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Shin-ichi Sasa

Publications and source records attributed to Shin-ichi Sasa.

At least 55 records · Page 3Linked to original sources
arXiv2021

Kinetic uncertainty relation on first passage time for accumulated current

The kinetic uncertainty relation (KUR) is a trade-off relation between the precision of an observable and the mean dynamical activity in a fixed time interval for a time-homogeneous and continuous-time Markov chain. In this letter, we derive the KUR on the first passage time for the time-integrated current from the information inequality at stopping times. The relation shows that the precision of the first passage time is bounded from above by the mean number of jumps up to that time. We apply our result to simple systems and demonstrate that the activity constraint gives a tighter bound than the thermodynamic uncertainty relation in the regime far from equilibrium.

cond-mat.stat-mech↗
arXiv2021

Van der Waals Cascade in Supercritical Turbulence near a Critical Point

We investigate a quite strong turbulence in a supercritical fluid near a gas-liquid critical point. Specifically, we consider a case in which the Kolmogorov scale is much smaller than the equilibrium correlation length $ξ$. Although equilibrium critical fluctuations are destroyed by turbulence, $ξ$ still provides a crossover length scale between two types of energy cascade. At scales much larger than $ξ$, the Richardson cascade becomes dominant, whereas at scales much smaller than $ξ$, another type of cascade, which we call the van der Waals cascade, is induced by density fluctuations. Experimental conditions required to observe the van der Waals cascade are also discussed.

physics.flu-dyn↗
arXiv2020

Effective Langevin equations leading to large deviation function of time-averaged velocity for a nonequilibrium Rayleigh piston

We study fluctuating dynamics of a freely movable piston that separates an infinite cylinder into two regions filled with ideal gas particles at the same pressure but different temperatures. To investigate statistical properties of the time-averaged velocity of the piston in the long-time limit, we perturbatively calculate the large deviation function of the time-averaged velocity. Then, we derive an infinite number of effective Langevin equations yielding the same large deviation function as in the original model. Finally, we provide two possibilities for uniquely determining the form of the effective model.

cond-mat.stat-mech↗
arXiv2020

Stochastic order parameter dynamics for phase coexistence in heat conduction

We propose a stochastic order parameter equation for describing phase coexistence in steady heat conduction near equilibrium. By analyzing the stochastic dynamics with a non-equilibrium adiabatic boundary condition, where total energy is conserved over time, we derive a variational principle that determines thermodynamic properties in non-equilibrium steady states. The resulting variational principle indicates that the temperature of the interface between the ordered region and the disordered region becomes greater (less) than the equilibrium transition temperature in the linear response regime when the thermal conductivity in the ordered region is less (greater) than that in the disordered region. This means that a super-heated ordered (super-cooled disordered) state appears near the interface, which was predicted by an extended framework of thermodynamics proposed in [N. Nakagawa and S.-i. Sasa, Liquid-gas transitions in steady heat conduction, Phys. Rev. Lett. {\bf 119}, 260602, (2017).]

cond-mat.stat-mech↗
arXiv2020

Equilibrium measurement method of slip length based on fluctuating hydrodynamics

We perform equilibrium molecular dynamics simulations for nanoscale fluids confined between two parallel walls and investigate how the autocorrelation function of force acting on one wall is related to the slip length. We demonstrate that for atomically smooth surfaces, the autocorrelation function is accurately described by linearized fluctuating hydrodynamics (LFH). Excellent agreement between the simulation and the LFH solution is found over a wide range of scales, specifically, from the time scale of fluid relaxation even to that of molecular motion. Fitting the simulation data yields a reasonable estimation of the slip length. We show that LFH provides a starting point for examining the relationship between the slip length and the force fluctuations.

cond-mat.stat-mech↗
arXiv2019

Fluctuation-response inequality out of equilibrium

We present a new approach to response around arbitrary out-of-equilibrium states in the form of a fluctuation-response inequality (FRI). We study the response of an observable to a perturbation of the underlying stochastic dynamics. We find that magnitude of the response is bounded from above by the fluctuations of the observable in the unperturbed system and the Kullback-Leibler divergence between the probability densities describing the perturbed and unperturbed system. This establishes a connection between linear response and concepts of information theory. We show that in many physical situations, the relative entropy may be expressed in terms of physical observables. As a direct consequence of this FRI, we show that for steady state particle transport, the differential mobility is bounded by the diffusivity. For a virtual perturbation proportional to the local mean velocity, we recover the thermodynamic uncertainty relation (TUR) for steady state transport processes. Finally, we use the FRI to derive a generalization of the uncertainty relation to arbitrary dynamics, which involves higher-order cumulants of the observable. We provide an explicit example, in which the TUR is violated but its generalization is satisfied with equality.

cond-mat.stat-mech↗
arXiv2019

Thermodynamic entropy as a Noether invariant in a Langevin equation

We study the thermodynamic entropy as a Noether invariant in a stochastic process. Following the Onsager theory, we consider the Langevin equation for a thermodynamic variable in a thermally isolated system. By analyzing the Martin-Siggia-Rose-Janssen-de Dominicis action of the Langevin equation, we find that this action possesses a continuous symmetry in quasi-static processes, which leads to the thermodynamic entropy as the Noether invariant for the symmetry.

cond-mat.stat-mech↗
arXiv2019

Global Thermodynamics for Heat Conduction Systems

We propose the concept of global temperature for spatially non-uniform heat conduction systems. With this novel quantity, we present an extended framework of thermodynamics for the whole system such that the fundamental relation of thermodynamics holds, which we call "global thermodynamics" for heat conduction systems. Associated with this global thermodynamics, we formulate a variational principle for determining thermodynamic properties of the liquid-gas phase coexistence in heat conduction, which corresponds to the natural extension of the Maxwell construction for equilibrium systems. We quantitatively predict that the temperature of the liquid-gas interface deviates from the equilibrium transition temperature. This result indicates that a super-cooled gas stably appears near the interface.

cond-mat.stat-mech↗
arXiv2019

Microscopic Reversibility and Macroscopic Irreversibility: From a viewpoint of Algorithmic Randomness

Emergence of deterministic and irreversible macroscopic behavior from deterministic and reversible microscopic dynamics is understood as a result of the law of large numbers. In this paper, we prove on the basis of the theory of algorithmic randomness that Martin-Löf random initial microstates satisfy an irreversible macroscopic law in the Kac infinite chain model. We find that the time-reversed state of a random state is not random as well as violates the macroscopic law.

cond-mat.stat-mech↗
arXiv2019

Statistical mechanical expressions of slip length

We provide general derivations of the partial slip boundary condition from microscopic dynamics and linearized fluctuating hydrodynamics. The derivations are based on the assumption of separation of scales between microscopic behavior, such as collision of particles, and macroscopic behavior, such as relaxation of fluid to global equilibrium. The derivations lead to several statistical mechanical expressions of the slip length, which are classified into two types. The expression in the first type is given as a local transport coefficient, which is related to the linear response theory that describes the relaxation process of the fluid. The second type is related to the linear response theory that describes the non-equilibrium steady state and the slip length is given as combination of global transport coefficients, which are dependent on macroscopic lengths such as a system size. Our derivations clarify that the separation of scales must be seriously considered in order to distinguish the expressions belonging to two types. Based on these linear response theories, we organize the relationship among the statistical mechanical expressions of the slip length suggested in previous studies.

cond-mat.stat-mech↗
arXiv2019

Microscopic determination of macroscopic boundary conditions in Newtonian liquids

We study boundary conditions applied to the macroscopic dynamics of Newtonian liquids from the view of microscopic particle systems. We assume the existence of microscopic boundary conditions that are uniquely determined from a microscopic description of the fluid and the wall. By using molecular dynamical simulations, we examine a possible form of the microscopic boundary conditions. In the macroscopic limit, we may introduce a scaled velocity field by ignoring the higher order terms in the velocity field that is calculated from the microscopic boundary condition and standard fluid mechanics. We define macroscopic boundary conditions as the boundary conditions that are imposed on the scaled velocity field. The macroscopic boundary conditions contain a few phenomenological parameters for an amount of slip, which are related to a functional form of the given microscopic boundary condition. By considering two macroscopic limits of the non-equilibrium steady state, we propose two different frameworks for determining macroscopic boundary conditions.

cond-mat.stat-mech↗
arXiv2018

Singular behaviour of time-averaged stress fluctuations on surfaces

We provide a method for calculating time-averaged stress fluctuations on surfaces in a viscous incompressible fluid at equilibrium. We assume that (i) the time-averaged fluctuating stress is balanced in equilibrium at each position and that (ii) the time-averaged fluctuating stress obeys a Gaussian distribution on the restricted configuration space given by (i). Using these assumptions with the Green-Kubo formula for the viscosity, we can derive the large deviation function of the time-averaged fluctuating stress. Then, using the saddle-point method for the large deviation function, we obtain the time-averaged surface stress fluctuations. As an example, for a fluid between two parallel plates, we study the time-averaged shear/normal stress fluctuations per unit area on the top plate at equilibrium. We show that the surface shear/normal stress fluctuations are inversely proportional to the distance between the plates.

cond-mat.stat-mech↗
arXiv2018

Thermal pure state path integral and emergent symmetry

We investigate a thermally isolated quantum many-body system with an external control represented by a time-dependent parameter. We formulate a path integral in terms of thermal pure states and derive an effective action for trajectories in a thermodynamic state space, where the entropy appears with its conjugate variable. In particular, for quasi-static operations, the symmetry for the uniform translation of the conjugate variable emerges in the path integral. This leads to the entropy as a Noether invariant.

cond-mat.stat-mech↗
arXiv2018

Thermodynamical path integral and emergent symmetry

We investigate a thermally isolated quantum many-body system with an external control represented by a step protocol of a parameter. The propagator at each step of the parameter change is described by thermodynamic quantities under some assumptions. For the time evolution of such systems, we formulate a path integral over the trajectories in the thermodynamic state space. In particular, for quasi-static operations, we derive an effective action of the thermodynamic entropy and its canonically conjugate variable. Then, the symmetry for the uniform translation of the conjugate variable emerges in the path integral. This leads to the entropy as a Noether invariant in quantum mechanics.

cond-mat.stat-mech↗
arXiv2018

Surface Critical Phenomena of a Free Bose Gas with Enhanced Hopping at the Surface

We study the Bose--Einstein condensation in a tight-binding model with a hopping rate enhanced only on a surface. We show that this model exhibits two different critical phenomena depending on whether the hopping rate on the surface $t_s$ exceeds the critical value $5t/4$, where $t$ is the hopping rate in the bulk. For $t_s/t<5/4$, normal Bose--Einstein condensation occurs, while the Bose--Einstein condensation for $t_s/t\geq5/4$ is characterized by the spatial localization of the macroscopic number of particles at the surface. By exactly calculating the surface free energy, we show that for $t_s/t<5/4$, the singularity of the surface free energy stems from diverging the correlation length in the bulk, while for $t_s/t\geq5/4$, it is induced by the coupling effects between the bulk and surface.

cond-mat.stat-mech↗
arXiv2018

How does pressure fluctuate in equilibrium?

We study fluctuations of pressure in equilibrium for classical particle systems. In equilibrium statistical mechanics, pressure for a microscopic state is defined by the derivative of a thermodynamic function or, more mechanically, through the momentum current. We show that although the two expectation values converge to the same equilibrium value in the thermodynamic limit, the variance of the mechanical pressure is in general greater than that of the pressure defined through the thermodynamic relation. We also present a condition for experimentally detecting the difference between them in an idealized measurement of momentum transfer.

cond-mat.stat-mech↗
arXiv2018

Current fluctuations and transport efficiency for general Langevin systems

We derive a universal bound on generalized currents in Langevin systems in terms of the mean-square fluctuations of the current and the total entropy production. This bound generalizes a relation previously found by Barato et al. to arbitrary times and transient states. Using the bound, we define a new efficiency for stochastic transport, which measures how close a given system comes to saturating the bound. The existence of such a bounded efficiency implies that stochastic transport is unavoidably accompanied by a fluctuations and dissipation, which cannot be reduced arbitrarily. We apply the definition of transport efficiency to steady state particle transport and heat engines and show that the transport efficiency may approach unity at finite current, in contrast to the thermodynamic efficiency. Finally, we derive a bound on purely diffusive transport in terms of the Shannon entropy.

cond-mat.stat-mech↗