Searcharxiv⌕ Search

arXiv subjects

Thiago R. de Oliveira

Publications and source records attributed to Thiago R. de Oliveira.

At least 19 recordsLinked to original sources

When Isolated Quantum Systems Appear Classical

The emergence of classical behavior and the origin of thermal equilibrium are two central problems in the foundations of physics. In the standard accounts, both phenomena are typically explained through interactions with an external environment: decoherence suppresses quantum interference, while coupling to a thermal bath drives relaxation toward equilibrium. Over the last decades, however, it has become clear that equilibration and thermalization can arise even in fully isolated quantum systems, in the operational sense that the expectation values of relevant observables remain close to equilibrium values for most of the time. Here, we ask whether the same intrinsic equilibration mechanism can also account for the emergence of classical behavior. Using rigorous bounds on equilibration in closed systems, we derive sufficient conditions under which a time-evolved pure state becomes, for most times, operationally indistinguishable from a classical mixture associated with a chosen physical property. We identify two complementary routes to such operational classicality: either the chosen property almost commutes with the system Hamiltonian or the observables used to probe the system lose access to the remaining coherence after equilibration. Our results show that classical behavior need not be confined to the energy basis and may emerge even when substantial coherence remains present in the equilibrium state. This establishes a direct connection between two foundational questions: the origin of thermalization in isolated quantum systems and the quantum-to-classical transition

quant-ph↗

Gauge-invariant thermodynamics of a finite-time quantum Otto engine

We investigate a finite-time quantum Otto engine within the framework of gauge-invariant quantum thermodynamics, using the Lipkin-Meshkov-Glick model as the working medium. In this formulation, thermodynamic quantities are defined on equivalence classes of thermodynamically indistinguishable states, leading naturally to gauge-invariant notions of work, heat, entropy, and efficiency. We derive explicit expressions for these quantities and show that the usual work performed during the unitary strokes decomposes into an invariant contribution, associated with changes in the instantaneous energy spectrum and populations, and a coherent contribution arising from finite-time quantum coherences. This decomposition induces the corresponding splittings of engine efficiency and entropy production, providing a geometric interpretation of finite-time irreversibility and clarifying the role of coherence in work extraction. By analyzing the cycle's dependence on driving speed and system size, we identify the engine's operating region and investigate the influence of criticality. We show that crossing the critical region substantially reduces the parameter space in which the cycle operates as a heat engine. At the same time, whenever the engine condition remains satisfied, the discrepancy between the conventional and gauge-invariant descriptions becomes strongly suppressed, indicating that the gauge-invariant sector predominantly carries the extracted work. These results establish a direct connection between gauge-invariant thermodynamics, finite-time irreversibility, and work extraction in many-body quantum thermal machines.

quant-ph↗

Emergence of Thermodynamics from Equilibration in Isolated Quantum Systems

Understanding how macroscopic thermodynamic behavior emerges from microscopic quantum dynamics remains an open problem. While equilibration of quantum observables is well established, thermodynamics also relies on variables not directly associated with linear operators, but which are defined instead as functions of expectation values. Whether and how such derived quantities inherit equilibration properties is an open question. Here, we establish that any continuously differentiable function of equilibrating expectation values also equilibrates. We apply this result to a bipartite isolated system, showing that the entropy and conjugate variables of each subsystem -- defined through Jaynes' maximum entropy principle -- equilibrate. Moreover, with the assumption that their equilibrium properties depend solely on local conserved quantities, we show the dynamical maximization of the total entropy, enforcing equality of conjugate variables across subsystems. These results provide a direct dynamical justification for entropy maximization and the emergence of thermodynamic equilibrium conditions, showing that fundamental principles of thermodynamics follow from the unitary evolution of quantum systems.

quant-ph↗

Necessity of entanglement for the typicality argument in statistical mechanics

Typicality arguments replace the postulated mixed state ensembles of statistical mechanics with pure states sampled uniformly at random, explaining why most microstates of large systems exhibit thermal behavior. This paradigm has been revived in quantum contexts, where entanglement is deemed essential, but no clear quantitative link between entanglement structure and typicality has been established. Here, we study pure quantum states with controlled multipartite entanglement and show that when entanglement grows with system size $N$, fluctuations in macroscopic observables decay exponentially with $N$, whereas if entanglement remains finite, one recovers only the classical $1/\sqrt{N}$ suppression. Our work thus provides a quantitative connection between entanglement structure and the emergence of typicality, demonstrating that entanglement is crucial for thermalization in small quantum systems but unnecessary to justify equilibrium in macroscopic ensembles. This unifies classical and quantum foundations of statistical mechanics by pinpointing exactly when and why entanglement matters.

quant-ph↗

Equilibration and the eigenstate thermalization hypothesis as limits to observing macroscopic quantum superpositions

Macroscopic quantum superpositions are widely believed to be unobservable because large systems cannot be perfectly isolated from their environments. Here, we show that even under perfect isolation, intrinsic unitary dynamics in generic many-body systems, as analyzed through the eigenstate thermalization hypothesis and random matrix theory, can suppress the observable signatures of macroscopic coherence. Using the Greenberger-Horne-Zeilinger (GHZ) state as a representative example, we demonstrate that while fully correlated measurements can initially distinguish a macroscopic superposition from its corresponding classical mixture, generic many-body evolution renders them operationally indistinguishable for most times. By analyzing both distinguishability measures and established quantifiers of macroscopic quantumness, we find that equilibration not only hides coherence from accessible observables but also suppresses the corresponding signatures of macroscopic quantumness, in particular within the additive-local framework considered here. These results identify unitary thermalization, independent of environmental decoherence, as a fundamental mechanism that limits the observation of macroscopic quantum effects.

quant-ph↗

Sensing ac fields with quantum many-body scars

Quantum many-body scars (MBS) exhibit weak ergodicity breaking and long-lived coherent dynamics within an otherwise thermal spectrum. We investigate their metrological properties using the quantum Fisher information (QFI), focusing on estimating the amplitude of a weak AC field in the PXP model. We show that the approximately uniform energy spacing of the scar tower enables collective resonant processes when the driving frequency matches integer multiples of the scar gap, resulting in a quadratic-in-time growth of the QFI over an extended time window. We analyze how the connectivity induced by different probe operators shapes sensing performance and demonstrate that staggered magnetization leads to a more favorable growth of the QFI with system size than homogeneous magnetization. Through frequency scanning and finite-size analysis, we characterize the scaling of the QFI with the number of particles. Finally, we develop a single-tower approximation under resonant driving, deriving a compact analytical expression that captures the time dependence and system-size scaling of the QFI. Our results establish how to leverage structured non-ergodic dynamics in quantum sensing protocols.

quant-ph↗

A finite-resources description of a measurement process and its implications for the "Wigner's Friend" scenario

Quantum mechanics started out as a theory to describe the smallest scales of energy in Nature. After a hundred years of development it is now routinely employed to describe, among others, quantum computers with thousands of qubits. This tremendous progress turns the debate of foundational questions into a technological imperative. In what follows we introduce a model of a quantum measurement process that consistently includes the impact of having access only to finite resources when describing a macroscopic system, like a measurement apparatus. Leveraging modern tools from equilibration of closed systems and typicality, we show how the measurement collapse can be seen as an effective description of a closed dynamics, of which we do not know all its details. Our model is then exploited to address the ``Wigner Friend Scenario'', and we observe that an agreement is reached when both Wigner and his friend acknowledge their finite resources perspective and describe the measurement process accordingly.

quant-ph↗

Foundation of statistical mechanics under even more experimentally realistic conditions

Understanding how macroscopic systems exhibit irreversible thermal behavior has been a long-standing challenge, first brought to prominence by Boltzmann. Recent advances have established rigorous conditions for isolated quantum systems to equilibrate to a maximum entropy state, contingent upon weak assumptions. These theorems, while powerful, apply for a sudden quench. However, natural processes involve finite-time perturbations or quenches, which raises a crucial question: Can these systems still equilibrate under more realistic, finite-time dynamics? In this work, we extend the established results to account for finite-time quenches, demonstrating that even under finite-time perturbations, the system will equilibrate provided it populates many significant energy levels. While the mathematical proof is more intricate than in the instantaneous case, the physical conclusion remains the same: sufficient perturbation leads to equilibration. Our results provide a broader and more physically realistic framework for understanding thermalization in isolated quantum systems

quant-ph↗

Smooth Crossover Between Weak and Strong Thermalization using Rigorous Bounds on Equilibration of Isolated Systems

It is usually expected and observed that non-integrable isolated quantum systems thermalize. However, for some non-integrable spin chain models, in a numerical study, initial states with oscillations that persisted for some time were found and the phenomenon was named weak thermalization. Later, it was argued that such oscillations will eventually decay suggesting that weak thermalization was about time scales and not the size of the fluctuations. Nevertheless, the analyses of the size of the fluctuations were more qualitative. Here, using exact diagonalization we analyze how the size of the typical fluctuation, after long enough time for equilibration to happen, scales with the system size. For that, we use rigorous mathematical upper bounds on the equilibration of isolated quantum systems. We show that weak thermalization can be understood to be due to the small effective dimension of the initial state. Furthermore, we show that the fluctuations decay exponentially with the system size for both weak and strong thermalization indicating no sharp transitions between these two regimes.

quant-ph↗

Canonical typicality under general quantum channels

With the control of ever more complex quantum systems becoming a reality, new scenarios are emerging where generalizations of the most foundational aspects of statistical quantum mechanics are imperative. In such experimental scenarios the often natural correspondence between the particles that compose the system and the relevant degrees-of-freedom might not be observed. In the present work we employ quantum channels to define generalized subsystems, which should capture the pertinent degrees-of-freedom, and obtain their associated canonical state. Moreover, we show that generalized subsystems also display the phenomena of canonical typicality, i.e., the generalized subsystem description generated from almost any microscopic pure state of the whole system will behave similarly as the corresponding canonical state. In particular we demonstrate that the property regulating the emergence of the canonical typicality behavior is the entropy of the channel used to define the generalized subsystem.

quant-ph↗

Work and efficiency fluctuations in a quantum Otto cycle with idle levels

We study the performance of a quantum Otto heat engine with two spins coupled by a Heisenberg interaction, taking into account not only the mean values of work and efficiency but also their fluctuations. We first show that, for this system, the output work and its fluctuations are directly related to the magnetization and magnetic susceptibility of the system at equilibrium with either heat bath. We analyze the regions where the work extraction can be done with low relative fluctuation for a given range of temperatures, while still achieving an efficiency higher than that of a single spin system heat engine. In particular, we find that, due to the presence of `idle' levels, an increase in the inter-spin coupling can either increase or decrease fluctuations, depending on the other parameters. In all cases, however, we find that the relative fluctuations in work or efficiency remain large, implying that this microscopic engine is not very reliable as a source of work.

quant-ph↗

Quantum Stirling engine based on dinuclear metal complexes

Low-dimensional metal complexes are versatile materials with tunable physical and chemical properties that make these systems promising platforms for caloric applications. In this context, this work proposes a quantum Stirling cycle based on a dinuclear metal complex as a working substance. The results show that the quantum cycle operational modes can be managed when considering the change in the magnetic coupling of the material and the temperature of the reservoirs. Moreover, magnetic susceptibility can be used to characterize the heat exchanges of each cycle step and, therefore, its performance. As a proof of concept, the efficiency of the heat engine is obtained from experimental susceptibility data. These results open doors for studying quantum thermodynamic cycles by using metal complexes; and further the development of emerging quantum technologies based on these advanced materials.

quant-ph↗

Nonadiabatic coupled-qubit Otto cycle with bidirectional operation and efficiency gains

We study a quantum Otto cycle that uses a 2-qubit working substance whose Hamiltonian does not commute with itself at different times during unitary strokes. We investigate how the cycle responds to the loss of quantum adiabaticity when these strokes are operated with a finite duration. We find that qualitative features such as the possibility of counter-rotating cycles operating as heat engines, or a cycle efficiency that can increase with a decrease in the temperature difference between the baths, are resilient even to highly nonadiabatic strokes. However, cycle efficiency rapidly decreases, although it can still remain above the standard Otto value for small degrees of quantum nonadiabaticity.

quant-ph↗

Efficiency gain and bidirectional operation of quantum engines with decoupled internal levels

We present a mechanism for efficiency increase in quantum heat engines containing internal energy levels that do not couple to the external work sink. The gain is achieved by using these levels to channel heat in a direction opposite to the one dictated by the second law. No quantum coherence, quantum correlations or ergotropy are required. A similar mechanism allows the engine to run in reverse and still produce useful work. We illustrate these ideas using a simple quantum Otto cycle in a coupled-spin system. We find this engine also exhibits other counterintuitive phenomenology. For example, its efficiency may increase as the temperature difference between the heat baths decreases. Conversely, it may cease to operate if the hotter bath becomes too hot or the colder bath too cold.

quant-ph↗

Measurement-based quantum heat engine in a multilevel system

We compare quantum Otto engines based on two different cycle models: a two-bath model, with a standard heat source and sink, and a measurement-based protocol, where the role of heat source is played by a quantum measurement. We furthermore study these cycles using two different `working substances': a single qutrit (spin-1 particle) or a pair of qubits (spin-1/2 particles) interacting via the XXZ Heisenberg interaction. Although both cycle models have the same efficiency when applied on a single-qubit working substance, we find that both can reach higher efficiencies using these more complex working substances, by exploiting the existence of `idle' levels, i.e., levels that do not shift while the spins are subjected to a variable magnetic field. Furthermore, with an appropriate choice of measurement, the measurement-based protocol becomes more efficient than the two-bath model.

quant-ph↗

Relative purity, speed of fluctuations, and bounds on equilibration times

We discuss the local equilibration of closed systems using the relative purity, a paradigmatic information-theoretic distinguishability measure that finds applications ranging from quantum metrology to quantum speed limits. First we obtain an upper bound on the average size of the fluctuations on the relative purity: it depends on the effective dimension resembling the bound obtained with the trace distance. Second, we investigate the dynamics of relative purity and its rate of change as a probe of the speed of fluctuations around the equilibrium. In turn, such speed captures the notion of how fast some nonequilibrium state approaches the steady state under the local nonunitary dynamics, somehow giving the information of the quantum speed limit towards the equilibration. We show that the size of fluctuations depends on the quantum coherences of the initial state with respect to the eigenbasis of the Hamiltonian, also addressing the role played by the correlations between system and reservoir into the averaged speed. Finally, we have derived a family of lower bounds on the time of evolution between these states, thus obtaining an estimate for the equilibration time at the local level. These results could be of interest to the subjects of equilibration, quantum speed limits, and also quantum metrology.

quant-ph↗

Violation of the Bell inequality in quantum critical random spin-$1/2$ chains

We investigate the entanglement and nonlocality properties of two random XX spin-1/2 critical chains, in order to better understand the role of breaking translational invariance to achieve nonlocal states in critical systems. We show that breaking translational invariance is a necessary but not sufficient condition for nonlocality, as the random chains remain in a local ground state up to a small degree of randomness. Furthermore, we demonstrate that the random dimer model does not have the same nonlocality properties of the translationally invariant chain, even though they share the same universality class for a certain range of randomness.

quant-ph↗

Equilibration time scales in closed many-body quantum systems

We show that the physical mechanism for the equilibration of closed quantum systems is dephasing, and identify the energy scales that determine the equilibration timescale of a given observable. For realistic physical systems (e.g those with local Hamiltonians), our arguments imply timescales that do not increase with the system size, in contrast to previously known upper bounds. In particular we show that, for such Hamiltonians, the matrix representation of local observables in the energy basis is banded, and that this property is crucial in order to derive equilibration times that are non-negligible in macroscopic systems. Finally, we give an intuitive interpretation to recent theorems on equilibration time-scale.

quant-ph↗