arXiv subjects

Tetsuya Ishikawa

Publications and source records attributed to Tetsuya Ishikawa.

At least 19 recordsLinked to original sources

arXiv2025

Soft and hard x-ray orbital-resolved photoemission study of a strongly correlated Cd-Ce quasicrystal approximant

We have investigated the orbital-dependent electronic states of Cd6Ce, a prototype of strongly correlated rare-earth-based Tsai-type quasicrystals and approximants (ACs) by soft and hard x-ray photoemission spectroscopy. Our results reveal that the 4f orbitals are predominantly hybridized with the valence-band electrons far from the Fermi level (EF), in sharp contrast to the hybridization with conduction electrons at EF seen for the intermetallic Ce-based compounds. This anomalous hybridization should be taken into account in discussing the unresolved magnetic ground state in Cd6Ce. These findings suggest that Cd-based ACs, some of which show the multi-step magnetic transitions, could provide a new platform for investigating novel magnetic properties that cannot be understood within the conventional framework of hybridization at EF.

cond-mat.str-el↗

arXiv2025

Paradigm Shift in Infrastructure Inspection Technology: Leveraging High-performance Imaging and Advanced AI Analytics to Inspect Road Infrastructure

Effective road infrastructure management is crucial for modern society. Traditional manual inspection techniques remain constrained by cost, efficiency, and scalability, while camera and laser imaging methods fail to capture subsurface defects critical for long-term structural integrity. This paper introduces ROVAI, an end-to-end framework that integrates high-resolution X-ray computed tomography imaging and advanced AI-driven analytics, aiming to transform road infrastructure inspection technologies. By leveraging the computational power of world-leading supercomputers, Fugaku and Frontier, and SoTA synchrotron facility (Spring-8), ROVAI enables scalable and high-throughput processing of massive 3D tomographic datasets. Our approach overcomes key challenges, such as the high memory requirements of vision models, the lack of labeled training data, and storage I/O bottlenecks. This seamless integration of imaging and AI analytics facilitates automated defect detection, material composition analysis, and lifespan prediction. Experimental results demonstrate the effectiveness of ROVAI in real-world scenarios, setting a new standard for intelligent, data-driven infrastructure management.

cs.DC↗

arXiv2019

Characterization of in-gap states in epitaxial CoFe2O4(111) layers grown on Al2O3(111)/Si(111) by resonant inelastic x-ray scattering

We have studied in-gap states in epitaxial CoFe2O4(111), which potentially acts as a perfect spin filter, grown on a Al2O3(111)/Si(111) structure by using ellipsometry, Fe L2,3-edge x-ray absorption spectroscopy (XAS), and Fe L2,3-edge resonant inelastic x-ray scattering (RIXS), and revealed the relation between the in-gap states and chemical defects due to the Fe2+ cations at the octahedral sites (Fe2+ (Oh) cations). The ellipsometry measurements showed the indirect band gap of 1.24 eV for the CoFe2O4 layer and the Fe L2,3-edge XAS confirmed the characteristic photon energy for the preferential excitation of the Fe2+ (Oh) cations. In the Fe L3-edge RIXS spectra, a band-gap excitation and an excitation whose energy is smaller than the band-gap energy (Eg = 1.24 eV) of CoF2O4, which we refer to as "below-band-gap excitation (BBGE)" hereafter, were observed. The intensity of the BBGE was strengthened at the preferential excitation energy of the Fe2+ (Oh) cations. In addition, the intensity of the BBGE was significantly increased when the thickness of the CoFe2O4 layer was decreased from 11 to 1.4 nm, which coincides with the increase in the site occupancy of the Fe2+ (Oh) cations with decreasing the thickness. These results indicate that the BBGE comes from the in-gap states of the Fe2+ (Oh) cations whose density increases near the heterointerface on the bottom Al2O3 layer. We have demonstrated that RIXS measurements and analyses in combination with ellipsometry and XAS are effective to provide an insight into in-gap states in thin-film oxide heterostructures.

cond-mat.mtrl-sci↗

arXiv2019

Scientific Opportunities with an X-ray Free-Electron Laser Oscillator

An X-ray free-electron laser oscillator (XFELO) is a new type of hard X-ray source that would produce fully coherent pulses with meV bandwidth and stable intensity. The XFELO complements existing sources based on self-amplified spontaneous emission (SASE) from high-gain X-ray free-electron lasers (XFEL) that produce ultra-short pulses with broad-band chaotic spectra. This report is based on discussions of scientific opportunities enabled by an XFELO during a workshop held at SLAC on June 29 - July 1, 2016

physics.ins-det↗

arXiv2018

Effect of Anisotropic Hybridization in YbAlB$_4$ Probed by Linear Dichroism in Core-Level Hard X-ray Photoemission Spectroscopy

We have probed the crystalline electric-field ground states of pure $|J = 7/2, J_z = \pm 5/2\rangle$ as well as the anisotropic $c$-$f$ hybridization in both valence fluctuating systems $α$- and $β$-YbAlB$_4$ by linear polarization dependence of angle-resolved core level photoemission spectroscopy. Interestingly, the small but distinct difference between \abyb was found in the polar angle dependence of linear dichroism, indicating the difference in the anisotropy of $c$-$f$ hybridization which may be essential to a heavy Fermi liquid state in $α$-YbAlB$_4$ and a quantum critical state in $β$-YbAlB$_4$.

cond-mat.str-el↗

arXiv2018

Linear dichroism in angle-resolved core-level photoemission spectra reflecting 4f ground-state symmetry of strongly correlated cubic Pr compounds

We report experimentally observed linear dichroism in angle-resolved core-level photoemission spectra of PrIr2Zn20 and PrB6 in cubic symmetry. The different anisotropic 4f charge distributions between the compounds due to the crystalline-electric-field splitting are responsible for the difference in the linear dichroism, which has been verified by spectral simulations with the full multiplet theory for a single-site Pr3+ ion in cubic symmetry. The observed linear dichroism and polarization-dependent spectra in two different photoelectron directions for PrIr2Zn20 are reproduced by theoretical analysis for the Gamma_3 ground state, whereas those of the Pr 3d and 4d core levels indicate the Gamma_5 ground state for PrB6.

cond-mat.str-el↗

arXiv2018

Microscope for X-ray orbital angular momentum imaging

Orbital angular momentum (OAM) of photons is carried upon the wave front of an optical vortex and is important in physics research due to its fundamental degree of freedom. As for the interaction with materials, the optical OAM was shown to be transferred to the valence electron based on modified selection rules where a single ion is carefully aligned to the center of a vortex [Schmiegelow et al.(2016)]. We here demonstrate an elaborate way of extracting the distributed OAMs in the two-dimensional x-ray wave field at the exit-face of the specimen by a vorticity-sensitive microscopy, which detects vorticity in the reciprocal-space wave field downstream of the optical vortices. This method enables us to measure the distributed topological charges and OAMs by a single image with the wide field of view over 300 $μ$m. Among various wavelength, the research of x-ray OAM is especially interesting since it could be closely related to the predicted OAM-induced x-ray dichroism [Veenendaal et al.(2007)].

physics.app-ph↗

arXiv2017

Optimal Investment and Pricing in the Presence of Defaults

We consider the optimal investment problem when the traded asset may default, causing a jump in its price. For an investor with constant absolute risk aversion, we compute indifference prices for defaultable bonds, as well as a price for dynamic protection against default. For the latter problem, our work complements Sircar & Zariphopoulou (2007), where it is implicitly assumed the investor is protected against default. We consider a factor model where the asset's instantaneous return, variance, correlation and default intensity are driven by a time-homogenous diffusion X taking values in an arbitrary region E. We identify the certainty equivalent with a semi-linear degenerate elliptic partial differential equation with quadratic growth in both function and gradient. Under a minimal integrability assumption on the market price of risk, we show the certainty equivalent is a classical solution. In particular, our results cover when X is a one-dimensional affine diffusion and when returns, variances and default intensities are also affine. Numerical examples highlight the relationship between the factor process and both the indifference price and default insurance. Lastly, we show the insurance protection price is not the default intensity under the dual optimal measure.

q-fin.MF↗

arXiv2017

Single-Shot 3D Diffractive Imaging of Core-Shell Nanoparticles with Elemental Specificity

We report 3D coherent diffractive imaging of Au/Pd core-shell nanoparticles with 6 nm resolution on 5-6 femtosecond timescales. We measured single-shot diffraction patterns of core-shell nanoparticles using very intense and short x-ray free electron laser pulses. By taking advantage of the curvature of the Ewald sphere and the symmetry of the nanoparticle, we reconstructed the 3D electron density of 34 core-shell structures from single-shot diffraction patterns. We determined the size of the Au core and the thickness of the Pd shell to be 65.0 +/- 1.0 nm and 4.0 +/- 0.5 nm, respectively, and identified the 3D elemental distribution inside the nanoparticles with an accuracy better than 2%. We anticipate this method can be used for quantitative 3D imaging of symmetrical nanostructures and virus particles.

physics.ins-det↗

arXiv2015

Evidence for Gamma_8 Ground-State Symmetry of Cubic YbB12 Probed by Linear Dichroism in Core-Level Photoemission

We have successfully observed linear dichroism in angle-resolved Yb3+ 3d5/2 core-level photoemission spectra for YbB12 in cubic symmetry. Its anisotropic 4f charge distribution due to the crystal-field splitting is responsible for the linear dichroism, which has been verified by spectral simulations using ionic calculations with the full multiplet theory for a single-site Yb3+ ion in cubic symmetry. The observed linear dichroism as well as the polarization-dependent spectra in two different photoelectron directions for YbB12 are quantitatively reproduced by theoretical analysis for the Gamma_8 ground state, indicating the Gamma_8 ground-state symmetry for the Yb3+ ions mixed with the Yb2+ state.

cond-mat.str-el↗

arXiv2015

Observation of Rapid Change of Crystalline Structure during the Phase Transition of the Palladium-Hydrogen System

We performed an X-ray diffraction experiment while palladium bulk absorbed and desorbed hydrogen to investigate the behavior of the crystalline lattice during the phase transition between the $α$ phase and $β$ phase. Fast growth of $β$ phase was observed around x=0.1 and x=0.45 of PdH$_x$. In addition, slight compression of the lattice at high hydrogen concentration and increase in the lattice constant and the line width of the $α$ phase after a cycle of absorption and desorption of hydrogen was observed. These behavior correlated with the change in the sample length, which may infer that the change in shape was related to the phase transition.

cond-mat.mtrl-sci↗

arXiv2014

Probing Strongly Correlated 4f-Orbital Symmetry of the Ground State in Yb Compounds by Linear Dichroism in Core-Level Photoemission

We show that the strongly correlated 4f-orbital symmetry of the ground state is revealed by linear dichroism in core-level photoemission spectra as we have discovered for YbRh2Si2 and YbCu2Si2. Theoretical analysis tells us that the linear dichroism reflects the anisotropic charge distributions resulting from crystalline electric field. We have successfully determined the ground-state 4f symmetry for both compounds from the polarization-dependent angle-resolved core-level spectra at a low temperature well below the first excitation energy. The excited-state symmetry is also probed by temperature dependence of the linear dichroism where the high measuring temperatures are of the order of the crystal-field-splitting energies.

cond-mat.str-el↗

arXiv2013

Single-shot 3D structure determination of nanocrystals with femtosecond X-ray free electron laser pulses

Coherent diffraction imaging (CDI) using synchrotron radiation, X-ray free electron lasers (X-FELs), high harmonic generation, soft X-ray lasers, and optical lasers has found broad applications across several disciplines. An active research direction in CDI is to determine the structure of single particles with intense, femtosecond X-FEL pulses based on diffraction-before-destruction scheme. However, single-shot 3D structure determination has not been experimentally realized yet. Here we report the first experimental demonstration of single-shot 3D structure determination of individual nanocrystals using ~10 femtosecond X-FEL pulses. Coherent diffraction patterns are collected from high-index-faceted nanocrystals, each struck by a single X-FEL pulse. Taking advantage of the symmetry of the nanocrystal, we reconstruct the 3D structure of each nanocrystal from a single-shot diffraction pattern at ~5.5 nm resolution. As symmetry exists in many nanocrystals and virus particles, this method can be applied to 3D structure studies of such particles at nanometer resolution on femtosecond time scales.

physics.optics↗

arXiv2010

Polaronic behavior of photoelectron spectra of Fe3O4 revealed by both hard X-ray and extremely low energy photons

Hard X-ray and extremely low energy bulk-sensitive photoelectron spectroscopy has been performed in the temperature range of 100-330 K for Fe3O4. In the high temperature phase just above the Verwey transition, the intensity at the Fermi level (EF) is still negligible, but it increases gradually with further increasing the temperature (250 K, 330 K) in consistence with the temperature dependence of the conductivity. The spectral behaviors near EF with temperature are well explained by the model, which takes the polaron effect into account.

cond-mat.str-el↗

arXiv2010

Light-Induced Atomic Desorption for loading a Sodium Magneto-Optical Trap

We report studies of photon-stimulated desorption (PSD), also known as light-induced atomic desorption(LIAD), of sodium atoms from a vacuum cell glass surface used for loading a magneto-optical trap (MOT). Fluorescence detection was used to record the trapped atom number and the desorption rate. We observed a steep wavelength dependence of the desorption process above 2.6 eV photon energy, a result significant for estimations of sodium vapor density in the lunar atmosphere. Our data fit well to a simple model for the loading of the MOT dependent only on the sodium desorption rate and residual gas density. Up to 3.7x10^7 Na atoms were confined under ultra-high vacuum conditions, creating promising loading conditions for a vapor cell based atomic Bose-Einstein condensate of sodium.

physics.atom-ph↗

arXiv2008

Quantitative Imaging of Single, Unstained Viruses with Coherent X-rays

Since Perutz, Kendrew and colleagues unveiled the structure of hemoglobin and myoglobin based on X-ray diffraction analysis in the 1950s, X-ray crystallography has become the primary methodology used to determine the 3D structure of macromolecules. However, biological specimens such as cells, organelles, viruses and many important macromolecules are difficult or impossible to crystallize, and hence their structures are not accessible by crystallography. Here we report, for the first time, the recording and reconstruction of X-ray diffraction patterns from single, unstained viruses. The structure of the viral capsid inside a virion was visualized. This work opens the door for quantitative X-ray imaging of a broad range of specimens from protein machineries, viruses and organelles to whole cells. Moreover, our experiment is directly transferable to the use of X-ray free electron lasers, and represents a major experimental milestone towards the X-ray imaging of single macromolecules.

physics.bio-ph↗

arXiv2007

Recoil effects of photoelectrons in a solid

High energy resolution C 1$s$ photoelectron spectra of graphite were measured at the excitation energy of 340, 870, 5950 and 7940eV using synchrotron radiation. On increasing the excitation energy, i.e., increasing kinetic energy of the photoelectron, the bulk origin C 1$s$ peak position shifts to higher binding energies. This systematic shift is due to the kinetic energy loss of the high-energy photoelectron by kicking the atom, and is clear evidence of the recoil effect in photoelectron emission. It is also observed that the asymmetric broadening increases for the higher energy photoelectrons. All these recoil effects can be quantified in the same manner as the Mössbauer effect for $γ$-ray emission from nuclei embedded in crystals.

cond-mat.other↗

arXiv2004

Electronic Structure of Strained Manganite Thin Films with Room Temperature Ferromagnetism Investigated by Hard X-ray Photoemission Spectroscopy

We report the bulk sensitive Hard X-ray (hv=5.95keV) core level photoemission spectroscopy to investigate the intrinsic electronic structure of strained (La0.85Ba0.15)MnO3 thin films. In a 20nm thick well-strained film with strongly enhanced ferromagnetism, a new sharp satellite peak appeared at the low energy site of the Mn 2p3/2 main peak, whereas a broader signal was observed for the unstrained film with 300nm thickness. Cluster calculations revealed that the intensity corresponded to the density of the state at the Fermi level relating to the magnitude of the ferromagnetic order. The satellite intensity also agreed quantitatively with the square of the magnetization.

cond-mat.str-el↗