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Tsutomu Nojima

Publications and source records attributed to Tsutomu Nojima.

At least 19 recordsLinked to original sources

Imaging and characterization of spontaneous vortices in a proximity-induced superconductor

Observation of spontaneous symmetry breaking is crucial for understanding continuous second-order phase transitions from disordered to ordered states, which often leads to the formation of topological defects. In superconductors, such topological defects manifest as quantized vortices. However, the formation and observation of spontaneous vortices in a uniform superconductor are challenging because extremely rapid cooling (>108 K/s) is generally required for that purpose. Here we conducted scanning superconducting quantum interference device microscope (SSM) measurements on an MgB2-based proximity-induced superconductor, an intrinsically inhomogeneous system. In this system, individual superconducting domains will reach internal equilibrium independently during cooling and choose their own phase before the global phase coherence is established via the long-range proximity coupling. The SSM measurements demonstrate that vortices are nucleated spontaneously even at a relatively slow cooling rate (~0.2 K/s). We also find that the vortices with different polarities, sizes, and shapes appear stochastically under near-zero-field conditions. The geometry of the spontaneous vortices is more extended than that of the field-induced Abrikosov vortices. Magnetic field profile analysis based on the London model elucidates that penetration depths of the extended vortices are anomalously large, exceeding several micrometers. This unusual morphology of the spontaneous vortices most likely imprints the information that is frozen at the moment of vortex formation. Our findings not only provide insights into the local phase differences present in the early stage of the phase transition in this proximity-induced superconducting system, but they also shed insights into the structure, formation, and stabilization of topological defects in highly disordered and inhomogeneous superconducting systems.

cond-mat.supr-con

Thickness dependence of diode efficiency in superconducting Fe(Se,Te)/FeTe thin-film heterostructure devices

The superconducting diode effect (SDE) is a nonreciprocal transport phenomenon, in which the superconducting critical current density depends on the polarity of the current. It has attracted recent attention because of its potential applications to a rectifier without energy dissipation. While SDE has been observed in a wide range of superconducting materials with broken inversion symmetry as well as thin-film heterostructures, the microscopic origin linking structural inversion asymmetry of electronic band, spin-orbit interaction, and vortex pinning remains to be clarified. In this study, we investigate SDE in Fe(Se,Te)/FeTe heterostructure devices as a function of the superconducting Fe(Se,Te) layer thickness tFST to elucidate the role of structural inversion asymmetry on the vortex-induced SDE. We find that the SDE efficiency monotonically increases with increasing tFST, which can be understood by considering that the band bending in the bulk Fe(Se,Te) layer induces the structural inversion asymmetry and thus, the Rashba spin-orbit interaction. In addition, we demonstrate almost 100% rectification for the Fe(Se,Te)/FeTe heterostructure devices in half- and full-wave oscillation configurations. Our findings point out the importance of structural architecture for realization of highly efficient SDE devices based on superconducting thin-film heterostructures.

cond-mat.supr-con

Systematic evolution of superconducting pairing strength and Seebeck coefficients in correlated infinite-layer La$_{1-x}$Sr$_x$NiO$_2$

The recently discovered superconducting infinite-layer nickelates offer a novel platform to explore an exotic pairing mechanism in multi-band systems towards high-temperature superconductivity and associated rich quantum phases, contrasting with cuprates. Here, we show that infinite-layer (La,Sr)NiO$_2$ exhibits strong-coupling superconductivity, resilient to in-plane magnetic fields exceeding 47 T at optimal doping - more than twice the Pauli limit for conventional BCS superconductors. This violation becomes pronounced towards the underdoped regime, implying an intriguing evolution of pairing glue. The unexpected observation of positive Seebeck coefficients in this regime indicates the presence of nontrivial electron correlations. Furthermore, our comprehensive investigation across the superconducting dome reveals that the evolution of (thermo)electric normal-state properties - specifically, the sign changes of the Hall and Seebeck coefficients - coincide with the evolution of superconducting anisotropy and pairing strength. This demonstrates a definitive link between electron correlations and strong-coupling superconductivity in (La,Sr)NiO$_2$, contributing to a unified framework for understanding unconventional superconductivity.

cond-mat.supr-con

A scaling relation of vortex-induced rectification effects in a superconducting thin-film heterostructure

Supercurrent rectification, nonreciprocal response of superconducting properties sensitive to the polarity of bias and magnetic field, has attracted growing interest as an ideal diode. While the superconducting rectification effect is a consequence of the asymmetric vortex pinning, the mechanisms to develop its asymmetric potentials have been a subject of ongoing debate, mainly focusing on microscopic breaking of spatial inversion symmetry and macroscopic imbalance of the sample structure. Here, we report on comparative study of the superconducting diode effect and nonreciprocal resistance in a superconducting Fe(Se,Te)/FeTe heterostructure. In normal state, we observe finite nonreciprocal resistance as a hallmark of the spin-orbit interaction with structural inversion asymmetry. In the superconducting state, we find that the strongly enhanced nonreciprocal coefficient in transition regime is directly coupled to the superconducting diode efficiency through a universal scaling law, indicating the role of spin-momentum-locked state on the asymmetric pinning potential. Our findings, providing a unified picture of the superconducting rectification, pave the way for functionalizing superconducting diode devices.

cond-mat.supr-con

Direct Observation of Vortices and Antivortices Generation in Phase-Separated Superconductor Sn-Pb Solder

Quantized vortices in type-II superconductors provide insights into the mechanisms of superconductivity. However, the generation of antivortices, characterized by magnetization antiparallel to the external magnetic field, remains less understood. In this study, we investigate Sn-Pb solder, a superconductor with phase-separated Sn and Pb phases, and report the observation of both vortices and antivortices. Scanning SQUID (superconducting quantum interference device) microscopy revealed the presence of both vortices and antivortices, while magneto-optical imaging demonstrated flux avalanches. Our results demonstrate that Sn in Sn-Pb solder behaves as a type-II superconductor when magnetic fluxes are trapped, despite bulk Sn being a type-I superconductor with a transition temperature (TcSn) of 3.7 K. Our findings suggest that the size effect and proximity effect with Pb contribute synergistically to induce type-II superconductivity in Sn Notably, vortices were observed at temperatures as high as 5 K, exceeding the bulk TcSn. Furthermore, the interplay between the type-I superconducting Pb phase and the type-II superconducting Sn phase results in the generation of antivortices, providing a mechanism to accommodate excess magnetic flux. This study shed light on new research on composites combining type-I and type-II superconductors.

cond-mat.supr-con

Metallisation of the Mott Insulator Ca$_{2}$RuO$_{4}$ using Electric Double-Layer Gating

To verify whether the Mott insulator Ca2RuO4 can be switched by applying electric-field alone, regardless of current flow, we employ metallisation using electric double-layer gating (EDLG). The resistance change due to EDLG occurs only when positive gate-voltage above +3 V is applied. The amplitude of the reduction, reaching ~97% of the initial value, is difficult to interpret as surface metallisation and is likely related to structural change in bulk.

cond-mat.str-el

Gate-controlled BCS-BEC crossover in a two-dimensional superconductor

The Bardeen-Cooper-Schrieffer (BCS) condensation and the Bose-Einstein condensation (BEC) are the two extreme limits of the ground state of the paired fermion systems. We report crossover behavior from the BCS condensation to the BEC realized in the two-dimensional (2D) superconductor, electron doped layered material ZrNCl. The phase diagram, established by simultaneous experiments of resistivity and tunneling spectra under the ionic gating, demonstrates the pseudogap phase at the low doping regime. In the low carrier density limit, $T_{\rm BKT}$ (Berezinskii-Kosterlitz-Thouless transition temperature for 2D superconductors) scales as $T_{\rm BKT}/T_{\rm F} = 0.12$, where $T_{\rm F}$ is the Fermi temperature, which is consistent with the theoretical upper bound expected in the BCS-BEC crossover regime. The present results indicate that the gate-doped semiconductor provides an ideal platform for the 2D BCS-BEC crossover without any added complexity, such as magnetic orders and density waves.

cond-mat.supr-con

Dynamical vortex phase diagram of 2D superconductivity in gated MoS2

Recent discoveries of two-dimensional (2D) superconductors have uncovered various new aspects of physical properties including vortex matter. In this paper, we report transport properties and a dynamical phase diagram at zero magnetic field in ion-gated MoS2. In addition to the universal jump in the current-voltage characteristic showing unambiguous evidence of the Berezinskii-Kosterlitz-Thouless (BKT) transition, we observed multiple peaks in the temperature- and current-derivative of the electrical resistance, based on which a dynamical phase diagram in the current-temperature plane was constructed. We found current-induced dynamical states of vortex-antivortex pairs, containing that with the phase slip line. Also, we present a global phase diagram of vortices in gated MoS2 which captures the nature of vortex matter of clean 2D superconductors.

cond-mat.supr-con

Quantum and classical ratchet motions of vortices in a 2D trigonal superconductor

Dynamical behavior of vortices plays central roles in the quantum phenomena of two-dimensional (2D) superconductors. Quantum metallic state, for example, showing an anomalous temperature-independent resistive state down to low-temperatures, has been a common subject in recently developed 2D crystalline superconductors, whose microscopic origin is still under debate. Here, we unveil a new aspect of the vortex dynamics in a noncentrosymmetric 2D crystalline superconductor of MoS$_{2}$ through the nonreciprocal transport measurement. The second harmonic resistance $R^{2w}$ at low temperature with high current indicates the classical vortex flow accompanying the ratchet motion. Furthermore, we found that $R^{2w}$ is substantially suppressed in the quantum metallic state with low current region, allowing identification of the quantum and classical ratchet motions of vortices by the magnitude of the second harmonic generation. This suggests that nonreciprocal transport measurement can be a powerful tool to probe the vortex dynamics in noncentrosymmetric 2D superconductors.

cond-mat.supr-con

Gate-controlled low carrier density superconductors: Toward the two-dimensional BCS-BEC crossover

Superconductivity mostly appears in high carrier density systems and sometimes exhibits common phase diagrams in which the critical temperature Tc continuously develops with carrier density. Superconductivity enhanced in lightly doped regime has seldom been reported, although it is an ideal direction towards the crossover between Bardeen-Cooper-Schrieffer (BCS) and Bose-Einstein condensate (BEC) limits, where the behavior of Cooper pairs changes dramatically. Here we report transport properties and superconducting gaps in single-crystalline lithium-intercalated layered nitrides (LixHfNCl and LixZrNCl) down to the low-doping regime, enabled by a combination of ionic gating device and tunneling spectroscopy. Upon the reduction of doping, both systems display the increase of Tc, up to 24.9 K especially in LixHfNCl, with the concomitant enhancement of two-dimensionality leading to a pseudogap state below 35.5 K as well as the increase of superconducting coupling strengths 2D/kBTc reaching 5.9. Such behavior in the carrier density region as low as 10^20 cm-3 indicates that lightly doped two-dimensional superconductors exhibit the unprecedented nature that is distinct from that in conventional superconductors, and offer a new route to access BCS-BEC crossover.

cond-mat.supr-con

Quantum phase transitions in highly crystalline two-dimensional superconductors

Superconductor-insulator transition is one of the remarkable phenomena driven by quantum fluctuation in two-dimensional (2D) systems. Such a quantum phase transition (QPT) was investigated predominantly on highly disordered thin films with amorphous or granular structures using scaling law with constant exponents. Here, we provide a totally different view of QPT in highly crystalline 2D superconductors. According to the magneto-transport measurements in 2D superconducting ZrNCl and MoS2, we found that the quantum metallic state commonly observed at low magnetic fields is converted via the quantum Griffiths state to the weakly localized metal at high magnetic fields. The scaling behavior, characterized by the diverging dynamical critical exponent (Griffiths singularity), indicates that the quantum fluctuation manifests itself as superconducting puddles, in marked contrast with the thermal fluctuation. We suggest that an evolution from the quantum metallic to the quantum Griffiths state is generic nature in highly crystalline 2D superconductors with weak pinning potentials.

cond-mat.supr-con

Macroscale three-dimensional proximity effect in disordered normal/superconductor nanocomposites

Recently, interest in Superconductor (S)-Normal (N) interfaces was renewed by the observation of exotic proximity effects in various systems, including S/semiconductor, S/ferromagnet, and S/topological insulator. In general, the proximity effect is enhanced in transparent weak links where coherent Andreev reflection is possible. Also, it is a common knowledge that the proximity effect is, by definition, is a localized phenomenon that can only be active in each S/N interface region. However, here we show that a three-dimensional (3D) macroscale proximity effect is realized in few-micrometer-thick MgO/Mg2Si/MgB2 nanocomposite layers with atomically smooth and clean heterointerfaces. We found from scanning superconducting quantum interference device (SQUID) microscopy measurements that a normal region of more than 100x100 square micrometers totally undergoes transition into a bulk-like superconducting state although the normal host originally contains less than ~10 vol % of superconducting MgB2 nanograins in a dispersed manner. In the proximity-induced superconducting region, vortex formation and annihilation processes as well as vortex-free Meissner regions were observed with respect to applied fields in a similar manner as Abrikosov vortices in type-II superconductors. Furthermore, we found that the induced superconducting layers exhibit an anisotropic magnetization behavior, in consistent with the formation of the large-scale superconducting coherence. This unusually extended proximity effect suggests that disorder-induced interaction and coupling of Andreev bound states, which are coherent superposition of time reversed electron hole pairs, is realized in the nanocomposite. Thus, the present results not only expand the limit of the proximity effect to bulk scales, but also provides a new route to obtain a proximity-induced superconducting state from disordered systems.

cond-mat.supr-con

Highly crystalline 2D superconductors

Recent technological advances in controlling materials have developed methods to produce idealized two-dimensional (2D) electron systems such as heterogeneous interfaces, molecular-beam-epitaxy (MBE) grown atomic layers, exfoliated thin flakes and field-effect devices. These 2D electron systems are highly-crystalline with less disorder in common, some of which indeed show sheet resistance more than one order of magnitude lower even in atomic layers or single layers than that of conventional amorphous/granular thin films. Here, we present a review on the recent developments of highly-crystalline 2D superconductors and a series of unprecedented physical properties discovered in these systems. In particular, we highlight the quantum metallic state (or possible metallic ground state), the quantum Griffiths phase in out-of-plane magnetic fields, and the superconducting state maintained in anomalously large in-plane magnetic fields, which were observed in exfoliated 2D materials, MBE-grown atomic-layer thin films and electric-double-layer (ion-gated) interfaces. These phenomena are discussed on the basis of weakened disorder and/or broken spatial inversion symmetry. These novel aspects suggest that highly-crystalline 2D systems are promising platforms for exploring new quantum physics and superconductors.

cond-mat.supr-con

Microscopic examinations of Co valences and spin states in electron-doped LaCoO$_{3}$

We studied the Co valences and spin states in electron-doped LaCo$_{1-y}$Te$_{y}$O$_3$ by measuring x-ray absorption spectra and electron spin resonance. The low-temperature insulating state involves the low-spin Co$^{3+}$ ($S=0$) and the high-spin Co$^{2+}$ state, which is described by $g=3.8$ and $j_{\rm eff}=1/2$. The results, in concurrence with the electron-hole asymmetry confirmed in electrical resistivity, coincide with a spin-blockade phenomenon in this system. Further, we discuss the $g$ factor in terms of the strong covalent-bonding nature and consider multiple origins of this phenomenon.

cond-mat.str-el

Superconductivity protected by spin-valley locking in ion-gated MoS2

Symmetry-breaking has been known to play a key role in noncentrosymmetric superconductors with strong spin-orbit-interaction (SOI). The studies, however, have been so far mainly focused on a particular type of SOI, known as Rashba SOI, whereby the electron spin is locked to its momentum at a right-angle, thereby leading to an in-planar helical spin texture. Here we discuss electric-field-induced superconductivity in molybdenum disulphide (MoS2), which exhibits a fundamentally different type of intrinsic SOI manifested by an out-of-plane Zeeman-type spin polarization of energy valleys. We find an upper critical field of approximately 52 T at 1.5 K, which indicates an enhancement of the Pauli limit by a factor of four as compared to that in centrosymmetric conventional superconductors. Using realistic tight-binding calculations, we reveal that this unusual behaviour is due to an inter-valley pairing that is symmetrically protected by Zeeman-type spin-valley locking against external magnetic fields. Our study sheds a new light on the interplay of inversion asymmetry with SOI in confined geometries, and its unprecedented role in superconductivity.

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Commensurate and Incommensurate Vortex States Confined in Mesoscopic Triangles of Weak Pinning Superconducting Thin Films

We report on the direct observation of vortex states confined in equilateral and isosceles triangular dots of weak pinning amorphous superconducting thin films with a scanning superconducting quantum interference device microscope. The observed images illustrate not only pieces of a triangular vortex lattice as commensurate vortex states, but also incommensurate vortex states including metastable ones. We comparatively analyze vortex configurations found in different sample geometries and discuss the symmetry and stability of commensurate and incommensurate vortex configurations against deformations of the sample shape.

cond-mat.supr-con

Metallic ground state in an ion-gated two-dimensional superconductor

Recently emerging two-dimensional (2D) superconductors in atomically thin layers and at heterogeneous interfaces are attracting growing interest in condensed matter physics. Here, we report that ion-gated ZrNCl surface, exhibiting a dome-shaped phase diagram with a maximum critical temperature of 14.8 kelvin, behaves as a superconductor persisting to the 2D limit. The superconducting thickness estimated from the upper critical fields is ~ 1.8 nanometers, which is thinner than one-unit-cell. The majority of the vortex phase diagram down to 2 kelvin is occupied by a metallic state with a finite resistance, owing to the quantum creep of vortices caused by extremely weak pinning and diminishing disorder. Our findings highlight the potential of electric-field-induced superconductivity, establishing a new platform for accessing quantum phases in clean 2D superconductors.

cond-mat.supr-con

Quenched metastable vortex states in Sr2RuO4

Sr2RuO4, a leading-candidate spin-triplet superconductor and a highly anisotropic quasi-two-dimensional type-II superconductor, provides unique opportunity to study unconventional as well as conventional vortex phases. To investigate its vortex-matter phases, we studied the ac susceptibility of Sr2RuO4 for fields parallel to the RuO2 plane by adapting two different thermal processes: In addition to the ordinary field sweep (FS) process, we newly employed the "each-point field cooling (EPFC)" process, in which the superconductivity is once thermally destroyed before collecting the data. We find that the ac susceptibility signal substantially changes with the EPFC process.This result indicates that we succeed in inducing new metastable vortex states by the EPFC process.We also find a new field scale H*1, below which the FS and EPFC processes provide the same value of the ac susceptibility. This new field scale suggests a liquid-like vortex state in the low-field region.

cond-mat.supr-con