arXiv subjects

Sophie Guéron

Publications and source records attributed to Sophie Guéron.

11 recordsLinked to original sources

arXiv2026

A metallic CrS$_2$ phase bridging the gap between two- and three-dimensional dichalcogenides

We report on the high-pressure synthesis of a CrS$_2$ phase in the form of single-crystalline nanorods. A structural refinement of Precession Electron Diffraction Tomography data confirms the nominal CrS$_2$ composition and unveils a ladder-type structure formed by portions of 1T-type CrS$_2$ layers characteristic of two-dimensional (2D) dichalcogenides connected by chains of edge-sharing CrS$_6$ octahedra characteristic of 3D dichalcogenides with marcasite structure. Ab initio density functional theory calculations of the relaxed structure confirm the stability of this structure and indicate a strong overlap of the 3d states of Cr with the 3p states of S, thus suggesting strong covalent Cr-S bonds and metallic behavior. Electrical resistivity, $\varrho$, measurements on single nanorods confirm this behavior and yield $\varrho \sim 2-20$ m$Ω$ cm at 4 K. The proposed ladder-like structure of CrS$_2$ forms open channels along the chain direction, which may be suitable for ionic conduction.

cond-mat.mtrl-sci↗

arXiv2026

Quantum transport reveals spin glass correlations in a 2D network of TbPc$_{2}$ single-molecule magnets grafted on graphene

The low temperature magnetoresistance of graphene functionalized by an array of magnetic Terbium Phthalocyanines molecules is found to exhibit a magnetic field-dependent 1/f noise, along with universal conductance fluctuations (UCFs) typical of a mesoscopic phase-coherent sample. A thorough analysis of the magnetic field, temperature and chemical potential dependence of this 1/f noise and UCFs reveals that long range, 2D Ising spin-glass like, magnetic correlations are induced in graphene through exchange interactions between the magnetic molecules and charge carriers in graphene. These experiments show that graphene functionalized with organic molecules constitutes a versatile platform for the investigation of magnetic phase transitions in two dimensions.

cond-mat.mes-hall↗

arXiv2022

Supercurrent Noise in a Phase-Biased Superconductor-Normal Ring in Thermal Equilibrium

In superconductor-normal-superconductor (SNS) junctions, dissipationless supercurrent is mediated via Andreev bound states (ABSs) controlled by the phase difference between the two superconductors. Theory has long predicted significant fluctuations, and thus a noise, of such supercurrent in equilibrium, due to the thermal excitation between the ABSs. Via the fluctuation-dissipation theorem (FDT), this leads paradoxically to a dissipative conductance even in the zero frequency limit. In this article, we directly measure the supercurrent noise in a phase-biased SNS ring inductively coupled to a superconducting resonator. Using the same setup, we also measure its admittance and quantitatively demonstrate the FDT for any phase. The dissipative conductance shows an 1/T temperature dependence, in contrast to the Drude conductance of unproximitized metal. This is true even at phase $π$ where the Andreev spectrum is gapless. Supported by linear response theory, we attribute this to the enhanced current correlation between the ABSs symmetrical across the Fermi level. Our results provide insight into the origin of noise in hydrid superconducting devices which may be useful for probing topologically protected ABSs.

cond-mat.mes-hall↗

arXiv2021

Novel transport phenomena in graphene induced by strong spin-orbit interaction

Graphene is known to have small intrinsic spin-orbit Interaction (SOI). In this review, we demonstrate that SOIs in graphene can be strongly enhanced by proximity effect when graphene is deposited on the top of transition metal dichalcogenides. We discuss the symmetry of the induced SOIs and differences between TMD underlayers in the capacity of inducing strong SOIs in graphene. The strong SOIs contribute to bring novel phenomena to graphene, exemplified by robust supercurrents sustained even under tesla-range magnetic fields.

cond-mat.mes-hall↗

arXiv2020

Phase-dependent dissipation and supercurrent of a graphene-superconductor ring under microwave irradiation

A junction with two superconductors coupled by a normal metal hosts Andreev bound states whose energy spectrum is phase-dependent and exhibits a minigap, resulting in a periodic supercurrent. Phase-dependent dissipation also appears at finite frequency due to relaxation of Andreev bound states. While dissipation and supercurrent versus phase have previously been measured near thermal equilibrium, their behavior in nonequilibrium is still elusive. By measuring the ac susceptibility of a graphene-superconductor junction under microwave irradiation, we find supercurrent response deviates from adiabatic ac Josephson effect as irradiation frequency is larger than relaxation rate. Notably, when irradiation frequency further increases above the minigap, the dissipation is enhanced at phase 0 where the minigap is largest and dissipation is minimum in equilibrium. We argue that this is evidence of the nonequilibrium distribution function which allows additional level transitions on the same side of the minigap. These results reveal that phase-dependent dissipation is more sensitive than supercurrent to microwave irradiation, and suggest a new method to investigate photon-assisted physics in proximitized superconducting system.

cond-mat.mes-hall↗

arXiv2019

Higher-Order Topology in Bismuth

The mathematical field of topology has become a framework to describe the low-energy electronic structure of crystalline solids. A typical feature of a bulk insulating three-dimensional topological crystal are conducting two-dimensional surface states. This constitutes the topological bulk-boundary correspondence. Here, we establish that the electronic structure of bismuth, an element consistently described as bulk topologically trivial, is in fact topological and follows a generalized bulk-boundary correspondence of higher-order: not the surfaces of the crystal, but its hinges host topologically protected conducting modes. These hinge modes are protected against localization by time-reversal symmetry locally, and globally by the three-fold rotational symmetry and inversion symmetry of the bismuth crystal. We support our claim theoretically and experimentally. Our theoretical analysis is based on symmetry arguments, topological indices, first-principle calculations, and the recently introduced framework of topological quantum chemistry. We provide supporting evidence from two complementary experimental techniques. With scanning-tunneling spectroscopy, we probe the unique signatures of the rotational symmetry of the one-dimensional states located at step edges of the crystal surface. With Josephson interferometry, we demonstrate their universal topological contribution to the electronic transport. Our work establishes bismuth as a higher-order topological insulator.

cond-mat.mtrl-sci↗

arXiv2018

Strong Spin-Orbit Interaction Induced in Graphene by Monolayer WS$_2$

We demonstrate strong anisotropic spin-orbit interaction (SOI) in graphene induced by monolayer WS$_2$. Direct comparison between graphene/monolayer WS$_2$ and graphene/bulk WS$_2$ system in magnetotransport measurements reveals that monolayer transition metal dichalcogenide (TMD) can induce much stronger SOI than bulk. Detailed theoretical analysis of the weak-antilocalization curves gives an estimated spin-orbit energy ($E_{\rm so}$) higher than 10 meV. The symmetry of the induced SOI is also discussed, and the dominant $z$ $\rightarrow$ $-z$ symmetric SOI can only explain the experimental results. Spin relaxation by the Elliot-Yafet (EY) mechanism and anomalous resistance increase with temperature close to the Dirac point indicates Kane-Mele (KM) SOI induced in graphene.

cond-mat.mes-hall↗

arXiv2018

Coherence-enhanced, phase-dependent dissipation in long SNS Josephson junctions: revealing Andreev Bound States dynamics

One of the best known causes of dissipation in ac driven quantum systems stems from photon absorption. Dissipation can also be caused by the retarded response to the time-dependent excitation, and in general gives insight into the system's relaxation times and mechanisms. We address the dissipation in a mesoscopic normal wire with superconducting contacts, that sustains a supercurrent at zero frequency and that may be expected to remain dissipationless at frequency lower than the superconducting gap. We probe the high frequency linear response of a Normal/Superconductor ring to a time-dependent flux by coupling it to a highly sensitive multimode microwave resonator. Far from being the simple derivative of the current-phase relation, the ring's ac susceptibility also displays a dissipative component whose phase dependence is a signature of the dynamical processes occurring within the Andreev spectrum. We show how dissipation is driven by the competition between the two aforementioned mechanisms. Depending on the relative strength of those contributions, dissipation can be maximal at $π$, when the minigap closes, or can be maximal near $ π/2$, when the dc supercurrent is maximal. We also find that the dissipative response increases at low temperature and can even exceed the normal state conductance. The results are confronted with predictions of the Kubo linear response and time-dependent Usadel equations. This experiment shows the power of the ac susceptibility measurement of individual hybrid mesoscopic systems in probing in a controlled way the quantum dynamics of ABS. By spanning different physical regimes, our experiments provide a unique access to inelastic scattering and spectroscopy of an isolated quantum coherent system. This technique should be a tool of choice to investigate topological superconductivity and detect the topological protection of edge states.

cond-mat.mes-hall↗

arXiv2016

Andreev spectrum with high spin-orbit interactions: revealing spin splitting and topologically protected crossings

We investigate numerically the Andreev spectrum of a multichannel mesoscopic quantum wire (N) with high spin-orbit interaction coupled to superconducting electrodes (S), contrasting topological and non topological behaviors. In the non topological case, modeled by a square lattice with Rashba interactions, we find that as soon as the normal quantum wires can host several conduction channels, the spin degeneracy of Andreev levels is lifted by a phase difference between the S reservoirs which breaks time reversal symmetry in zero Zeeman field. The Andreev states remain degenerate at phases multiple of $π$ for which time reversal symmetry is preserved, giving rise to level crossings which are not lifted by disorder. In contrast with the dc Josephson current, the finite frequency admittance (susceptibility) is very sensitive to these level crossings and the lifting of their degeneracy by a small Zeeman field. More interesting is the case of the hexagonal lattice with next nearest neighbor spin-orbit interactions which exhibit 1D topological helical edge states \cite{Kane2005}. The finite frequency admittance carries then a very specific signature at low temperature of a protected Andreev level crossing at $π$ and zero energy in the form of a sharp peak split by a Zeeman field.

cond-mat.mes-hall↗

arXiv2016

Ballistic edge states in Bismuth nanowires revealed by SQUID interferometry

Spin-orbit interactions are known to have drastic effects on the band structure of heavy-element-based materials. Celebrated examples are the recently identified 3D and 2D topological insulators. In those systems transport takes place at surfaces or along edges, and spin-momentum locking provides protection against (non-magnetic) impurity scattering, favoring spin-polarized ballistic transport. We have used the measurement of the current phase relation of a micrometer-long single crystal bismuth nanowire connected to superconducting electrodes, to demonstrate that transport occurs ballistically along two edges of this high-spin-orbit material. In addition, we show that a magnetic field can induce to 0-pi transitions and phi0-junction behavior, thanks to the extraordinarily high g-factor and spin orbit coupling in this system, providing a way to manipulate the phase of the supercurrent-carrying edge states.

cond-mat.mes-hall↗

arXiv2014

Strain superlattices and macroscale suspension of Graphene induced by corrugated substrates

We investigate the organized formation of strain, ripples and suspended features in macroscopic CVD-prepared graphene sheets transferred onto a corrugated substrate made of an ordered arrays of silica pillars of variable geometries. Depending on the aspect ratio and sharpness of the corrugated array, graphene can conformally coat the surface, partially collapse, or lay, fakir-like, fully suspended between pillars over tens of micrometers. Upon increase of pillar density, ripples in collapsed films display a transition from random oriented pleats emerging from pillars to ripples linking nearest neighboring pillars organized in domains of given orientation. Spatially-resolved Raman spectroscopy, atomic force microscopy and electronic microscopy reveal uniaxial strain domains in the transferred graphene, which are induced and controlled by the geometry. We propose a simple theoretical model to explain the transition between suspended and collapsed graphene. For the arrays with high aspect ratio pillars, graphene membranes stays suspended over macroscopic distances with minimal interaction with pillars tip apex. It offers a platform to tailor stress in graphene layers and open perspectives for electron transport and nanomechanical applications.

cond-mat.mes-hall↗