arXiv subjects

Takeshi Egami

Publications and source records attributed to Takeshi Egami.

At least 37 records · Page 2Linked to original sources

arXiv2016

Correlation between Fragility and the Arrhenius Crossover Phenomenon in Metallic, Molecular, and Network Liquids

We report the observation of a distinct correlation between the kinetic fragility index $m$ and the reduced Arrhenius crossover temperature $θ_A = T_A/T_g$ in various glass-forming liquids, identifying three distinguishable groups. In particular, for 11 glass-forming metallic liquids, we universally observe a crossover in the mean diffusion coefficient from high-temperature Arrhenius to low-temperature super-Arrhenius behavior at approximately $θ_A \approx 2$ which is in the stable liquid phases. In contrast, for fragile molecular liquids, this crossover occurs at much lower $θ_A \approx 1.4$ and usually in their supercooled states. The $θ_A$ values for strong network liquids spans a wide range higher than 2. Intriguingly, the high-temperature activation barrier $E_\infty$ is universally found to be $\sim 11\ k_B T_g$ and uncorrelated with the fragility or the reduced crossover temperature $θ_A$ for metallic and molecular liquids. These observations provide a way to estimate the low-temperature glassy characteristics ($T_g$ and $m$) from the high-temperature liquid quantities ($E_\infty$ and $θ_A$).

cond-mat.soft↗

arXiv2015

Selective control of oxygen sublattice stability by epitaxial strain in Ruddlesden-Popper films

Oxygen-defect control has long been considered an influential tuning knob for producing various property responses in complex oxide films. In addition to physical property changes, modification to the lattice structure, specifically lattice expansion, with increasing oxygen vacancy concentrations has been reported often and has become the convention for oxide materials. However, the current understanding of the lattice behavior in oxygen-deficient films becomes disputable when considering compounds containing different bonding environments or atomic layering. Moreover, tensile strain has recently been discovered to stabilize oxygen vacancies in epitaxial films, which further complicates the interpretation of lattice behavior resulting from their appearance. Here, we report on the selective strain control of oxygen vacancy formation and resulting lattice responses in the layered, Ruddlesden-Popper phases, La1.85Sr0.15CuO4. We found that a drastically reduced Gibbs free energy for oxygen vacancy formation near the typical growth temperature for tensile-strained epitaxial LSCO accounts for the large oxygen non-stoichiometry. Additionally, oxygen vacancies form preferentially in the equatorial position of the CuO2 plane, leading to a lattice contraction, rather than the expected expansion, observed with apical oxygen vacancies. Since oxygen stoichiometry plays a key role in determining the physical properties of many complex oxides, the strong strain coupling of oxygen nonstoichiometry and the unusual structural response reported here can provide new perspectives and understanding to the structure and property relationships of many other functional oxide materials.

cond-mat.mtrl-sci↗

arXiv2014

Growth control of the oxidation state in vanadium oxide thin films

Precise control of the chemical valence or oxidation state of vanadium in vanadium oxide thin films is highly desirable for not only fundamental research, but also technological applications that utilize the subtle change in the physical properties originating from the metal- insulator transition (MIT) near room temperature. However, due to the multivalent nature of vanadium and the lack of a good understanding on growth control of the oxidation state, stabilization of phase pure vanadium oxides with a single oxidation state is extremely challenging. Here, we systematically varied the growth conditions to clearly map out the growth window for preparing phase pure epitaxial vanadium oxides by pulsed laser deposition for providing a guideline to grow high quality thin films with well-defined oxidation states of V2(+3)O3, V(+4)O2, and V2(+5)O5. A well pronounced MIT was only observed in VO2 films grown in a very narrow range of oxygen partial pressure P(O2). The films grown either in lower (< 10 mTorr) or higher P(O2) (> 25 mTorr) result in V2O3 and V2O5 phases, respectively, thereby suppressing the MIT for both cases. We have also found that the resistivity ratio before and after the MIT of VO2 thin films can be further enhanced by one order of magnitude when the films are further oxidized by post-annealing at a well-controlled oxidizing ambient. This result indicates that stabilizing vanadium into a single valence state has to compromise with insufficient oxidation of an as grown thin film and, thereby, a subsequent oxidation is required for an improved MIT behavior.

cond-mat.mtrl-sci↗

arXiv2014

Local Energy Landscape in a Simple Liquid

It is difficult to relate the properties of liquids and glasses directly to their structure because of complexity in the structure which defies precise definition. The potential energy landscape (PEL) approach is a very insightful way to conceptualize the structure-property relationship in liquids and glasses, particularly on the effect of temperature and history. However, because of the highly multi-dimensional nature of the PEL it is hard to determine, or even visualize, the actual details of the energy landscape. In this article we introduce a modified concept of the local energy landscape (LEL) which is limited in phase space, and demonstrate its usefulness using molecular dynamics simulation on a simple liquid at high temperatures. The local energy landscape is given as a function of the local coordination number, the number of the nearest neighbor atoms. The excitations in the LEL corresponds to the so-called beta-relaxation process. The LEL offers a simple but useful starting point to discuss complex phenomena in liquids and glasses.

cond-mat.soft↗

arXiv2014

Anisotropic neutron spin resonance in underdoped superconducting NaFe1-xCoxAs

We use polarized inelastic neutron scattering (INS) to study spin excitations in superconducting NaFe0.985Co0.015As (C15) with static antiferromagnetic (AF) order along the a-axis of the orthorhombic structure and NaFe0.935Co0.045As (C45) without AF order. In previous unpolarized INS work, spin excitations in C15 were found to have a dispersive sharp resonance near Er1=3.25 meV and a broad dispersionless mode at Er2=6 meV. Our neutron polarization analysis reveals that the dispersive resonance in C15 is highly anisotropic and polarized along the a- and c-axis, while the dispersionless mode is isotropic similar to that of C45. Since the a-axis polarized spin excitations of the anisotropic resonance appear below Tc, our data suggests that the itinerant electrons contributing to the magnetism are also coupled to the superconductivity.

cond-mat.supr-con↗

arXiv2014

Fractional Einstein relation for strongly disordered semiconductors

A novel Einstein relation (fractional Einstein relation, FER) for the electric conduction in non-crystalline semiconductors is presented. FER and the generalized Einstein relation (GER) [Phys. Rev. E 8, 1296 (1998)] are compared to the result of the Monte Carlo (MC) simulation, and is confirmed that FER exhibits better agreement than GER. The cruial feature of FER is that it reflects the violation of the detailed balance in the coarse-grained hopping process, while it is preserved in the original Einstein relation or GER.

cond-mat.dis-nn↗

arXiv2014

Dynamical Crossover in Soft Colloids below the Overlap Concentration

The dynamics of soft colloids in solutions is characterized by internal collective motion as well as center-of-mass diffusion. Using neutron scattering we demonstrate that the competition between the relaxation processes associated with these two degrees of freedom results in strong dependence of dynamics and structure on colloid concentration, c, even well below the overlap concentration c*. We show that concurrent with increasing inter-particle collisions, substantial structural dehydration and slowing-down of internal dynamics occur before geometrically defined colloidal overlap develops. While previous experiments have shown that the average size of soft colloids changes very little below c*, we find a marked change in both the internal structure and internal dynamics with concentration. The competition between these two relaxation processes gives rise to a new dynamically-defined dilute threshold concentration well below c*.

physics.chem-ph↗

arXiv2013

Tunneling Electroresistance Induced by Interfacial Phase Transitions in Ultrathin Oxide Heterostructures

The ferroelectric (FE) control of electronic transport is one of the emerging technologies in oxide heterostructures. Many previous studies in FE tunnel junctions (FTJs) exploited solely the differences in the electrostatic potential across the FTJs that are induced by changes in the FE polarization direction. Here, we show that in practice the junction current ratios between the two polarization states can be further enhanced by the electrostatic modification in the correlated electron oxide electrodes, and that FTJs with nanometer thin layers can effectively produce a considerably large electroresistance ratio at room temperature. To understand these surprising results, we employed an additional control parameter, which is related to the crossing of electronic and magnetic phase boundaries of the correlated electron oxide. The FE-induced phase modulation at the heterointerface ultimately results in an enhanced electroresistance effect. Our study highlights that the strong coupling between degrees of freedom across heterointerfaces could yield versatile and novel applications in oxide electronics.

cond-mat.mtrl-sci↗

arXiv2013

Double neutron spin resonances and gap anisotropy in underdoped superconducting NaFe0.985Co0.015As

We use inelastic neutron scattering to show that superconductivity in electron-underdoped NaFe0.985Co0.015As induces a dispersive sharp resonance near Er1 = 3:25 meV and a broad dis- persionless mode at Er2 = 6 meV. However, similar measurements on overdoped superconducting NaFe0:955Co0:045As find only a single sharp resonance at Er = 7 meV. We connect these results with the observations of angle-resolved photoemission spectroscopy that the superconducting gaps in the electron Fermi pockets are anisotropic in the underdoped material but become isotropic in the overdoped case. Our analysis indicates that both the double neutron spin resonances and gap anisotropy originate from the orbital dependence of the superconducting pairing in the iron pnic- tides. Our discovery also shows the importance of the inelastic neutron scattering in detecting the multiorbital superconducting gap structures of iron pnictides.

cond-mat.supr-con↗

arXiv2013

DC electric field effect on the anomalous exponent of the hopping conduction in the one-dimensional disorder model

DC electric field effect on the anomalous exponent of the hopping conduction in the disorder model is investigated. First, we explain the model and derive an analytical expression of the effective waiting time for the general case. We show that the exponent depends on the external field. Then we focus on a one-dimensional system in order to illustrate the features of the anomalous exponent. We derive approximate expressions of the anomalous exponent of the system analytically. For the case of a weak field, the anomalous exponent is consistent with that of diffusive systems. This is consistent with the treatments of Barkai et al. [Phys. Rev. E {\bf 63}, 046118 (2001)] and our result supports their theory. On the other hand, for the case of a strong field and a strong disorder, the time evolution of the exponent clearly differs from that in the weak field. The exponent is consistent with the well-known expression of the anomalous exponent in the Multiple Trapping Model at mesoscopic time scales. In the long time limit, a transition of the anomalous exponent to the same value of the weak field occurs. For the case of a strong field and a weak disorder, the exponent is equal to 1 and thus the diffusion is normal. These findings are verified by the Monte Carlo simulation.

cond-mat.dis-nn↗

arXiv2013

Magnetic anisotropy in hole-doped superconducting Ba 0.67K 0.33Fe 2As2 probed by polarized inelastic neutron scattering

We use polarized inelastic neutron scattering (INS) to study spin excitations of optimally hole-doped superconductor Ba$_{0.67}$K$_{0.33}$Fe$_2$As$_{2}$ ($T_c=38$ K). In the normal state, the imaginary part of the dynamic susceptibility, $χ^{\prime\prime}(Q,ω)$, shows magnetic anisotropy for energies below $\sim$7 meV with c-axis polarized spin excitations larger than that of the in-plane component. Upon entering into the superconducting state, previous unpolarized INS experiments have shown that spin gaps at $\sim$5 and 0.75 meV open at wave vectors $Q=(0.5,0.5,0)$ and $(0.5,0.5,1)$, respectively, with a broad neutron spin resonance at $E_r=15$ meV. Our neutron polarization analysis reveals that the large difference in spin gaps is purely due to different spin gaps in the c-axis and in-plane polarized spin excitations, resulting resonance with different energy widths for the c-axis and in-plane spin excitations. The observation of spin anisotropy in both opitmally electron and hole-doped BaFe$_2$As$_2$ is due to their proximity to the AF ordered BaFe$_2$As$_2$ where spin anisotropy exists below $T_N$.

cond-mat.supr-con↗

arXiv2012

Space-time dependence of the anomalous exponent of electric transport in the disorder model

Space-time dependence of the anomalous exponent of electric transport in the disorder model is presented. We show that the anomalous exponent depends on time, according to the time-evolution of the number of the effective neighbouring sites. Transition from subdiffusive to normal transport at long-enough time is recovered. The above result indicates that the spatial structure, specifically the network structure, of the hopping sites might be a novel element which determines the anomalous exponent. This leads to the feature that the scaling property of the electric transport to time is insensitive to other elements, such as the distance of the sites or the spatial dimension of the system. These findings are verified by means of Monte Carlo simulation. The relation of the result to the conventional knowledge of the Multiple Trapping Model is shown by deriving it as a special case of the disorder model.

cond-mat.dis-nn↗

arXiv2012

Strongly coupled phase transition in ferroelectric/correlated electron oxide heterostructures

We fabricated ultrathin ferroelectric/correlated electron oxide heterostructures composed of the ferroelectric Pb(Zr0.2Ti0.8)O3 and the correlated electron oxide (CEO) La0.8Sr0.2MnO3 on SrTiO3 substrates by pulsed laser epitaxy. The hole accumulation in the ultrathin CEO layer was substantially modified by heterostructuring with the ferroelectric layer, resulting in an insulator-metal transition. In particular, our thickness dependent study showed that drastic changes in transport and magnetic properties were strongly coupled to the modulation of charge carriers by ferroelectric field effect, which was confined to the vicinity of the interface. Thus, our results provide crucial evidence that strong ferroelectric field effect control can be achieved in ultrathin (10 nm) heterostructures, yielding at least a 100,000-fold change in resistivity.

cond-mat.mtrl-sci↗

arXiv2012

Glass Dynamics at High Strain Rates

We present a shear-transformation-zone (STZ) theoretical analysis of molecular-dynamics simulations of a rapidly sheared metallic glass. These simulations are especially revealing because, although they are limited to high strain rates, they span temperatures ranging from well below to well above the glass transition. With one important discrepancy, the STZ theory reproduces the simulation data, including the way in which those data can be made to collapse onto simple curves by a scaling transformation. The STZ analysis implies that the system's behavior at high strain rates is controlled primarily by effective-temperature thermodynamics, as opposed to system-specific details of the molecular interactions. The discrepancy between theory and simulations occurs at the lower strain rates for temperatures near the glass transition. We argue that this discrepancy can be resolved by the same multi-species generalization of STZ theory that has been proposed recently for understanding frequency-dependent viscoelastic responses, Stokes-Einstein violations, and stretched-exponential relaxation in equilibrated glassy materials.

cond-mat.mtrl-sci↗

arXiv2012

Atomic Mechanism of Flow in Simple Liquids under Shear

Atomic correlations in a simple liquid in steady-state flow under shear stress were studied by molecular dynamics simulation. The local atomic level strain was determined through the anisotropic pair-density function (PDF). The atomic level strain has a limited spatial extension whose range is dependent on the strain rate and extrapolates to zero at the critical strain rate. A failure event is identified with altering the local topology of atomic connectivity by exchanging bonds among neighboring atoms.

cond-mat.dis-nn↗

arXiv2011

Spin waves in the $(π,0)$ magnetically ordered iron chalcogenide Fe$_{1.05}$Te

We use inelastic neutron scattering to show that the spin waves in the iron chalcogenide Fe$_{1.05}$Te display novel dispersion clearly different from those in the related iron pnictide systems. By fitting the spin waves to a Heisenberg Hamiltonian, we extract magnetic exchange couplings that are dramatically different from both predictions by density functional calculations and measurements on the iron pnictide CaFe$_2$As$_2$. While the nearest-neighbor exchange couplings in CaFe$_2$As$_2$ and Fe$_{1.05}$Te are quite different, their next-nearest-neighbor exchange couplings are similar. These results suggest that superconductivity in the pnictides and chalcogenides share a common magnetic origin that is intimately associated with the next-nearest-neighbor magnetic coupling between the irons.

cond-mat.supr-con↗

arXiv2010

Spinor and Twistor Formulations of Tensionless Bosonic Strings in Four Dimensions

Spinor and twistor formulations of tensionless bosonic strings in 4-dimensional Minkowski space are constructed. We begin with a first-order action that is equivalent to the Nambu-Goto action in the tensionful case and that leads to a spinorial action in the tensionless case. From this spinorial action, we find an alternative spinorial action useful for constructing a simple twistor formulation of tensionless strings. The twistor formulation is steadily constructed in accordance with a fundamental concept of twistor theory. We investigate local internal symmetries inherent in the twistorial action for a tensionless string and carry out some classical analyses of the tensionless string expressed in a twistorial form.

hep-th↗

arXiv2010

Anisotropic Neutron Spin Resonance in Superconducting BaFe$_{1.9}$Ni$_{0.1}$As$_2$

We use polarized inelastic neutron scattering to show that the neutron spin resonance below $T_c$ in superconducting BaFe$_{1.9}$Ni$_{0.1}$As$_2$ ($T_c=20$ K) is purely magnetic in origin. Our analysis further reveals that the resonance peak near 7~meV only occurs for the planar response. This challenges the common perception that the spin resonance in the pnictides is an isotropic triplet excited state of the singlet Cooper pairs, as our results imply that only the $S_{001}=\pm1$ components of the triplet are involved.

cond-mat.supr-con↗