arXiv subjects

Stefanie N. Milam

Publications and source records attributed to Stefanie N. Milam.

At least 19 recordsLinked to original sources

arXiv2026

A JWST Study of Stardust. II. Polycyclic Aromatic Hydrocarbons in Comet 81P/Wild 2 and Implications for Primitive Solar System Carbon

We report observations of comet 81P/Wild 2, target of the Stardust sample return mission, on UT 2023 March 20 and 24 at a heliocentric distance ($r_H$) of 1.85 au using the NIRSpec and MIRI integral field unit spectrographs on board the James Webb Space Telescope (JWST). This study is the first compositional comparison between JWST remote-sensing spectroscopy of a solar system object against terrestrial analysis of its returned samples. Recent work determined contributions of molecular emission from coma volatiles and thermal emission from the nucleus and coma dust grains to these spectra. Subtracting the molecular and thermal emission models produces a residual spectrum with a clear resonance near 3.37 $μ$m and multiple others spanning the $6 - 12$ $μ$m region. Analysis of these residuals provides strong evidence for the presence of polycyclic aromatic hydrocarbons (PAHs) in the coma of 81P/Wild 2. The resulting PAH populations reflect material incorporated into the nucleus of 81P/Wild 2 that was inherited from the diffuse interstellar medium, the interstellar medium, and the protoplanetary disk. The PAHs sensed by JWST are compared to those detected in laboratory analyses of the Stardust mission returned samples.

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arXiv2026

JWST Reveals Refractory-Rich Water Ice in Interstellar Comet 3I/ATLAS: Evidence for a Continuum of Grain Properties across Protoplanetary Disks

We present JWST/NIRSpec PRISM observations of the interstellar comet 3I/ATLAS obtained on 2025 August 6 (Epoch 1), 2025 December 22 (Epoch 2), and 2026 April 1 (Epoch 3), spanning eight months around perihelion at heliocentric distances of 3.3, 2.4, and 5.7 au, respectively. The spectra reveal a broad 3 $μ$m absorption band together with H$_2$O, CO$_2$, and CO gas emission. Unlike previously reported water-ice-rich Solar System comae, the strong 3 $μ$m absorption is accompanied by weak or absent 1.5 and 2.0 $μ$m water-ice bands. Spectral modeling indicates that the observations are best reproduced by submicron- to micron-sized water-ice-bearing aggregates containing refractory material. Compared with Epoch 1, the Epoch 3 spectrum favors the presence of a second population of larger, micron-sized, ice-rich aggregates and exhibits a subtle Fresnel-like structure near 3.1 $μ$m, consistent with crystalline water ice. The observations can be explained by either crystalline water ice at both epochs, with the spectral evolution arising primarily from changes in grain size and refractory mixing, or an evolution from an amorphous-like to crystalline state. The spectral properties of 3I bridge those of water-ice-bearing Solar System comae and several spectral classes of mid-sized trans-Neptunian objects, suggesting that the icy building blocks of planetesimals formed in different protoplanetary disks may span a continuum in the physical state of water ice, ranging from pure ice grains to water-ice-bearing aggregates with varying refractory content at submicron-to-micron scales, with 3I extending toward the refractory-rich end of this continuum.

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arXiv2026

JWST Spatial-Spectral Mapping of Green Comet C/2022 E3 (ZTF)

We report a survey of molecular emission from cometary volatiles using the James Webb Space Telescope (JWST) toward Oort cloud comet C/2022 E3 (ZTF) carried out on UT 2023 February 28 and March 1 at a heliocentric distance (rH) of 1.33 au. These measurements of H2O, HCN, CH3OH, C2H6, CH4, CO, CO2, 13CO2, and OCS sampled post-perihelion molecular chemistry in C/2022 E3. A suite of near to mid-infrared OH (prompt emission) transitions were also detected. This work presents nucleus-centered spectra for all detected species, spatial-spectral maps of column density and rotational temperature as a function of distance from the nucleus for all except C2H6, HCN, and OH, and maps of co-measured continuum. The spatial distributions of both quantities were anisotropic for all mapped molecules; however, H2O showed distributions distinct from the remaining species. Coma-averaged values of the ortho-to-para ratio (OPR) for H2O and the 12CO2/13CO2 ratio derived from these maps were consistent with the statistical equilibrium value of 3 and the terrestrial value of 89, respectively. The modeled mass fraction of the sub-micron dust grains is dominated by amorphous carbon (56%) followed by amorphous Mg:Fe pyroxene (28%), crystalline olivine (10%), and amorphous Mg:Fe olivine (5%) with a crystalline mass fraction of 0.2385(0.0008). We compare the volatile and dust composition of C/2022 E3 (ZTF) against comets measured to date, including those surveyed by JWST.

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arXiv2026

A JWST Study of Stardust. I. Infrared Spectroscopy of Comet 81P/Wild 2 and Overall Composition

We report observations of comet 81P/Wild 2, target of the Stardust sample return mission, on UT 2023 March 20 and 24 at a heliocentric distance ($r_H$) of 1.85 au using the NIRSpec and MIRI integral field unit spectrographs on board the James Webb Space Telescope (JWST). This study is the first compositional comparison between JWST remote-sensing spectroscopy of a solar system object against terrestrial analysis of its returned samples. We securely detected molecular emission from H$_2$O, CH$_4$, C$_2$H$_6$, CH$_3$OH, CO, CO$_2$, $^{13}$CO$_2$, OCS, HCN, and CN and find molecular abundances consistent within $2σ$ with those reported during previous perihelion passages. The water ortho-to-para ratio was $2.76\pm0.05$, and the $^{12}$CO$_2$/$^{13}$CO$_2$ ratio was $85\pm4$. Thermal emission from the nucleus and dust was detected and modeled, providing an effective nucleus radius of $1.77\pm0.04$ km and a dust composition (relative mass fraction of the submicron grains) of $\sim36\%$ amorphous carbon, $\sim25\%$ amorphous Mg:Fe olivine, $\sim23\%$ Mg-rich crystalline olivine, and $\sim15\%$ amorphous Mg:Fe pyroxene. The crystalline mass fraction of the sub-micron grains in the coma was $0.362\pm0.003$. Comparison of the JWST-derived thermal model against the fine-grained materials in Stardust returned samples demonstrates complementarity between the missions, with each most sensitive to a different population of the coma dust grains.

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arXiv2026

PEARLS: NuSTAR and XMM-Newton Extragalactic Survey of the JWST North Ecliptic Pole Time Domain Field VI: Multiwavelength SED Analysis

We model spectral energy distributions of 261 X-ray sources to $z \sim 5$ in the North Ecliptic Pole Time Domain Field, extending prior XMM-Newton and NuSTAR analyses. Using the star-forming main sequence (SFMS) and black hole accretion rate (BHAR) frameworks, we find that SFRs generally lie below the SFMS while most BHARs exceed the population average, as expected for X-ray-selected samples. There is a strong correlation ($ρ=+0.73$) between SFR relative to the SFMS and specific AGN luminosity, $L_{AGN}/M_*$; galaxies with the highest $L_{AGN}/M_*$ exist at or above the SFMS. X-ray luminosity correlates with SFR ($ρ=+0.80$), revealing a star-forming and X-ray luminous "cold quasar" population consistent with dramatic, short-timescale accretion episodes. Low-mass galaxies show BHARs well above the population averaged value for their mass whereas high-mass galaxies' SMBHs accrete at the population averaged BHAR, suggesting "growth spurt" and "maintenance-mode" accretion, respectively. Traditional AGN classifications (obscured, unobscured, or radio-loud) do not reveal these distinctions, demonstrating the X-ray perspective's unique ability to identify rare AGN phases that are critical for the instantaneous link between galaxies and their SMBHs.

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arXiv2026

Coma Physics of an Interstellar Object: JWST Spatial-Spectral Mapping of 3I/ATLAS

We report a survey of molecular emission from cometary volatiles using the James Webb Space Telescope (JWST) toward interstellar object 3I/ATLAS carried out on UT 2025 December 22 and 23 at a heliocentric distance ($r_H$) of $2.37-2.41$ au. These measurements of CO, CO$_2$, H$_2$O, CH$_3$OH, and CH$_4$ sampled molecular chemistry in 3I/ATLAS as it receded from its encounter with our Sun and entered the vicinity of the H$_2$O ice line -- the region between $r_H$ = $2-3$ au where the temperature becomes too low for H$_2$O to vigorously sublime and CO and CO$_2$ begin to control the overall activity. CO was the most abundant molecule, followed by H$_2$O and CO$_2$, whose molecular abundances with respect to CO were $(40.5\pm3.1)\%$ and ($41.6\pm0.3)\%$, respectively. This work presents spatial-spectral maps of column density and rotational temperature as a function of distance from the nucleus for all detected species. The spatial distributions of both quantities were highly anisotropic for the apolar species in the coma of 3I/ATLAS, yet were more nearly symmetric for the polar molecules. These results demonstrate how volatiles were segregated in the nucleus ices of 3I/ATLAS and reveal heating and cooling mechanisms in its coma. Derived maps of the ortho-to-para ratio (OPR) for H$_2$O were flat with increasing distance from the nucleus and consistent with a coma-averaged value $\mathrm{OPR}=2.7\pm0.2$, slightly less than the expected equilibrium value of three.

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arXiv2026

JWST Observations of Asteroid 2024 YR4 Rule Out a 2032 Lunar Impact and Demonstrate a New Regime for Planetary Defense Follow-up

At the end of its discovery apparition, the $\sim$60 m near-Earth object 2024 YR4 was associated with a non-zero probability of lunar impact during its 2032 December 22 close approach. While posing no threat to Earth, a lunar impact of this scale could have consequences for Earth-orbiting infrastructure, as well as for human exploration on and around the Moon. We present new JWST/NIRCam observations from 2026 February 18 and 26 that extend the observational arc by eight months, reduce the uncertainty in the 2032 lunar encounter by a factor $>$30, and constitute the faintest detection of a near-Earth object to date, reaching $V \sim 30.5$ -- beyond the $V \sim 27$ ground-based limit. The updated orbit solution yields a predicted miss distance of $22{\,}900 \pm 800$ km (1$σ$) from the center of the Moon, thus ruling out a lunar impact. Despite challenges due to the limited number of reference stars and saturation and trailing effects, we derive astrometric positions with three independent analysis methods, demonstrating consistency at the $\lesssim$50 mas level. These observations extend the orbital arc at epochs when the object is not accessible from the ground, advancing the timeline for hazard assessment by two years relative to the next feasible ground-based recovery. This capability is critical in an emerging regime of planetary defense characterized by the discovery of decameter-scale objects by next-generation surveys. These objects are far more common but rapidly become inaccessible to ground-based follow-up. In this regime, hazard assessment can become follow-up-limited, requiring targeted space-based observations, such as those demonstrated here, to reliably constrain impact probabilities on operationally relevant timescales.

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arXiv2026

PEARLS: Two Distinct Populations of AGN Hosts Moving Between Star Formation and Quiescence

We present the results of AGN--host-galaxy decomposition using JWST/NIRCam, HST/ACS, and HST/WFC3 imaging of the North Ecliptic Pole Time Domain Field (NEP-TDF). The light-profiles of 36 NIRCam-selected AGN candidates are modeled for measurement of their point sources, and point source-subtracted host-galaxy emission is used in SED modeling for star formation rate (SFR) estimation. Offsets from the canonical star-forming main sequence (SFMS) show that the host galaxies form two distinct groups distinguished by their star formation: a ``bridge'' between the moderate SFRs of radio sources and low SFRs of X-ray sources, and a cleanly-separated ``branch'' above $Δ\rm SFMS = -1$ whose SFR trends positively with AGN fraction. Branch galaxies include late-type galaxies with X-ray and radio detections and more dominant point sources that are most certainly AGN, while bridge galaxies have predominantly early-type morphologies with weaker point sources that may be due to compact stellar bulges. Both groups show evidence of recent transition between star formation and quiescence, but neither group shows preference for higher or lower stellar mass or redshift, suggesting that star formation in NIRCam-selected AGN-hosts is more strongly determined by AGN activity than by stellar mass.

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arXiv2026

Water D/H in 3I/ATLAS as a Probe of Formation Conditions in Another Planetary System

Water reservoirs in the Solar System exhibit a deuterium enrichment that links back to the physical environment at the time of stellar birth. Gas-phase and ice-grain deuterium enrichments occur through chemical processes that operate at low temperatures ($<$~30~K) pointing towards an origin in the prestellar molecular cloud or in the outer parts of the protoplanetary disk. However, not all stars are born in environments similar to our Sun, nor do their subsequent evolutionary histories follow the same path. These environmental differences can be traced by the water deuterium-to-hydrogen (D/H) ratio. Here we use ALMA observations of the interstellar comet 3I/ATLAS to constrain the water D/H ratio in extrasolar cometary material. With a water D/H value of [D/H]$_{\mathrm{H_2O}} > 6.6\times10^{-3}$, 3I/ATLAS shows a deuterium enrichment exceeding Earth's ocean value by more than a factor of $\gtrsim40$ and typical Solar System cometary values by more than a factor of $\gtrsim30$. The elevated deuterium enrichment points to water that formed under colder, less irradiated conditions and from less thermally processed material, consistent with an origin in a planetary system that formed under different physical and chemical conditions than our own.

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arXiv2026

Monitoring Volatile Evolution in Disrupting Comet D/2021 A1 (Leonard) with NOEMA and APEX

We report a pre-perihelion survey of volatile emissions from comet D/2021 A1 (Leonard) with the Northern Extended Millimeter Array (NOEMA; UT 2021 Nov. 5, 21, and Dec. 1) and the Atacama Pathfinder Experiment (APEX; UT 2021 Dec. 9-10), spanning heliocentric distances ($r_H$) from 1.3 to 0.80 au. We securely detected HCN and CS and place 3$σ$ upper limits on CH$_3$OH, H$_2$CO, and CO abundances. Line kinematics and NOEMA spatial constraints indicate that HCN was released at or near the nucleus (parent scale length $<300$ km), while CS showed higher gas expansion velocities and mixing ratios that increased with decreasing $r_H$ $-$ consistent with production from a distributed source. Across our campaign, CS mixing ratios relative to H$_2$O increased by a factor of $\sim$5, from $0.02 \pm 0.01\%$ at $r_H$ = 1.3 au to $0.10\pm0.02\%$ by $r_H$ = 0.80 au. HCN mixing ratios in our data rose modestly, from $0.04 \pm 0.02\%$ at $r_H$ = 1.3 au to $0.07 \pm 0.02\%$ by $r_H$ = 0.81 au. However, contemporaneous measurements from other facilities placed HCN consistently at a higher absolute level ($\sim\!0.08\%$) with additional variability. Once cross-facility measurements were included, the HCN abundance showed no statistically robust monotonic dependence on $r_H$. Variability in both species during the mid-December outbursts and fragmentation suggests that D/2021 A1's volatile evolution reflected not only solar insolation but also disruption processes, underscoring the value of multi-epoch, multi-instrument monitoring to capture rapid, species-dependent changes.

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arXiv2026

The Evolution in Coma Molecular Composition of Comet C/2017 K2 (PanSTARRS) Across the H$_2$O Sublimation Zone: ALMA Imaging of an H$_2$O-Dominated Coma

We report a survey of molecular emission from cometary volatiles using the Atacama Large Millimeter/Submillimeter Array (ALMA) toward comet C/2017 K2 (PanSTARRS) carried out on UT 2022 September 21, 22, and 23 at a heliocentric distance ($r_H$) of 2.1 au. These measurements of HCN, CS, CO, CH$_3$OH, and H$_2$CO (along with continuum emission from dust) sampled molecular chemistry in C/2017 K2 at the inner edge of the H$_2$O sublimation zone, the region from $r_H$ = 2-3 au where H$_2$O begins vigorously subliming and increasingly dominating comet activity, discerning parent from daughter or extended source species. This work presents spectrally integrated flux maps, production rates, and parent scale lengths for each molecule. CH$_3$OH, CO, and HCN were produced within $\sim$250 km of the nucleus, potentially including contributions from sublimation of icy grains. CS was consistent with production from CS$_2$ photolysis, and H$_2$CO required production from extended sources in the coma. An ortho-to-para ratio OPR=$2.9\pm0.4$ for H$_2$CO was derived from simultaneously measured transitions of each spin species. The continuum was extended and spatially resolved, consistent with thermal emission from dust in the coma. Analysis of the continuum visibilities provided an upper limit on the nucleus diameter $d<6.6$ km and coma dust masses of $1.2-2.4\times10^{11}$ kg.

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arXiv2026

CH$_3$OH and HCN in Interstellar Comet 3I/ATLAS Mapped with the ALMA Atacama Compact Array: Distinct Outgassing Behaviors and a Remarkably High CH$_3$OH/HCN Production Rate Ratio

We report the detection of methanol (CH$_3$OH) toward interstellar comet 3I/ATLAS using the Atacama Compact Array of the Atacama Large Millimeter/Submillimeter Array (ALMA) on UT 2025 August 28, September 18 and 22, and October 1, and of hydrogen cyanide (HCN) on September 12 and 15. These observations spanned pre-perihelion heliocentric distances ($r_H$) of 2.6 -- 1.7 au. The molecules showed outgassing patterns distinct from one another, with HCN production being depleted in the sunward hemisphere of the coma, whereas CH$_3$OH was enhanced in that direction. Statistical analysis of molecular scale lengths in 3I/ATLAS indicated that CH$_3$OH included production from coma sources at $L_p>258$ km at 99% confidence. However low signal-to-noise on long baselines, which sample emission on small spatial scales closest to the nucleus, prevented definitively ruling out CH$_3$OH as purely a parent species. In contrast, HCN production was indistinguishable from direct nucleus sublimation. The CH$_3$OH production rate increased sharply from August through October, including an uptick near the inner edge of the H$_2$O sublimation zone at $r_H$ = 2 au. Compared to comets measured to date at radio wavelengths, the derived CH$_3$OH/HCN ratios in 3I/ATLAS of $124^{+30}_{-34}$ and $79^{+11}_{-14}$ on September 12 and 15, respectively, are among the most enriched values measured in any comet, surpassed only by anomalous solar system comet C/2016 R2 (PanSTARRS).

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arXiv2026

Coma Volatile Composition and Thermal Physics in Comet C/2022 E3 (ZTF) Measured Near Closest Approach to Earth with NASA-IRTF

The 2023 perihelion passage of comet C/2022 E3 (ZTF) afforded an opportunity to measure the abundances and spatial distributions of coma volatiles in an Oort cloud comet at high spatial resolution near its close approach to Earth ($Δ_\mathrm{min}\sim 0.28$ au on UT February 1). We conducted near-infrared spectroscopic observations of C/2022 E3 (ZTF) using iSHELL at the NASA Infrared Telescope Facility on UT 2023 February 9. Our measurements securely detected fluorescent emission from H$_2$O, CO, OCS, CH$_3$OH, CH$_4$, C$_2$H$_6$, C$_2$H$_2$, and HCN. For each instrumental setting we took exposures with the slit oriented parallel and also perpendicular to the projected Sun-comet vector, thereby enabling a test of the spatial distributions of these molecules. We report rotational temperatures, production rates, and abundance ratios (i.e., mixing ratios) for all sampled species. Our measurements found that molecular abundances in C/2022 E3 were depleted compared to their average values in Oort cloud comets with the exception of OCS, which was consistent. The H$_2$O production rate varied significantly and was likely tied to nucleus rotation effects. Measurements at the two slit orientations showed distinct column density and rotational temperature profiles for H$_2$O. Peak temperatures occurred off-nucleus and slower cooling was present in the anti-sunward hemisphere, consistent with the presence of icy grain sublimation in the coma.

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arXiv2026

JCMT detection of HCN emission from 3I/ATLAS at 2.1 AU

We report the detection of HCN ($J=3-2$) rotational emission from comet 3I/ATLAS at a heliocentric distance of 2.13 AU with the James Clerk Maxwell Telescope (JCMT). Observations were conducted from 07 August 2025 and 14 September 2025 (UT) using the $^{\prime}\overline U^{\prime}\overline u$ heterodyne receiver and ACSIS spectroscopic backend. The HCN line was detected at $>6σ$ on 14 Sep 2025 (UT) and a production rate of $Q({\rm HCN})=(4.0\pm1.7)\times10^{25}\ {\rm s}^{-1}$ was derived by non-LTE radiative transfer modelling. Preliminary estimates of the HCN/H$_2$O and CN/HCN abundance ratios suggest values similar to Solar System comets.

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arXiv2026

PEARLS: 21 Transients Found in the Three-Epoch NIRCam Observations in the Continuous Viewing Zone of the James Webb Space Telescope

We present 21 transients from our three-epoch, four-band NIRCam observations covering 14.16 arcmin^2 in the Spitzer IRAC Dark Field (IDF), taken by the JWST Prime Extragalactic Areas for Reionization and Lensing Science program with a time cadence of ~6 months. A separate Hubble Space Telescope program provided Advanced Camera for Surveys optical imaging contemporaneous with the second and third epochs of the NIRCam observations. The NIRSpec spectroscopy on three transients confirmed a Type Ia supernova at z=1.63 and the host galaxies of the other two at z=2.64 and 1.90, respectively. Combining these with the photometric redshifts (z_ph) of the host galaxies in the rest of the sample, we find that the transients are in either a "mid-z" group at z>1.6 with M_V < -16.0 mag or a "low-z" group at z < 0.4 with M_H > -14.0 mag. The mid-z transients are consistent with supernovae. In contrast, the low-z transients' luminosities fall in the range of the so-called "gap transients" between supernovae and novae. However, this latter conclusion is only tentative due to possible catastrophic failures in z_ph that could bias them to low-z. Conversely, if they are indeed at z < 0.4, it would be worth studying similar transients in the future. Our work further demonstrates the power of NIRCam in transient science and also shows that it would be more fruitful to carry out a long-term monitoring program with more passbands, a higher cadence and prompt follw-up spectroscopy. Being in the continuous viewing zone of the JWST, the IDF is an ideal field for this purpose.

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arXiv2025

JWST occultation reveals unforeseen complexity in Chariklo's ring system

Ring systems have been discovered around several small bodies in the outer Solar System through stellar occultations. While such measurements provide key information about ring geometry and dynamical interactions, little is known about their origins, lifetimes, evolutionary pathways, or compositions. Here we report near-infrared observations with the James Webb Space Telescope (JWST) of a stellar occultation by (10199) Chariklo, a Centaur known to host a double-ring system. Our JWST measurements show that Chariklo's inner dense ring has become significantly more opaque than in previous observations, pointing to ongoing replenishment processes or dynamical restructuring. In contrast, the outer ring exhibits a much weaker near-infrared occultation signature than seen in earlier visible-light detections. This discrepancy may reflect material loss, suggesting that the outer ring could be transient, or may arise from wavelength-dependent opacity. These scenarios, which are not mutually exclusive, point to an unprecedented level of complexity in small-body ring systems, distinct from those observed around any other minor bodies in the Solar System.

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arXiv2025

JWST/NIRSpec Observations of Salacia-Actaea and Máni: Exploring Population-level Trends among Water-ice-rich Kuiper Belt Objects

We present observations of the midsized Kuiper Belt objects (KBOs) Salacia$-$Actaea and Máni, obtained with the Near-Infrared Spectrograph on JWST. The satellite Actaea was fully blended with Salacia at the spatial resolution of the integral field unit, and we extracted the combined spectrum. The 0.7$-$5.1 $μ$m reflectance spectra of Salacia$-$Actaea and Máni display prominent water-ice absorption bands at 1.5, 2, 3, and 4$-$5 $μ$m. The $ν_{3}$ fundamental vibrational band of carbon dioxide ice at 4.25 $μ$m is present in both spectra. From a quantitative band-depth analysis of the entire current JWST spectroscopic sample of water-ice-rich KBOs, we find strong evidence for a positive covariance between relative water-ice abundance and size, which may indicate the emergent impacts of internal differentiation and cryovolcanic production of surface water ice on midsized KBOs. A detailed look at the distribution of 2 and 3 $μ$m band depths suggests additional sources of variability, such as different water-ice grain sizes. In addition, we report an apparent transition in the carbon dioxide band depth at object diameters of roughly 300$-$500 km, with larger objects showing systematically weaker absorptions, although selection effects within the sample do not allow us to confidently distinguish between a size-dependent phenomenon and a correlation with dynamical class.

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arXiv2025

JWST detection of a carbon dioxide dominated gas coma surrounding interstellar object 3I/ATLAS

3I/ATLAS is the third confirmed interstellar object to visit our Solar System, and only the second to display a clear coma. Infrared spectroscopy with the James Webb Space Telescope (JWST) provides the opportunity to measure its coma composition and determine the primary activity drivers. We report the first results from our JWST NIRSpec campaign for 3I/ATLAS, at an inbound heliocentric distance of $r_H=3.32$ au. The spectral images (spanning 0.6-5.3 $μ$m) reveal a CO2 dominated coma, with enhanced outgassing in the sunward direction, and the presence of H2O, CO, OCS, water ice and dust. The coma CO2/H2O mixing ratio of $7.6\pm0.3$ is among the highest ever observed in a comet, and is 4.5-sigma above the trend as a function of heliocentric distance for long-period and Jupiter-family comets (excluding the outlier C/2016 R2). Our observations are compatible with an intrinsically CO2-rich nucleus, which may indicate that 3I/ATLAS contains ices exposed to higher levels of radiation than Solar System comets, or that it formed close to the CO2 ice line in its parent protoplanetary disk. A low coma H2O gas abundance may also be implied, for example, due to inhibited heat penetration into the nucleus, which could suppress the H2O sublimation rate relative to CO2 and CO.

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