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T. Venkatesan

Publications and source records attributed to T. Venkatesan.

At least 91 records · Page 5Linked to original sources

Observation of large anisotropy in c-axis oriented thin films of MgB$_{2}$ prepared by an in situ pulsed laser deposition process

A large anisotropy in the upper critical field (H$_{C2}$) is observed for MgB$_{2}$ films grown in situ by a pulsed laser deposition process involving growth and annealing of Mg and B multilayers. Measurements of resistivity as a function of temperature and magnetic field yield the estimated zero temperature values of H$_{C2}$ in the range 100 to 130 T and about 10 T, for the field in ab plane and along c axis, respectively, depending on the criterion chosen for the transition temperature. The corresponding anisotropy parameter is thus in the range 9 to 13. The estimated coherence length in ab plane is about 50 Å, whereas that in the c direction is much smaller (\approx 5 Å). No significant magnetoresistance is observed in the normal state.

cond-mat.supr-con↗

Superconducting MgB2 thin films by pulsed laser deposition

Growth of MgB2 thin films by pulsed laser deposition is examined under ex situ and in situ processing conditions. For the ex situ process, Boron films grown by PLD were annealed at 900 C with excess Mg. For the in situ process, different approaches involving ablation from a stoichiometric target under different growth conditions, as well as multilayer deposition involving interposed Mg layers were examined and analyzed. Magnetic measurements on ex situ processed films show TC of ~39 K, while the current best in situ films show a susceptibility transition at ~ 22 K.

cond-mat.supr-con↗

Optical Cooper Pair Breaking Spectroscopy of Cuprate Superconductors

The photon energy dependence of optical Cooper pair breaking rate (CPBR) is studied for compressibly strained La1.85Sr0.15CuO4 (LSCO) films and YBa2Cu2.92Zn0.08O7-delta (YBCZO) thin films, and compared to that in YBa2Cu3O7-delta (YBCO). Unlike in the case of YBCO, the CPBR for LSCO does not show obvious photon energy dependence. In YBCZO the CPBR shows strong photon energy dependence similar to YBCO, but with a red shift in the peak position. Analysis of these results strongly favours a physical picture based on electronic phase separation in high Tc superconductivity.

cond-mat.supr-con↗

Spin-Polarized Transport Across an La$_{0.7}$Sr$_{0.3}$MnO$_{3}$/YBa$_{2}$Cu$_{3}$O$_{7}$ Interface: Role of Andreev Bound States

Transport across an La$_{0.7}$Sr$_{0.3}MnO$_{3}/YBa$_{2}Cu$_{3}$O$_{7}$(LSMO/YBCO), interface is studied as a function of temperature and surface morphology. For comparison, control measurements are performed in non-magnetic heterostructures of LaNiO$_{3}$/YBCO and Ag/YBCO. In all cases, YBCO is used as bottom layer to eliminate the channel resistance and to minimize thermal effects. The observed differential conductance re ects the role of Andreev bound states in a-b planes, and brings out for the first time the suppression of such states by the spin-polarized transport across the interface. The theoretical analysis of the measured data reveals decay of the spin polarization near the LSMO surface with temperature, consistent with the reported photoemission data.

cond-mat.str-el↗

Sharp resonant multiplet in femto-second optical pair-breaking spectroscopy of YBa2Cu3O7-delta

Femto-second optical pair breaking spectroscopy is performed on optimally doped YBa2Cu3O7-delta near 1.5eV. Dramatic photon energy dependence with a sharp triplet fine structure is seen for the first time. The peak separations are attributable to the reported phonon and magnetic excitations in the system. The power dependence is non-linear with differing exponents for the three contributions. These results imply the presence of insulating antiferromagnetic domains in the superconducting state of YBCO over sub-picosecond time scale, and thereby favor an electronic phase separation picture.

cond-mat.supr-con↗

Strain driven charge-ordered state in La$_{0.67}$Ca$_{0.33}$MnO$_3$

We present evidence for the coexistence of ferromagnetic metallic and charge ordered insulating phases in strained thin films of La$_{0.67}$Ca$_{0.33}$MnO$_3$ at low temperatures. Such a phase separated state is confirmed using low temperature magnetic force microscopy and magnetotransport measurements. This phase separated state is not observed in the bulk form of this compound and is caused by the structural inhomogeneities due to the non-uniform distribution of strain in the film. The strain weakens the low temperature ferromagnetic metallic state and a charge ordered insulator is formed at the high strain regions. The slow dynamics of the transport properties of the mixed phase is illustrated by measurements of the long time scale relaxation of the electrical resistance.

cond-mat.str-el↗

Is there a vortex-glass transition in high-temperature superconductors?

We show that DC voltage versus current measurements of a YBCO micro-bridge in a magnetic field can be collapsed onto scaling functions proposed by Fisher, Fisher, and Huse, as is widely reported in the literature. We find, however, that good data collapse is achieved for a wide range of critical exponents and temperatures. These results strongly suggest that agreement with scaling alone does not prove the existence of a phase transition. We propose a criterion to determine if the data collapse is valid, and thus if a phase transition occurs. To our knowledge, none of the data reported in the literature meet our criterion.

cond-mat.supr-con↗

Evidence for small or intermediate-size polarons in the ferromagnetic state of manganites

Oxygen-isotope effects on the intrinsic resistivity have been studied in high-quality epitaxial thin films of La_{0.75}Ca_{0.25}MnO_{3} and Nd_{0.7}Sr_{0.3}MnO_{3}. We found that the residual resistivity ρ_{o} increases by about 15(3)% upon replacing ^{16}O by ^{18}O. This provides strong evidence for the presence of small or intermediate-size polarons in the metallic ferromagnetic state. Furthermore, the temperature dependent part of the resistivity at low temperatures consists of an AT^{4.5} term contributed from 2-magnon scattering, and a Bω_{s}/\sinh^{2}(\hbarω_{s}/2k_{B}T) term which arises from scattering by a soft optical phonon mode. The absolute magnitudes of the coefficient A and the phonon frequency \hbarω_{s} for both isotope samples are in quantitative agreement with theoretical predictions.

cond-mat.str-el↗

Evidence for the immobile bipolaron formation in the paramagnetic state of the magnetoresistive manganites

Recent research suggests that the charge carriers in the paramagnetic state of the magnetoresistive manganites are small polarons. Here we report studies of the oxygen-isotope effects on the intrinsic resistivity and thermoelectric power in several ferromagnetic manganites. The precise measurements of these isotope effects allow us to make a quantitative data analysis. Our results do not support a simple small-polaron model, but rather provide compelling evidence for the presence of small immobile bipolarons, i.e., pairs of small polarons. Since the bipolarons in the manganites are immobile, the present result alone appears not to give a positive support to the bipolaronic superconductivity theory for the copper-based perovskites.

cond-mat.str-el↗

Metallic and nonmetallic double perovskites: A case study of A$_2$FeReO$_6$ (A= Ca, Sr, Ba)

We have investigated the structure and electronic properties of ferrimagnetic double perovskites, A2FeReO6 (A= Ca, Sr, Ba). The A=Ba phase is cubic (Fm3m) and metallic, while the A=Ca phase is monoclinic (P21/n) and nonmetallic. 57Fe Mossbauer spectroscopy shows that iron is present mainly in the high-spin (S=5/2) Fe3+ state in the Ca compound, while it occurs in an intermediate state between high-spin Fe2+ and Fe3+ in the Ba compound. It is argued that a direct Re t2g - Re t2g interaction is the main cause for the metallic character of the Ba compound; the high covalency of Ca-O bonds and the monoclinic distortion (which lifts the degeneracy of t2g states) seem to disrupt the Re-Re interaction in the case of the Ca compound, making it non-metallic for the same electron count.

cond-mat.str-el↗

Colossal electroresistance and electronic phase separation in mixed-valent manganites

The sensitivity of transport in CMR manganite to external fields is examined using a PZT-based field effect configuration with a La0.7Ca0.3MnO3 channel subjected to electric and magnetic fields, separately and in conjugation. We not only find a colossal electroresistance (CER) of ~76% at 4X10^5 V/cm, but also a remarkable complimentarity of this CER with the widely studied CMR. Specifically, the ERmax (MRmax) of the system is largely independent of the magnetic (electric) field biasing, and for equal conductivity values, the ER (MR) is lower (higher) for T Tp. The size and systematics of the effect strongly favor a percolative phase separation picture.

cond-mat.str-el↗

Oxygen isotope effects in high-quality thin films of manganites: Quantitative constraints on the physics of manganites

Oxygen isotope effects on the transport properties have been studied in high-quality epitaxial thin films of La_{0.75}Ca_{0.25}MnO_{3} and Nd_{0.7}Sr_{0.3}MnO_{3}. In the paramagnetic state, the resistivity can be well fitted by ρ(T) = (A/\sqrt{T})\exp(E_ρ/k_{B}T) with the parameters A and E_{a} depending strongly on the oxygen isotope mass. The resistivity below 80 K almost perfectly follows ρ= ρ_{o}+ Bω_{s}/\sinh^{2}(\hbarω_{s}/2k_{B}T) with \hbarω_{s}/k_{B} \sim 100 K. Both ρ_{o} and B increase by about 15(3)% upon raplacing $^{16}$O by $^{18}$O. The results provide quantitative constraints on the basic physics of manganites.

cond-mat.str-el↗

Two-phase behavior in strained thin films of hole-doped manganites

We present a study of the effect of biaxial strain on the electrical and magnetic properties of thin films of manganites. We observe that manganite films grown under biaxial compressive strain exhibit island growth morphology which leads to a non-uniform distribution of the strain. Transport and magnetic properties of these films suggest the coexistence of two different phases, a metallic ferromagnet and an insulating antiferromagnet. We suggest that the high strain regions are insulating while the low strain regions are metallic. In such non-uniformly strained samples, we observe a large magnetoresistance and a field-induced insulator to metal transition.

cond-mat.str-el↗

Effects of annealing and strain on La_{1-x}Ca_{x}MnO_{3} thin films: a new phase diagram in the ferromagnetic region

Oriented, single phase thin films of La_{1-x}Ca_{x}MnO_{3} have been deposited onto (100)-oriented LaAlO_{3} (0.1<x<0.5) substrates using the Pulsed Laser Deposition technique. While for some compositions the physical properties (transport and magnetization) of the as-grown films are higher than the bulk values, for other calcium contents the optimized properties are obtained only after annealing under oxygen. These data can be partly explained by changes in oxygen content, resulting in cationic vacancies and thus self-doping effects - accompanying structural changes, may be the cause of properties beyond the phase diagram. We propose a new phase diagram for (La_{1-x}Ca_{x})_{1-y}\square_{y}MnO_{3} (0.1<x<0.5) thin films.

cond-mat.mtrl-sci↗

The effect of substrate induced strain on the charge-ordering transition in Nd_{0.5}Sr_{0.5}MnO_{3} thin films

We report the synthesis and characterization of Nd_{0.5}Sr_{0.5}MnO_{3} thin films grown by the Pulsed Laser Deposition technique on 100 -oriented LaAlO_{3} substrates. X-ray diffraction (XRD) studies show that the films are 101 -oriented, with a strained and quasi-relaxed component, the latter increasing with film thickness. We observe that transport properties are strongly dependent on the thickness of the films. Variable temperature XRD down to 100 K suggests that this is caused by substrate induced strain on the films.

cond-mat.mtrl-sci↗

Low energy excitations in crystalline perovskite oxides: Evidence from noise experiments

In this paper we report measurements of 1/f noise in a crystalline metallic oxide with perovskite structure down to 4.2K. The results show existence of localized excitations with average activation energy $\approx$ 70-80 meV which produce peak in the noise at T $\approx$ 35-40K. In addition, it shows clear evidence of tunnelling type two-level-systems (as in glasses) which show up in noise measurements below 30K.

cond-mat.dis-nn↗

Kinetics of electric field induced oxygen ion migration in epitaxial metallic oxide films

In this paper we report the observation of curent induced change of resistance of thin metallic oxide films. The resistance changes at a very low current (current density $J \geq 10^{3}$ A/cm$^{2}$). We find that the time dependence associated with the processes (increase of resistance) show a streched exponential type dependence at lower temperature, which crosses over to a creep type behavior at $T \geq$ 350 K. The time scale associated shows a drastic drop in the magnitude at $T \approx$ 350 K, where a long range diffusion sets in increasing the conductivity noise. The phenomena is like a "glass-transition" in the random lattice of oxygen ions.

cond-mat.dis-nn↗

Optical Conductivity of Manganites: Crossover from Jahn-Teller Small Polaron to Coherent Transport in the Ferromagnetic State

We report on the optical properties of the hole-doped manganites Nd_{0.7}Sr _{0.3}MnO_{3}, La_{0.7}Ca_{0.3}MnO_{3}, and La_{0.7}Sr_{0.3}MnO_{3}. The low-energy optical conductivity in the paramagnetic-insulating state of these materials is characterized by a broad maximum near 1 eV. This feature shifts to lower energy and grows in optical oscillator strength as the temperature is lowered into the ferromagnetic state. It remains identifiable well below Tc and transforms eventually into a Drude-like response. This optical behavior and the activated transport in the paramagnetic state of these materials are consistent with a Jahn-Teller small polaron. The optical spectra and oscillator strength changes compare well with models that include both double exchange and the dynamic Jahn-Teller effect in the description of the electronic structure.

cond-mat.str-el↗