arXiv subjects

T. Yokoya

Publications and source records attributed to T. Yokoya.

At least 19 recordsLinked to original sources

arXiv2019

Enhanced thermoelectricity by controlled local structure in bismuth-chalcogenides

Spectroscopic techniques, including photoelectron spectroscopy, diffuse reflectance, and x-ray absorption, are used to investigate the electronic structure and the local structure of LaOBiS$_{2-x}$Se$_x$ thermoelectric material. It is found that Se substitution effectively suppresses local distortion, that can be responsible for the increased carrier mobility together with a change in the electronic structure. The results suggest a possible way to control thermoelectric properties by tuning of the local crystal structure of these materials.

cond-mat.mtrl-sci↗

arXiv2018

Origins of thermal spin depolarization in half-metallic ferromagnet CrO$_2$

Using high-resolution spin-resolved photoemission spectroscopy, we observed a thermal spin depolarization to which all spin-polarized electrons contribute. Furthermore we observed a distinct minority spin state near the Fermi level and a corresponding depolarization that seldom contributes to demagnetization. The origin of this depolarization has been identified as the many-body effect characteristics of half-metallic ferromagnets. Our investigation opens an experimental field of itinerant ferromagnetic physics focusing on phenomena with sub-meV energy scale.

cond-mat.str-el↗

arXiv2018

Determination of the local structure of Sr$_{2-x}$M$_x$IrO$_4$ (M = K, La) as a function of doping and temperature

The local structure of correlated spin-orbit insulator Sr$_{2-x}$M$_x$IrO$_4$ (M = K, La) has been investigated by Ir L$_3$-edge extended x-ray absorption fine structure measurements. The measurements were performed as a function of temperature for different dopings induced by substitution of Sr with La or K. It is found that Ir-O bonds have strong covalency and they hardly show any change across the Néel temperature. In the studied doping range, neither Ir-O bonds nor their dynamics, measured by their mean square relative displacements, show any appreciable change upon carrier doping, indicating possibility of a nanoscale phase separation in the doped system. On the other hand, there is a large increase of the static disorder in Ir-Sr correlation, larger for K doping than La doping. Similarities and differences with respect to the local lattice displacements in cuprates are briefly discussed.

cond-mat.str-el↗

arXiv2018

Temperature-dependent local structure of superconducting BaPd$_2$As$_2$ and SrPd$_2$As$_2$

The local structures of 122-type paradium arsenides, namely BaPd$_2$As$_2$ and SrPd$_2$As$_2$, are examined by As K-edge extended x-ray absorption fine structure measurements to find a possible correlation between the variation of their superconducting transition temperature and the local structure. The local atomic distances are found to be consistent with average distances measured by diffraction techniques. The temperature dependence of mean square relative displacements reveal that, while BaPd$_2$As$_2$ is characterized by a local As-Pd soft mode, albeit with larger atomic disorder, SrPd$_2$As$_2$ shows anomalous As-Pd correlations with a kink at $\sim$160 K due to hardening by raising temperature. We have discussed implications of these results and possible mechanism of differing superconducting transition temperature in relation with the structural instability.

cond-mat.supr-con↗

arXiv2017

Direct observation of double valence-band extrema and anisotropic effective masses of the thermoelectric material SnSe

Synchrotron-based angle-resolved photoemission spectroscopy is used to determine the electronic structure of layered SnSe, which was recently turned out to be a potential thermoelectric material. We observe that the top of the valence band consists of two nearly independent hole bands, whose tops differ by ~20 meV in energy, indicating the necessity of a multivalley model to describe the thermoelectric properties. The estimated effective masses are anisotropic, with in-plane values of 0.16-0.39 m$_0$ and an out-of-plane value of 0.71 m$_0$, where m$_0$ is the rest electron mass. Information of the electronic structure is essential to further enhance the thermoelectric performance of hole-doped SnSe.

cond-mat.mtrl-sci↗

arXiv2017

Evolution of remnant Fermi surface state in lightly-doped correlated spin-orbit insulator Sr$_{2-x}$La$_x$IrO$_4$

Electronic structure has been studied in lightly electron doped correlated spin-orbit insulator Sr$_2$IrO$_4$ by angle-resolved photoelectron spectroscopy. We have observed coexistence of the lower Hubbard band and the in-gap band, the momentum dependence of the latter traces that of the band calculations without on-site Coulomb repulsion. The in-gap state remained anisotropically gapped in all observed momentum area, forming a remnant Fermi surface state, evolving towards the Fermi energy by carrier doping. These experimental results show a striking similarity with those observed in deeply underdoped cuprates, suggesting the common nature of the nodal liquid states observed in both compounds.

cond-mat.str-el↗

arXiv2014

Proximity to Fermi-surface topological change in superconducting LaO0.54F0.46BiS2

The electronic structure of nearly optimally-doped novel superconductor LaO$_{1-x}$F$_x$BiS$_2$ (${\it x}$ = 0.46) was investigated using angle-resolved photoemission spectroscopy (ARPES). We clearly observed band dispersions from 2 to 6 eV binding energy and near the Fermi level (${\it E}_{\rm F}$), which are well reproduced by first principles calculations when the spin-orbit coupling is taken into account. The ARPES intensity map near ${\it E}_{\rm F}$ shows a square-like distribution around the $Γ$(Z) point in addition to electronlike Fermi surface (FS) sheets around the X(R) point, indicating that FS of LaO$_{0.54}$F$_{0.46}$BiS$_2$ is in close proximity to the theoretically-predicted topological change.

cond-mat.supr-con↗

arXiv2014

Pressure-dependent magnetization and magnetoresistivity studies on the tetragonal FeS (mackinawite): revealing its intrinsic metallic character

The transport and magnetic properties of the tetragonal Fe$_{1+δ}$S were investigated using magnetoresistivity and magnetization within 2$\leq T\leq $300 K, $H\leq$70 kOe and $P\leq$ 3.0 GPa. In addition, room-temperature X-ray diffraction and photoelectron spectroscopy were also applied. In contrast to previously reported nonmetallic character, Fe$_{1+δ}$S is intrinsically metallic but due to a presence of a weak localization such metallic character is not exhibited below room temperature. An applied pressure reduces strongly this additional resistive contribution and as such enhances the temperature range of the metallic character which, for $\sim$3 GPa, is evident down to 75 K. The absence of superconductivity as well as the mechanism behind the weak localization will be discussed.

cond-mat.str-el↗

arXiv2010

Electronic structure of pristine and K-doped solid picene: Non-rigid-band change and its implication for electron-intramolecular-vibration interaction

We use photoemission spectroscopy to study electronic structures of pristine and K-doped solid picene. The valence band spectrum of pristine picene consists of three main features with no state at the Fermi level (EF), while that of K-doped picene has three structures similar to those of pristine picene with new states near EF, consistent with the semiconductor-metal transition. The K-induced change cannot be explained with a simple rigid-band model of pristine picene, but can be interpreted by molecular orbital calculations considering electron-intramolecular-vibration interaction. Excellent agreement of the K-doped spectrum with the calculations points to importance of electron-intramolecular-vibration interaction in K-doped picene.

cond-mat.mtrl-sci↗

arXiv2008

Relation between Superconducting Gap Minima and Nesting Vector in YNi2B2C

We have performed ultrahigh-resolution angle-resolved photoemission spectroscopy to directly observe the large superconducting (SC) gap anisotropy (GA) of YNi2B2C. The result shows large SC GA with a smooth variation along an intersection of a Fermi surface (FS) around the $Γ$-Z line and nearly isotropic SC gap values for two intersections of FSs around the X-P line but with a point-like non-zero minimum only for one sheet. The point-like SC gap minimum can be connected by the nesting vector reported from band calculations. The results show unexpectedly complicated SC GA of borocarbide superconductors.

cond-mat.supr-con↗

arXiv2008

Bulk electronic structure of the antiferromagnetic superconducting phase in ErNi2B2C

We have performed temperature (T) - dependent laser-photoemission spectroscopy of antiferromagnetic (AF) superconductor ErNi2B2C to study the electronic-structure evolution reflecting the interplay between antiferromagnetism and superconductivity. The spectra at the superconducting (SC) phase show a very broad spectral shape. T-dependent SC gap shows a sudden deviation from the BCS prediction just below TN. This observation can be well explained by the theoretical model and thus represents characteristic bulk electronic structure of the AF SC phase for the first time.

cond-mat.supr-con↗

arXiv2007

Hidden Charge-Density-Wave Order in a Low-Tc Superconductor 2H-NbSe2

The Charge-density-wave(CDW) in 2H-NbSe2(TCDW ~ 33 K), which coexists with superconductivity(Tc = 7.2 K), is investigated using Angle-resolved photoemission spectroscopy as a function of temperature. Across TCDW, energy and momentum(k) distribution curves show changes associated with the primary and secondary CDW vectors. The CDW is due to hidden charge order occurring at specific k-points on Fermi surfaces in the 2-dimensional Brillouin zone(2D BZ) with spectral weight suppression, but no gap formation. The study rules out nesting in the 2D BZ and the van Hove singularity driven CDW transition in 2H-NbSe2.

cond-mat.str-el↗

arXiv2006

Angle-resolved photoemission study of cobalt oxide superconductor NaxCoO2.yH2O : Observation of the Fermi surface

Cobalt oxide superconductor NaxCoO2.yH2O is studied by angle-resolved photoemission spectroscopy (ARPES). We report the Fermi surface (FS) topology and electronic structure near the Fermi level (EF) of NaxCoO2.yH2O. Our result indicates the presence of the hexagonal FS centered at G point, while the small pocket FSs along G-K direction are absent similar to NaxCoO2. The top of the eg' band, which is expected in band calculations to form the small pocket FSs, extends to within 20 - 50 meV below EF, more closer to EF than in NaxCoO2. We discuss its possible role in superconductivity, comparing with other experimental and theoretical results.

cond-mat.supr-con↗

arXiv2006

Observation of superconducting gap in boron-doped diamond by laser-excited photoemission spectroscopy

We have investigated the low energy electronic state of a boron-doped diamond thin film by the ultrahigh resolution laser-excited photoemission spectroscopy. We observed a clear shift of the leading edge below 11 K indicative of a superconducting gap opening ($Δ\sim 0.78$ meV at 4.5 K). The gap feature is significantly broad and the well-defined quasiparticle peak is not recognizable even at the lowest temperature of measurement 4.5 K. We discuss our result in terms of possible disorder effect on superconductivity in this system.

cond-mat.supr-con↗

arXiv2005

Bulk and surface-sensitive high-resolution photoemission study of Mott-Hubbard systems SrVO$_3$ and CaVO$_3$

We study the electronic structure of Mott-Hubbard systems SrVO$_{3}$ and CaVO$_3$ with bulk and surface-sensitive high-resolution photoemission spectroscopy (PES), using a VUV laser, synchrotron radiation and a discharge lamp ($hν$ = 7 - 21 eV). A systematic suppression of the density of states (DOS) within $\sim$ 0.2 eV of the Fermi level ($E_F$) is found on decreasing photon energy i.e. on increasing bulk sensitivity. The coherent band in SrVO$_{3}$ and CaVO$_3$ is shown to consist of surface and bulk derived features, separated in energy. The stronger distortion on surface of CaVO$_{3}$ compared to SrVO$_{3}$ leads to higher surface metallicity in the coherent DOS at $E_F$, consistent with recent theory.

cond-mat.str-el↗

arXiv2005

Temperature dependent Luttinger surfaces

The Luttinger surface of an organic metal (TTF-TCNQ), possessing charge order and spin-charge separation, is investigated using temperature dependent angle-resolved photoemission spectroscopy. The Luttinger surface topology, obtained from momentum distribution curves, changes from quasi-2D(dimensional) to quasi-1D with temperature. The high temperature quasi-2D surface exhibits 4$k_F$ charge-density-wave (CDW) superstructure in the TCNQ derived holon band, in the absence of 2$k_F$ order. Decreasing temperature results in quasi-1D nested 2$k_F$ CDW order in the TCNQ spinon band and in the TTF surface. The results establish the link in momentum-space between charge order and spin-charge separation in a Luttinger liquid.

cond-mat.str-el↗

arXiv2005

Role of CDW fluctuations on the spectral function in a metallic CDW system

Angle-resolved photoemission spectroscopy of ZrTe3 has been performed from room temperature(T) down to 6 K (across Tcdw = 63K) to study the charge-density-wave (CDW) fluctuation effects in a metallic CDW compound having Fermi surface (FS) sheets with differing dimensionality. While spectra on the 3-dimensional(D) FS show typical Fermi-Dirac function-like T-dependence, those along the quasi 1-D FS show formation of a pseudogap, starting at a much higher T than Tcdw. Simultaneously, a van-Hove singularity consisting of the quasi 1D FS intersecting the 3D FS shows increase of coherence. This demonstrates the role of CDW fluctuations on the spectral function, and relation to the dimensionality of the states, in a metallic CDW system.

cond-mat.mtrl-sci↗

arXiv2005

Evidence for suppressed metallicity on the surface of La2-xSrxCuO4 and Nd2-xCexCuO4

Hard X-ray Photoemission spectroscopy (PES) of copper core electronic states, with a probing depth of $\sim$60 Å, is used to show that the Zhang-Rice singlet feature is present in La$_2$CuO$_4$ but is absent in Nd$_2$CuO$_4$. Hole- and electron doping in La$_{2-x}$Sr$_x$CuO$_4$ (LSCO) and Nd$_{2-x}$Ce$_x$CuO$_4$ (NCCO) result in new well-screened features which are missing in soft X-ray PES. Impurity Anderson model calculations establish metallic screening as its origin, which is strongly suppressed within 15 $\textÅ$ of the surface. Complemented with X-ray absorption spectroscopy, the small chemical-potential shift in core levels ($\sim0.2$ eV) are shown to be consistent with modifications of valence and conduction band states spanning the band gap ($\sim1$ eV) upon hole- and electron-doping in LSCO and NCCO.

cond-mat.supr-con↗