Searcharxiv⌕ Search

arXiv subjects

V. S. Sastry

Publications and source records attributed to V. S. Sastry.

14 recordsLinked to original sources
arXiv2010

Superconductivity in Ru substituted BaFe2-xRuxAs2

The occurrence of bulk superconductivity at ~22 K is reported in polycrystalline samples of BaFe2-xRuxAs2 for nominal Ru content in the range of x=0.75 to 1.125. A systematic suppression of the spin density wave transition temperature (TSDW) precedes the appearance of superconductivity in the system. A phase diagram is proposed based on the measured TSDW and superconducting transition temperature (TC) variations as a function of Ru composition. Band structure calculations, indicate introduction of electron carriers in the system upon Ru substitutiom. The calculated magnetic moment on Fe shows a minimum at x=1.0, suggesting that the suppression of the magnetic moment is associated with the emergence of superconductivity. Results of low temperature and high field Mossbauer measurements are presented. These indicate weakening of magnetic interaction with Ru substitution

cond-mat.supr-con↗
arXiv2007

Nitrogen ion beam synthesis of InN in InP (100) at elevated temperature

InN phase is grown in crystalline InP(100) substrates by 50 keV N+ implantation at an elevated temperature of 400 deg C followed by annealing at 525 deg C in N2 ambient. Crystallographic structural and Raman scattering studies are performed for the characterization of grown phases. Temperature- and power-dependent photoluminescence studies show direct band-to-band transition peak ~1.06 eV at temperatures <=150K. Implantations at an elevated temperature with a low ion beam current and subsequent low temperature annealing step are found responsible for the growth of high-quality InN phase.

cond-mat.mtrl-sci↗
arXiv2007

Bulk ferromagnetism and large changes in photoluminescence intensity by magnetic field in $β$-Ga$_2$O$_3$

In this letter we report observation of room temperature ferromagnetism in bulk Ga$_2$O$_3$ . We also observe large (10-60%) increase/decrease in photoluminescence. In the red(700 nm wavelength)/blue(500 nm), with the application of small magnetic field(0.4 Tesla). We argue, that ferromagnetism occurs entirely due to chains of oxygen(O(3) sites, Fig. 5) vacancies. We propose a simple model to explain, origin and location of moment, formation of ferromagnetic dislocation needles, and strong increase/decrease ofred/blue photoluminescence intensity with magnetic field.

cond-mat.mtrl-sci↗
arXiv2005

Double metal-insulator transitions and magnetoresistance:An intrinsic feature of Ru substituted La(0.67)Ca(0.33)MnO(3)

In this paper, we examine the possible influence of extrinsic factors on the electrical and magnetotransport of La(0.67)Ca(0.33)Mn(1-x)Ru(x)O(3) (x < 0.10). These results not only exclude the extrinsic factors, but establishes the fact that the metal transitions both exhibiting MR is intrinsic to Ru substituted La(0.67)Ca(0.33)MnO(3) and the system. These results substantiate our hypothesis that Ru substituted system undergoes a magnetic phase separation involving the co-existence of two ferromagnetic-metallic phases in its ground state.

cond-mat.mtrl-sci↗
arXiv2005

Ti substituted La(0.67)Ca(0.33)MnO(3) ortho-perovskites: Dominant role of local structure on the electrical transport and magnetic properties

We discuss the effects of local structure on the electrical transport and magnetic properties of La(0.67)Ca(0.33)Mn(1-x)Ti(x)O(3) system.Based on the intercomparison of the structure, transport and magnetic properties of the Mn site substituted La(0.67)Ca(0.33)MnO(3) with isovalent diamagnetic and paramagnetic ions, we argue that local structural effects have a decisive role to play, compared to the local spin coupling effects, in the ferromagnetic-metallic ground state of the CMR manganites

cond-mat.str-el↗
arXiv2005

Drastic ground state changes induced by Ni substitution in NaxCoO2

We report on the effect of Ni substitution at the Co site on the physical properties of NaxCoO2 system by investigating the series NaxCo1-yNiyO2 (x=0.75, 0<y<0.15). An upturn in the resistivity is observed in all Ni substituted samples as the temperature is lowered, suggestive of the occurrence of a Metal-Insulator Transition (MIT). The temperature at which this transition occurs increases with Ni content. The temperature dependence of the resistivity in the metallic region in the Ni substituted samples shows a T2 dependence, which is qualitatively different from that observed in the pristine sample. The evolution of the Fano asymmetry parameter, extracted by analyzing the lineshape of the IR active in-plane Co-O mode, both as a function of Ni concentration and temperature corroborates the occurrence of the MIT. It is argued that the progressive substitution of the Co4+ ions with Ni increases the probability of double occupancy and therefore the on-site Coulomb interaction energy leading to a shift in the thermodynamically driven MIT to higher temperatures.

cond-mat.str-el↗
arXiv2004

Structure, Tranport and Magnetism of La(0.67)Ca(0.33)Mn(1-x)Ta(x)O(3)

For the first time,we report the effect of pentavalent subtitution at the Mn site of La(0.67)Ca(0.33)MnO(3). The ferromagnetic -metallic ground state modifies to a cluster-glass insulator beyond x=0.03. The observed suppression in the transition temperatures (39K/at.%) is the largest reported for the Mn site subtituted manganites. We argue that charge state(valence) of the substituent has a dominant role in affecting the ferromagnetic - metallic ground state of CMR manganites.

cond-mat.mtrl-sci↗
arXiv2004

Blue luminescence of Au nanoclusters embedded in silica matrix

Photoluminescence study using the 325 nm He-Cd excitation is reported for the Au nanoclusters embedded in SiO2 matrix. Au clusters are grown by ion beam mixing with 100 KeV Ar+ irradiation on Au [40 nm]/SiO2 at various fluences and subsequent annealing at high temperature. The blue bands above ~3 eV match closely with reported values for colloidal Au nanoclusters and supported Au nanoislands. Radiative recombination of sp electrons above Fermi level to occupied d-band holes are assigned for observed luminescence peaks. Peaks at 3.1 eV and 3.4 eV are correlated to energy gaps at the X- and L-symmetry points, respectively, with possible involvement of relaxation mechanism. The blue shift of peak positions at 3.4 eV with decreasing cluster size is reported to be due to the compressive strain in small clusters. A first principle calculation based on density functional theory using the full potential linear augmented plane wave plus local orbitals (FP-LAPW+LO) formalism with generalized gradient approximation (GGA) for the exchange correlation energy is used to estimate the band gaps at the X- and L-symmetry points by calculating the band structures and joint density of states (JDOS) for different strain values in order to explain the blueshift of ~0.1 eV with decreasing cluster size around L-symmetry point.

cond-mat.mtrl-sci↗
arXiv2003

Tuning of the superconducting and ferromagnetic transitions by Cu doping for Ru in GdSr2RuCu2O8

In order to explore the possibility of tuning superconducting and ferromagnetic transitions by Cu doping (for Ru) in GdSr2RuCu2O8, we have carried out synthesis and characterization of GdSr2Ru{1-x}Cu{2+x)O8 (x = 0, 0.05, 0.1, 0.2) and studied their physical properties. Coexistence of superconductivity and ferromagnetism is observed in all the Cu doped samples studied here. The zero field susceptibility data suggests formation of a spontaneous vortex phase. Cu doping decreases the ferromagnetic Curie temperature, whereas the superconducting transition temperature increases until an optimal concentration x~0.1. This reflects an increase in hole transfer to the CuO2 planes and reduction of ferromagnetic order within the ruthenate layers.

cond-mat.supr-con↗
arXiv2002

Study of Normal and Superconducting States of MgCNi_3 upon Fe and Co Substitution and External Pressure

Results of our study on the superconducting and normal state properties of the recently discovered superconductor MgCNi_3, the effect of Fe and Co substitution at the Ni site and the effect of pressure are reported. It is shown that a two band model provides a consistent interpretation of the temperature dependence of the normal state resistance and the Hall constant. Whereas band structure calculations suggest an increase in T_c upon partial substitution of Ni with Fe and Co, Co substitution quenches superconductivity and Fe substitution leads to an increase followed by a decrease in T_c. The observed variation of T_c may be explained in terms of a competition between increase in T_c due to increase in density of states and a decrease due to spin fluctuations. Based on these results, it is suggested that the spin fluctuations are weaker in Fe doped samples as compared to the Co doped ones. An initial decrease in T_c (and the normal state resistance) followed by an increase is observed on application of pressure. The decrease in T_c for small applied pressures can be understood in terms of the decrease in the density of states at the Fermi level. The subsequent increase in T_c with pressure is due to a lattice softening or a structural phase transition, consistent with the band structure calculations. It is conjectured that suppression of spin fluctuations by pressure may also be responsible for the observed increase in T_c at higher pressures.

cond-mat.supr-con↗
arXiv2001

Infrared absorption in superconducting MgB2

Infrared absorption measurements in the range of 125 to 700 cm^(-1) have been carried out as a function of temperature upto 5 K in MgB2. The absorption spectrum is characterised by a broad band centred at 485 cm^{-1}, with shoulders at 333 and 387 cm^{-1}. Studies on the temperature dependence of absorption, indicate that these modes initially harden with the lowering of temperature, and this trend is arrested at ~ 100 K, below which they soften. Further, in the case of the mode at 333 cm^{-1}, there is a distinct softening associated with the superconducting transition at 39 K. The implications of these experimental results in the context of superconductivity in MgB2 are discussed.

cond-mat.supr-con↗
arXiv1998

Low temperature hcp to monoclinic structural transition in solid C$_{70}$ : Is there an intermediate phase?"

We follow the structural transformation in solid C$_{70}$ from the high temperature hcp to a low temperature monoclinic phase using x-ray diffraction studies at controlled cooling-rates from 0.0033 to 0.42 K/min. Rapid cooling of the sample gives the signature of a two-step transformation which disappears when the system is transformaed quasi-statically. These experimental results can be rationalised using a simple mean field, Langevin dynamical theory using a free energy functional with minima corresponding to the parent and two competing product phases such that one of these product phases remains metastable throughout. The implication of our results on the existence of the intermediate phase in the sequence, hcp-dhcp-monoclinic, of structural transitions in solid C$_{70}$ with the lowering of temperature is discussed.

cond-mat.mtrl-sci↗
arXiv1998

Low-temperature structural model of hcp solid C$_{70}$

We report intermolecular potential-energy calculations for solid C_${70}$ and determine the optimum static orientations of the molecules at low temperature; we find them to be consistent with the monoclinic structural model proposed by us in an earlier report [Solid State Commun. {\bf 105), 247 (1998)]. This model indicates that the C_5 axis of the molecule is tilted by an angle $\approx$18^o from the monoclinic b axis in contrast with the molecular orientation proposed by Verheijen {\it et al.} [J. Chem. Phys. {\bf 166}, 287 (1992)] where the C_5 axis is parallel to the monoclinic b axis. In this calculation we have incorporated the effective bond charge Coulomb potential together with the Lennard-Jones potential between the molecule at the origin of the monoclinic unit cell and its six nearest neighbours, three above and three below. The minimum energy configuration for the molecular orientations turns out to be at $θ$=18^o, $ϕ$=8^o, and $ψ$=5^o, where $θ$, $ϕ$, and $ψ$ define the molecular orientations.

cond-mat↗