arXiv subjects

Simona Onori

Publications and source records attributed to Simona Onori.

26 records · Page 2Linked to original sources

arXiv2022

Core-shell enhanced single particle model for lithium iron phosphate batteries: model formulation and analysis of numerical solutions

In this paper, a core-shell enhanced single particle model for iron-phosphate battery cells is formulated, implemented, and verified. Starting from the description of the positive and negative electrodes charge and mass transport dynamics, the positive electrode intercalation and deintercalation phenomena and associated phase transitions are described with the core-shell modeling paradigm. Assuming two phases are formed in the positive electrode, one rich and one poor in lithium, a core-shrinking problem is formulated and the phase transition is modeled through a shell phase that covers the core one. A careful discretization of the coupled partial differential equations is proposed and used to convert the model into a system of ordinary differential equations. To ensure robust and accurate numerical solutions of the governing equations, a sensitivity analysis of numerical solutions is performed and the best setting, in terms of solver tolerances, solid phase concentration discretization points, and input current sampling time, is determined in a newly developed probabilistic framework. Finally, unknown model parameters are identified at different C-rate scenarios and the model is verified against experimental data.

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arXiv2022

Effect of State of Charge Uncertainty on Battery Energy Storage Systems

Battery energy storage systems (BESSs) provide many benefits to the electricity grid, including stability, backup power, and flexibility in introducing more clean energy sources. As BESS penetration grows, knowledge of the uncertainty in the battery's state of charge (SOC) estimate is crucial for planning optimal BESS power injection trajectories. This paper proposes a framework for quantifying SOC estimation uncertainty based on battery rest periods. An uncertainty analysis is presented for a BESS participating in the frequency regulation market.

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arXiv2022

Core-shell enhanced single particle model for LiFePO$_4$ batteries

In this paper, a novel electrochemical model for LiFePO$_4$ battery cells that accounts for the positive particle lithium intercalation and deintercalation dynamics is proposed. Starting from the enhanced single particle model, mass transport and balance equations along with suitable boundary conditions are introduced to model the phase transformation phenomena during lithiation and delithiation in the positive electrode material. The lithium-poor and lithium-rich phases are modeled using the core-shell principle, where a core composition is encapsulated with a shell composition. The coupled partial differential equations describing the phase transformation are discretized using the finite difference method, from which a system of ordinary differential equations written in state-space representation is obtained. Finally, model parameter identification is performed using experimental data from a 49Ah LFP pouch cell.

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arXiv2022

Sensitivity analysis of a mean-value exergy-based internal combustion engine model

In this work, we conduct a sensitivity analysis of the mean-value internal combustion engine exergy-based model, recently developed by the authors, with respect to different driving cycles, ambient temperatures, and exhaust gas recirculation rates. Such an analysis allows to assess how driving conditions and environment affect the exergetic behavior of the engine, providing insights on the system's inefficiency. Specifically, the work is carried out for a military series hybrid electric vehicle.

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arXiv2021

Mean-value exergy modeling of internal combustion engines: characterization of feasible operating regions

In this paper, a novel mean-value exergy-based modeling framework for internal combustion engines is developed. The characterization of combustion irreversibilities, thermal exchange between the in-cylinder mixture and the cylinder wall, and non-stoichiometric combustion allows for a comprehensive description of the availability transfer and destruction phenomena in the engine. The model is applicable to internal combustion engines operating both in steady-state and over a sequence of operating points and can be used to characterize the whole engine operating region, allowing to create static maps describing the exergetic behavior of the engine as a function of speed and load. The application of the proposed modeling strategy is shown for a turbocharged diesel engine. Ultimately, the static maps, while providing insightful information about inefficiencies over the whole operating field of the engine, are the enabling step for the development of exergy-based control strategies aiming at minimizing the overall operational losses of ground vehicles.

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arXiv2021

Modeling Degradation for Second-life Battery: Preliminary Results

This paper presents a novel battery modeling framework based on the enhanced single particle model (ESPM) to account for degradation mechanisms of second-life batteries. While accounting for the transport and electrochemical phenomena in the battery solid and electrolyte phases, the dominant anode-related aging mechanisms, namely, solid electrolyte interphase (SEI) layer growth and lithium plating, are modeled. For the first time, the loss of active material (LAM), which describes the tendency of anode and cathode, over time, to reduce the electrode material available for intercalation and deintercalation, is introduced in the ESPM. Moreover, the coupling of the aging modes with the LAM dynamics provides a comprehensive framework that can be employed for the prediction of both linear and non-linear capacity fade crucial to assess second-life battery. Thus, relying on data borrowed from [18], a model parameter identification and a comprehensive sensitivity analysis are performed to prove the effectiveness of the modeling approach.

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arXiv2021

Exergy-based modeling framework for hybrid and electric ground vehicles

Exergy, or availability, is a thermodynamic concept representing the useful work that can be extracted from a system evolving from a given state to a reference state. It is also a system metric, formulated from the first and the second law of thermodynamics, encompassing the interactions between subsystems and the resulting entropy generation. In this paper, an exergy-based analysis for ground vehicles is proposed. The study, a first to the authors' knowledge, defines a comprehensive vehicle and powertrain-level modeling framework to quantify exergy transfer and destruction phenomena for the vehicle's longitudinal dynamics and its energy storage and conversion devices (namely, electrochemical energy storage, electric motor, and ICE). To show the capabilities of the proposed model in quantifying, locating, and ranking the sources of exergy losses, two case studies based on an electric vehicle and a parallel hybrid electric vehicle are analyzed considering a real-world driving cycle. This modeling framework can serve as a tool for the future development of ground vehicles management strategies aimed at minimizing exergy losses rather than fuel consumption.

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arXiv2021

On-line Capacity Estimation for Lithium-ion Battery Cells via an Electrochemical Model-based Adaptive Interconnected Observer

Battery aging is a natural process that contributes to capacity and power fade, resulting in a gradual performance degradation over time and usage. State of Charge (SOC) and State of Health (SOH) monitoring of an aging battery poses a challenging task to the Battery Management System (BMS) due to the lack of direct measurements. Estimation algorithms based on an electrochemical model that take into account the impact of aging on physical battery parameters can provide accurate information on lithium concentration and cell capacity over a battery's usable lifespan. A temperature-dependent electrochemical model, the Enhanced Single Particle Model (ESPM), forms the basis for the synthesis of an adaptive interconnected observer that exploits the relationship between capacity and power fade, due to the growth of Solid Electrolyte Interphase layer (SEI), to enable combined estimation of states (lithium concentration in both electrodes and cell capacity) and aging-sensitive transport parameters (anode diffusion coefficient and SEI layer ionic conductivity). The practical stability conditions for the adaptive observer are derived using Lyapunov's theory. Validation results against experimental data show a bounded capacity estimation error within 2% of its true value. Further, effectiveness of capacity estimation is tested for two cells at different stages of aging. Robustness of capacity estimates under measurement noise and sensor bias are studied.

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