arXiv subjects

Simon Čopar

Publications and source records attributed to Simon Čopar.

At least 19 recordsLinked to original sources

arXiv2026

Molecular chirality controls droplet division and helical fiber formation in liquid crystal emulsions

Molecular chirality is a source of broken mirror symmetry, but using it to control mesoscale structures with a tunable length scale remains challenging. Here, we demonstrate that adding a chiral dopant to nematic liquid crystal droplets bounded by a deformable two-surfactant interface controls their morphogenesis: the ratio of droplet diameter to cholesteric pitch determines whether droplets divide asymmetrically or symmetrically upon cooling, and whether they transform into single- or double-strand helical fibers. The fiber periodicity and thickness both scale linearly with the cholesteric pitch, which varies by less than 2% with temperature across the self-shaping window. Numerical simulations reveal that chirality-driven elastic stresses at the interface destabilize the droplets and trigger cusp-mediated shape transformations. These results establish cholesteric pitch as a design variable to precisely control droplet division and decouple the dimensions of spontaneously formed mesoscale structures from temperature dependence.

cond-mat.soft↗

arXiv2025

Multistable polar textures in geometrically frustrated nematic liquid crystals

The ability to manipulate polar entities with multiple external fields opens exciting possibilities for emerging functionalities and novel applications in spin systems, photonics, metamaterials, and soft matter. Liquid crystals (LCs), exhibiting both a crystalline structure and liquid fluidity, represent a promising platform for manipulating phases with polar molecular order, notably ferroelectric ones. However, achieving a polar symmetry is challenging with rod-shaped LC molecules, which form predominantly apolar nematic phases. We report an approach in which a geometric lattice confinement of nematic LCs is used to induce planar polar order on the scale of a mesoscopic metamaterial. We confine the nematic LC in a micropillar array, forming topological defect-pillar pairs of elastic dipoles with a free top interface in contact with an immiscible fluid. The resulting dipole lattice configurations can be programmed rheologically by flowing the top fluid and maintained even after flow cessation, a phenomenon attributed to orientational multistability of the dipoles. This multi-memory effect enables the encoding and reconfiguration of directional information. Overall, this research establishes a foundational understanding of topological dipoles under confinement and shear flow, enabling the detection, tracking, and recording of flow profiles and paving the way for future advances in soft matter physics and stimuli-responsive materials.

cond-mat.soft↗

arXiv2025

Controlling curvature of self-assembling surfaces via patchy particle design

Curved structures in soft matter and biological systems commonly emerge as a result of self-assembly processes where building blocks aggregate in a controlled manner, giving rise to specific system structure and properties. Learning how to precisely tune the curved geometry of these assemblies can in turn elucidate new ways of controlling their functionality. We discuss how one can target self-assembly into surfaces with specified Gaussian curvature in a one-component system of model patchy particles. Given the vast design space of potential patch distributions, we address the problem using an inverse design approach based on automatic differentiation and develop an optimization scheme which solves the exploding gradients problem that arises when we differentiate through long molecular dynamics trajectories. We discuss the model requirements for successful optimization, determine the significant hyperparameter choices influencing algorithm performance and, finally, we demonstrate that we can consistently design patch patterns for assembly into clusters with different target curvature radii.

cond-mat.soft↗

arXiv2024

Anisotropic DLVO-like interaction for charge patchiness in colloids and proteins

The behaviour and stability of soft and biological matter depend significantly on electrostatic interactions, as particles such as proteins and colloids acquire a charge when dispersed in an electrolytic solution. A typical simplification used to understand bulk phenomena involving electrostatic interactions is the isotropy of the charge on the particles. However, whether arising naturally or by synthesis, charge distributions are often inhomogeneous, leading to an intricate particle-particle interaction landscape and complex assembly phenomena. The fundamental complexity of these interactions gives rise to models based on distinct assumptions and varying degrees of simplifications which can blur the line between genuine physical behaviour and artefacts arising from the choice of a particular electrostatic model. Building upon the widely-used linearized Poisson-Boltzmann theory, we propose a theoretical framework that -- by bridging different models -- provides a robust DLVO-like description of electrostatic interactions between inhomogeneously charged particles. By matching solely the {\em single-particle} properties of two different mean-field models, we find a quantitative agreement between the {\em pair interaction energies} over a wide range of system parameters. Our work identifies a strategy to merge different models of inhomogeneously charged particles and paves the way to a reliable, accurate, and computationally affordable description of their interactions.

cond-mat.soft↗

arXiv2024

Many-defect solutions in planar nematics: interactions, spiral textures and boundary conditions

From incompressible flows to electrostatics, harmonic functions can provide solutions to many two-dimensional problems and, similarly, the director field of a planar nematic can be determined using complex analysis. We derive a closed-form solution for a quasi-steady state director field induced by an arbitrarily large set of point defects and circular inclusions with or without fixed rotational degrees of freedom, and compute the forces and torques acting on each defect or inclusion. We show that a complete solution must include two types of singularities, generating a defect winding number and its spiral texture, which have a direct effect on defect equilibrium textures and their dynamics. The solution accounts for discrete degeneracy of topologically distinct free energy minima which can be obtained by defect braiding. The derived formalism can be readily applied to equilibrium and slowly evolving nematic textures for active or passive fluids with multiple defects present within the orientational order.

cond-mat.soft↗

arXiv2023

From coffee stains to uniform deposits: significance of the contact-line mobility

Hypothesis: Contact-line motion upon drying of sessile droplet strongly affects the solute transport and solvent evaporation profile. Hence, it should have a strong impact on the deposit formation and might be responsible for volcano-like, dome-like and at deposit morphologies. Experiments: A method based on a thin-film interference was used to track the drop height profile and contact line motion during the drying. A diverse set of drying scenarios was obtained by using inks with different solvent compositions and by adjusting the substrate wetting properties. The experimental data was compared to the predictions of phenomenological model. Findings: We highlight the essential role of contact-line mobility on the deposit morphology of solution-based inks. A pinned contact line produces exclusively ring-like deposits under normal conditions. On the contrary, drops with a mobile contact line can produce ring-, at- or dome-like morphology. The developed phenomenological model shows that the deposit morphology depends on solvent evaporation profile, evolution of the drop radius relative to its contact angle, and the ratio between initial and maximal (gelling) solute concentration. These parameters can be adjusted by the ink solvent composition and substrate wetting behaviour, which provides a way for deposition of uniform and at deposits via inkjet printing.

physics.flu-dyn↗

arXiv2021

Measure of distance and overlap between two arbitrary ellipses on a sphere

Various packing problems and simulations of hard and soft interacting particles, such as microscopic models of nematic liquid crystals, reduce to calculations of intersections and pair interactions between ellipsoids. When constrained to a spherical surface, curvature and compactness lead to nontrivial behavior that finds uses in physics, computer science and geometry. A well-known idealized isotropic example is the Tammes problem of finding optimal non-intersecting packings of equal hard disks. The anisotropic case of elliptic particles remains, on the other hand, comparatively unexplored. We develop an algorithm to detect collisions between ellipses constrained to the two-dimensional surface of a sphere based on a solution of an eigenvalue problem. We investigate and discuss topologically distinct ways two ellipses may touch or intersect on a sphere, and define a contact function that can be used for construction of short- and long-range pair potentials.

cond-mat.soft↗

arXiv2021

Long-range order in quadrupolar systems on spherical surfaces

Understanding the interplay between topology and ordering in systems on curved manifolds, governed by anisotropic interactions, takes a central role in many fields of physics. In this paper, we investigate the effects of lattice symmetry and local positional order on orientational ordering in systems of long-range interacting point quadrupoles on a sphere in the zero temperature limit. Locally triangular spherical lattices show long-range ordered quadrupolar configurations only for specific symmetric lattices as strong geometric frustration prevents general global ordering. Conversely, the ground states on Caspar-Klug lattices are more diverse, with many different symmetries depending on the position of quadrupoles within the fundamental domain. We also show that by constraining the quadrupole tilts with respect to the surface normal, which models interactions with the substrate, and by considering general quadrupole tensors, we can manipulate the ground state configuration symmetry.

cond-mat.soft↗

arXiv2020

Gaps in the fractional parts of square roots

Fractional parts of the first $N$ natural numbers fill the unit interval with asymptotically uniform density. However, the gaps around rational points shrink at an asymptotically lower rate $N^{-1/2}$, and their widths scale with the Thomae ("popcorn") function. This curious connection is derived and related geometrically to shadow pattern in the Euclid's orchard. Generalized cases of higher radicals and their convergence rates, are also investigated.

math.NT↗

arXiv2020

Symmetry breaking of dipole orientations on Caspar-Klug lattices

Anisotropic dipole-dipole interaction often plays a key role in biological, soft, and complex matter. For it to induce non-trivial order in the system, there must be additional repulsive interactions or external potentials involved that partially or completely fix the positions of the dipoles. These positions can often be represented as an underlying lattice on which dipole interaction induces orientational ordering of the particles. On lattices in the Euclidean plane, dipoles have been found to assume different ground state configurations depending on the lattice type, with a global ordering in the form of a macrovortex being observed in many cases. A similar macrovortex configuration of dipoles has recently been shown to be the sole ground state for dipoles positioned on spherical lattices based on solutions of the Thomson problem. At the same time, no symmetric configurations have been observed, even though the positional order of Thomson lattices exhibits a high degree of symmetry. Here, we show that a different choice of spherical lattices based on Caspar-Klug construction leads to ground states of dipoles with various degrees of symmetry, including the icosahedral symmetry of the underlying lattice. We analyze the stability of the highly symmetric metastable states, their symmetry breaking into subsymmetries of the icosahedral symmetry group, and present a phase diagram of symmetries with respect to lattice parameters. The observed relationship between positional order and dipole-induced symmetry breaking hints at ways of fine-tuning the structure of spherical assemblies and their design.

cond-mat.soft↗

arXiv2020

Three-Dimensional Active Defect Loops

We describe the flows and morphological dynamics of topological defect lines and loops in three-dimensional active nematics and show, using theory and numerical modelling, that they are governed by the local profile of the orientational order surrounding the defects. Analysing a continuous span of defect loop profiles, ranging from radial and tangential twist to wedge $\pm 1/2$ profiles, we show that the distinct geometries can drive material flow perpendicular or along the local defect loop segment, whose variation around a closed loop can lead to net loop motion, elongation or compression of shape, or buckling of the loops. We demonstrate a correlation between local curvature and the local orientational profile of the defect loop, indicating dynamic coupling between geometry and topology. To address the general formation of defect loops in three dimensions, we show their creation via bend instability from different initial elastic distortions.

cond-mat.soft↗

arXiv2020

Microfluidic control over topological states in channel-confined nematic flows

Compared to isotropic liquids, orientational order of nematic liquid crystals makes their rheological properties more involved, and thus requires fine control of the flow parameters to govern the orientational patterns. In microfluidic channels with perpendicular surface alignment, nematics discontinuously transition from perpendicular structure at low flow rates to flow-aligned structure at high flow rates. Here we show how precise tuning of the driving pressure can be used to stabilize and manipulate a previously unresearched topologically protected chiral intermediate state which arises before the homeotropic to flow-aligned transition. We characterize the mechanisms underlying the transition and construct a phenomenological model to describe the critical behaviour and the phase diagram of the observed chiral flow state, and evaluate the effect of a forced symmetry breaking by introduction of a chiral dopant. Finally, we induce transitions on demand through channel geometry, application of laser tweezers, and careful control of the flow rate.

cond-mat.soft↗

arXiv2020

Sculpting stable structures in pure liquids

Pure liquids in thermodynamic equilibrium are structurally homogeneous. In liquid crystals, flow and light pulses are used to create reconfigurable domains with polar order. Moreover, through careful engineering of concerted microfluidic flows and localized opto-thermal fields, it is possible to achieve complete control over the nucleation, growth, and shape of such domains. Experiments, theory, and simulations indicate that the resulting structures can be stabilized indefinitely, provided the liquids are maintained in a controlled non-equilibrium state. The resulting sculpted liquids could find applications in microfluidic devices for selective encapsulation of solutes and particles into optically active compartments that interact with external stimuli.

cond-mat.soft↗

arXiv2019

Orientational ordering of point dipoles on a sphere

Arrangement of interacting particles on a sphere is historically a well known problem, however, ordering of particles with anisotropic interaction, such as the dipole-dipole interaction, has remained unexplored. We solve the orientational ordering of point dipoles on a sphere with fixed positional order with numerical minimization of interaction energy and analyze stable configurations depending on their symmetry and degree of ordering. We find that a macrovortex is a generic ground state, with various discrete rotational symmetries for different system sizes, while higher energy metastable states are similar, but less ordered. We observe orientational phase transitions and hysteresis in response to changing external field both for the fixed sphere orientation with respect the field, as well as for a freely-rotating sphere. For the case of a freely rotating sphere, we also observe changes of the symmetry axis with increasing field strength.

cond-mat.soft↗

arXiv2019

Topology of three-dimensional active nematic turbulence confined to droplets

Active nematics contain topological defects which under sufficient activity move, create and annihilate in a chaotic quasi-steady state, called active turbulence. However, understanding active defects under confinement is an open challenge, especially in three-dimensions. Here, we demonstrate the topology of three-dimensional active nematic turbulence under the spherical confinement, using numerical modelling. In such spherical droplets, we show the three-dimensional structure of the topological defects, which due to closed confinement emerge in the form of closed loops or surface-to-surface spanning line segments. In the turbulent regime, the defects are shown to be strongly spatially and time varying, with ongoing transformations between positive winding, negative winding and twisted profiles, and with defect loops of zero and non-zero topological charge. The timeline of the active turbulence is characterised by four types of bulk topology-linked events --- breakup, annihilation, coalescence and cross-over of the defects --- which we discuss could be used for the analysis of the active turbulence in different three-dimensional geometries. The turbulent regime is separated by a first order structural transition from a low activity regime of a steady-state vortex structure and an offset single point defect. We also demonstrate coupling of surface and bulk topological defect dynamics by changing from strong perpendicular to inplane surface alignment. More generally, this work is aimed to provide insight into three-dimensional active turbulence, distinctly from the perspective of the topology of the emergent three-dimensional topological defects.

cond-mat.soft↗

arXiv2019

Spherical structure factor and classification of hyperuniformity on the sphere

Understanding how particles are arranged on the sphere is not only central to numerous physical, biological, and materials systems but also finds applications in mathematics and in analysis of geophysical and meteorological measurements. In contrast to particle distributions in Euclidean space, restriction that the particles should lie on the sphere brings about several important constraints. These require a careful extension of quantities used for particle distributions in Euclidean space to those confined to the sphere. We introduce a framework designed to analyze and classify structural (dis)order in particle distributions constrained to the sphere. The classification is based on the concept of hyperuniformity, which was introduced 15 years ago and since then studied extensively in Euclidean space, yet has only very recently been considered for the sphere. We build our framework on a generalization of the structure factor on the sphere, which we relate to the power spectrum of the corresponding multipole expansion. The spherical structure factor is then shown to couple with cap number variance, a measure of local density fluctuations, allowing us to derive different forms of the variance. In this way, we construct a classification of hyperuniformity for scale-free particle distributions on the sphere and show how it can be extended to other distributions as well. We demonstrate that hyperuniformity on the sphere can be defined either through a vanishing spherical structure factor at low multipole numbers or through a scaling of the cap number variance, in both cases extending the Euclidean definition while pointing out crucial differences. Our work provides a comprehensive tool for detecting long-range order on spheres and the analysis of spherical computational meshes, biological and synthetic spherical assemblies, and ordering phase transitions in spherically-distributed particles.

cond-mat.soft↗

arXiv2016

Topological defects in cholesteric liquid crystal shells

We investigate experimentally and numerically the defect configurations emerging when a cholesteric liquid crystal is confined to a spherical shell. We uncover a rich scenario of defect configurations, some of them non-existent in nematic shells, where new types of defects are stabilized by the helical ordering of the liquid crystal. In contrast to nematic shells, here defects are not simple singular points or lines, but have a large structured core. Specifically, we observe five different types of cholesteric shells. We study the statistical distribution of the different types of shells as a function of the two relevant geometrical dimensionless parameters of the system. By playing with these parameters, we are able to induce transitions between different types of shells. These transitions involve interesting topological transformations in which the defects recombine to form new structures. Surprisingly, the defects do not approach each other by taking the shorter distance route (geodesic), but by following intricate paths.

cond-mat.soft↗

arXiv2014

The Geometry of the Cholesteric Phase

We propose a construction of a cholesteric pitch axis for an arbitrary nematic director field as an eigenvalue problem. Our definition leads to a Frenet-Serret description of an orthonormal triad determined by this axis, the director, and the mutually perpendicular direction. With this tool we are able to compare defect structures in cholesterics, biaxial nematics, and smectics. Though they all have similar ground state manifolds, the defect structures are different and cannot be, in general, translated from one phase to the other.

cond-mat.soft↗