arXiv subjects

Silvia Damerio

Publications and source records attributed to Silvia Damerio.

10 recordsLinked to original sources

arXiv2026

Optimization of Epitaxial Mn4N Thin Films Grown by Sputtering for Spintronic Applications

Ferrimagnetic Mn4N has recently emerged as a promising rare-earth-free platform for spintronic devices due to its low magnetization, high domain wall mobility, and strong anomalous Hall response. However, the realization of thin films with robust perpendicular magnetic anisotropy (PMA) and spin-orbit torque (SOT) functionality through scalable deposition techniques remains a significant challenge. In this work, we systematically investigate the growth of Mn4N thin films by reactive magnetron sputtering and determine the conditions required to achieve high-quality films suitable for SOT applications. We demonstrate that epitaxial, single-crystalline Mn4N films with strong PMA can be obtained on MgO(100), whereas films deposited on SrTiO3(100) exhibit a textured structure. The optimized films show square-shaped hysteresis loops with high remanence, large and tunable coercivity, and a pronounced anomalous Hall effect. By combining structural, magnetic, and magnetotransport characterization with density functional theory calculations, we reveal that epitaxial strain plays a key role in tuning magnetic anisotropy, while also showing that it is not the only contributing factor. In particular, our results emphasize the importance of interfacial effects in stabilizing PMA. Finally, we demonstrate efficient current-induced magnetization switching in Mn4N/Pt bilayers, confirming strong interfacial spin transparency. These findings establish sputtered Mn4N as a promising and versatile material platform for energy-efficient spin-orbitronic devices.

cond-mat.mtrl-sci↗

arXiv2025

Magnetotransport signatures of spin-orbit coupling in high-temperature cuprate superconductors

Spin transport in superconductors offers a compelling platform to merge the dissipationless nature of superconductivity with the functional promise of spin-based electronics. A significant challenge in achieving spin polarisation in conventional superconductors stems from the singlet state of Cooper pairs, which exhibit no net spin. The generation of spin-polarised carriers, quasiparticles, or triplet pairs in superconductors has predominantly been realised in hybrid superconductor/ferromagnet systems through proximity-induced spin polarisation. Historically, cuprate superconductors have been characterised by strong electronic correlations but negligible spin-orbit coupling. Here, we report exceptionally large anisotropic magnetoresistance and a pronounced planar Hall effect arising near the superconducting phase transition in the prototypical high-temperature cuprate superconductor YBa2Cu3O7-x without using a proximity ferromagnet. These effects, unprecedented in centrosymmetric cuprates, emerge from spin-polarised quasiparticle transport mediated by strong spin-orbit coupling. By systematically tuning magnetic field strength, orientation, temperature, and doping, we show clear evidence of spin-orbit-driven transport phenomena in a material class long thought to lack such interactions. Our findings reveal an unexpected spin-orbit landscape in cuprates and open a route to engineer spintronic functionalities in high-temperature superconductors.

cond-mat.mes-hall↗

arXiv2025

Tunable spin and orbital torques in Cu-based magnetic heterostructures

Current-induced torques originating from earth-abundant 3d elements offer a promising avenue for low-cost and sustainable spintronic memory and logic applications. Recently, orbital currents -- transverse orbital angular momentum flow in response to an electric field -- have been in the spotlight since they allow current-induced torque generation from 3d transition metals. Here, we report a comprehensive study of the current-induced spin and orbital torques in Cu-based magnetic heterostructures. We show that high torque efficiencies can be achieved in engineered Ni80Fe20/Cu bilayers where Cu is naturally oxidized, exceeding the ones found in the archetypical Co/Pt. Furthermore, we demonstrate sign and amplitude control of the damping-like torque by manipulating the oxidation state of Cu via solid-state gating. Our findings provide insights into the interplay between charge, spin, and orbital transport in Cu-based heterostructures and open the door to the development of gate-tunable spin-orbitronic devices.

cond-mat.mtrl-sci↗

arXiv2023

Magnetoresistive detection of perpendicular switching in a magnetic insulator

Spintronics offers promising routes for efficient memory, logic, and computing technologies. The central challenge in spintronics is electrically manipulating and detecting magnetic states in devices. The electrical control of magnetization via spin-orbit torques is effective in both conducting and insulating magnetic layers. However, the electrical readout of magnetization in the latter is inherently difficult, limiting its use in practical applications. Here, we demonstrate magnetoresistive detection of perpendicular magnetization reversal in an electrically insulating ferrimagnet, terbium iron garnet (TbIG). To do so, we use TbIG|Cu|TbCo, where TbCo is a conducting ferrimagnet and serves as the reference layer, and Cu is a nonmagnetic spacer. Current injection through Cu|TbCo allows us to detect the magnetization reversal of TbIG with a simple resistance readout during an external magnetic field sweep. By examining the effect of measurement temperature, TbCo composition, and Cu thickness on the sign and amplitude of the magnetoresistance, we conclude that the spin-dependent electron scattering at the TbIG|Cu interface is the underlying cause. Technologically-feasible magnetoresistive detection of perpendicular switching in a ferrimagnetic garnet is a breakthrough, as it opens broad avenues for novel insulating spintronic devices and concepts.

cond-mat.mes-hall↗

arXiv2023

Evolution of ferromagnetic stripes in FePt films at low temperature

Patterns of ferroic domains and domain walls are being intensively studied to implement new logic schemes. Any technological application of such objects depends on a detailed understanding of them. This study analyzes patterns of ferromagnetic stripes on equiatomic FePt thin films at low temperatures. Since FePt is known to develop a transition from in-plane homogeneous magnetization to stripes upon varying its thickness, multiple samples are studied to consider the critical value within the analyzed range. Stripes' width demonstrates the well-known Murayama's law while a non-trivial dependence on temperature is also reported. Moreover, the room-temperature uniform distribution of the pattern evolves into a distorted one upon temperature cycling. Finally, dissimilar striped patterns are obtained upon reducing and increasing temperature indicating the states are dependent on the history of applied stimuli rather than the parametric conditions.

cond-mat.mtrl-sci↗

arXiv2023

Sputtered terbium iron garnet films with perpendicular magnetic anisotropy for spintronic applications

We report the structural, magnetic, and interfacial spin transport properties of epitaxial terbium iron garnet (TbIG) ultrathin films deposited by magnetron sputtering. High crystallinity was achieved by growing the films on gadolinium gallium garnet (GGG) substrates either at high temperature, or at room temperature followed by thermal annealing, above 750 °C in both cases. The films display large perpendicular magnetic anisotropy (PMA) induced by compressive strain, and tunable structural and magnetic properties through growth conditions or the substrate lattice parameter choice. The ferrimagnetic compensation temperature (TM) of selected TbIG films was measured through temperature-dependent anomalous Hall effect (AHE) in Pt/TbIG heterostructures. In the studied films, TM was found to be between 190-225 K, i.e., approximately 25-60 K lower than the bulk value, which is attributed to the combined action of Tb deficiency and oxygen vacancies in the garnet lattice evidenced by x-ray photoelectron spectroscopy measurements. Sputtered TbIG ultrathin films with large PMA and highly tunable properties reported here can provide a suitable material platform for a wide range of spintronic experiments and device applications.

cond-mat.mtrl-sci↗

arXiv2022

Dynamic Tilting of Ferroelectric Domain Walls via Optically Induced Electronic Screening

Optical excitation perturbs the balance of phenomena selecting the tilt orientation of domain walls within ferroelectric thin films. The high carrier density induced in a low-strain BaTiO3 thin film by an above-bandgap ultrafast optical pulse changes the tilt angle that 90° a/c domain walls form with respect to the substrate-film interface. The dynamics of the changes are apparent in time-resolved synchrotron x-ray scattering studies of the domain diffuse scattering. Tilting occurs at 298 K, a temperature at which the a/b and a/c domain phases coexist but is absent at 343 K in the better ordered single-phase a/c regime. Phase coexistence at 298 K leads to increased domain-wall charge density, and thus a larger screening effect than in the single-phase regime. The screening mechanism points to new directions for the manipulation of nanoscale ferroelectricity.

cond-mat.mtrl-sci↗

arXiv2022

Unusual ferrimagnetism in CaFe2O4

Incomplete cancellation of collinear antiparallel spins gives rise to ferrimagnetism. Even if the oppositely polarized spins are owing to the equal number of a single magnetic element having the same valence state, in principle, a ferrimagnetic state can still arise from the crystallographic inequivalence of the host ions. However, experimental identification of such a state as ferrimagnetic is not straightforward because of the tiny magnitude expected for M and the requirement for a sophisticated technique to differentiate similar magnetic sites. We report a synchrotron-based resonant x-ray investigation at the Fe L2,3 edges on an epitaxial film of CaFe2O4, which exhibits two magnetic phases with similar energies. We find that while one phase of CaFe2O4 is antiferromagnetic, the other one is ferrimagnetic with an antiparallel arrangement of an equal number of spins between two distinct crystallographic sites with very similar local coordination environments. Our results further indicate two distinct origins of an overall minute M; one is intrinsic, from distinct Fe3+ sites, and the other one is extrinsic, arising from defective Fe2+ likely forming weakly-coupled ferrimagnetic clusters. These two origins are uncorrelated and have very different coercive fields. Hence, this work provides a direct experimental demonstration of ferrimagnetism solely due to crystallographic inequivalence of the Fe3+ as the origin of the weak M of CaFe2O4.

cond-mat.mtrl-sci↗

arXiv2020

Structure and magnetic properties of epitaxial CaFe2O4 thin films

CaFe2O4 is a highly anisotropic antiferromagnet reported to display two spin arrangements with up-up-down-down (phase A) and up-down-up-down (phase B) configurations. The relative stability of these phases is ruled by the competing ferromagnetic and antiferromagnetic interactions between Fe3+ spins arranged in two different environments, but a complete understanding of the magnetic structure of this material does not exist yet. In this study we investigate epitaxial CaFe2O4 thin films grown on TiO2 (110) substrates by means of Pulsed Laser Deposition (PLD). Structural characterization reveals the coexistence of two out-of-plane crystal orientations and the formation of three in-plane oriented domains. The magnetic properties of the films, investigated macroscopically as well as locally, including highly sensitive Mossbauer spectroscopy, reveal the presence of just one order parameter showing long-range ordering below T = 185 K and the critical nature of the transition. In addition, a non-zero in-plane magnetization is found, consistent with the presence of uncompensated spins at phase or domain boundaries, as proposed for bulk samples.

cond-mat.mtrl-sci↗

arXiv2019

Periodicity doubling cascades: direct observation in ferroelastic materials

Very sensitive responses to external forces are found near phase transitions. However, phase transition dynamics and pre-equilibrium phenomena are difficult to detect and control. We have directly observed that the equilibrium domain structure following a phase transition in BaTiO3, a ferroelectric and ferroelastic material, is attained by halving of the domain periodicity, sequentially and multiple times. The process is reversible, displaying periodicity doubling as temperature is increased. This observation is backed theoretically and can explain the fingerprints of domain period multiplicity observed in other systems, strongly suggesting this as a general model for pattern formation during phase transitions in ferroelastic materials.

cond-mat.mtrl-sci↗