arXiv subjects

Simon Čopar

Publications and source records attributed to Simon Čopar.

25 records · Page 2Linked to original sources

arXiv2013

Exploiting imperfections: Directed assembly of surface colloids via bulk topological defects

We exploit the long-ranged elastic fields inherent to confined nematic liquid crystals to assemble colloidal particles trapped at the liquid crystal interface into reconfigurable structures with complex symmetries and packings. Spherical colloids with homeotropic anchoring trapped at the interface between air and the nematic liquid crystal 5CB create quadrupolar distortions in the director field causing particles to repel and consequently form close-packed assemblies with a triangular habit. Here we report on complex, open structures organized via interactions with defects in the bulk. Specifically, by confining the nematic liquid crystal in an array of microposts with homeotropic anchoring conditions, we cause defect rings to form at well-defined locations in the bulk of the sample. These defects source elastic deformations that direct the assembly of the interfacially-trapped colloids into ring-like assemblies, which recapitulate the defect geometry even when the microposts are completely immersed in the nematic. When the surface density of the colloids is high, they form a ring near the defect and a hexagonal lattice far from it. Since topographically complex substrates are easily fabricated and liquid crystal defects are readily reconfigured, this work lays the foundation for a new, robust mechanism to dynamically direct assembly over large areas by controlling surface anchoring and associated bulk defect structure.

cond-mat.soft↗

arXiv2013

Ring around the colloid

In this work, we show that Janus washers, genus-one colloids with hybrid anchoring conditions, form topologically required defects in nematic liquid crystals. Experiments under crossed polarizers reveal the defect structure to be a rigid disclination loop confined within the colloid, with an accompanying defect in the liquid crystal. When confined to a homeotropic cell, the resulting colloid-defect ring pair tilts relative to the far field director, in contrast to the behavior of toroidal colloids with purely homeotropic anchoring. We show that this tilting behavior can be reversibly suppressed by the introduction of a spherical colloid into the center of the toroid, creating a new kind of multi-shape colloidal assemblage.

cond-mat.soft↗

arXiv2013

Singular Values, Nematic Disclinations, and Emergent Biaxiality

Both uniaxial and biaxial nematic liquid crystals are defined by orientational ordering of their building blocks. While uniaxial nematics only orient the long molecular axis, biaxial order implies local order along three axes. As the natural degree of biaxiality and the associated frame, that can be extracted from the tensorial description of the nematic order, vanishes in the uniaxial phase, we extend the nematic director to a full biaxial frame by making use of a singular value decomposition of the gradient of the director field instead. New defects and degrees of freedom are unveiled and the similarities and differences between the uniaxial and biaxial phase are analyzed by applying the algebraic rules of the quaternion group to the uniaxial phase.

cond-mat.soft↗

arXiv2012

Quaternions and hybrid nematic disclinations

Disclination lines in nematic liquid crystals can exist in different geometric conformations, characterised by their director profile. In certain confined, colloidal and even more prominently in chiral nematics, the director profile may vary along the disclination line. We construct a robust geometric decomposition of director profile variations in closed disclination loops based on a quaternion description and use it to apply topological classification to linked loops with arbitrary variation of the profile. The description bridges the gap between the known abstract classification scheme derived from homotopy theory and the observable local features of disclinations. We compare the resulting decomposition of disclination loop features to a similar decomposition of nematic textures on closed surfaces.

cond-mat.soft↗

arXiv2012

Topological and geometric decomposition of nematic textures

Directional media, such as nematic liquid crystals and ferromagnets, are characterized by their topologically stabilized defects in directional order. In nematics, boundary conditions and surface-treated inclusions often create complex structures, which are difficult to classify. Topological charge of point defects in nematics has ambiguously defined sign and its additivity cannot be ensured when defects are observed separately. We demonstrate how the topological charge of complex defect structures can be determined by identifying and counting parts of the texture that satisfy simple geometric rules. We introduce a parameter called the defect rank and show that it corresponds to what is intuitively perceived as a point charge based on the properties of the director field. Finally, we discuss the role of free energy constraints in validity of the classification with the defect rank.

cond-mat.soft↗

arXiv2011

Reconfigurable knots and links in chiral nematic colloids

Tying knots and linking microscopic loops of polymers, macromolecules, or defect lines in complex materials is a challenging task for material scientists. We demonstrate the knotting of microscopic topological defect lines in chiral nematic liquid crystal colloids into knots and links of arbitrary complexity by using laser tweezers as a micromanipulation tool. All knots and links with up to six crossings, including the Hopf link, the Star of David and the Borromean rings are demonstrated, stabilizing colloidal particles into an unusual soft matter. The knots in chiral nematic colloids are classified by the quantized self-linking number, a direct measure of the geometric, or Berry's, phase. Forming arbitrary microscopic knots and links in chiral nematic colloids is a demonstration of how relevant the topology can be for the material engineering of soft matter.

cond-mat.soft↗

arXiv2011

Nematic braids: topological invariants and rewiring of disclinations

The conventional topological description given by the fundamental group of nematic order parameter does not adequately explain the entangled defect line structures that have been observed in nematic colloids. We introduce a new topological invariant, the self-linking number, that enables a complete classification of entangled defect line structures in general nematics, even without particles, and demonstrate our formalism using colloidal dimers, for which entangled structures have been previously observed. We also unveil a simple rewiring scheme for the orthogonal crossing of two -1/2 disclinations, based on a tetrahedral rotation of two relevant disclination segments, that allows us to predict possible nematic braids and calculate their self-linking numbers.

cond-mat.soft↗