arXiv subjects

Vivien Parmentier

Publications and source records attributed to Vivien Parmentier.

At least 19 recordsLinked to original sources

arXiv2026

A parameterised approach to disequilibrium retrievals in the JWST era: Application to NIRCam observations of HD 189733b

Atmospheric retrievals are a widely used technique for inferring the physical and chemical properties of exoplanetary atmospheres from observed spectra. A common simplifying assumption in such analyses is that the atmosphere is in thermochemical equilibrium, which allows the use of precomputed chemical abundance grids as a function of pressure, temperature, metallicity ([M/H]), and carbon-to-oxygen ratio (C/O). However, exoplanet atmospheres often deviate from equilibrium, particularly at lower temperatures or in the presence of strong vertical mixing. In this work, we investigate the impact of disequilibrium chemistry on retrieval outcomes by generating synthetic James Webb Space Telescope (JWST) observations of HD\,189733\,b with varying strengths of vertical mixing. We demonstrate that assuming thermochemical equilibrium can lead to significant biases in the retrieved atmospheric parameters, including incorrect estimates of C/O and [M/H]. To address this, we incorporate transport-induced quenching of carbon and nitrogen-bearing species into the retrieval framework by allowing the quench pressures to be free parameters. We show that this approach recovers the correct bulk atmospheric properties in most cases. Finally, we apply our disequilibrium retrieval model to published JWST/NIRCam transmission observations of HD\,189733\,b and find tentative evidence for quenching. We also find tentative evidence for the photochemically active region of the atmosphere via a newly developed H$_2$S parameterisation, this is the first time this has been constrained in a hot Jupiter atmosphere.

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arXiv2026

Asymmetric nightside CO2 features, inefficient heat transport, and precise evolutionary constraints: Spectroscopic phase curves reveal the past and present of a white dwarf-brown dwarf binary

We present the first JWST phase curve of a white dwarf-brown dwarf binary, a NIRSpec PRISM observation of ZTFJ0038+2030. Short-period white dwarf-brown dwarf binaries provide unique laboratories to probe substellar atmospheres. Tidal locking drives hot Jupiter-like atmospheric dynamics in the brown dwarf. The system's formation history offers a window into planetary systems around post-main-sequence stars. We obtain a full-orbit phase curve of ZTF0038, including a total eclipse of the white dwarf, which enables us to separate the two components' emission throughout the entire orbit, and we model the brown dwarf's phase-resolved emission spectra using substellar atmosphere forward models and atmospheric retrievals. The PRISM spectrum covers ~80% of the brown dwarf's bolometric emission, enabling a nearly model-independent energy balance calculation, which yields a day-to-nightside heat transport efficiency of <10%. Inefficient heat redistribution is further supported by the phase curve shape and the nightside spectrum closely resembling non-irradiated mid-to-late T dwarfs. The spectroscopic phase curves reveal a stark nightside asymmetry associated with a strong CO2 absorption feature at 4.2 um, while the retrieved abundances indicate a longitudinally homogeneous distribution of CO2 as well as all other key species detected in the atmosphere. The precise internal luminosity measurement of the brown dwarf informs both the age of the WD-BD system (7.5-8.8 Gyr) and indicates a low common-envelope ejection efficiency. These data illustrate the exquisite opportunity to probe the three-dimensional processes of substellar atmospheres, connect substellar and exoplanet atmospheres, and probe the evolution of post-main-sequence planetary systems using WD-BDs.

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arXiv2026

Glossy Silicate Clouds on the Scorched Dayside of LTT9779b

Discovered deep within the "Neptunian desert", LTT9779b remains the only known ultra-hot Neptune, prompting significant speculation regarding its unique formation and evolutionary history. Its exceptionally high geometric albedo has previously been attributed either to the presence of clouds or to an extremely metal-rich atmosphere. Here, we present a comprehensive panchromatic analysis of its dayside atmosphere using JWST NIRISS and NIRSpec/G395H observations to characterize its atmospheric structure and composition. Leveraging the exceptional signal-to-noise ratio (S/N) in the observed spectra, we report a 3-to-5$\sigma$ detection of dayside clouds, with strong evidence for Mg$_2$SiO$_4$(s) (silicate) condensation. This constitutes the first statistically significant detection of clouds on the dayside of a Neptunian-mass exoplanet. We demonstrate that a highly reflective cloud deck, rather than an extremely high-metallicity atmosphere, is the most likely explanation for the planet's anomalously high optical albedo. Furthermore, our atmospheric retrievals yield robust detections of both CO ($\sim$4.88$\sigma$) and CO$_2$ ($\sim$8.76$\sigma$), while providing tentative constraints on the H$_2$O abundance and upper limits on SiO, TiO, and VO. Finally, our analysis places a robust constraint on the C/O ratio of 0.984 $\pm$ 0.019. This aligns LTT9779b with other known ultra-hot Jupiters exhibiting super-solar C/O ratios, suggesting a broader trend driven by the sequestration of oxygen-bearing condensates in ultra-hot atmospheres.

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arXiv2026

C, N, O, S, and photochemistry in a temperate giant planet orbiting a late M dwarf

We report the JWST NIRSpec/PRISM transit spectrum of TOI-6894b, an exceptional 420 K sub-Saturn that is the only known giant planet transiting a late M dwarf. Remarkably, both the light curve and the transit spectrum exhibit almost no stellar contamination. The spectrum is dominated by prominent absorption features from CH$_4$ and the photochemical product CS$_2$. For the first time in a transit spectrum, NH$_3$ is visually evident, while subtler features from H$_2$O, and CO$_2$ can also be seen. We significantly improve upon state-of-the-art photochemical reaction networks, and use our new network to run radiative-convective photochemical models at different metallicities. These models show that the spectrum--in particular the size of the NH$_3$ and CO$_2$ features relative to the CH$_4$ and H$_2$O features--is most consistent with a metallicity of 3--10$\times$ solar. Using a semi-free retrieval framework that perturbs the self-consistent model's abundance and temperature profiles to fit the data, we find that the planet's C/O, N/O, and S/O ratios are broadly consistent with solar values. A grid retrieval on 1D radiative-convective photochemical equilibrium (RCPE) models reveals a similar result: $[M/H]=0.46 \pm 0.08$ and C/O=$0.69 \pm 0.06$. The planet's atmospheric metallicity, abundance ratios, and bulk metal fraction are all strikingly similar to that of Jupiter, Saturn, and other gas giant exoplanets, despite orbiting a very low-mass star.

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arXiv2026

Photochemical Production of CS2 in Temperate-to-Warm Gas Giant Exoplanet Atmospheres

Sulfur chemistry has emerged as an important probe of exoplanet atmospheres in the JWST era, although observational constraints have thus far been largely limited to SO2 and H2S in warm and hot exoplanets. Recent JWST observations have revealed CS2 in several cooler gas-giant exoplanets, yielding a new tracer of sulfur chemistry. However, the detailed chemical pathways responsible for the formation of CS2 remain poorly understood. Here, we use TOI-6894 b, a temperate gas giant with evidence for CS2, as a test case for one-dimensional photochemical kinetic-transport modeling and sensitivity analyses of CS2 chemistry. We show that CS2 is produced through coupled thermochemical and photochemical processes involving CH4 and H2S as the primary carbon and sulfur reservoirs, with S2 photolysis driving disequilibrium sulfur chemistry. Our models provide a physically consistent explanation for the observed CS2 feature in TOI-6894 b. Extending our analysis to gas giant exoplanets spanning a wide range of Teq, we find that CS2 abundance peaks in temperate to warm atmospheres (Teq ~ 500 - 700 K), and declines toward both lower and higher temperatures. This temperature dependence provides a unified framework for interpreting current CS2 observations, accounting for reported detections in temperate to warm planets and the lack of detections in colder and hotter giant exoplanets. Our results establish CS2 as a complementary probe of sulfur inventories and atmospheric metallicity in cool gas giant exoplanets

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arXiv2026

Magnetic field strengths of hot giant exoplanets consistent with Solar System values

Magnetic fields are ubiquitous in the universe. They play a key role in shaping the activity of stars, the habitability of rocky planets, and the long-term retention of planetary atmospheres. Theoretical scaling laws are largely constrained by the limited set of stars and Solar System planets, leading to a wide range of possible values for hot giant planets outside of the Solar System from fractions of the Jovian field to orders of magnitude larger. Ultra-hot Jupiters, with their highly ionised atmospheres, provide a new avenue to probe magnetic effects, as their atmospheric circulation could be directly sensitive to atmospheric magnetic field strength. Using high-spectral resolution observations targeting the iron lines of ultra-hot Jupiters we measure the Doppler shift and thus the wind speed of seven transiting ultra-hot Jupiters. We find a clear decrease of wind speed with increasing planetary temperature, a trend inconsistent with purely hydrodynamic mechanisms but naturally reproduced by magnetic drag. From this relation we estimate the possible strength of magnetic fields of hot giant planets to at most a few gauss - comparable to the Jovian equatorial field. Our results support the idea that magnetic fields affect the atmospheric circulation of ultra-hot Jupiters and could provide a crucial benchmark for scaling laws used to predict magnetic fields in exoplanets, from hot Jupiters to rocky Earths with additional implications for future direct observations.

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arXiv2026

Atmospheric asymmetries in WASP-121 b revealed by rotational transits detected with JWST

Close-in exoplanets are tidally locked to their host star and thus exhibit extreme atmospheric temperature gradients. It has been theorized that the fraction of star light absorbed by such planets during transit changes as a function of orbital phase as progressively hotter or colder atmospheric gas rotates into view, but this effect has not been observed so far. Here, we show that two transits of the ultra-hot Jupiter WASP-121 b, acquired with JWST/NIRSpec and NIRISS, exhibit asymmetric transit light curves caused by the planet's rotation during transit. We observe increasing CO absorption and slightly decreasing H$_2$O absorption in the transmission spectrum, as the planet rotates. These results are indicative of a stronger longitudinal temperature gradient across the evening than across the morning terminator, consistent with higher temperatures in the eastern half than in the western half of the dayside. The observed changes of the transmission spectrum with orbital phase are in line with the temperature increase causing thermal dissociation of H$_2$O, while CO remains abundant. The observation of longitudinal gradients of atmospheric temperature and chemistry from the planet's rotational transit provides a new probe for constraining atmospheric heterogeneity using JWST beyond differences between morning and evening terminators from limb asymmetries.

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arXiv2026

A population view of transiting hot giant exoplanets: Tracing Fe and Ti chemistry with ESPRESSO and MAROON-X

Hot and ultra-hot Jupiters offer a unique laboratory to study atmospheric chemistry at the population level using ground-based high-resolution spectroscopy. Fe and Ti are key tracers of thermal and chemical structure, yet they exhibit different observational trends across the population. We present a homogeneous reanalysis of high-resolution transmission spectra of ten hot and ultra-hot Jupiters observed with VLT/ESPRESSO and Gemini-N/MAROON-X. We search for neutral Fe and Ti absorption and perform injection-recovery tests using models spanning a range of Ti-depletion levels and T-p profiles. For direct comparison across observations, we introduce the relative cross-correlation metric, $\Delta$Ti-Fe. We detect Fe in 7 and Ti in 4 planets above 5$\sigma$. Across the population, $\Delta$Ti-Fe decreases sharply towards lower equilibrium temperatures. Under the assumption of equal Ti depletion across planets, isothermal models fail to reproduce this trend, instead requiring a temperature-dependent depletion of Ti that increases toward cooler planets, consistent with cold-trapping processes in cooler atmospheres. Models with inverted T-p profiles naturally reproduce the decline without invoking temperature-dependent depletion. There, Ti is converted into TiO in deeper, cooler layers and then removed from the gas phase through condensation, leading to strong suppression of the observable atomic Ti signal. Nevertheless, even in the gradient models, overall depletion of Ti relative to Fe is required to match the hottest planets. Our results demonstrate that observable refractory chemistry is governed by the interplay of molecular partitioning, ionisation, condensation, and cold-trapping processes, as well as the vertical structure of ultra-hot Jupiter atmospheres. Additional observations will be necessary to distinguish between temperature-dependent cold-trapping and overall depletion.(abbrev.)

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arXiv2026

The Roasting Marshmallows Program with IGRINS on Gemini South V: Atmosphere of MASCARA-1b is Enriched in Refractory Elements

Ultra-hot Jupiters (UHJs; $T_{\rm eq} \gtrsim 2000$ K) enable simultaneous detection of volatile (ice-forming) and refractory (rock-forming) species in planetary atmospheres, providing a powerful diagnostic of planet formation and atmospheric processing. We present a comprehensive high-resolution cross-correlation spectroscopy (HRCCS) analysis of the UHJ MASCARA-1b ($T_{\rm eq} \approx 2600$ K) using the IGRINS and IGRINS-2 spectrographs. We detect robust (SNR$>$4) signals from H$_2$O, CO, OH, Fe I, Mg I, Ca I, and Ti I, marking the most complete atmospheric inventory of MASCARA-1b to date. Using a chemically consistent atmospheric inference framework, we constrain elemental abundances to a typical precision of $\approx$0.2 dex, retrieving a solar atmospheric metallicity ([M/H]$_\odot$ $= 0.07^{+0.17}_{-0.13}$ $\approx 1.2\times$ solar), a C/O ratio (C/O $= 0.65^{+0.08}_{-0.08}$) consistent with solar value (C/O $=$ 0.59), an enhanced refractory abundance ([R/H]$_\odot$ $= 0.40^{+0.23}_{-0.17} \approx 2.5\times$ solar; $\approx 3.8\times$ stellar), and a moderately super-solar refractory-to-volatile ratio ([R/V]$_\odot$ $= 0.36^{+0.11}_{-0.09}$ $\approx 2.3\times$ solar). Comparison with formation models suggests that MASCARA-1b most likely accreted material between the soot-H$_2$O or H$_2$O-CO snowlines (at 68$\%$ confidence). We additionally find stellar values for atmospheric Ti/Mg and Ca/Mg ratios (at 68$\%$ confidence). The Mg/Fe is also found to be consistent with stellar value at 95$\%$ confidence. Therefore, we do not find strong indication of nightside cold trapping in MASCARA-1b. As homogeneous refractory-to-volatile measurements expand across the UHJ population, particularly with upcoming Extremely Large Telescopes, these diagnostics will enable statistically robust tests of emerging trends in giant planet formation and atmospheric evolution.

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arXiv2026

The CRIMSON survey I: super-stellar SiO in the directly imaged companion TWA 5 B from high-resolution M-band spectroscopy

Silicon is a key refractory element in giant planet atmospheres, which governs the formation of magnesium-silicate clouds, and reflects the quantity of silicates accreted during formation. While observations of directly imaged giant exoplanets have focused on the measurement of volatile species (e.g. CO, H$_2$O), high-resolution spectroscopy with CRIRES+ M-band provides access to gas phase silicon chemistry in sub-stellar atmospheres, through the ro-vibrational band head of SiO at 4 $\mu$m. Here, we present the first results of the CRIMSON survey of silicon chemistry in directly imaged companions with CRIRES+ M-band. We report the strong detection of gaseous SiO (S/N = 7.5) in the directly imaged companion TWA 5 B, with an atmospheric abundance of log(SiO) = $-3.56^{+0.42}_{-0.32}$ VMR, providing access to the refractory content of the atmosphere. The high retrieved SiO abundance implies the absence of significant magnesium-silicate cloud condensation, and thus the atmospheric silicon abundance is contained almost entirely within the observed gas phase SiO. Using the detection of refractory silicon, together with strong detections of the volatile species CO (S/N = 9.1) and H$_2$O (S/N = 18.8), we measure a stellar C/O and a marginally sub-stellar O/Si and C/Si, but a super-stellar Si/H ([Si/H]$_{\star}$ = $1.41^{+0.42}_{-0.32}$). Collectively, these volatile-to-refractory ratios are consistent with formation through core-accretion beyond the CO snowline, or gravitational instability followed by substantial solid enrichment. Finally, we discuss how gas phase SiO provides a unique diagnostic of the cloud properties in hot gas-giants, and can be used to probe the dominant cloud species forming across the directly imaged planet and isolated brown dwarf populations.

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arXiv2026

Towards Doppler eclipse mapping of hot Jupiters. An observational perspective on WASP-33 b with SPIRou

In the last decade, ground-based high-resolution spectroscopy (HRS) has emerged as a powerful method to probe exoplanet atmospheres both in transit and thermal emission. With HRS science now maturing to reveal these planet's thermal, compositional, and dynamical structure in three dimensions, novel strategies will be key to extracting the maximal scientific output from these rich datasets. In this article, we investigate the potential of exploiting eclipses in order to retrieve spatial constraints on exoplanet dayside atmospheres with HRS, as has been successfully applied at lower spectral resolutions with space-based facilities. To attempt this, we obtained an observations of 8 eclipses (ingress and egress) of the ultra-hot Jupiter WASP-33b with SPIRou. We analysed these data with the publicly available ATMOSPHERIX pipeline, which we combined with the starry Python package to fit the eclipse mapping signal. Additionally, we performed injection-recovery tests on archival data to evaluate the detection limits that could be reached with further observations. From our data, we obtain the first tentative detection of CO from in-eclipse data alone, validating that ingresses and egresses may be stacked coherently to boost detection limits. In combination with longer phase-coverage dayside data, our eclipses marginally improve constraints on the planetary rotation velocity. Through injection recovery tests, we show that our results are scaling according to expectations for a synchronously rotating WASP-33b, implying that a further 15 eclipses with SPIRou would be required to measure the planet's rotation using this method. Finally, we present promising detection limits for this method on the population of hot-Jupiters with next generation telescopes, and highlight remaining challenges in data processing for short time series and/or slowly accelerating planets.

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arXiv2026

HAT-P-70b through the Eyes of MAROON-X: Constraining Elemental Abundances of Metals and Insights on Atmosphere Dynamics

Ultra-hot Jupiters (UHJs) are exceptional laboratories for studying planetary atmospheres under extreme irradiation conditions. With close-in tidally locked orbits, these planets can have daysides hot enough for metals to be significantly ionized while still maintaining nightsides cold enough for refractory species to potentially condense. We present an analysis of the ultra-hot Jupiter HAT-P-70b taken with the MAROON-X high-resolution spectrograph. Using cross-correlations, we detect 14 neutral and singly ionized species, including Fe I, Fe II, Ti I, Ca I, Ca II, Cr I, Na I, V I, Mn I, Ni I, Mg I, Ba II, O I, and Sr I, with tentative evidence for H I, Co I, and K I. The absorption signals exhibit blueshifts on the order of a few $\mathrm{km\,s^{-1}}$, consistent with day-to-night winds. We further constrain relative abundances with atmospheric retrievals and demonstrate that some inferred elemental abundance ratios depend strongly on modeling assumptions. In particular, we show that a well-mixed retrieval approach neglecting ionization can strongly bias highly ionizable elements such as Ca and Ti. Accounting for the effects of equilibrium chemistry and thermal ionization generally results in inferred elemental abundance ratios that are closer to expectations for a solar-like composition, although not in all cases. Interestingly, we find a distinct nickel enrichment on HAT-P-70b, adding to the growing number of UHJ studies where the Ni abundance is seemingly enhanced. Our results underline the importance of considering physical and chemical atmospheric processes such as ionization when interpreting high-resolution transmission spectra of UHJs.

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arXiv2026

Horizontal transport as a source of disequilibrium chemistry on the nightside of a hot exoplanet

Hot Jupiters have temperature gradients of several hundreds of degrees between their permanent day and nightsides. In equilibrium, the primary carbon reservoir is expected to transition from CO on the dayside to CH4 on the nightside. Theory predicts that the atmospheric circulation, characterised by km/s winds, can advect chemical species from the dayside to the nightside faster than the time needed for the CO-to-CH4 chemical reaction to reach equilibrium. However direct evidence of this process has, so far, remained elusive, partly because it is often degenerate with other processes, such as vertical mixing or non-stellar elemental abundances. Here, we present observational evidence for such day-to-night transport of chemical species by observing both the dayside and the nightside of the hot Jupiter NGTS-10A b with the JWST/NIRSpec instrument. We constrain the presence of H2O and CO with similar abundances on both the dayside and nightside. Our observations are compatible with a solar-composition atmosphere at chemical equilibrium on the dayside, but indicative of disequilibrium chemistry for the nightside as it is significantly depleted in CH4 compared to equilibrium chemistry predictions. We further show that the lack of CH4 on the planet's nightside cannot be attributed to non-solar elemental abundances or to vertical mixing mechanisms and must therefore be due to horizontal chemical quenching. Our study shows the fundamental role atmospheric transport plays in shaping the distribution of chemical species on exoplanet atmospheres.

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arXiv2026

The Days Drag On on WASP-121 b: Interpreting its NIRISS Spectroscopic Phase Curve with General Circulation Models

Ultra-hot Jupiters present extreme atmospheric phenomena not found in the Solar System. These planets' daysides experience strong temperature inversions, molecular species (including H2) dissociate, and magnetism disrupts their atmospheric circulation. On their nightsides H2 can recombine and clouds may form. Spectroscopic phase curves let us measure these spatially inhomogeneous conditions, which can then be interpreted with three-dimensional (3-D) models. In this work we compare the JWST/NIRISS spectroscopic phase curve of the ultra-hot Jupiter WASP-121 b to state-of-the-art 3-D models with varying modeling assumptions, including the aforementioned physical phenomena. We demonstrate the importance of accurately accounting for the planet's radius in comparison between data and models, as it changes the implied overall planetary emission. We find that the 3-D models predict planet emission $\sim$12% higher than observed, contributing to a continued tension between measured and predicted hot Jupiter albedos. We identify multiple pieces of evidence that confirm a strong source of drag operating in this planet's atmosphere. In addition, the nightside emission spectrum is devoid of strong absorption features, which may be best explained by nightside clouds. One feature of the dataset that is not matched by the 3-D models is a trend of increasing eastward phase offset with decreasing wavelength, for wavelengths shorter than $\sim$1.4 \textmu m. This result is not consistent with reflection from dayside clouds, nor can it be explained by removing atmospheric opacity sources. Our analysis highlights the complexities in generating 3-D models and interpreting observations of ultra-hot Jupiters in the JWST era.

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arXiv2026

The tale of the 3 planets: 3D cloud feedback enhances the spectral diversity of warm Jupiters

JWST has shown a large diversity in warm Jupiter spectra, despite only small variations in the planetary parameters. However, the main driver of this diversity remains unclear. We aim to identify the mechanisms responsible for the spectral difference of three warm Jupiter-size exoplanets observed by JWST: whereas WASP-80b appears mostly cloud-free, both WASP-107b and WASP-69b have spectra dominated by clouds. We model each planet using the same framework, ADAM (formerly SPARC/MITgcm), which solves for the interactions among cloud transport, radiative transfer, and atmospheric circulation in 3D. We investigate the role of three condensate species, Na$_2$S, KCl, and MgSiO$_3$, and four particle sizes (0.1, 1, 5, and 10 $\mu$m). Clouds settle deeper in the atmosphere of the higher-gravity planet WASP-80b than in WASP-107b, reproducing their spectral difference naturally. For WASP-107b, three clouds can reproduce the NIRCam observations: 5 $\mu$m Na$_2$S, 1 $\mu$m KCl, and 5 $\mu$m MgSiO$_3$ models. However, these cannot match the scattering slope observed at shorter wavelengths in NIRISS and the possible silicate feature in the MIRI bandpass, suggesting a multi-modal distribution of clouds. Our model predicts that small silicate particles should be homogeneously distributed and thus cannot account for the difference between the two limb spectra in the MIRI bandpass. Finally, applying the same model to WASP-69b does not yield a partially cloudy dayside solution that fits the emission spectra, as proposed in a previous study. Coupling among 3D circulation, clouds, and radiative transfer can enhance the spectral diversity of warm Jupiter exoplanets, particularly through changes in cloudiness with gravity. The combination of multi-phase, wide-wavelength coverage and models that couple clouds, circulation, and radiative transfer is key to advancing our understanding of these new objects.

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arXiv2026

The Identification of CS2 and Evidence for Carbon-Sulfur Chemical Coupling in a Warm Giant Exoplanet Atmosphere

Transmission spectroscopy with the James Webb Space Telescope (JWST) is revealing growing chemical complexity in giant exoplanet atmospheres. Of particular interest is sulfur, which had essentially no observational constraints before JWST. Recent work has shown that a planet's atmospheric sulfur content traces its refractory budget and is therefore a sensitive indicator of formation pathways. But despite the growing library of JWST data, the sulfur inventory of giant exoplanets remains poorly constrained: sulfur-bearing species are governed by disequilibrium chemistry and by kinetic networks that are still being revised. Here we present a transmission spectrum of the warm giant planet WASP-80 b obtained with JWST/NIRCam and MIRI over 2.4 $\mu$m--10$\mu$m in three transits. We uniquely identify CS$_2$ in our transmission spectrum using the combination of the two absorption features in NIRCam and MIRI at a significance of $\ln (B)=17.89$ ($\sigma = 6.3$). Our grid-based retrievals yield $\mathrm{[M/H] = \:} 0.54^{+0.17}_{-0.12}$ and $\mathrm{C/O =\:}0.43^{+0.12}_{-0.08}$ which result in $\log(\mathrm{X_{CS_2}})$ abundances of $\sim-4.5$. The latest carbon-sulfur kinetics networks produce substantially greater amounts of CS$_2$ than past works, enabling good fits ($\chi^2/\mathrm{N_{data}}\sim1.2$) to the data without invoking extreme abundance patterns. These results identify CS$_2$ as an observable tracer of sulfur disequilibrium chemistry and provide observational support for theoretically predicted carbon-sulfur chemical coupling in giant exoplanet atmospheres.

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arXiv2026

The EXoplanet Climate Infrared TElescope (EXCITE): A balloon-borne mission to measure spectroscopic phase curves of transiting hot Jupiters

The EXoplanet Climate Infrared TElescope (EXCITE) is a balloon-borne mission dedicated to measuring spectroscopic phase curves of hot Jupiter-type exoplanets. Phase curve measurements can be used to characterize an exoplanet's longitude-dependent atmospheric composition and energy circulation patterns. EXCITE carries a 0.5 m primary mirror and moderate resolution diffraction-limited spectrograph with spectral coverage from 0.8--3.5 um. EXCITE is designed to fly from a long-duration balloon (LDB). EXCITE will observe through the peak of a target's spectral energy distribution (SED) and through spectral signatures of hydrogen and carbon-containing molecules. In this paper, we present the science goals of EXCITE, detail the as-built instrument, and discuss its performance during a 2024 engineering flight from Fort Sumner, New Mexico.

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arXiv2025

Challenges in the detection of gases in exoplanet atmospheres

Claims of detections of gases in exoplanet atmospheres often rely on comparisons between models including and excluding specific chemical species. However, the space of molecular combinations available for model construction is vast and highly degenerate. Only a limited subset of these combinations is typically explored for any given detection. As a result, apparent detections of trace gases risk being artifacts of incomplete modeling rather than robust identification of atmospheric constituents, especially in the low signal-to-noise regime. Using the sub-Neptune K2-18 b as a case study, we show that recent biosignature claims vanish when the model space is expanded, with numerous alternatives providing equally good or better fits. We demonstrate that the significance of a claimed detection relies on the choice of models being compared, and that model preference does not in itself imply the presence of a specific gas. We recommend treating model comparisons instead as relative adequacy tests, which should be supported by theoretical predictions and complementary metrics of statistical significance in order to attribute a signal to a particular gas.

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