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Taylor J. Bell

Publications and source records attributed to Taylor J. Bell.

At least 19 recordsLinked to original sources

Looking for TRAPPIST-1 external planets' emission in JWST archival data

The TRAPPIST-1 system has been thoroughly observed with JWST. Unfortunately, stellar contamination issues strongly limit the interpretation of transit observations. As for emission observations, only the two closest planets have been observed through five dedicated JWST programs. We gathered all these emission observations and tried to detect the combined emission of the external planets in previous JWST MIRI observations of TRAPPIST-1; this paper presents our approach and our results. We could not achieve sufficient precision to detect the thermal emission of the outer planets and to discriminate between an all-bare rocks and an all-atmospheres scenario. However, we show that a~60 hours continuous observations at a specific phase range, when the gradient of thermal flux from the outer planets is maximum, could allow us to achieve this goal.

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A new window in time: a mid-infrared slit spectroscopy mode for precision time-series astronomy with JWST/MIRI

The Mid-Infrared Instrument (MIRI) on board the James Webb Space Telescope (JWST) provides Low Resolution Spectroscopy (LRS) over 5-12 um at a resolving power of R ~ 100. To date, all MIRI LRS time-series observations (TSOs) have been carried out in slitless mode, since long-duration pointing stability within the narrow 4.7'' x 0.51'' slit could not previously be guaranteed, leading to the possibility of degraded TSOs due to jitter. Commissioning activities established the telescope jitter to be less than 1 milliarcsecond (mas), four times less than the initial requirement. It was, therefore, worth assessing the suitability of the MIRI LRS slit as a TSO mode for precision time-domain science; this is the aim of the Cycle 3 program (PID 6219, PI: A. Dyrek). We observed a transit of the exoplanet HAT-P-12b over ~10 hours and compared the results to archival slitless observations of the same target (PID 1281, PI: P.-O. Lagage). Two independent data reductions of the transit spectra of both slit and slitless configurations are consistent within 1 sigma, validating the feasibility of the new mode. A joint fit of the slit and slitless observations confirms the presence of a spectral feature near 7.5 um. Using measured JWST pointing variations, we estimated slit-loss variations to be smaller than 40 ppm at 10 um. The drawback of the slitless mode is a higher background. Compellingly, the slit background is ~ 38 times lower on average than in slitless mode, improving sensitivity for faint targets (Jmag ~ 13-15). We also identified time-correlated noise unique to the slit dataset at long wavelengths, which requires further investigation. This new capability of TSOs in slit mode, which will be supported in Cycle 7 (in 2028), opens a new avenue for precision time-series astronomy for faint targets with JWST/MIRI.

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Phase-dependent chemistry of WASP-43 b revealed with a suite of one-, two-, and three-dimensional models

Our goal is to investigate the chemistry of the hot Jupiter WASP-43 b in detail using theoretical models, considering the constraints of the James Webb Space Telescope MIRI phase curve. With a suite of pseudo-two-dimensional and three-dimensional photochemical models, we simulate the composition of WASP-43 b in various configurations, and compare them with atmospheric retrieval models. We confirm that disequilibrium chemistry in our theoretical models reduces the methane concentration on the planet night side for wind jet speeds > 500 m/s. Varying the metallicity in the models induces large changes in the CO$_2$ and SO$_2$ concentrations, with SO$_2$ producing mid-infrared absorption features in synthetic emission spectra of the night side at atmospheric metallicities > 10x solar. Our models provide evidence for pole-to-equator circulation enhancing the CH$_4$, NH$_3$, and HCN abundances, which is nonetheless insufficient for detectable spectral features. Finally, we show that H$_2$O, CO, and CO$_2$ are robustly modeled, but species affected by photochemistry are more sensitive to model-specific assumptions and pathways. We conclude that horizontal quenching is the prime mechanism that explains the non-detection of methane in the MIRI phase-curve of WASP-43 b. This mechanism requires only moderate wind speeds and is operative at various thermal structures and atmospheric metallicities. Furthermore, coupled carbon-sulfur chemistry leads to an additional decrease in methane compared to previous models in the literature that did not contain sulfur chemistry. We do not favor a high metallicity as it would have led to observable SO$_2$ features in the MIRI spectra. Our study shows that phase-dependent photochemistry models are essential tools in the interpretation of hot-Jupiter phase curves, but benchmarking is needed to improve the accuracy of photochemical models in the future.

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The tale of the 3 planets: 3D cloud feedback enhances the spectral diversity of warm Jupiters

JWST has shown a large diversity in warm Jupiter spectra, despite only small variations in the planetary parameters. However, the main driver of this diversity remains unclear. We aim to identify the mechanisms responsible for the spectral difference of three warm Jupiter-size exoplanets observed by JWST: whereas WASP-80b appears mostly cloud-free, both WASP-107b and WASP-69b have spectra dominated by clouds. We model each planet using the same framework, ADAM (formerly SPARC/MITgcm), which solves for the interactions among cloud transport, radiative transfer, and atmospheric circulation in 3D. We investigate the role of three condensate species, Na$_2$S, KCl, and MgSiO$_3$, and four particle sizes (0.1, 1, 5, and 10 $μ$m). Clouds settle deeper in the atmosphere of the higher-gravity planet WASP-80b than in WASP-107b, reproducing their spectral difference naturally. For WASP-107b, three clouds can reproduce the NIRCam observations: 5 $μ$m Na$_2$S, 1 $μ$m KCl, and 5 $μ$m MgSiO$_3$ models. However, these cannot match the scattering slope observed at shorter wavelengths in NIRISS and the possible silicate feature in the MIRI bandpass, suggesting a multi-modal distribution of clouds. Our model predicts that small silicate particles should be homogeneously distributed and thus cannot account for the difference between the two limb spectra in the MIRI bandpass. Finally, applying the same model to WASP-69b does not yield a partially cloudy dayside solution that fits the emission spectra, as proposed in a previous study. Coupling among 3D circulation, clouds, and radiative transfer can enhance the spectral diversity of warm Jupiter exoplanets, particularly through changes in cloudiness with gravity. The combination of multi-phase, wide-wavelength coverage and models that couple clouds, circulation, and radiative transfer is key to advancing our understanding of these new objects.

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The Identification of CS2 and Evidence for Carbon-Sulfur Chemical Coupling in a Warm Giant Exoplanet Atmosphere

Transmission spectroscopy with the James Webb Space Telescope (JWST) is revealing growing chemical complexity in giant exoplanet atmospheres. Of particular interest is sulfur, which had essentially no observational constraints before JWST. Recent work has shown that a planet's atmospheric sulfur content traces its refractory budget and is therefore a sensitive indicator of formation pathways. But despite the growing library of JWST data, the sulfur inventory of giant exoplanets remains poorly constrained: sulfur-bearing species are governed by disequilibrium chemistry and by kinetic networks that are still being revised. Here we present a transmission spectrum of the warm giant planet WASP-80 b obtained with JWST/NIRCam and MIRI over 2.4 $\mu$m--10$\mu$m in three transits. We uniquely identify CS$_2$ in our transmission spectrum using the combination of the two absorption features in NIRCam and MIRI at a significance of $\ln (B)=17.89$ ($\sigma = 6.3$). Our grid-based retrievals yield $\mathrm{[M/H] = \:} 0.54^{+0.17}_{-0.12}$ and $\mathrm{C/O =\:}0.43^{+0.12}_{-0.08}$ which result in $\log(\mathrm{X_{CS_2}})$ abundances of $\sim-4.5$. The latest carbon-sulfur kinetics networks produce substantially greater amounts of CS$_2$ than past works, enabling good fits ($\chi^2/\mathrm{N_{data}}\sim1.2$) to the data without invoking extreme abundance patterns. These results identify CS$_2$ as an observable tracer of sulfur disequilibrium chemistry and provide observational support for theoretically predicted carbon-sulfur chemical coupling in giant exoplanet atmospheres.

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Cloudy solutions for the clear skies of WASP-80b: 3D cloud feedback on the atmosphere and spectra of a warm Jupiter

Close-in warm Jupiters orbiting M dwarf stars are expected to exhibit diverse atmospheric chemistry, with clouds playing a key role in shaping their albedo, heat distribution, and spectral properties. We study WASP-80b, a warm Jupiter orbiting an M dwarf star, using the latest JWST panchromatic emission and transmission spectra to comprehensively characterise its atmosphere, including cloud coverage, chemical composition, and particle sizes, and compare the observations with predictions from the general circulation models (GCMs). We used a GCM, ADAM (ADvanced Atmospheric MITgcm, formerly known as SPARC/MITgcm), combined with the latest JWST data to study the atmosphere of WASP-80b. A cloud module with radiatively active, tracer-based clouds was integrated with the GCM to study the effects on the atmosphere and the spectrum. We find that the emission and transmission spectra of WASP-80b are only compatible with cloudless atmospheres or with clouds composed of sufficiently large particles, namely Na$_2$S ($\geq 10 μ$m), KCl ($\geq 1 μ$m), and MgSiO$_3$ ($\geq 5 μ$m). For these large-particle cloud cases, efficient gravitational settling confines the clouds to deeper atmospheric layers, resulting in weak spectral signatures. Smaller particles are ruled out due to their strong radiative feedback on the atmospheric structure. Overall, our results suggest that WASP-80b's atmosphere is either effectively cloud-free or contains clouds composed of large, settled particles whose opacity has little impact on the observable atmosphere. This underscores the importance of particle size and vertical cloud distribution in interpreting exoplanet spectra. Future observations at shorter wavelengths may help distinguish between large-particle cloud scenarios and a truly cloudless atmosphere.

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First JWST thermal phase curves of temperate terrestrial exoplanets reveal no thick atmosphere around TRAPPIST-1 b and c

We report JWST/MIRI 15 $μ$m phase curves of TRAPPIST-1 b and c, revealing thermal emission consistent with their irradiation levels, assuming no efficient heat redistribution. We find that TRAPPIST-1 b shows a high dayside brightness temperature (490 $\pm$ 17 K), no significantly detectable nightside emission ($F_{\rm b, Night, max}$ = $39_{-27}^{+55}$ ppm), and no phase offset -- features consistent with a low-albedo, airless ultramafic rocky surface. TRAPPIST-1 c exhibits a lower dayside brightness temperature (369 $\pm$ 23 K), and a nightside flux statistically indistinguishable from that of TRAPPIST-1 b ($F_{\rm c, Night, max}$ = $62_{-43}^{+60}$ ppm). Atmosphere models with surface pressures $\geq$1 bar and efficient greenhouse effects are strongly disfavoured for both planets. TRAPPIST-1 b is unlikely to possess any substantial atmosphere, while TRAPPIST-1 c may retain a tenuous, greenhouse-poor O$_2$-dominated atmosphere or be similarly airless with a more reflective surface. These results suggest divergent evolutionary pathways or atmospheric loss processes, despite similar compositions. These measurements tightly constrain atmosphere retention in the inner TRAPPIST-1 system.

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A Comprehensive Reanalysis of K2-18 b's JWST NIRISS+NIRSpec Transmission Spectrum

Sub-Neptunes are the most common type of planet in our galaxy. Interior structure models suggest that the coldest sub-Neptunes could host liquid water oceans underneath their hydrogen envelopes -- sometimes called ``hycean'' planets. JWST transmission spectra of the $\sim$ 250 K sub-Neptune K2-18 b were recently used to report detections of CH$_4$ and CO$_2$, alongside weaker evidence of (CH$_3$)$_2$S (dimethyl sulfide, or DMS). Atmospheric CO$_2$ was interpreted as evidence for a liquid water ocean, while DMS was highlighted as a potential biomarker. However, these notable claims were derived using a single data reduction and retrieval modeling framework, which did not allow for standard robustness tests. Here we present a comprehensive reanalysis of K2-18 b's JWST NIRISS SOSS and NIRSpec G395H transmission spectra, including the first analysis of the second-order NIRISS SOSS data. We incorporate multiple well-tested data reduction pipelines and retrieval codes, spanning 60 different data treatments and over 250 atmospheric retrievals. We confirm the detection of CH$_4$ ($\approx 4σ$), with a volume mixing ratio range $-2.14 \leq \log_{10} \mathrm{CH_4} \leq -0.53$, but we find no statistically significant or reliable evidence for CO$_2$ or DMS. Finally, we assess the retrieved atmospheric composition using photochemical-climate and interior models, demonstrating that our revised composition of K2-18\,b can be explained by an oxygen-poor mini-Neptune without requiring a liquid water surface or life.

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A Precise Metallicity and Carbon-to-Oxygen Ratio for a Warm Giant Exoplanet from its Panchromatic JWST Emission Spectrum

WASP-80 b, a warm sub-Jovian (equilibrium temperature ~820 K, 0.5 Jupiter masses), presents an opportunity to characterize a rare gas giant exoplanet around a low-mass star. In addition, its moderate temperature enables its atmosphere to host a range of carbon and oxygen species (H$_2$O, CH$_4$, CO, CO$_2$, NH$_3$). In this paper, we present a panchromatic emission spectrum of WASP-80 b, the first gas giant around a late K/early M-dwarf star and the coolest planet for which the James Webb Space Telescope has obtained a complete emission spectrum spanning 2.4-12 $μ$m, including NIRCam F322W2 (2.4-4 $μ$m) and F444W (4-5 $μ$m), and MIRI LRS (5-12 $μ$m). We report confident detections of H$_2$O, CH$_4$, CO, and CO$_2$, and a tentative detection of NH$_3$. We estimate WASP-80 b's atmospheric metallicity and carbon-to-oxygen ratio and compare them with estimates for other gas giants. Despite the relative rarity of giant planets around low-mass stars, we find that WASP-80 b's composition is consistent with other hot gas giants, suggesting that the formation pathway of WASP-80 b may not be dissimilar from hot gas giants around higher-mass stars.

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A Panchromatic Characterization of the Evening and Morning Atmosphere of WASP-107 b: Composition and Cloud Variations, and Insight into the Effect of Stellar Contamination

Limb-resolved transmission spectroscopy has the potential to transform our understanding of exoplanetary atmospheres. By separately measuring the transmission spectra of the evening and morning limbs, these atmospheric regions can be individually characterized, shedding light into the global distribution and transport of key atmospheric properties from transit observations alone. In this work, we follow up the recent detection of limb asymmetry on the exoplanet WASP-107 b (Murphy et al. 2024) by reanalyzing literature observations of WASP-107 b using all of JWST's science intruments (NIRISS, NIRCam, NIRSpec, and MIRI) to measure its limb transmission spectra from $\sim$1-12 $μ$m. We confirm the evening--morning temperature difference inferred previously and find that it is qualitatively consistent with predictions from global circulation models. We find evidence for evening--morning variation in SO$_2$ and CO$_2$ abundance, and significant cloud coverage only on WASP-107 b's morning limb. We find that the NIRISS and NIRSpec observations are potentially contaminated by occulted starspots, which we leverage to investigate stellar contamination's impact on limb asymmetry measurements. We find that starspot crossings can significantly bias the inferred evening and morning transmission spectra depending on when they occur during the transit, and develop a simple correction model which successfully brings these instruments' spectra into agreement with the uncontaminated observations.

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A JWST Panchromatic Thermal Emission Spectrum of the Warm Neptune Archetype GJ 436b

GJ 436b is the archetype warm Neptune exoplanet. The planet's thermal emission spectrum was previously observed via intensive secondary eclipse campaigns with Spitzer. The atmosphere has long been interpreted to be extremely metal-rich, out of chemical equilibrium, and potentially tidally heated. We present the first panchromatic emission spectrum of GJ 436b observed with JWST's NIRCAM (F322W2 and F444W) and MIRI (LRS) instruments between 2.4 and 11.9 $μ$m. Surprisingly, the JWST spectrum appears significantly fainter around 3.6 $μ$m than that implied by Spitzer photometry. The molecular absorption features in the spectrum are relatively weak, and we only find tentative evidence of CO$_2$ absorption at 2$σ$ significance. Under the assumption of a day-side blackbody, we find $T_{\rm day}$=662.8$\pm$5.0 K, which is similar to the zero Bond albedo equilibrium temperature. We use it to obtain a 3$σ$ upper limit on the Bond albedo of $A_B{\le}$0.66. To understand the spectrum we employ 1D radiative-convective models but find that atmospheric constraints depend strongly on model assumptions. If thermochemical equilibrium is assumed, we find a cloudy metal-enriched atmosphere (metallicity $\ge$ 300$\times$solar). We employ 1D photochemical modeling to show that the observed spectrum is also consistent with a cloud-free, relatively lower-metallicity atmosphere (metallicity $\ge$ 80$\times$solar) with a cold internal temperature ($T_{\rm int}$$\sim$60 K). These are much lower metallicities and internal temperatures than inferences from Spitzer photometry. The low $T_{\rm day}$ and non-detection of transmission features at high spectral resolution does suggest a role for cloud opacity, but this is not definitive.

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A Possible Metal-Dominated Atmosphere Below the Thick Aerosols of GJ 1214 b Suggested by its JWST Panchromatic Transmission Spectrum

GJ1214b is the archetype sub-Neptune for which thick aerosols have prevented us from constraining its atmospheric properties for over a decade. In this study, we leverage the panchromatic transmission spectrum of GJ1214b established by HST and JWST to investigate its atmospheric properties using a suite of atmospheric radiative transfer, photochemistry, and aerosol microphysical models. We find that the combined HST, JWST/NIRSpec and JWST/MIRI spectrum can be well-explained by atmospheric models with an extremely high metallicity of [M/H]$\sim$3.5 and an extremely high haze production rate of $F_{\rm haze}{\sim}10^{-8}$--$10^{-7}$ g cm$^{-2}$ s$^{-1}$. Such high atmospheric metallicity is suggested by the relatively strong CO2 feature compared to the haze absorption feature or the CH4 feature in the NIRSpec-G395H bandpass of 2.5--5 $μ$m. The flat 5--12 $μ$m MIRI spectrum also suggests a small scale height with a high atmospheric metallicity that is needed to suppress a prominent 6 $μ$m haze feature. We tested the sensitivity of our interpretation to various assumptions for uncertain haze properties, such as optical constants and production rate, and all models tested here consistently suggest extremely high metallicity. Thus, we conclude that GJ1214b likely has a metal-dominated atmosphere where hydrogen is no longer the main atmospheric constituent. We also find that different assumptions for the haze production rate lead to distinct inferences for the atmospheric C/O ratio. We stress the importance of high precision follow-up observations to confirm the metal-dominated atmosphere and to constrain the C/O ratio, which provides further insights on the planet formation process. The confirmation of the metal-dominated atmosphere is particularly crucial, as it challenges the conventional understanding of interior structure and evolution of sub-Neptunes.

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Combined analysis of the 12.8 and 15 $μm$ JWST/MIRI eclipse observations of TRAPPIST-1 b

The first JWST/MIRI photometric observations of TRAPPIST-1 b allowed for the detection of the thermal emission of the planet at 15 $μm$, suggesting that the planet could be a bare rock with a zero albedo and no redistribution of heat. These observations at 15 $μm$ were acquired as part of GTO time that included a twin program at 12.8 $μm$ in order to have a measurement in and outside the CO$_2$ absorption band. Here we present five new occultations of TRAPPIST-1 b observed with MIRI in an additional photometric band at 12.8 $μm$. We perform a global fit of the 10 eclipses and derive a planet-to-star flux ratio and 1-$σ$ error of 452 $\pm$ 86 ppm and 775 $\pm$ 90 ppm at 12.8 $μm$ and 15 $μm$, respectively. We find that two main scenarios emerge. An airless planet model with an unweathered (fresh) ultramafic surface, that could be indicative of relatively recent geological processes fits well the data. Alternatively, a thick, pure-CO2 atmosphere with photochemical hazes that create a temperature inversion and result in the CO2 feature being seen in emission also works, although with some caveats. Our results highlight the challenges in accurately determining a planet's atmospheric or surface nature solely from broadband filter measurements of its emission, but also point towards two very interesting scenarios that will be further investigated with the forthcoming phase curve of TRAPPIST-1 b.

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Evidence for Morning-to-Evening Limb Asymmetry on the Cool Low-Density Exoplanet WASP-107b

The atmospheric properties of hot exoplanets are expected to be different between the morning and the evening limb due to global atmospheric circulation. Ground-based observations at high spectral resolution have detected this limb asymmetry in several ultra-hot (>2000 K) exoplanets, but the prevalence of the phenomenon in the broader exoplanetary population remains unexplored. Here we use JWST/NIRCam transmission spectra between 2.5 and 4.0 $μ$m to find evidence of limb asymmetry on exoplanet WASP-107 b. With its equilibrium temperature of 770 K and low density of 0.126 gm c$^{-3}$, WASP-107 b probes a very different regime compared to ultra-hot giant planets and was not expected to exhibit substantial spatial heterogeneity according to atmospheric models. We infer instead a morning-evening temperature difference on the order of 100 K with a hotter evening limb. Further observations on other cooler exoplanets are needed to determine whether WASP-107 b is an outlier or the models underestimate the presence of limb asymmetry in exoplanets.

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Possible Carbon Dioxide Above the Thick Aerosols of GJ 1214 b

Sub-Neptune planets with radii smaller than Neptune (3.9 Re) are the most common type of planet known to exist in The Milky Way, even though they are absent in the Solar System. These planets can potentially have a large diversity of compositions as a result of different mixtures of rocky material, icy material and gas accreted from a protoplanetary disk. However, the bulk density of a sub-Neptune, informed by its mass and radius alone, cannot uniquely constrain its composition; atmospheric spectroscopy is necessary. GJ 1214 b, which hosts an atmosphere that is potentially the most favorable for spectroscopic detection of any sub-Neptune, is instead enshrouded in aerosols (thus showing no spectroscopic features), hiding its composition from view at previously observed wavelengths in its terminator. Here, we present a JWST NIRSpec transmission spectrum from 2.8 to 5.1 um that shows signatures of carbon dioxide and methane, expected at high metallicity. A model containing both these molecules is preferred by 3.3 and 3.6 sigma as compared to a featureless spectrum for two different data analysis pipelines, respectively. Given the low signal-to-noise of the features compared to the continuum, however, more observations are needed to confirm the carbon dioxide and methane signatures and better constrain other diagnostic features in the near-infrared. Further modeling of the planet's atmosphere, interior structure and origins will provide valuable insights about how sub-Neptunes like GJ 1214 b form and evolve.

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A Comprehensive Analysis Spitzer 4.5 $μ$m Phase Curve of Hot Jupiters

Although exoplanetary science was not initially projected to be a substantial part of the Spitzer mission, its exoplanet observations set the stage for current and future surveys with JWST and Ariel. We present a comprehensive reduction and analysis of Spitzer's 4.5 micron phase curves of 29 hot Jupiters on low-eccentricity orbits. The analysis, performed with the Spitzer Phase Curve Analysis (SPCA) pipeline, confirms that BLISS mapping is the best detrending scheme for most, but not all, observations. Visual inspection remains necessary to ensure consistency across detrending methods due to the diversity of phase curve data and systematics. Regardless of the model selection scheme - whether using the lowest-BIC or a uniform detrending approach - we observe the same trends, or lack thereof. We explore phase curve trends as a function of irradiation temperature, orbital period, planetary radius, mass, and stellar effective temperature. We discuss the trends that are robustly detected and provide potential explanations for those that are not observed. While it is almost tautological that planets receiving greater instellation are hotter, we are still far from confirming dynamical theories of heat transport in hot Jupiter atmospheres due to the sample's diversity. Even among planets with similar temperatures, other factors like rotation and metallicity vary significantly. Larger, curated sample sizes and higher-fidelity phase curve measurements from JWST and Ariel are needed to firmly establish the parameters governing day-night heat transport on synchronously rotating planets.

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A roadmap for the atmospheric characterization of terrestrial exoplanets with JWST

Ultra-cool dwarf stars are abundant, long-lived, and uniquely suited to enable the atmospheric study of transiting terrestrial companions with JWST. Amongst them, the most prominent is the M8.5V star TRAPPIST-1 and its seven planets. While JWST Cycle 1 observations have started to yield preliminary insights into the planets, they have also revealed that their atmospheric exploration requires a better understanding of their host star. Here, we propose a roadmap to characterize the TRAPPIST-1 system -- and others like it -- in an efficient and robust manner. We notably recommend that -- although more challenging to schedule -- multi-transit windows be prioritized to mitigate the effects of stellar activity and gather up to twice more transits per JWST hour spent. We conclude that, for such systems, planets cannot be studied in isolation by small programs, but rather need large-scale, jointly space- and ground-based initiatives to fully exploit the capabilities of JWST for the exploration of terrestrial planets.

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Sulfur Dioxide and Other Molecular Species in the Atmosphere of the Sub-Neptune GJ 3470 b

We report observations of the atmospheric transmission spectrum of the sub-Neptune exoplanet GJ 3470 b taken using the Near-Infrared Camera (NIRCam) on JWST. Combined with two archival HST/WFC3 transit observations and fifteen archival Spitzer transit observations, we detect water, methane, sulfur dioxide, and carbon dioxide in the atmosphere of GJ 3470 b, each with a significance of >3-sigma. GJ 3470 b is the lowest mass -- and coldest -- exoplanet known to show a substantial sulfur dioxide feature in its spectrum, at $M_{p}$=11.2${\,{\rm M}_{\oplus}}$ and $T_{eq}$=600$\,$K. This indicates disequilibrium photochemistry drives sulfur dioxide production in exoplanet atmospheres over a wider range of masses and temperatures than has been reported or expected. The water, carbon dioxide, and sulfur dioxide abundances we measure indicate an atmospheric metallicity of approximately $100\times$ Solar. We see further evidence for disequilibrium chemistry in our inferred methane abundance, which is significantly lower than expected from equilibrium models consistent with our measured water and carbon dioxide abundances.

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