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Stephan Herminghaus

Publications and source records attributed to Stephan Herminghaus.

At least 37 records · Page 2Linked to original sources

Network representations of non-equilibrium steady states: Cycle decompositions, symmetries and dominant paths

Non-equilibrium steady states (NESS) of Markov processes give rise to non-trivial cyclic probability fluxes. Cycle decompositions of the steady state offer an effective description of such fluxes. Here, we present an iterative cycle decomposition exhibiting a natural dynamics on the space of cycles that satisfies detailed balance. Expectation values of observables can be expressed as cycle "averages", resembling the cycle representation of expectation values in dynamical systems. We illustrate our approach in terms of an analogy to a simple model of mass transit dynamics. Symmetries are reflected in our approach by a reduction of the minimal number of cycles needed in the decomposition. These features are demonstrated by discussing a variant of an asymmetric exclusion process (TASEP). Intriguingly, a continuous change of dominant flow paths in the network results in a change of the structure of cycles as well as in discontinuous jumps in cycle weights.

math-ph↗

Wetting on Random Roughness: the Ubiquity of Wenzel Prewetting

The wetting properties of solid substrates with macroscopic random roughness are considered as a function of the microscopic contact angle of the wetting liquid and its partial pressure in the surrounding gas phase. It is shown that Wenzel prewetting, which has been recently predicted for a rather wide class of roughness profiles derived from Gaussian random processes by a general distortion procedure, should in fact be ubiquitous and prevail under even much milder conditions. The well-known transition occurring at Wenzel's angle is accompanied by a prewetting transition, at which a jump in the adsorbed liquid volume occurs. This should be present on most surfaces bearing homogeneous, isotropic random roughness.

cond-mat.soft↗

Simple model squirmers with tunable velocity

We present a scheme of self-propelling liquid droplets which closely mimics the locomotion of some protozoal organisms, so-called squirmers. In contrast to other schemes proposed earlier, locomotion paths are not self-avoiding, since the effect of the squirmer on the surrounding medium is weak. Our results suggest that not only the velocity, but also the mode of operation (i.e., the spherical harmonics of the flow field) can be controlled by appropriate variation of parameters.

cond-mat.soft↗

Bilayer membranes in micro-fluidics: from gel emulsions to soft functional devices

We outline a concept of self-assembled soft matter devices based on micro-fluidics, which use surfactant bilayer membranes as their main building blocks, arrested in geometric structures provided by top-down lithography. Membranes form spontaneously when suitable water-in-oil emulsions are forced into micro-fluidic channels at high dispersed-phase volume fractions. They turn out to be remarkably stable even when pumped through the micro-fluidic channel system. Their geometric arrangement is self-assembling, driven by interfacial energy and wetting forces. The ordered membrane arrays thus emerging can be loaded with amphiphilic functional molecules, ion channels, or just be used as they are, exploiting their peculiar physical properties. For wet electronic circuitry, the aqueous droplets then serve as the 'solder points'. Furthermore, the membranes can serve as well-controlled coupling media between chemical processes taking place in adjacent droplets. This is shown for the well-known Belousov-Zhabotinski reaction. Suitable channel geometries can be used to (re-) arrange the droplets, and thereby their contents, in a controlled way by just moving the emulsion through the device. It thereby appears feasible to construct complex devices out of molecular-size components in a self-assembled, but well controlled manner.

cond-mat.soft↗

Dilute Wet Granulates: Nonequilibrium Dynamics and Structure Formation

We investigate a gas of wet granular particles, covered by a thin liquid film. The dynamic evolution is governed by two-particle interactions, which are mainly due to interfacial forces in contrast to dry granular gases. When two wet grains collide, a capillary bridge is formed and stays intact up to a certain distance of withdrawal when the bridge ruptures, dissipating a fixed amount of energy. A freely cooling system is shown to undergo a nonequillibrium dynamic phase transition from a state with mainly single particles and fast cooling to a state with growing aggregates, such that bridge rupture becomes a rare event and cooling is slow. In the early stage of cluster growth, aggregation is a self-similar process with a fractal dimension of the aggregates approximately equal to D_f ~ 2. At later times, a percolating cluster is observed which ultimately absorbs all the particles. The final cluster is compact on large length scales, but fractal with D_f ~ 2 on small length scales.

cond-mat.soft↗

Cooling and aggregation in wet granulates

Wet granular materials are characterized by a defined bond energy in their particle interaction such that breaking a bond implies an irreversible loss of a fixed amount of energy. Associated with the bond energy is a nonequilibrium transition, setting in as the granular temperature falls below the bond energy. The subsequent aggregation of particles into clusters is shown to be a self-similar growth process with a cluster size distribution that obeys scaling. In the early phase of aggregation the clusters are fractals with D_f=2, for later times we observe gelation. We use simple scaling arguments to derive the temperature decay in the early and late stages of cooling and verify our results with event-driven simulations.

cond-mat.soft↗

Stability and dewetting of thin liquid films

The stability of thin liquid coatings is of fundamental interest in every- day life. Homogeneous and non-volatile liquid coatings may dewet either by heterogeneous nucleation, thermal nucleation, or spinodal dewetting. Wetting and dewetting is explained on a fundamental level, including a discussion of relevant interactions. The article will also address the various dewetting scenarios and explain how the effective interface potential governs the behavior obtained for various stratified substrates and film thicknesses.

cond-mat.soft↗

Tackling master equations with a flux loop transform

A procedure is introduced which allows to represent the dynamics of a non-equilibrium system violating detailed balance by its steady state loop fluxes. It is shown that detailed balance is restored in this representation, such that the non-equilibrium steady state follows a simple Boltzmann distribution. A novel algorithm for the construction of the steady state densities naturally emerges, as well as an expression for a 'free energy' functional which attains a minimum in the steady state.

cond-mat.stat-mech↗

Fluidization of wet granular matter

We have studied the effect of small amounts of added liquid on the dynamic behavior of a granular system consisting of spherical glass beads. The critical acceleration $Γ$ for fluidization is found to increase strongly when liquid is added. It furthermore depends on the bead radius, the height of the sample, and the shaking frequency. As our main result, we find that these dependencies can be presented in a factorized form. We present a simple model which accounts for most of our findings.

cond-mat.stat-mech↗

The number of capillary bridges in a wet granular medium

We observed the appearance of capillary bridges in a granular medium consisting of glass beads after adding small amounts of liquid. We found the initial bridge formation depending on the bead roughness. Furthermore we obtained a statistics for the average number of bridges for randomly packed beads in dependence of the liquid content and were able to find an explanation therefore based on recent models and former experimental data.

cond-mat.stat-mech↗

Mixing and condensation in a wet granular medium

We have studied the effect of small amounts of added liquid on the dynamic behavior of a granular system consisting of a mixture of glass beads of two different sizes. Segregation of the large beads to the top of the sample is found to depend in a nontrivial way on the liquid content. A transition to viscoplastic behavior occurs at a critical liquid content, which depends upon the bead size. We show that this transition can be interpreted as a condensation due to the hysteretic liquid bridge forces connecting the beads, and provide the corresponding phase diagram.

cond-mat.stat-mech↗

Generic morphologies of viscoelastic dewetting fronts

A simple model is put forward which accounts for the occurrence of certain generic dewetting morphologies in thin liquid coatings. It demonstrates that by taking into account the elastic properties of the coating, a morphological phase diagram may be derived which describes the observed structures of dewetting fronts. It is demonstrated that dewetting morphologies may also serve to determine nanoscale rheological properties of liquids.

cond-mat.soft↗

Adsorption Isotherms of Hydrogen: The Role of Thermal Fluctuations

It is shown that experimentally obtained isotherms of adsorption on solid substrates may be completely reconciled with Lifshitz theory when thermal fluctuations are taken into account. This is achieved within the framework of a solid-on-solid model which is solved numerically. Analysis of the fluctuation contributions observed for hydrogen adsorption onto gold substrates allows to determine the surface tension of the free hydrogen film as a function of film thickness. It is found to decrease sharply for film thicknesses below seven atomic layers.

cond-mat.stat-mech↗

Nucleation Induced Undulative Instability in Thin Films of nCB Liquid Crystals

A surface instability is reported in thin nematic films of 5CB and 8CB, occurring near the nematic--isotropic phase transition. Although this instability leads to patterns reminiscent of spinodal dewetting, we show that it is actually based on a nucleation mechanism. Its characteristic wavelength does not depend markedly on film thickness, but strongly on the heating rate.

cond-mat.soft↗

Shape of a liquid front upon dewetting

We examine the profile of a liquid front of a film that is dewetting a solid substrate. Since volume is conserved, the material that once covered the substrate is accumulated in a rim close to the three phase contact line. Theoretically, such a profile of a Newtonian liquid resembles an exponentially decaying harmonic oscillation that relaxes into the prepared film thickness. For the first time, we were able to observe this behavior experimentally. A non-Newtonian liquid - a polymer melt - however, behaves differently. Here, viscoelastic properties come into play. We will demonstrate that by analyzing the shape of the rim profile. On a nm scale, we gain access to the rheology of a non-Newtonian liquid.

cond-mat.soft↗

A Universal Nucleation Mechanism for Solvent Cast Polymer Film Rupture

It is shown that the intrinsic stress in solvent cast polymer coatings plays a key role in the nucleation of holes in the film. Nucleation is important because it is meanwhile clear that heterogeneous nucleation is the only relevant rupture mechanism for the technologically relevant thickness regime well above 100 nm. The most striking feature is that in contrast to what has been widely believed, the number density of holes scales not algebraically, but exponentially with the film thickness.

cond-mat.soft↗

A Transient Instability in Thin Films of nCB Liquid Crystals

A transient surface instability is reported in thin nematic films of 5CB and 8CB, occurring near the nematic-isotropic phase transition. Although this instability leads to patterns reminiscent of spinodal dewetting, we show that it is actually based on a nucleation mechanism. Its characteristic wavelength does not depend markedly on film thickness, but strongly on the heating rate.

cond-mat.soft↗

The Glass Transition of Thin Polymer Films: Some Questions, and a Possible Answer

A simple and predictive model is put forward explaining the experimentally observed substantial shift of the glass transition temperature, Tg, of sufficiently thin polymer films. It focuses on the limit of small molecular weight, where geometrical `finite size' effects on the chain conformation can be ruled out. The model is based on the idea that the polymer freezes due to memory effects in the viscoelastic eigenmodes of the film, which are affected by the proximity of the boundaries. The elastic modulus of the polymer at the glass transition turns out to be the only fitting parameter. Quantitative agreement is obtained with our experimental results on short chain polystyrene (Mw = 2 kg/mol), as well as with earlier results obtained with larger molecules. Furthermore, the model naturally accounts for the weak dependence of the shift of Tg upon the molecular weight. It furthermore explains why supported films must be thinner than free standing ones to yield the same shift, and why the latter depends upon the chemical properties of the substrate. Generalizations for arbitrary experimental geometries are straightforward.

cond-mat.soft↗