arXiv subjects

Vivien Parmentier

Publications and source records attributed to Vivien Parmentier.

At least 37 records · Page 2Linked to original sources

arXiv2026

Horizontal transport as a source of disequilibrium chemistry on the nightside of a hot exoplanet

Hot Jupiters have temperature gradients of several hundreds of degrees between their permanent day and nightsides. In equilibrium, the primary carbon reservoir is expected to transition from CO on the dayside to CH4 on the nightside. Theory predicts that the atmospheric circulation, characterised by km/s winds, can advect chemical species from the dayside to the nightside faster than the time needed for the CO-to-CH4 chemical reaction to reach equilibrium. However direct evidence of this process has, so far, remained elusive, partly because it is often degenerate with other processes, such as vertical mixing or non-stellar elemental abundances. Here, we present observational evidence for such day-to-night transport of chemical species by observing both the dayside and the nightside of the hot Jupiter NGTS-10A b with the JWST/NIRSpec instrument. We constrain the presence of H2O and CO with similar abundances on both the dayside and nightside. Our observations are compatible with a solar-composition atmosphere at chemical equilibrium on the dayside, but indicative of disequilibrium chemistry for the nightside as it is significantly depleted in CH4 compared to equilibrium chemistry predictions. We further show that the lack of CH4 on the planet's nightside cannot be attributed to non-solar elemental abundances or to vertical mixing mechanisms and must therefore be due to horizontal chemical quenching. Our study shows the fundamental role atmospheric transport plays in shaping the distribution of chemical species on exoplanet atmospheres.

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arXiv2026

The Days Drag On on WASP-121 b: Interpreting its NIRISS Spectroscopic Phase Curve with General Circulation Models

Ultra-hot Jupiters present extreme atmospheric phenomena not found in the Solar System. These planets' daysides experience strong temperature inversions, molecular species (including H2) dissociate, and magnetism disrupts their atmospheric circulation. On their nightsides H2 can recombine and clouds may form. Spectroscopic phase curves let us measure these spatially inhomogeneous conditions, which can then be interpreted with three-dimensional (3-D) models. In this work we compare the JWST/NIRISS spectroscopic phase curve of the ultra-hot Jupiter WASP-121 b to state-of-the-art 3-D models with varying modeling assumptions, including the aforementioned physical phenomena. We demonstrate the importance of accurately accounting for the planet's radius in comparison between data and models, as it changes the implied overall planetary emission. We find that the 3-D models predict planet emission $\sim$12% higher than observed, contributing to a continued tension between measured and predicted hot Jupiter albedos. We identify multiple pieces of evidence that confirm a strong source of drag operating in this planet's atmosphere. In addition, the nightside emission spectrum is devoid of strong absorption features, which may be best explained by nightside clouds. One feature of the dataset that is not matched by the 3-D models is a trend of increasing eastward phase offset with decreasing wavelength, for wavelengths shorter than $\sim$1.4 \textmu m. This result is not consistent with reflection from dayside clouds, nor can it be explained by removing atmospheric opacity sources. Our analysis highlights the complexities in generating 3-D models and interpreting observations of ultra-hot Jupiters in the JWST era.

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arXiv2026

The tale of the 3 planets: 3D cloud feedback enhances the spectral diversity of warm Jupiters

JWST has shown a large diversity in warm Jupiter spectra, despite only small variations in the planetary parameters. However, the main driver of this diversity remains unclear. We aim to identify the mechanisms responsible for the spectral difference of three warm Jupiter-size exoplanets observed by JWST: whereas WASP-80b appears mostly cloud-free, both WASP-107b and WASP-69b have spectra dominated by clouds. We model each planet using the same framework, ADAM (formerly SPARC/MITgcm), which solves for the interactions among cloud transport, radiative transfer, and atmospheric circulation in 3D. We investigate the role of three condensate species, Na$_2$S, KCl, and MgSiO$_3$, and four particle sizes (0.1, 1, 5, and 10 $μ$m). Clouds settle deeper in the atmosphere of the higher-gravity planet WASP-80b than in WASP-107b, reproducing their spectral difference naturally. For WASP-107b, three clouds can reproduce the NIRCam observations: 5 $μ$m Na$_2$S, 1 $μ$m KCl, and 5 $μ$m MgSiO$_3$ models. However, these cannot match the scattering slope observed at shorter wavelengths in NIRISS and the possible silicate feature in the MIRI bandpass, suggesting a multi-modal distribution of clouds. Our model predicts that small silicate particles should be homogeneously distributed and thus cannot account for the difference between the two limb spectra in the MIRI bandpass. Finally, applying the same model to WASP-69b does not yield a partially cloudy dayside solution that fits the emission spectra, as proposed in a previous study. Coupling among 3D circulation, clouds, and radiative transfer can enhance the spectral diversity of warm Jupiter exoplanets, particularly through changes in cloudiness with gravity. The combination of multi-phase, wide-wavelength coverage and models that couple clouds, circulation, and radiative transfer is key to advancing our understanding of these new objects.

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arXiv2026

Cloudy solutions for the clear skies of WASP-80b: 3D cloud feedback on the atmosphere and spectra of a warm Jupiter

Close-in warm Jupiters orbiting M dwarf stars are expected to exhibit diverse atmospheric chemistry, with clouds playing a key role in shaping their albedo, heat distribution, and spectral properties. We study WASP-80b, a warm Jupiter orbiting an M dwarf star, using the latest JWST panchromatic emission and transmission spectra to comprehensively characterise its atmosphere, including cloud coverage, chemical composition, and particle sizes, and compare the observations with predictions from the general circulation models (GCMs). We used a GCM, ADAM (ADvanced Atmospheric MITgcm, formerly known as SPARC/MITgcm), combined with the latest JWST data to study the atmosphere of WASP-80b. A cloud module with radiatively active, tracer-based clouds was integrated with the GCM to study the effects on the atmosphere and the spectrum. We find that the emission and transmission spectra of WASP-80b are only compatible with cloudless atmospheres or with clouds composed of sufficiently large particles, namely Na$_2$S ($\geq 10 μ$m), KCl ($\geq 1 μ$m), and MgSiO$_3$ ($\geq 5 μ$m). For these large-particle cloud cases, efficient gravitational settling confines the clouds to deeper atmospheric layers, resulting in weak spectral signatures. Smaller particles are ruled out due to their strong radiative feedback on the atmospheric structure. Overall, our results suggest that WASP-80b's atmosphere is either effectively cloud-free or contains clouds composed of large, settled particles whose opacity has little impact on the observable atmosphere. This underscores the importance of particle size and vertical cloud distribution in interpreting exoplanet spectra. Future observations at shorter wavelengths may help distinguish between large-particle cloud scenarios and a truly cloudless atmosphere.

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arXiv2025

Challenges in the detection of gases in exoplanet atmospheres

Claims of detections of gases in exoplanet atmospheres often rely on comparisons between models including and excluding specific chemical species. However, the space of molecular combinations available for model construction is vast and highly degenerate. Only a limited subset of these combinations is typically explored for any given detection. As a result, apparent detections of trace gases risk being artifacts of incomplete modeling rather than robust identification of atmospheric constituents, especially in the low signal-to-noise regime. Using the sub-Neptune K2-18 b as a case study, we show that recent biosignature claims vanish when the model space is expanded, with numerous alternatives providing equally good or better fits. We demonstrate that the significance of a claimed detection relies on the choice of models being compared, and that model preference does not in itself imply the presence of a specific gas. We recommend treating model comparisons instead as relative adequacy tests, which should be supported by theoretical predictions and complementary metrics of statistical significance in order to attribute a signal to a particular gas.

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arXiv2025

A Comparison of 1D and 3D Exoplanet Atmosphere Model Grids: ScCHIMERA and the SPARC/MITgcm

Inferring the properties of transiting exoplanet atmospheres relies on comparing models to spectroscopic observations. Atmosphere models, however, make a range of assumptions, from one-dimensional (1D, varying with altitude) radiative-convective equilibrium (RCE) to three-dimensional (3D) general circulation models (GCMs). The goal of this investigation is to determine the causes of differences in dayside thermal emission spectra resulting from 3D-GCMs (using SPARC/MITgcm) and 1D-RCE models (using ScCHIMERA). We conduct a one-to-one comparison of 1D-RCE models and 3D-GCMs with the same outgoing bolometric thermal flux over a grid of equilibrium temperatures, gravities, metallicities, and rotation periods. Each 1D-RCE model assumes heat redistribution in the planet's atmosphere consistent with that in the corresponding 3D-GCM's photosphere. Comparing corresponding models, the dayside average pressure-temperature (PT) structures can be broken into four vertical regions, each influencing wavelength-dependent differences in their spectra. Furthermore, the dayside average 3D-GCM PTs for planets with Teq=1400 K exhibit a temperature inversion, whereas corresponding 1D-RCE models do not. We find that spectral differences between 1D-RCE models and 3D-GCMs with the same parameters decrease for hotter planets because the spectral shapes more closely resemble blackbodies. To a lesser extent, spectral differences increase for planets with longer rotation periods because of smaller day-night temperature contrasts in the photosphere. Finally, we compare spectral differences to realistic observational uncertainties from JWST with the NIRISS SOSS, NIRSpec G395H, and MIRI LRS instrument modes. We find that 1D-RCE models and 3D-GCMs with the same parameters can produce dayside spectral differences larger than JWST's uncertainty, potentially biasing data-model inferences.

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arXiv2025

A Stellar Magnesium to Silicon ratio in the atmosphere of an exoplanet

The elemental compositions of exoplanets encode information about their formation environments and internal structures. While volatile ratios such as carbon-to-oxygen (C/O) are used to trace formation location, the rock-forming elements - magnesium (Mg), silicon (Si), and iron (Fe) - govern interior mineralogy and are commonly assumed to reflect the host star's abundances. Yet this assumption remains largely untested. Ultra-hot Jupiters, gas-giant exoplanets with dayside temperatures above 3000 K, provide rare access to refractory elements that remain gaseous. Here we present high-resolution thermal emission spectroscopy of the exoplanet WASP-189b (Teq = 3354^{+27}_{-34} K) obtained with the Immersion Grating Infrared Spectrometer (IGRINS) on Gemini South. We detect neutral iron (Fe I), magnesium (Mg I), silicon (Si I), water (H_2O), carbon monoxide (CO), and hydroxyl (OH) at signal-to-noise ratios exceeding 4, and retrieve their elemental abundances. We show that the Mg/Si, Fe/Mg, and Si/Fe ratios are consistent with stellar values, while the refractory-to-volatile ratio is enhanced by roughly a factor of ~2. These findings demonstrate that giant-planet atmospheres can preserve stellar-like rock-forming ratios, providing an empirical validation of the stellar-proxy assumption that underpins planetary composition and formation models across exoplanet systems.

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arXiv2025

No TiO detected in the hot Neptune-desert planet LTT-9779 b in reflected light at high spectral resolution

LTT-9779 b is an inhabitant of the hot Neptune desert and one of only a few planets with a measured high albedo. Characterising the atmosphere of this world is the key to understanding what processes dominate in creating the hot Neptune desert. We aim to characterise the reflected light of LTT-9779 b at high spectral resolution to break the degeneracy between clouds and atmospheric metallicity. This is key to interpreting its mass loss history which may illuminate how it kept its place in the desert. We use the high resolution cross-correlation spectroscopy technique on four half-nights of ESPRESSO observations in 4-UT mode (16.4-m effective mirror) to constrain the reflected light spectrum of LTT-9779 b. We do not detect the reflected light spectrum of LTT-9779 b despite these data having the expected sensitivity at the level 100 ppm. Injection tests on the post-eclipse data indicate that TiO should have been detected for a range of different equilibrium chemistry models. Therefore this non-detection suggests TiO depletion in the western hemisphere however, this conclusion is sensitive to temperature which impacts the chemistry in the upper atmosphere and the reliability of the line list. Additionally, we are able to constrain the top of the western cloud deck to $P_{\text{top, western}}<10^{-2.0}$ bar and the top of the eastern cloud deck $P_{\text{top, eastern}}<10^{-0.5}$ bar, which is consistent with the predicted altitude of MgSiO$_3$ and Mg$_2$SiO$_4$ clouds from JWST NIRISS/SOSS. While we do not detect the reflected light spectrum of LTT-9779 b, we have verified that this technique can be used in practice to characterise the high spectral resolution reflected light of exoplanets so long as their spectra contain a sufficient number of deep spectral lines. Therefore this technique may become an important cornerstone of exoplanet characterisation with the ELT and beyond.

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arXiv2025

Horizontal and vertical exoplanet thermal structure from a JWST spectroscopic eclipse map

Highly-irradiated giant exoplanets known as "ultra-hot Jupiters" are anticipated to exhibit large variations of atmospheric temperature and chemistry as a function of longitude, latitude, and altitude. Previous observations have hinted at these variations, but the existing data have been fundamentally restricted to probing hemisphere-integrated spectra, thereby providing only coarse information on atmospheric gradients. Here we present a spectroscopic eclipse map of an extrasolar planet, resolving the atmosphere in multiple dimensions simultaneously. We analyze a secondary eclipse of the ultra-hot Jupiter WASP-18b observed with the NIRISS instrument on JWST. The mapping reveals weaker longitudinal temperature gradients than were predicted by theoretical models, indicating the importance of hydrogen dissociation and/or nightside clouds in shaping global thermal emission. Additionally, we identify two thermally distinct regions of the planet's atmosphere: a "hotspot" surrounding the substellar point and a "ring" near the dayside limbs. The hotspot region shows a strongly inverted thermal structure due to the presence of optical absorbers and a water abundance marginally lower than the hemispheric average, in accordance with theoretical predictions. The ring region shows colder temperatures and poorly constrained chemical abundances. Similar future analyses will reveal three-dimensional thermal, chemical, and dynamical properties of a broad range of exoplanet atmospheres.

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arXiv2025

Heat Reveals What Clouds Conceal: Global Carbon & Longitudinally Asymmetric Chemistry on LTT 9779 b

LTT-9779 b is an ultra-hot Neptune (Rp ~ 4.7 Re, Mp ~ 29 Me) orbiting its Sun-like host star in just 19 hours, placing it deep within the "hot Neptune desert," where Neptunian planets are seldom found. We present new JWST NIRSpec G395H phase-curve observations that probe its atmospheric composition in unprecedented detail. At near-infrared wavelengths, which penetrate the high-altitude clouds inferred from previous NIRISS/SOSS spectra, thermal emission reveals a carbon-rich atmosphere with opacity dominated by carbon monoxide (CO) and carbon dioxide (CO2). Both species are detected at all orbital phases, with retrieved mixing ratios of 10^-1 for CO and 10^-4 for CO2, indicating a globally well-mixed reservoir of carbon-bearing gases. We also moderately detect water vapor (H2O) and tentatively detect sulfur dioxide (SO2), providing insight into its chemistry and possible photochemical production under intense stellar irradiation. From these detections we infer a carbon-to-oxygen ratio near unity (C/O ~ 1) and a metallicity exceeding 500X Solar, consistent with equilibrium chemistry predictions for high-temperature atmospheres. This enrichment raises the mean molecular weight, reducing atmospheric escape, and likely helps LTT-9779 b retain a substantial atmosphere despite extreme irradiation. Our findings show that LTT-9779 b survives where few planets can, maintaining a carbon-rich atmosphere in a region where hot Neptune-class worlds are expected to evaporate. This makes LTT-9779 b a valuable laboratory for studying atmospheric escape and chemical processes under extreme conditions, offering new insight into the survival of planets in the hot Neptune desert.

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arXiv2025

A High Geometric Albedo for LTT9779b Points Towards a Metal-rich Atmosphere and Silicate Clouds

Aims: In this work, we aim to confirm the high albedo of the benchmark ultrahot Neptune LTT9779b using 20 secondary eclipse measurements of the planet observed with CHEOPS. In addition, we perform a search for variability in the reflected light intensity of the planet as a function of time. Methods: First, we used the TESS follow-up data of LTT9779b from three sectors (2, 29, and 69) to remodel the transit signature and estimate an updated set of transit and ephemeris parameters, which were directly used in the modeling of the secondary eclipse lightcurves. This involved a critical noise-treatment algorithm, including sophisticated techniques such as wavelet denoising and Gaussian Process (GP) regression, to constrain noise levels from various sources. In addition to using the officially released reduced aperture photometry data from CHEOPS DRP, we also reduced the raw data using an independent PSF photometry pipeline, known as PIPE, to verify the robustness of our analysis. The extracted secondary eclipse lightcurves were modeled using the PYCHEOPS package, where we have detrended the background noise correlated with the spacecraft roll angle, originating from the inhomogeneous and asymmetric shape of the CHEOPS point spread function, using an N-order glint function. Results: Our independent lightcurve analyses have resulted in consistent estimations of the eclipse depths, with values of 89.9$\pm$13.7 ppm for the DRP analysis and 85.2$\pm$13.1 ppm from PIPE, indicating a high degree of statistical agreement. Adopting the DRP value yields a highly constrained geometric albedo of 0.73$\pm$0.11. No significant eclipse depth variability is detected down to a level of $\sim$37 ppm. Conclusions: Our results confirm that LTT9779b exhibits a strikingly high optical albedo, which substantially reduces the internal energy budget of the planet compared to more opaque...

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arXiv2025

A Precise Metallicity and Carbon-to-Oxygen Ratio for a Warm Giant Exoplanet from its Panchromatic JWST Emission Spectrum

WASP-80 b, a warm sub-Jovian (equilibrium temperature ~820 K, 0.5 Jupiter masses), presents an opportunity to characterize a rare gas giant exoplanet around a low-mass star. In addition, its moderate temperature enables its atmosphere to host a range of carbon and oxygen species (H$_2$O, CH$_4$, CO, CO$_2$, NH$_3$). In this paper, we present a panchromatic emission spectrum of WASP-80 b, the first gas giant around a late K/early M-dwarf star and the coolest planet for which the James Webb Space Telescope has obtained a complete emission spectrum spanning 2.4-12 $μ$m, including NIRCam F322W2 (2.4-4 $μ$m) and F444W (4-5 $μ$m), and MIRI LRS (5-12 $μ$m). We report confident detections of H$_2$O, CH$_4$, CO, and CO$_2$, and a tentative detection of NH$_3$. We estimate WASP-80 b's atmospheric metallicity and carbon-to-oxygen ratio and compare them with estimates for other gas giants. Despite the relative rarity of giant planets around low-mass stars, we find that WASP-80 b's composition is consistent with other hot gas giants, suggesting that the formation pathway of WASP-80 b may not be dissimilar from hot gas giants around higher-mass stars.

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arXiv2025

A Panchromatic Characterization of the Evening and Morning Atmosphere of WASP-107 b: Composition and Cloud Variations, and Insight into the Effect of Stellar Contamination

Limb-resolved transmission spectroscopy has the potential to transform our understanding of exoplanetary atmospheres. By separately measuring the transmission spectra of the evening and morning limbs, these atmospheric regions can be individually characterized, shedding light into the global distribution and transport of key atmospheric properties from transit observations alone. In this work, we follow up the recent detection of limb asymmetry on the exoplanet WASP-107 b (Murphy et al. 2024) by reanalyzing literature observations of WASP-107 b using all of JWST's science intruments (NIRISS, NIRCam, NIRSpec, and MIRI) to measure its limb transmission spectra from $\sim$1-12 $μ$m. We confirm the evening--morning temperature difference inferred previously and find that it is qualitatively consistent with predictions from global circulation models. We find evidence for evening--morning variation in SO$_2$ and CO$_2$ abundance, and significant cloud coverage only on WASP-107 b's morning limb. We find that the NIRISS and NIRSpec observations are potentially contaminated by occulted starspots, which we leverage to investigate stellar contamination's impact on limb asymmetry measurements. We find that starspot crossings can significantly bias the inferred evening and morning transmission spectra depending on when they occur during the transit, and develop a simple correction model which successfully brings these instruments' spectra into agreement with the uncontaminated observations.

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arXiv2025

The radiative effects of photochemical hazes on the atmospheric circulation and phase curves of sub-Neptunes

Measuring the atmospheric composition of hazy sub-Neptunes like GJ~1214b through transmission spectroscopy is difficult because of the degeneracy between mean molecular weight and haziness. It has been proposed that phase curve observations can break this degeneracy because of the relationship between mean molecular weight (MMW) and phase curve amplitude. However, photochemical hazes can strongly affect phase curve amplitudes as well. We present a large set of GCM simulations of the sub-Neptune GJ~1214b that include photochemical hazes with varying atmospheric composition, haze opacity and haze optical properties. In our simulations, photochemical hazes cause temperature changes of up to 200~K, producing thermal inversions and cooling deeper regions. This results in increased phase curve amplitudes and adds a considerable scatter to the phase curve amplitude--metallicity relationship. However, we find that if the haze production rate is high enough to significantly alter the phase curve, the secondary eclipse spectrum will exhibit either emission features or strongly muted absorption features. Thus, the combination of a white-light phase curve and a secondary eclipse spectrum can successfully distinguish between a hazy, lower MMW and a clear, high MMW scenario.

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arXiv2025

Clouds and Hazes in GJ 1214b's Metal-Rich Atmosphere

The sub-Neptune GJ 1214b has an infamously flat transmission spectrum, likely due to thick aerosols in its atmosphere. A recent JWST MIRI spectroscopic phase curve of GJ 1214 b added to this picture, suggesting a highly reflective and metal-rich atmosphere. Using a 3D General Circulation Model with both photochemical hazes and condensate clouds, we characterize how different aerosol types affect the atmospheric structure of GJ 1214 b and manifest in its spectroscopic phase curve. Additionally, we reanalyze the original GJ 1214 b JWST phase curve. The reanalysis shows a hotter nightside, similar dayside temperature, and a lower, but still elevated, Bond albedo (0.42 +/- 0.11) than the original results. We find that a scenario with both clouds and hazes is most consistent with the JWST phase curve. Reflective clouds or hazes are needed to explain the large Bond albedo, and hazes or a super-solar metallicity help account for the several hundred Kelvin day-night temperature difference measured by the phase curve.

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arXiv2025

Low 4.5 μm Dayside Emission Disfavors a Dark Bare-Rock scenario for the Hot Super-Earth TOI-431 b

The full range of conditions under which rocky planets can host atmospheres remains poorly understood, especially in the regime of close-in orbits around late-type stars. One way to assess the presence of atmospheres on rocky exoplanets is to measure their dayside emission as they are eclipsed by their host stars. Here, we present Spitzer observations of the 4.5 $μ$m secondary eclipses of the rocky super-Earth TOI-431 b, whose mass and radius indicate an Earth-like bulk composition (3.07 $\pm$ 0.35 M$_{\oplus}$, 1.28 $\pm$ 0.04 R$_{\oplus}$). Exposed to more than 2000 times the irradiation of Earth, dayside temperatures of up to 2400K are expected if the planet is a dark bare-rock without a significant atmosphere. Intriguingly, despite the strong stellar insolation, we measure a secondary eclipse depth of only 33 $\pm$ 22 ppm, which corresponds to a dayside brightness temperature of $1520_{-390}^{+360}$K. This notably low eclipse depth disagrees with the dark bare-rock scenario at the 2.5$σ$ level, and suggests either that the planet is surrounded by an atmosphere, or that it is a bare-rock with a highly reflective surface. In the atmosphere scenario, the low dayside emission implies the efficient redistribution of heat to the nightside, or by molecular absorption in the 4-5 $μ$m bandpass. In the bare-rock scenario, a surface composition made of a high-albedo mineral species such as ultramafic rock can lead to reduced thermal emission consistent with low eclipse depth measurement. Follow-up spectroscopic observations with the James Webb Space Telescope hold the key to constraining the nature of the planet.

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arXiv2025

Constraining the Scattered Light properties of LTT 9779 b Using HST/WFC3 UVIS

A planet's albedo is a fundamental property that sets its energy budget by dictating the fraction of incident radiation absorbed versus reflected back to space. Generally, optical eclipse observations have revealed the majority of hot, giant planets to have low albedos, indicating dayside atmospheres dominated by absorption instead of reflection. However, there are several exceptions to this rule, including the ultra-hot-Neptune LTT 9779b, which have been found to have high geometric albedos. We observed four eclipses of LTT 9779b with the G280 grism of the Hubble Space Telescope's WFC3 UVIS mode; targeting the scattering signatures of the cloud condensate species causing the planet's elevated reflectivity. However, we do not definitively detect the planet's eclipse in our observations, with injection-recovery tests yielding a 3-$σ$ upper limit of 113 ppm on the eclipse depth of LTT 9779b in the 0.2-0.8$μ$m waveband. We create reflectance spectrum grids for LTT 9779b's dayside using VIRGA/PICASO and compare to our UVIS limit, as well as previously published CHEOPS and TESS eclipse photometry. We find that silicate condensates are best able to explain LTT 9779b's highly-reflective dayside. Our forward model grids only enable weak constraints on vertical mixing efficiency, and suggest that, regardless of their particular composition, the clouds are likely composed of smaller and more reflective particles. Our work facilitates a deeper understanding of the reflectance properties of LTT 9779b as well as the UVIS spectroscopic mode itself, which will remain the community's primary access to UV wavelengths until next-generation telescopes like the Habitable Worlds Observatory.

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arXiv2025

A JWST Panchromatic Thermal Emission Spectrum of the Warm Neptune Archetype GJ 436b

GJ 436b is the archetype warm Neptune exoplanet. The planet's thermal emission spectrum was previously observed via intensive secondary eclipse campaigns with Spitzer. The atmosphere has long been interpreted to be extremely metal-rich, out of chemical equilibrium, and potentially tidally heated. We present the first panchromatic emission spectrum of GJ 436b observed with JWST's NIRCAM (F322W2 and F444W) and MIRI (LRS) instruments between 2.4 and 11.9 $μ$m. Surprisingly, the JWST spectrum appears significantly fainter around 3.6 $μ$m than that implied by Spitzer photometry. The molecular absorption features in the spectrum are relatively weak, and we only find tentative evidence of CO$_2$ absorption at 2$σ$ significance. Under the assumption of a day-side blackbody, we find $T_{\rm day}$=662.8$\pm$5.0 K, which is similar to the zero Bond albedo equilibrium temperature. We use it to obtain a 3$σ$ upper limit on the Bond albedo of $A_B{\le}$0.66. To understand the spectrum we employ 1D radiative-convective models but find that atmospheric constraints depend strongly on model assumptions. If thermochemical equilibrium is assumed, we find a cloudy metal-enriched atmosphere (metallicity $\ge$ 300$\times$solar). We employ 1D photochemical modeling to show that the observed spectrum is also consistent with a cloud-free, relatively lower-metallicity atmosphere (metallicity $\ge$ 80$\times$solar) with a cold internal temperature ($T_{\rm int}$$\sim$60 K). These are much lower metallicities and internal temperatures than inferences from Spitzer photometry. The low $T_{\rm day}$ and non-detection of transmission features at high spectral resolution does suggest a role for cloud opacity, but this is not definitive.

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