-mat.stat-mech↗

arXiv2022

Characterizing the asymmetry in hardness between synthesis and destruction of heteropolymers

We present a simple model describing the assembly and disassembly of heteropolymers consisting of two types of monomers $A$ and $B$. We prove that no matter how we manipulate the concentrations of $A$ and $B$, it takes longer than the exponential function of $d$ to synthesize a fixed amount of the desired heteropolymer, where $d$ is the number of $A$-$B$ connections. We also prove the decomposition time is linear for chain length $n$. When $d$ is proportional to $n$, synthesis and destruction have an exponential asymmetry. Our findings may facilitate research on the more general asymmetry of operational hardness.

cond-mat.stat-mech↗

arXiv2022

A Simple XY Model for Cascade Transfer

We propose a modified XY model in which cascade transfer emerges from spatially local interactions, where the spin corresponds to the "velocity" of a turbulent field. For this model, we theoretically calculate the scale-to-scale energy flux and the equal time correlation function in $d$ dimensions. The result indicates an inverse energy cascade with the non-Kolmogorov energy spectrum proportional to $k^{-3}$. We also numerically confirm the result for the cases $d=2$ and $d=3$. We thus conclude that the cascade transfer in our model represents a different universality class from standard fluid turbulence.

cond-mat.stat-mech↗

arXiv2022

Geometric decomposition of entropy production in out-of-equilibrium systems

Two qualitatively different ways of driving a physical system out of equilibrium, time-dependent and non-conservative forcing, are reflected by the decomposition of the system's entropy production into excess and housekeeping parts. We show that the difference between these two types of driving gives rise to a geometric formulation in terms of two orthogonal contributions to the currents in the system. This geometric picture in a natural way leads to variational expressions for both the excess and housekeeping entropy, which allow calculating both contributions independently from the trajectory data of the system. We demonstrate this by calculating the excess and housekeeping entropy of a particle in a time-dependent, tilted periodic potential.

cond-mat.stat-mech↗

arXiv2022

Continuous time-reversal and equality in the thermodynamic uncertainty relation

We introduce a continuous time-reversal operation which connects the time-forward and time-reversed trajectories in the steady state of an irreversible Markovian dynamics via a continuous family of stochastic dynamics. This continuous time-reversal allows us to derive a tighter version of the thermodynamic uncertainty relation (TUR) involving observables evaluated relative to their local mean value. Moreover, the family of dynamics realizing the continuous time-reversal contains an equilibrium dynamics halfway between the time-forward and time-reversed dynamics. We show that this equilibrium dynamics, together with an appropriate choice of the observable, turns the inequality in the TUR into an equality. We demonstrate our findings for the example of a particle diffusing in a tilted periodic potential.

cond-mat.stat-mech↗

arXiv2022

Improving thermodynamic bounds using correlations

We discuss how to use correlations between different physical observables to improve recently obtained thermodynamics bounds, notably the fluctuation-response inequality (FRI) and the thermodynamic uncertainty relation (TUR). We show that increasing the number of measured observables will always produce a tighter bound. This tighter bound becomes particularly useful if one of the observables is a conserved quantity, whose expectation is invariant under a given perturbation of the system. For the case of the TUR, we show that this applies to any function of the state of the system. The resulting correlation-TUR takes into account the correlations between a current and a non-current observable, thereby tightening the TUR. We demonstrate our finding on a model of the $\text{F}_1$-ATPase molecular motor, a Markov jump model consisting of two rings and transport through a two-dimensional channel. We find that the correlation-TUR is significantly tighter than the TUR and can be close to an equality even far from equilibrium.

cond-mat.stat-mech↗

arXiv2021

Macroscopic stability of time evolution of Gibbs measures

We introduce two properties, macroscopic mixing and transitive mixing, to represent the macroscopic stability of time evolution of Gibbs measures. We claim that these are fundamental properties of macroscopic systems that exhibit relaxation to an equilibrium state. As an illustration, we show that a simple mechanical system on a lattice possesses these two properties.

cond-mat.stat-mech↗

arXiv2021

Emergence of surface long-range order under uniform shear flow

We study the two-dimensional surface long-range order in a non-equilibrium steady state under shear flow using the three-dimensional conserved $O(N)$ model. Whereas the correlation on the surface is enhanced by increasing interactions within the surface, the long-range order cannot be realized at equilibrium because of divergent thermal fluctuations associated with the low dimensionality of the surface. Here, the shear flow is applied parallel to the surface, on which the flow is set to zero. Despite the shear flow not affecting the order parameter on the surface directly, the fluctuations at the surface are strongly suppressed by the flow away from the surface, leading to the surface long-range order. We demonstrate these results through an exact analysis in the large-$N$ limit, where non-linear fluctuations are self-consistently treated.

cond-mat.stat-mech↗

arXiv2021

Microscopic theory of the fluctuating hydrodynamics in nonlinear lattices

The theory of fluctuating hydrodynamics has been an important tool for analyzing macroscopic behavior in nonlinear lattices. However, despite its practical success, its microscopic derivation is still incomplete. In this work, we provide the microscopic derivation of fluctuating hydrodynamics, using the coarse-graining and projection technique; the equivalence of ensembles turns out to be critical. The Green-Kubo (GK) like formula for the bare transport coefficients is presented in a numerically computable form. Our numerical simulations show that the bare transport coefficients exist for a sufficiently large but finite coarse-graining length in the infinite lattice within the framework of the GK like formula. This demonstrates that the bare transport coefficients uniquely exist for each physical system.

cond-mat.stat-mech↗

arXiv2021

Long-range phase order in two dimensions under shear flow

We theoretically and numerically investigate a two-dimensional O(2) model where an order parameter is convected by shear flow. We show that a long-range phase order emerges in two dimensions as a result of anomalous suppression of phase fluctuations by the shear flow. Furthermore, we use the finite-size scaling theory to demonstrate that a phase transition to the long-range ordered state from the disordered state is second order. At a transition point far from equilibrium, the critical exponents turn out to be close to the mean-field value for equilibrium systems.

cond-mat.stat-mech↗

arXiv2021

Perturbative solution of a propagating interface in the phase field model

When a stable ordered phase and a metastable disordered phase are separated by a flat interface, the metastable state changes to the stable state through the propagation of the interface. For cases in which latent heat is generated, the interface displacement during some time interval is proportional to the square root of the time interval when the extent of supercooling is less than a certain value. We demonstrate this behavior by deriving a perturbative solution for a propagating interface in the phase field model. We calculate the leading-order contribution explicitly, and find that the interface temperature deviates from the equilibrium transition temperature in proportion to the interface velocity.

cond-mat.stat-mech↗