arXiv subjects

Silvia Spezzano

Publications and source records attributed to Silvia Spezzano.

At least 19 recordsLinked to original sources

arXiv2026

Complex Organic Molecules in Protostars with ALMA Spectral Surveys (COMPASS) VI. Discovery of a class I methanol maser transition and its association with acetaldehyde

CH3OH masers that are collisionally pumped, referred to as `class I', commonly trace shock interfaces in star-forming regions, but their incidence in low-mass protostars remains poorly quantified. We use data from the COMPASS ALMA Large Program to establish the occurrence, spatial origin, and excitation of a newly detected class I CH3OH maser at 302.9 GHz towards low-mass protostars and to test whether its pumping environments exhibit signatures of shock-driven complex chemistry. COMPASS provides unbiased line surveys of 11 sources between 279.0 and 311.7 GHz at typical angular resolutions of 0.3"-0.5". Rotation diagram analysis of departures from LTE in the 302.9 GHz CH3OH excitation robustly reveals masing in seven of 11 sources, with peak brightness temperatures from a few to ~10^3 K. The brightest detection is towards HOPS 108 and is likely associated with the powerful outflow from the nearby intermediate-mass protostar HOPS 370. Excluding this case, the maser is detected in six of ten low-mass protostars (60%). All six are Class 0 sources interacting with dense ambient material, whereas the non-detections comprise three Class I sources and one isolated Class 0 core, indicating a preference for early evolutionary stages and gas-rich environments for outflow-ambient medium interactions. The maser emission is spatially coincident with thermal CH3OH along outflow cavity walls and bow shocks, but is more compact and knot-like. Among the surveyed COMs, only CH3CHO closely traces the shocked morphology of the 302.9 GHz maser, and only around HOPS 108. These results show that class I CH3OH masers in low-mass protostellar systems are more prevalent than previously recognised and preferentially occur in younger, more embedded sources. More sensitive CH3CHO observations are needed to test whether a similar relationship with shock-driven chemistry also applies in the low-mass regime.

astro-ph.GA↗

arXiv2026

Complex Organic Molecules in Protostars with ALMA Spectral Surveys (COMPASS) II. Approach to data reduction and products for line-rich broadband (sub)millimeter spectra

Studying the chemical composition of the warm gas surrounding embedded solar-type protostars is one of the areas for which the Atacama Large Millimeter/submillimeter Array (ALMA) is particularly well suited. Recently, the ALMA Large Program ``Complex Organic Molecules in Protostars with ALMA Spectral Surveys'' (COMPASS) carried out an observing campaign of a sample of 11 protostellar regions to investigate the chemical impact of their environments and evolutionary stages. The aim of this paper is to provide the observational and procedural information necessary for the community to understand the analysis presented in forthcoming scientific papers by the COMPASS collaboration, and to enable archival research using the data products provided by our team and the ALMA Science Archive. This paper describes the technical setup of the observations, and it outlines the data-processing pipeline and primary data products from this initiative. The Common Astronomy Software Applications (CASA) was used for initial calibration following the standard ALMA Pipeline, and then IMAGER was used for self-calibration and imaging. We describe post-processing done with Python to achieve favorable continuum subtraction, correct for the primary beam response, and extract spectra. We discuss our strategy for mitigating data challenges, including those related to data volume and continuum subtraction for spectral line analysis. The incorporation of IMAGER in our workflow was advantageous in terms of the computing efficiency which allowed us to benchmark several imaging parameters and techniques; we also demonstrate that the imaging outcomes using IMAGER or CASA are scientifically comparable. Numerous data products are generated for the program, including image cubes for the 36 spectral windows targeting each source, extracted spectra, and continuum images.

astro-ph.SR↗

arXiv2026

The complex organic molecular content in the L1517B starless core

Recent observations of the pre-stellar core L1544 and the younger starless core L1498 have revealed that complex organic molecules (COMs) are enhanced in the gas phase toward their outer and intermediate-density shells. Our goal is to determine the level of chemical complexity toward the starless core L1517B, which seems younger than L1498, and compare it with the other two previously studied cores to see if there is a chemical evolution within the cores. We have carried out 3 mm high-sensitivity observations toward two positions in the L1517B starless core: the core's centre and the position where the methanol emission peaks (at a distance of $\sim$5000 au from the core's centre). Our observations reveal that a lower number of COMs and COM precursors are detected in L1517B with respect to L1498 and L1544, and also show lower abundances. Besides methanol, we only detected CH$_3$O, H$_2$CCO, CH$_3$CHO, CH$_3$CN, CH$_3$NC, HCCCN, and HCCNC. Their measured abundances are $\sim$3 times larger toward the methanol peak than toward the core's centre, mimicking the behaviour found toward the more evolved cores L1544 and L1498. We propose that the differences in the chemical complexity observed between the three studied starless cores are a consequence of their evolution, with L1517B being the less evolved one, followed by L1498 and L1544. Chemical complexity in these cores seems to increase over time, with N-bearing molecules forming first and O-bearing COMs forming at a later stage as a result of the catastrophic depletion of CO.

astro-ph.GA↗

arXiv2026

A tale of two isotopes: Spatial variation in HCN fractionation toward young cores

Context. Isotopic fractionation can serve as a powerful tracer of the chemical evolution during star and planet formation. To accurately interpret observations, it is crucial to identify the dominant pathways of nitrogen and carbon fractionation at different evolutionary stages. Aims. We aim to study nitrogen and carbon fractionation in a sample of young cores at the onset of star formation. Methods. We map H$^{13}$CN and HC$^{15}$N around one starless and three pre-stellar cores. We compute the $N$(H$^{13}$CN)/$N$(HC$^{15}$N) column density ratio across the cores and compare the distribution with $N$(H$_2$) maps from $\textit{Herschel}$/SPIRE. In addition, we calculate $^{14}$N/$^{15}$N maps using the double isotope method for comparison with earlier studies. The results are compared with astrochemical modeling of carbon and nitrogen fractionation for a one-dimensional pre-stellar core model. Results. The computed $N$(H$^{13}$CN)/$N$(HC$^{15}$N) ratio exhibit clear spatial variation across the maps. This variation is correlated with $N$(H$_2$) in three out of four cores. Conclusions. Our analysis reveals a correlation between the H$^{13}$CN/HC$^{15}$N ratios and the $N$(H$_2$) maps. According to the astrochemical model, the correlation is mainly due to variations in the $^{12}$C/$^{13}$C ratio. Consequently, the results caution against applying the double-isotope method to derive $^{14}$N/$^{15}$N ratios without independently assessing possible spatial variations in the $^{12}$C/$^{13}$C ratio. Furthermore, the leading cause of the isotopic variation in the model is not isotope-selective photodissociation, but rather more efficient fractionation through exchange reactions at lower temperatures in the denser regions of the cores.

astro-ph.SR↗

arXiv2026

Using Scattered Near-Infrared Light to Map Water Ice in Prestellar Cores with SPHEREx

We present the first coreshine-derived, spatially-resolved maps of the 3 $μ$m H$_2$O ice absorption feature in four prestellar cores, using SPHEREx spectra. Ices are a key component of dense cores in molecular clouds, playing a central role in the chemistry of planet formation around young stars. However, spatially resolved abundance studies remain limited, typically relying on unevenly distributed background star sightlines. Here, we take advantage of the all-sky spectrophotometric capabilities of SPHEREx to construct ice absorption maps with uniform spatial resolution using the illumination of dense cores by scattered Galactic radiation, or coreshine. To demonstrate proof of concept, we analyse the spatially varying H$_2$O ice absorption in four nearby (~140 pc) prestellar cores - L1544, CrA 151, L260 and L1512. Two cores follow the expected spatial trend of ice absorption peaking at the centre, but the two densest cores show a surprising drop in observed ice absorption in the innermost regions. To interpret the absorption maps, we construct analytical and simulated models of a Bonnor-Ebert sphere illuminated by scattering. We study the effects of different geometric configurations, ice mass fractions, and spatial differences in ice composition. None of these can explain the reduced central absorption, pointing to an unexplained physical or chemical effect operating in the densest prestellar regions. Our simulations further show that spectra derived from coreshine provide a robust tracer of spatially varying ice density and composition, establishing SPHEREx scattered-light spectroscopy as a powerful new probe of ice in dense cores.

astro-ph.GA↗

arXiv2026

Chemical Complexity in the Early Stages of Star Formation in the SKAO Era

About 350 molecules have been identified in the interstellar medium (ISM), including complex molecules relevant to prebiotic chemistry. A remarkable level of molecular diversity has been observed from the earliest stages of star formation, providing the initial chemical inventory inherited by planetary systems. Radio observations have played a pivotal role in these discoveries, starting with the identification of the first polyatomic molecule, $\text{NH}_3$ (Cheung et al. 1968). (Sub-)millimeter observations have revealed complex organic molecules of prebiotic relevance, including formamide ($\text{NH}_2\text{CHO}$), glycolaldehyde ($\text{CH}_2\text{OHCHO}$), and even urea ($(\text{NH}_2)_2\text{CO}$), and hydroxylamine ($\text{NH}_2\text{OH}$), which are possible precursors of RNA nucleotides (Ceccarelli et al. 2023; Jiménez-Serra et al. 2020). However, in dense protostellar regions, dust opacity hampers the detection of molecular emission. Additionally, large molecules and those containing heavy atoms, which have rotational transitions at lower frequencies, often remain inaccessible to current instruments. The Square Kilometre Array Observatory (SKAO) will provide an unprecedented combination of sensitivity and angular resolution at radio wavelengths. This will allow for the detection of prebiotic species and offer new insights into the chemical pathways that shape emerging planetary systems (Jiménez-Serra et al. 2022). This chapter details the scientific questions and advancements that the SKAO, and more specifically, SKA-Mid equipped with the Band 5 receivers, will pursue in the field of astrochemistry, focusing on the chemical complexity in both high-mass and solar-type star-forming regions.

astro-ph.SR↗

arXiv2026

Jets and Outflows in Young Stellar Objects with the SKAO

Jets and outflows are ubiquitous phenomena associated with the formation of young stellar objects (YSOs). They play a crucial role in removing angular momentum from the accreting system and in regulating star-formation efficiency. Theoretical studies and observations with ALMA and VLA have shown that jets and winds may have a crucial role in promoting dust growth in the envelope-disc system and in shaping the physical and chemical properties of the surrounding environment. Despite these significant advances, many fundamental questions remain unanswered regarding the acceleration, collimation, and chemical impact of jets and outflows from YSOs. The SKA-project will overcome the limitations of current mm/cm-facilities by enabling high-angular resolution and high-sensitivity cm-observations, crucial for probing jets/outflows near YSOs. Radio recombination lines, combined with proper motions, offer a unique opportunity to study the 3D-kinematics of jets. Non-thermal linearly polarised synchrotron emission will allow measuring magnetic field strength and morphology at unprecedented scales of a few au. Observations of dust emission in outflow cavities will allow studying how dust grows and is eventually transported from the disc to the envelope and back. Finally, the SKA-project will allow exploring the dust composition and chemical enrichment in shocks, where sputtering/shattering of grains cause the release of their mantles and refractory cores in the gas-phase. Complementary to ALMA's detection of simple and complex organic molecules, the SKAO will probe, for the first time, long carbon chains/rings, several Cl-, Al-, Mg-, and other metal-bearing species (missed by current sub-mm facilities).

astro-ph.GA↗

arXiv2026

Probing the ion-neutral drift velocity towards the L1544 prestellar core: Detection of ambipolar diffusion using N$_2$D$^+$ and para-NH$_2$D

The dynamical role of the magnetic field in the star formation process is tightly linked to the coupling between matter and the field. This coupling is due to the interaction between ions and neutrals in the partially ionized interstellar medium. When the ionization degree drops in the dense environment of prestellar cores, the magnetic field and the matter may decouple, leading to differences in the infalling velocities of ions and neutrals known as ambipolar diffusion. The onset of gravitational collapse resulting from ion-neutral decoupling has never been observed. The aim of this work is to search for signatures of ambipolar diffusion within a prestellar core. We observed the deuterated N$_2$D$^+$ ion and the neutral para-NH$_2$D species towards the prototypical prestellar core L1544. These two species are ideal tracers of prestellar cores sampling the same high densities in the core interior. We compared the velocity centroid and linewidth maps of the ion-neutral pair. We find a mean ion-neutral velocity difference of $\sim$0.05 km/s towards the core. By comparing with predictions from self-consistent calculations of the ambipolar resistivity including dust grain growth, we interpret the observed ion-neutral velocity difference in L1544 as a signature of ambipolar diffusion. We do not detect a significant ion-neutral linewidth difference that may be attributed to the subsonic infall motions of the gas in L1544 and geometrical effects in the presence of inclination. These results emphasize the role of dust grain growth at the prestellar core stage in setting the ambipolar resistivity and regulating the dynamical evolution of dense cores towards their collapse into protostars. We propose that measurements of ion-neutral drift velocities provide new constraints on the total magnetic field strength and the dust size distribution within prestellar cores.

astro-ph.GA↗

arXiv2026

Carbon chain diversity in L1544 and IRAS 16293-2422: an astrochemical pathfinder study for the SKAO

Astrochemical observations have revealed a surprisingly high level of chemical complexity, including long carbon chains, in the earliest stages of Sun-like star formation. The origin of these species and whether they undergo further growth, possibly contributing to the molecular complexity of planetary systems, remain open questions. We present recent observations performed using the 100-m Green Bank Telescope of the prestellar core L1544 and the protostellar system IRAS 16293-2422. In L1544, we detected several complex carbon-bearing species, including $\mathrm{C_2S}$, $\mathrm{C_3S}$, $\mathrm{C_3N}$, $\mathrm{c\text{-}C_3H}$, $\mathrm{C_4H}$, and $\mathrm{C_6H}$, complementing previously reported emission of cyanopolyynes. In IRAS 16293-2422, we detected $\mathrm{c\text{-}C_3H}$ and, for the first time, $\mathrm{HC_7N}$. Thanks to the high spectral resolution, we refine the rest frequencies of several $\mathrm{c\text{-}C_3H}$ and $\mathrm{C_6H}$ transitions. We perform radiative transfer analysis, highlighting a chemical difference between the two sources: IRAS 16293-2422 shows column densities 10-100 times lower than L1544. We perform astrochemical modeling, employing an up-to-date chemical network with revised reaction rates. The models reproduce the general trends, with cyanopolyyne and polyynyl radical abundances decreasing as molecular size increases, but they underestimate the abundances of cyanopolyynes longer than $\mathrm{HC_5N}$ by up to two orders of magnitude. Current models, which include the dominant neutral-neutral formation routes, cannot account for this discrepancy, suggesting that the chemical network is incomplete. We propose that additional ion-molecule reactions are crucial for the formation of these species. Developing a more comprehensive chemical network for long carbon chains is essential for accurately interpreting present and future observations.

astro-ph.GA↗

arXiv2025

The Emergence of Prebiotic Chemistry in the ISM

Contrary to popular belief, the interstellar medium (ISM) is not empty; it is filled with atoms, dust particles, and molecules. Some of these molecules may have been the very building blocks of life that, delivered to Earth via comets and meteorites, could have given rise to Life itself. A large-area single-dish telescope with superb sensitivity, field-of-view and multi-band instruments will allow us to explore the limits of chemical complexity in the interstellar medium, across our Galaxy and in external galaxies, determining whether amino acids, sugars, or RNA/DNA nucleobases can form in space.

astro-ph.IM↗

arXiv2025

First mapping of prebiotic molecule CH2NH in a pre-stellar core

We present the first spatially resolved map of methanimine CH2NH in the prestellar core L1544 using the IRAM 30m telescope. The 2$_{0,2}$-1$_{0,1}$ line at 127 GHz was mapped with 20" resolution ($\sim$2800 au), revealing extended CH2NH emission across the core. The peak line intensity coincides with the well-known c-C3H2 peak, while the integrated intensity peaks between the HNCO and dust continuum peaks due to broader linewidths in the latter region. Column densities of CH2NH are $\sim$(0.5-1.4$\times$)10$^{12}$ cm$^{-2}$, corresponding to fractional abundances of $5\times10^{-11}$-$1\times10^{-10}$, with a trend decreasing from the southern, carbon-chain rich region to the dust and HNCO peak in the north. Comparison with complementary molecular maps and the gas-grain chemical model of Sipilä et al. suggests that neutral-neutral gas-phase reactions and dissociative recombination dominate in the outer carbon-chain shell. This study demonstrates that CH2NH, a simple nitrogen- and carbon-bearing molecule previously detected with pointed observations in other cold cores, is present and spatially extended in the evolved pre-stellar core L1544. This indicates that prebiotic nitrogen-carbon chemistry continues efficiently up to the onset of gravitational collapse, providing key constraints for astrochemical models and the early stages of chemical complexity leading to amino acids.

astro-ph.GA↗

arXiv2025

First Detection of CH3OD in Prestellar Cores

The isotopic ratios of deuterated methanol derived around protostars are commonly used to infer the physical conditions under which they formed in the earlier prestellar stage. However, there is a discrepancy in the ratio of the singly deuterated methanol isotopologues, CH2DOH/CH3OD, between low- and high-mass protostars, which puts into question whether prestellar isotopic ratios are generally preserved during the star- and planet-forming process. Resolving this puzzle is only made harder by the complete lack of data on this ratio in the prestellar stage. This work presents observations with the IRAM 30m telescope that securely detect CH3OD in the prestellar core L1448 in Perseus and tentatively in B213-C6 in Taurus. This work constrains the ratio of CH2DOH/CH3OD and the D/H ratios for both singly deuterated methanol isotopologues for the first time at the prestellar stage. Column densities calculated under the assumption of local thermal equilibrium lead to a CH2DOH/CH3OD ratio of 2.8-8.5 in L1448 and $\leq$ 5.7 in B213-C6. The values are marginally consistent with the statistically expected ratio of 3, but most assumptions put the values in an elevated range in line with values found around low-mass protostars. The D/H ratio in CH2DOH is between 3.6% and 6.8% in L1448 and in the range of 2.4-5.8% in B213-C6. The D/H ratio derived for CH3OD is lower, namely 1.4-4.4% in L1448 and $\leq$ 3.8% in B213-C6.

astro-ph.GA↗

arXiv2025

New Orbital Constraints for YSES 1 b and HR 2562 B from High-Precision Astrometry and Planetary Radial Velocities

We present new VLTI/GRAVITY astrometry and updated orbit fits for the directly imaged companions YSES 1 b and HR 2562 B, substellar objects straddling the planet-brown dwarf boundary. Using high-precision astrometry, radial velocity (RV) data, and proper motions, we derive revised orbital parameters with orbitize! arXiv:1910.01756. For YSES 1 b, the inclusion of GRAVITY astrometry and a relative radial velocity measurement from arXiv:2409.16660 overcomes the traditional challenge of constraining eccentricities for distant companions, enabling the first orbit fit and yielding a constrained eccentricity of 0.44 (0.20). This represents the first full orbit fit for the system. Additionally, we calculate a median line-of-sight stellar obliquity of 12 (+11, -8) degrees, providing further insight into the system's dynamical architecture. For HR 2562 B, our analysis agrees with arXiv:2302.04893, confirming a low-eccentricity orbit (0.34 (0.20)) and an inclination of 87 (1) degrees. We find HR 2562 B's orbit to be nearly coplanar with the debris disk, with a mutual inclination of 3.7 (0.3) degrees. For both YSES 1 b and HR 2562 B the lower eccentricities favor an in situ formation scenario over extreme scattering or cloud fragmentation.

astro-ph.EP↗

arXiv2025

Nascent chemical complexity in prestellar core IRAS 16293E: complex organics and deuterated methanol

Prestellar cores represent early sites of low-mass ($M$ $\leq$ few M$_\odot$) star and planet formation and provide insight into initial chemical conditions of complex organic molecules (COMs). Deuterated COMs trace the degree of molecular inheritance and/or reprocessing, as high deuteration in protostellar systems suggests COMs forming during the prestellar stage when deuteration is enhanced. Within the L1689N molecular cloud, the prestellar core IRAS 16293E sits $90^{"}$ eastward of the chemically-rich IRAS 16293-2422 A and B protostellar system. A unique view of star formation inside a common natal cloud, IRAS 16293A, B, and E all show some of the highest levels of deuteration in the ISM, with a number of D/H ratios $10^{5}$ times higher than Solar. We investigate for the first time the deuteration levels of the simplest COM, methanol (CH$_3$OH), in IRAS 16293E. Using the Arizona Radio Observatory (ARO) 12 m telescope, we target favorable transitions of CH$_2$DOH, CHD$_2$OH, $^{13}$CH$_3$OH, and several higher complexity COMs (including acetaldehyde, CH$_3$CHO, methyl formate, HCOOCH$_3$, and dimethyl ether, CH$_3$OCH$_3$) in the 3 mm band. Follow-up observations with the Yebes 40 m telescope provided additional transitions in the 7 mm (Q-band). We report the first detections of these COMs and deuterated methanol in prestellar core IRAS 16293E and use our observations to calculate excitation temperatures, column densities, and relative abundance ratios. Striking similarities are found between relative molecular ratios and D/H values when comparing IRAS 16293E to the A and B protostars, as well as to a heterogeneous sample of other prestellar cores, protostars, and the comet 67P/Churyumov-Gerasimenko. Our results support the idea that there is a limited amount of chemical reprocessing of COMs when prestellar cores collapse and heat-up during the protostellar phase.

astro-ph.GA↗

arXiv2025

Statistical nuclear spin ratios of deuterated ammonia in the pre-stellar core L1544

We determined the ortho/para (o/p) ratios of NH2D and NHD2 in the archetypical pre-stellar core L1544. The core was observed in the two lowest rotational lines of ortho- and para-NH2D using the APEX and the IRAM 30 m telescopes. The ground-state lines of ortho- and para-NHD2 were observed with APEX. The distributions of chemical abundances in the core were predicted using a gas-grain chemistry model with two different scenarios concerning proton transfer reactions in the gas. One of the scenarios, the so-called full scrambling (FS), allows protons and deuterons to be completely mixed in the intermediate reaction complex before dissociation, whereas the other describes these reactions as proton or deuteron hops (PH). We also tested assumed abundance profiles independent of the chemistry models. Radiative transfer calculations were used to simulate the observed NH2D and NHD2 lines from the predicted and assumed abundance profiles. Our modelling efforts suggest that the ground-state lines of NH2D and NHD2 at the wavelength 0.9 mm that are observable with the same beam and in the same spectrometer band are the most reliable probes of the o/p ratios. Simulations using the PH reaction scheme show systematically better agreement with the observations than simulations with the FS model. Simulations using a broken power law abundance profile as a function of the gas density give spin ratios that are close to the predictions of the PH scenario: o/p-NH2D=2.85+-0.05, o/p-NHD2=2.10+-0.06 (1 sigma). The o/p ratios predicted by the PH scenario in the gas phase correspond to the nuclear spin statistical weights, that is, o/p-NH2D=3, o/p-NHD2=2. In view of the fact that H and D atom addition reactions on grain surfaces also result in these ratios, it is reasonable to assume that the spin ratios of interstellar ammonia and its deuterated forms are in general equal to their statistical values.

astro-ph.GA↗

arXiv2025

BASIL: Fast broadband line-rich spectral-cube fitting and image visualization via Bayesian quadrature

Mapping the spatial distributions and abundances of complex organic molecules in hot cores and hot corinos is crucial for understanding the astrochemical pathways and the inheritance of prebiotic material by nascent planetary systems. However, the line-rich spectra from these sources pose significant challenges for robustly fitting molecular parameters due to severe line blending and unidentified lines. We present an efficient framework, Bayesian Active Spectral-cube Inference and Learning (BASIL), for estimating molecular parameter maps for hundreds of molecules based on the local thermodynamic equilibrium (LTE) model, applied to wideband spectral datacubes of line-rich sources. We adopted stochastic variational inference to infer molecular parameters from spectra at individual positions, balancing between fitting accuracy and computational speed. For obtaining parameter maps, instead of querying every location or pixel, we introduced an active learning framework based on Bayesian quadrature and its parallelization. Specifically, we assessed and selected the locations or pixels of spectrum that are most informative for estimating the entire set of parameter maps by training a Gaussian processes model. By greedily selecting locations with maximum information gain, we achieve sublinear convergence. We benchmarked BASIL on a large synthetic datacube and demonstrated that it produces accurate 468 molecular parameter maps from 117 molecules within ~180 hours, orders of magnitude faster than traditional pixel-by-pixel fitting using Markov chain Monte Carlo methods, with visually reliable results emerging in just ~20 hours. Additional training iterations provide progressively more accurate results. This quick visualization meets the demands of big data in modern astronomical surveys.

astro-ph.GA↗

arXiv2025

Laboratory rotational spectroscopy leads to the first interstellar detection of singly deuterated methyl mercaptan (CH$_{2}$DSH)

We report an extensive rotational spectroscopic analysis of singly deuterated methyl mercaptan (CH$_{2}$DSH) using both millimeter and far-infrared synchrotron spectra to achieve a global torsional analysis of the three lowest torsional substates (e$_{0}$, e$_{1}$, and o$_{1}$) of this non-rigid species. A fit including 3419 millimeter wave transitions along with 43 infrared torsional subband centers was performed with root mean square deviations of 0.233 MHz and 0.270 cm$^{-1}$, respectively, resulting in 68 fit parameters. A spectroscopic catalogue built from this analysis for a temperature of 125 K has led to the first interstellar detection of CH$_{2}$DSH towards the Solar-like protostar IRAS 16293-2422 B. We report the identification of 46 transitions, including eight relatively unblended lines, resulting in a derived column density of (3.0$\pm$0.3)$\times$10$^{14}$ cm$^{-2}$. The column density ratio for HDCS/CH$_{2}$DSH compared to HDCO/CH$_{2}$DOH suggests a difference in the interstellar chemistry between the sulphur and oxygen complex organics, in particular a different link between H$_{2}$CO and CH$_{3}$OH and between H$_{2}$CS and CH$_{3}$SH. This is the first interstellar detection of a deuterated sulphur-bearing COM and therefore an important step into understanding the chemical origin of sulphur-based prebiotics.

astro-ph.GA↗

arXiv2024

Probing the Physics of Star-Formation (ProPStar) III. No evidence for dissipation of turbulence down to 20 mpc (4 000 au) scale

Context. Turbulence is a key component of molecular cloud structure. It is usually described by a cascade of energy down to the dissipation scale. The power spectrum for subsonic incompressible turbulence is $k^{-5/3}$, while for supersonic turbulence it is $k^{-2}$. Aims. We aim to determine the power spectrum in an actively star-forming molecular cloud, from parsec scales down to the expected magnetohydrodynamic (MHD) wave cutoff (dissipation scale). Methods. We analyze observations of the nearby NGC 1333 star-forming region in three different tracers to cover the different scales from $\sim$10 pc down to 20 mpc. The largest scales are covered with the low density gas tracer $^{13}$CO (1-0) obtained with single dish, the intermediate scales are covered with single-dish observations of the C$^{18}$O (3-2) line, while the smallest scales are covered in H$^{13}$CO$^+$ (1-0) and HNC (1-0) with a combination of NOEMA interferometer and IRAM 30m single dish observations. The complementarity of these observations enables us to generate a combined power spectrum covering more than two orders of magnitude in spatial scale. Results. We derive the power spectrum in an active star-forming region spanning more than 2 decades of spatial scales. The power spectrum of the intensity maps shows a single power-law behavior, with an exponent of 2.9$\pm$0.1 and no evidence of dissipation. Moreover, there is evidence for the power-spectrum of the ions to have more power at smaller scales than the neutrals, which is opposite from theoretical expectations. Conclusions. We show new possibilities of studying the dissipation of energy at small scales in star-forming regions provided by interferometric observations.

astro-ph.GA↗