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Simona Onori

Publications and source records attributed to Simona Onori.

At least 19 recordsLinked to original sources

Cross-modal topology decodes battery faults from sparse voltage snapshots

Battery safety remains the primary bottleneck for mass electric vehicle (EV) adoption, yet field monitoring is hamstrung by a fundamental asymmetry: complex electrochemical faults must be diagnosed via sparse, low-frequency voltage measurements. Existing methods struggle to resolve the signal ambiguity between overlapping fault modes without hardware upgrades. Here, we demonstrate that these distinct fault fingerprints are not lost, but topologically folded within voltage snapshots. We introduce DeFault, a cross-modal diagnostic framework that mathematically unfolds one-dimensional voltage sequences into multi-dimensional phase-space topologies. DeFault employs a bidirectional cross-attention mechanism that acts as an autonomous, physics-aligned filter, explicitly decoding compounded fault modes that remain fundamentally invisible to sequence-based methods. Validated on a field dataset of 16.4 million data records from 99 in-service EVs, our method achieves an average accuracy of 0.96 and an F1 score of 0.84 for four fault types using only 500-second snapshots (spanning <100 mV). This work proves that high-fidelity, interpretable electrochemical diagnosis is achievable on legacy fleets without new sensors, providing a scalable solution for the battery safety crisis.

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Design of an embedded hardware platform for cell-level diagnostics in commercial battery modules

While battery aging is commonly studied at the cell-level, evaluating aging and performance within battery modules remains a critical challenge. Testing cells within fully assembled modules requires hardware solutions to access cell-level information without compromising module integrity. In this paper, we design and develop a hardware testing platform to monitor and control the internal cells of battery modules contained in the Audi e-tron battery pack. The testing is performed across all 36 modules of the pack. The platform integrates voltage sensors, balancing circuitry, and a micro-controller to enable safe, simultaneous cell screening without disassembling the modules. Using the proposed testing platform, cell voltage imbalances within each module are constrained to a defined reference value, and cell signals can be safely accessed, enabling accurate and non-invasive cell-level state-of-health assessments. On a broader scale, our solution allows for the quantification of internal heterogeneity within modules, providing valuable insights for both first- and second-life applications and supporting efficient battery pack maintenance and repurposing.

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Merging Physics-Based Synthetic Data and Machine Learning for Thermal Monitoring of Lithium-ion Batteries: The Role of Data Fidelity

Since the internal temperature is less accessible than surface temperature, there is an urgent need to develop accurate and real-time estimation algorithms for better thermal management and safety. This work presents a novel framework for resource-efficient and scalable development of accurate, robust, and adaptive internal temperature estimation algorithms by blending physics-based modeling with machine learning, in order to address the key challenges in data collection, model parameterization, and estimator design that traditionally hinder both approaches. In this framework, a physics-based model is leveraged to generate simulation data that includes different operating scenarios by sweeping the model parameters and input profiles. Such a cheap simulation dataset can be used to pre-train the machine learning algorithm to capture the underlying mapping relationship. To bridge the simulation-to-reality gap resulting from imperfect modeling, transfer learning with unsupervised domain adaptation is applied to fine-tune the pre-trained machine learning model, by using limited operational data (without internal temperature values) from target batteries. The proposed framework is validated under different operating conditions and across multiple cylindrical batteries with convective air cooling, achieving a root mean square error of 0.5 °C when relying solely on prior knowledge of battery thermal properties, and less than 0.1 °C when using thermal parameters close to the ground truth. Furthermore, the role of the simulation data quality in the proposed framework has been comprehensively investigated to identify promising ways of synthetic data generation to guarantee the performance of the machine learning model.

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Assessing Geographical and Seasonal Influences on Energy Efficiency of Electric Drayage Trucks

The electrification of heavy-duty vehicles is a critical pathway towards improved energy efficiency of the freight sector. The current battery electric truck technology poses several challenges to the operations of commercial vehicles, such as limited driving range, sensitivity to climate conditions, and long recharging times. Estimating the energy consumption of heavy-duty electric trucks is crucial to assess the feasibility of the fleet electrification and its impact on the electric grid. This paper focuses on developing a model-based simulation approach to predict and analyze the energy consumption of drayage trucks used in ports logistic operations, considering seasonal climate variations and geographical characteristics. The paper includes results for three major container ports within the United States, providing region-specific insights into driving range, payload capacity, and charging infrastructure requirements, which will inform decision-makers in integrating electric trucks into the existing drayage operations and plan investments for electric grid development.

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Analyzing cell-to-cell heterogeneities and cell configurations in parallel-connected battery modules using physics-based modeling

In parallel-connected cells, cell-to-cell (CtC) heterogeneities can lead to current and thermal gradients that may adversely impact the battery performance and aging. Sources of CtC heterogeneity include manufacturing process tolerances, poor module configurations, and inadequate thermal management. Understanding which CtC heterogeneity sources most significantly impact battery performance is crucial, as it can provide valuable insights. In this study, we use an experimentally validated electrochemical battery model to simulate hundreds of battery configurations, each consisting of four cells in parallel. We conduct a statistical analysis to evaluate the relative importance of key cell-level parameters, interconnection resistance, cell spacing, and location on performance and aging. The analysis reveals that heterogeneities in electrode active material volume fractions primarily impact module capacity, energy, and cell current, leading to substantial thermal gradients. However, to fully capture the output behavior, interconnection resistance, state of charge gradients and the effect of the temperature on parameter values must also be considered. Additionally, module design configurations, particularly cell location, exacerbate thermal gradients, accelerating long-term module degradation. This study also offers insights into optimizing cell arrangement during module design to reduce thermal gradients and enhance overall battery performance and longevity. Simulation results with four cells indicate a reduction of 51.8% in thermal gradients, leading to a 5.2% decrease in long-term energy loss.

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Fast data augmentation for battery degradation prediction

Degradation prediction for lithium-ion batteries using data-driven methods requires high-quality aging data. However, generating such data, whether in the laboratory or the field, is time- and resource-intensive. Here, we propose a method for the synthetic generation of capacity fade curves based on limited battery tests or operation data without the need for invasive battery characterization, aiming to augment the datasets used by data-driven models for degradation prediction. We validate our method by evaluating the performance of both shallow and deep learning models using diverse datasets from laboratory and field applications. These datasets encompass various chemistries and realistic conditions, including cell-to-cell variations, measurement noise, varying charge-discharge conditions, and capacity recovery. Our results show that it is possible to reduce cell-testing efforts by at least 50% by substituting synthetic data into an existing dataset. This paper highlights the effectiveness of our synthetic data augmentation method in supplementing existing methodologies in battery health prognostics while dramatically reducing the expenditure of time and resources on battery aging experiments.

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Onboard Health Estimation using Distribution of Relaxation Times for Lithium-ion Batteries

Real-life batteries tend to experience a range of operating conditions, and undergo degradation due to a combination of both calendar and cycling aging. Onboard health estimation models typically use cycling aging data only, and account for at most one operating condition e.g., temperature, which can limit the accuracy of the models for state-of-health (SOH) estimation. In this paper, we utilize electrochemical impedance spectroscopy (EIS) data from 5 calendar-aged and 17 cycling-aged cells to perform SOH estimation under various operating conditions. The EIS curves are deconvoluted using the distribution of relaxation times (DRT) technique to map them onto a function $\textbf{g}$ which consists of distinct timescales representing different resistances inside the cell. These DRT curves, $\textbf{g}$, are then used as inputs to a long short-term memory (LSTM)-based neural network model for SOH estimation. We validate the model performance by testing it on ten different test sets, and achieve an average RMSPE of 1.69% across these sets.

cs.LG

Finite-volume method and observability analysis for core-shell enhanced single particle model for lithium iron phosphate batteries

The increasing adoption of Lithium Iron Phosphate (LFP) batteries in Electric Vehicles is driven by their affordability, abundant material supply, and safety advantages. However, challenges arise in controlling/estimating unmeasurable LFP states such as state of charge (SOC), due to its flat open circuit voltage, hysteresis, and path dependence dynamics during intercalation and de-intercalation processes. The Core Shell Average Enhanced Single Particle Model (CSa-ESPM) effectively captures the electrochemical dynamics and phase transition behavior of LFP batteries by means of Partial Differential-Algebraic Equations (PDAEs). These governing PDAEs, including a moving boundary Ordinary Differential Equation (ODE), require a fine-grained spatial grid for accurate and stable solutions when employing the Finite Difference Method (FDM). This, in turn, leads to a computationally expensive system intractable for the design of real-time battery management system algorithms. In this study, we demonstrate that the Finite Volume Method (FVM) effectively discretizes the CSa-ESPM and provides accurate solutions with fewer than 4 control volumes while ensuring mass conservation across multi ple operational cycles. The resulting control-oriented reduced order FVM-based CSa-ESPM is experimentally validated using various C-rate load profiles and its observability is assessed through nonlinear observability analysis. Our results reveal that different current inputs and discrete equation numbers influence model observability, with non-observable regions identified where solid-phase concentration gradients are negligible.

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Comparing Mass-Preserving Numerical Methods for the Lithium-Ion Battery Single Particle Model

The single particle model (SPM) is a reduced electrochemical model that holds promise for applications in battery management systems due to its ability to accurately capture battery dynamics; however, the numerical discretization of the SPM requires careful consideration to ensure numerical stability and accuracy. In this paper, we present a comparative study of two mass-preserving numerical schemes for the SPM: the finite volume method and the control volume method. Using numerical simulations, we systematically evaluate the performance of these schemes, after independently calibrating the SPM discretized with each scheme to experimental data, and find a tradeoff between accuracy (quantified by voltage root-mean-square error) and computational time. Our findings provide insights into the selection of numerical schemes for the SPM, contributing to the advancement of battery modeling and simulation techniques.

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A Microgrid Deployment Framework to Support Drayage Electrification

The electrification of heavy-duty commercial vehicles (HDCVs) is pivotal in reducing greenhouse gas emissions and urban air pollution; however, this transition poses significant challenges for the existing electric grid, which is not designed to meet the high electricity demands of HDCVs. This can lead to a less effective reduction in freight transportation's carbon intensity despite significant electrification efforts. Deploying renewable energy sources, such as photovoltaics, alongside energy storage solutions, is essential to address these challenges. This paper examines the current grid limitations and explores the critical role of microgrid deployment, integrating solar and battery energy storage systems, in supporting the electrification of HDCVs. We propose an integrated framework that is designed to enhance regional grid capacity and decrease carbon intensity by identifying viable sites where a microgrid can be deployed and provide estimates for the deployment cost. Furthermore, using this framework, we quantify the maximal impact of microgrid deployment in reducing CO2 emissions when we optimize the use of the available power. As a demonstration, we apply our framework to the region of the Port of Savannah, GA USA.

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Domain knowledge-guided machine learning framework for state of health estimation in Lithium-ion batteries

Accurate estimation of battery state of health is crucial for effective electric vehicle battery management. Here, we propose five health indicators that can be extracted online from real-world electric vehicle operation and develop a machine learning-based method to estimate the battery state of health. The proposed indicators provide physical insights into the energy and power fade of the battery and enable accurate capacity estimation even with partially missing data. Moreover, they can be computed for portions of the charging profile and real-world driving discharging conditions, facilitating real-time battery degradation estimation. The indicators are computed using experimental data from five cells aged under electric vehicle conditions, and a linear regression model is used to estimate the state of health. The results show that models trained with power autocorrelation and energy-based features achieve capacity estimation with maximum absolute percentage error within 1.5% to 2.5% .

cs.LG

Towards a BMS2 Design Framework: Adaptive Data-driven State-of-health Estimation for Second-Life Batteries with BIBO Stability Guarantees

A key challenge that is currently hindering the widespread use of retired electric vehicle (EV) batteries for second-life (SL) applications is the ability to accurately estimate and monitor their state of health (SOH). Second-life battery systems can be sourced from different battery packs with lack of knowledge of their historical usage. To tackle the in-the-field use of SL batteries, this paper introduces an online adaptive health estimation approach with guaranteed bounded-input-bounded-output (BIBO) stability. This method relies exclusively on operational data that can be accessed in real time from SL batteries. The effectiveness of the proposed approach is shown on a laboratory aged experimental data set of retired EV batteries. The estimator gains are dynamically adapted to accommodate the distinct characteristics of each individual cell, making it a promising candidate for future SL battery management systems (BMS2).

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Taking Second-life Batteries from Exhausted to Empowered using Experiments, Data Analysis, and Health Estimation

The reuse of retired electric vehicle batteries in grid energy storage offers environmental and economic benefits. This study concentrates on health monitoring algorithms for retired batteries deployed in grid storage. Over 15 months of testing, we collect, analyze, and publicize a dataset of second-life batteries, implementing a cycling protocol simulating grid energy storage load profiles within a 3-4 V voltage window. Four machine-learning-based health estimation models, relying on online-accessible features and initial capacity, are compared, with the selected model achieving a mean absolute percentage error below 2.3% on test data. Additionally, an adaptive online health estimation algorithm is proposed by integrating a clustering-based method, thus limiting estimation errors during online deployment. These results showcase the feasibility of repurposing retired batteries for second-life applications. Based on obtained data and power demand, these second-life batteries exhibit potential for over a decade of grid energy storage use.

cs.LG

COBRAPRO: A MATLAB toolbox for Physics-based Battery Modeling and Co-simulation Parameter Optimization

COBRAPRO is a new open-source physics-based battery modeling software with the capability to conduct closed-loop parameter optimization using experimental data. Physics-based battery models require systematic parameter calibration to accurately predict battery behavior across different usage scenarios. While parameter calibration is essential to predict the dynamic behavior of batteries, many existing open-source DFN modeling tools lack integrated parameter identification routines. COBRAPRO addresses this gap by featuring an embedded parameter optimization framework that optimizes the model parameters by minimizing the error between the simulated and experimentally observed current-voltage data. With COBRAPRO, users can non-invasively identify unknown battery model parameters for any given battery chemistry.

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EV-EcoSim: A grid-aware co-simulation platform for the design and optimization of electric vehicle charging infrastructure

To enable the electrification of transportation systems, it is important to understand how technologies such as grid storage, solar photovoltaic systems, and control strategies can aid the deployment of electric vehicle charging at scale. In this work, we present EV-EcoSim, a co-simulation platform that couples electric vehicle charging, battery systems, solar photovoltaic systems, grid transformers, control strategies, and power distribution systems, to perform cost quantification and analyze the impacts of electric vehicle charging on the grid. This python-based platform can run a receding horizon control scheme for real-time operation and a one-shot control scheme for planning problems, with multi-timescale dynamics for different systems to simulate realistic scenarios. We demonstrate the utility of EV-EcoSim through a case study focused on economic evaluation of battery size to reduce electricity costs while considering impacts of fast charging on the power distribution grid. We present qualitative and quantitative evaluations on the battery size in tabulated results. The tabulated results delineate the trade-offs between candidate battery sizing solutions, providing comprehensive insights for decision-making under uncertainty. Additionally, we demonstrate the implications of the battery controller model fidelity on the system costs and show that the fidelity of the battery controller can completely change decisions made when planning an electric vehicle charging site.

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Combining physics-based and machine learning methods to accelerate innovation in sustainable transportation and beyond: a control perspective

Lithium-ion batteries are playing a key role in the sustainable energy transition. To fully exploit the potential of this technology, a variety of modeling, estimation, and prediction problems need to be addressed to enhance its design and optimize its utilization. Batteries are complex electrochemical systems whose behavior drastically changes as a function of aging, temperature, C-rate, and state of charge, posing unique modeling and control research questions. In this tutorial paper, we provide insights into three battery modeling methodologies, namely first principle, machine learning, and hybrid modeling. Each approach has its own strengths and weaknesses, and by means of three case studies we describe main characteristics and challenges of each of the three methods.

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Evaluating feasibility of batteries for second-life applications using machine learning

This paper presents a combination of machine learning techniques to enable prompt evaluation of retired electric vehicle batteries as to either retain those batteries for a second-life application and extend their operation beyond the original and first intent or send them to recycle facilities. The proposed algorithm generates features from available battery current and voltage measurements with simple statistics, selects and ranks the features using correlation analysis, and employs Gaussian Process Regression enhanced with bagging. This approach is validated over publicly available aging datasets of more than 200 cells with slow and fast charging, with different cathode chemistries, and for diverse operating conditions. Promising results are observed based on multiple training-test partitions, wherein the mean of Root Mean Squared Percent Error and Mean Percent Error performance errors are found to be less than 1.48% and 1.29%, respectively, in the worst-case scenarios.

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Extending life of Lithium-ion battery systems by embracing heterogeneities via an optimal control-based active balancing strategy

This paper formulates and solves a multi-objective fast charging-minimum degradation optimal control problem (OCP) for a lithium-ion battery module made of series-connected cells equipped with an active balancing circuitry. The cells in the module are subject to heterogeneity induced by manufacturing defects and non-uniform operating conditions. Each cell is expressed via a coupled nonlinear electrochemical, thermal, and aging model and the direct collocation approach is employed to transcribe the OCP into a nonlinear programming problem (NLP). The proposed OCP is formulated under two different schemes of charging operation: (i) same-charging-time (OCP-SCT) and (ii) different-charging-time (OCP-DCT). The former assumes simultaneous charging of all cells irrespective of their initial conditions, whereas the latter allows for different charging times of the cells to account for heterogeneous initial conditions. The problem is solved for a module with two series-connected cells with intrinsic heterogeneity among them in terms of state of charge and state of health. Results show that the OCP-DCT scheme provides more flexibility to deal with heterogeneity, boasting of lower temperature increase, charging current amplitudes, and degradation. Finally, comparison with the common practice of constant current (CC) charging over a long-term cycling operation shows that promising savings, in terms of retained capacity, are attainable under both the control (OCP-SCT and OCP-DCT) schemes.

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