arXiv subjects

Vladimir Sechovsky

Publications and source records attributed to Vladimir Sechovsky.

18 recordsLinked to original sources

arXiv2026

Metamagnetism in UTe2: the roles of itinerancy and localization

The metamagnetic transition in UTe$_2$ plays a key role in stabilizing two enigmatic field-induced superconducting phases. One of these phases (SC2) is truncated by the transition, lying directly below it, while the other (SC3) sits predominantly above it and appears to be stabilized because of it. While numerous pulsed field studies have examined this transition, comparatively few steady field experiments have investigated it. Here we report a suite of measurements of metamgnetism in UTe$_2$, at ambient pressure by torque magnetometry and extraction magnetometry techniques, and of the magnetoconductance under pressure. Our steady field measurements resolve a complex sub-structure within the transition, with separate features that possess different temperature evolutions, pointing to distinct contributions from itinerant and localized moments. The itinerant contribution might relate to a possible spin-density wave state. We theoretically model the evolution of Kondo and RKKY interactions and propose that the SC2 state is stabilized under pressure due to the collapse of magnetic anisotropy, leading to an enhancement of longitudinal spin fluctuations along the hard $b$ axis, which are pair-forming in the $p$-wave channel.

cond-mat.str-el↗

arXiv2026

Electrically-controllable superconducting memory effect in UTe2

If a computer could be assembled from superconducting components, the energy efficiency would far surpass that of conventional electronics. Historic research efforts towards this goal yielded pivotal breakthroughs in the development and discovery of scanning tunnelling microscopy and high temperature superconductivity. Although recent strides have been taken in advancing superconducting diode and switching technologies, harnessing read/writeable memory functionality in superconducting platforms has remained challenging. Here we show that bulk single crystal specimens of the triplet superconductor candidate uranium ditelluride (UTe$_2$) possess such properties. Upon applying a magnetic field to access an intermediate regime straddling two distinct superconducting phases, we find that direct current pulses can push the material in and out of a metastable state possessing an enhanced critical current $J_c$. This switching is controllable by the strength and duration of the stimuli, with the system `remembering' whether it is in the high or low $J_c$ state for extended periods. We interpret this to be due to competition between two distinct vortex species, which can be perturbatively pushed into a non-equilibrium high-disorder configuration with stronger pinning forces and thus higher $J_c$. Rather than requiring proximate magnetic or semiconducting interfaces, this memory functionality appears to be an intrinsic property of UTe$_2$ rooted in the superconducting order itself. Our findings underscore the rich complexity of quantum vortex matter, and demonstrate the viability of engineering a new class of superconducting memory elements with ultralow-power switching.

cond-mat.supr-con↗

arXiv2026

Direct Observation of the Spillover of High Magnetic Field-induced SC3 Superconductivity Outside the Spin-Polarized State in UTe2

In our recent study of the high magnetic field phase landscape of UTe$_2$ [Phys. Rev. X 15, 021019 (2025)] we found indirect evidence that the SC3 superconducting phase spills out beyond the first-order phase boundary of the spin-polarized state. This prior study was limited to a maximal field strength of 41.5 T, and mapped the $b-ac$ rotation plane. Here we measure a high quality sample with residual resistivity ratio RRR = 605 under rotations in the $b-c$ plane up to 45 T. This extended field range helps to unambiguously demonstrate the spillover of SC3 outside the polarized paramagnetic state. This is identified by the observation of zero resistance at low temperatures, for magnetic field strengths lower than the metamagnetic transition field resolved at higher temperatures. This observation is consistent with the scenario that electronic pairing of the SC3 phase is mediated by quantum critical fluctuations.

cond-mat.supr-con↗

arXiv2025

Opposite pressure effects on magnetic phase transitions in NiBr2

NiI2 and NiBr2 are archetypal van der Waals (vdW) triangular-lattice multiferroics that host incommensurate helimagnetic order at the lowest temperatures and undergo a transition to collinear antiferromagnetic order upon heating. Focusing on NiBr2, we reveal that both antiferromagnetic phases exhibit a pronounced sensitivity to hydrostatic pressure. The Neel temperature of the collinear phase increases steeply at 20 K/GPa, reaching 100 K at 3 GPa without any indication of saturation, whereas the helimagnetic phase is completely suppressed only above 0.8 GPa. This behavior contrasts sharply with NiI2, in which both helical and collinear phases are strengthened until a moderate pressure of 6 GPa, above which the helical phase instantly disappears. Ab initio calculations identify the second-nearest interlayer exchange interaction (j2') as the primary driver stabilizing the collinear AFM phase in NiBr2. In addition, the in-plane exchange ratio renders the helical order in NiBr2 considerably more fragile, enabling its suppression under relatively small pressures. These results underscore the dominant role of interlayer interactions in governing the distinct pressure responses of the magnetic phases in NiBr2 and NiI2.

cond-mat.mtrl-sci↗

arXiv2025

Metamagnetic ripples in the UTe2 high magnetic field phase diagram

The heavy fermion metamagnet uranium ditelluride possesses two distinct magnetic field--induced superconducting states. One of these superconductive phases resides at magnetic fields immediately below a first-order metamagnetic transition to a field--polarized paramagnetic state at a field strength $H_m$, while the other exists predominantly above $H_m$. However, little is known about the microscopic properties of this polarized paramagnetic state. Here we report pulsed magnetic field measurements tracking the evolution of $H_m$ for polar and azimuthal inclinations in the vicinity of the crystallographic $b-a$ plane. We uncover a region of the phase diagram at high fields $>$ 50 T with a ripple-like non-monotonic dependence of $H_m$ on the orientation of field. Within this ripple in the metamagnetic transition surface, $H_m$ exhibits an anomalous temperature dependence. Our results point towards the presence of complex magnetic interactions and possible magnetic sub-phases at high magnetic fields in UTe$_2$, which may have important implications for the manifestation of exotic field-induced superconductivity.

cond-mat.str-el↗

arXiv2024

Unique magnetic structure of the vdW antiferromagnet VBr$_3$

VBr$_3$ is a van der Waals antiferromagnet below the N\'eel temperature of 26.5 K with a saturation moment of 1.2 mB/f.u. above the metamagnetic transitions detected in the in-plane and out-of-plane directions. To reveal the AFM structure of VBr$_3$ experimentally, we performed a single-crystal neutron diffraction study on a large high-quality crystal. The collected data confirmed a slight monoclinic distortion of the high-temperature rhombohedral structure below 90 K. The magnetic structure was, nevertheless, investigated within the R-3 model. The antiferromagnetic structure propagation vector k = (1, 0, 0.5) was revealed. In an attempt to determine the magnetic structure, 72 non-equivalent magnetic reflections were recorded. The experimental data were confronted with the magnetic space groups dictated by the R-3 lattice symmetry and propagation vector. The best agreement between the experimental data and the magnetic structure model was obtained for the space group P-1.1'_c. The magnetic unit cell of the proposed unique antiferromagnetic structure with periodicity 6c is built from two identical triple layers antiferromagnetically coupled along the c axis. Each triple layer comprises a N\'eel antiferromagnetic monolayer sandwiched between two antiferromagnetically coupled ferromagnetic monolayers.

cond-mat.mtrl-sci↗

arXiv2024

Magnetic signatures of pressure-induced multicomponent superconductivity in UTe$_2$

The phase diagram of the heavy fermion compound UTe$_2$ contains multiple superconducting phases, several of which show characteristics of odd-parity pairing. We have investigated the pressure dependence of the superconducting transition in high-quality crystals of UTe$_2$ by tracking its signature in the magnetic susceptibility $\chi(T)$. A single, sharp superconducting transition is observed at low pressures 0.3 GPa. At higher pressure, a second feature emerges in $\chi(T)$, which is located at the lower-temperature thermodynamic phase boundary previously identified in specific heat measurements. This second transition anomaly in $\chi(T)$ can be attributed to a step change in the London penetration depth, providing direct evidence for a change in the superconducting order parameter of UTe$_2$. Thermodynamic constraints suggest that the low temperature, high pressure superconducting state is distinct from zero pressure superconductivity as well as from the high pressure, high temperature superconducting state, raising the possibility of multicomponent superconductivity in high pressure UTe$_2$.

cond-mat.supr-con↗

arXiv2022

Terahertz Magnetic and Lattice Excitations in van der Waals Ferromagnet VI3

We use the synergy of infrared, terahertz, and Raman spectroscopies with DFT calculations to shed light on the magnetic and lattice properties of VI3. The structural transition at TS1 = 79 K is accompanied by a large splitting of polar phonon modes. Below TS1, strong ferromagnetic fluctuations are observed. The variations of phonon frequencies at 55 K induced by magnetoelastic coupling enhanced by spin-orbit interaction indicate the proximity of long-range ferromagnetic order. Below TC = 50 K, two Raman modes simultaneously appear and show dramatic softening in the narrow interval around the temperature TS2 of the second structural transition associated with the order-order magnetic phase transition. Below TS2, a magnon in the THz range appears in Raman spectra. The THz magnon observed in VI3 indicates the application potential of 2D van der Waals ferromagnets in ultrafast THz spintronics, which has previously been considered an exclusive domain of antiferromagnets.

cond-mat.mtrl-sci↗

arXiv2022

Large orbital magnetic moment in VI3

The existence of the V3+ ion orbital moment is the open issue of the nature of magnetism in the van der Waals ferromagnet VI3. The huge magnetocrystalline anisotropy in conjunction with the significantly reduced ordered magnetic moment compared to the spin-only value provides strong but indirect evidence of a significant V orbital moment. We used the unique capability of X-ray magnetic circular dichroism to determine the orbital component of the total magnetic moment and provide for the first time a direct proof of an exceptionally sizable orbital moment of the V3+ ion in VI3. Our ligand field multiplet simulations of the XMCD spectra in synergy with the results of DFT calculations agree with the existence of two V sites with different orbital occupations and therefore different OM magnitudes in the ground state.

cond-mat.mtrl-sci↗

arXiv2022

Crystal structure evolution in the van der Waals transition metal trihalides

Most transition-metal trihalides are dimorphic. The representative chromium-based triad, CrCl3, CrBr3, CrI3, is characterized by the low-temperature phase adopting the trigonal BiI3 type while the structure of the high-temperature phase is monoclinic of AlCl3 type (C2/m). The structural transition between the two crystallographic phases is of the first-order type with large thermal hysteresis in CrCl3 and CrI3. We studied crystal structures and structural phase transitions of vanadium-based counterparts VCl3, VBr3, and VI3 by measuring specific heat, magnetization, and X-ray diffraction as functions of temperature and observed an inverse situation. In these cases, the high-temperature phase has a higher symmetry while the low-temperature structure reveals a lower symmetry. The structural phase transition between them shows no measurable hysteresis in contrast to CrX3. Possible relations of the evolution of the ratio c/a of the unit cell parameters, types of crystal structures, and nature of the structural transitions in V and Cr trihalides are discussed.

cond-mat.mtrl-sci↗

arXiv2022

Alloying driven transition between ferro- and antiferromagnetism in UTGe compounds: the UCo1-xIrxGe case

The evolution of magnetic properties of isostructural and isoelectronic solid solutions of the superconducting itinerant 5f-electron ferromagnet UCoGe with antiferromagnet UIrGe was studied by magnetization, AC susceptibility, specific heat, and electrical resistivity measurements of a series of UCo1-xIrxGe compounds in polycrystalline and single crystalline form at various temperatures and magnetic fields. Both the weak ferromagnetism and superconductivity in UCoGe were found to have vanished already for very low Ir substitution for Co x = 0.02. The antiferromagnetism of UIrGe is gradually suppressed. This is documented by a rapid decrease in both Neel temperature and the critical field of the metamagnetic transition with decreasing Ir concentration, which both tend to vanish just above x = 0.8. The section of the T-x phase diagram in the range x between 0.02 and 0.8 is dominated by a correlated paramagnetic phase exhibiting very broad bumps in temperature dependencies of b-axis magnetization and specific heat developing with increasing x. For x = 0.24, wide peaks appear in the c-axis thermomagnetic curves due to antiferromagnetic correlations which may eventually lead to frozen incoherent spin configurations at low temperatures. The correlated paramagnetic phase is also accompanied by specific electrical resistivity anomalies. The T-x phase diagram determined for the UCo1-xIrxGe compounds contrasts with the behavior of the related URh1-xIrxGe system, which was reported to exhibit an extended concentration range of stable ferromagnetism in Rh rich compounds and a discontinuous transformation between the ferromagnetic and antiferromagnetic phases at a critical Rh-Ir concentration.

cond-mat.str-el↗

arXiv2018

Magnetic field induced phenomena in UIrGe in fields applied along b axis

The metamagnetic transition between the antiferromagnetic and paramagnetic state in UIrGe has been studied at various temperatures by magnetization, heat capacity and magnetocaloric-effect measurements on a single crystal in static and pulsed magnetic fields applied along the orthorhombic b-axis. A first-order transition is observed at temperatures below 13 K and a second-order one at higher temperatures up to the Néel temperature (TN = 16.5 K). The first-order transition is accompanied by a dramatic increase of the Sommerfeld coefficient. Magnetization measurements extended to the paramagnetic range revealed an anomalous S-shape (inflection point at a magnetic field Hm) in magnetization isotherms at temperatures above 13 K and a temperature dependence of susceptibility with a maximum at Tmax well above TN. The lines representing the temperature-induced evolution of Hm and field-induced evolution of Tmax, respectively, are bound for the point in the magnetic phase diagram at which the order of metamagnetic transition changes. A tentative scenario explaining these anomalies by antiferromagnetic correlations or short-range order in the paramagnetic state is discussed.

cond-mat.str-el↗

arXiv2015

Polarized neutron diffraction and X-ray magnetic circular dichroism study of Ru doped UCoGe

We report on microscopic study of the ferromagnetism enhancement in the Ru doped ferromagnetic superconductor (FM SC) UCoGe. For that purpose, two single crystals with composition UCo0.97Ru0.03Ge and UCo0.88Ru0.12Ge were prepared. Both single crystals were investigated by polarized neutron diffraction (PND) at low temperatures in magnetic fields and the latter one also by the soft X-ray magnetic circular dichroism (XMCD) method. UCo0.96Ru0.03Ge and UCo0.88Ru0.12Ge have been found ordering ferromagnetically below the Curie temperature TC = 6 K and 8.5 K, respectively, which are considerable higher than TC = 3 K of UCoGe. The increase of TC is accompanied by enhancement of the spontaneous moment to ms = 0.11 mB/f.u. and ms = 0.21 mB/f.u., respectively. The analysis of the PND results assigns the ferromagnetism enhancement mainly to the growth of the orbital part of uranium 5 f moment. In contrast to the published results of PND study of the parent UCoGe, we have found parallel orientation of the U and Co moments in both doped compounds. Evolution of magnetic characteristics with Ru concentration is discussed within a scenario considering the varying 5 f-ligand hybridization as the key mechanism.

cond-mat.str-el↗

arXiv2015

Gradual localization of 5f states in orthorhombic UTX ferromagnets - polarized neutron diffraction study of Ru substituted UCoGe

We report on a microscopic study of the evolution of ferromagnetism in the Ru substituted ferromagnetic superconductor (FM SC) UCoGe crystallizing in the orthorhombic TiNiSi-type structure. For that purpose, two single crystals with composition UCo0.97Ru0.03Ge and UCo0.88Ru0.12Ge have been prepared and characterized by magnetization, AC susceptibility, specific heat and electrical resistivity measurements. Both compounds have been found to order ferromagnetically below TC = 6.5 K and 7.5 K, respectively, which is considerably higher than the TC = 3 K of the parent compound UCoGe. The higher values of TC are accompanied by enhanced values of the spontaneous moment mspont. = 0.11 mB/f.u. and mspont. = 0.21 mB/f.u., respectively in comparison to the tiny spontaneous moment of UCoGe (about 0.07mB/f.u.). No sign of superconductivity was detected in either compound. The magnetic moments of the samples were investigated on the microscopic scale using polarized neutron diffraction (PND) and for UCo0.88Ru0.12Ge also by soft X-ray magnetic circular dichroism (XMCD). The analysis of the PND results indicates that the observed enhancement of ferromagnetism is mainly due to the growth of the orbital part of the uranium 5f moment mL(U), reflecting a gradual localization of the 5f electrons with Ru substitution. In addition, the parallel orientation of the U and Co moments has been established in both substituted compounds. The results are discussed and compared with related isostructural ferromagnetic UTX compounds (T - transition metals, X - Si, Ge) in the context of a varying degree of the 5f-ligand hybridization.

cond-mat.str-el↗

arXiv2015

Evolution of magnetism in Pd-substituted Ce$_2$RhIn$_8$ single crystals

The evolution of magnetism and superconductivity in Ce$_2$Rh$_{1-x}$Pd$_x$In$_8$ solid solutions has been studied within the entire concentration range by means of thermodynamic and magnetic measurements at ambient pressure and at temperatures between 0.35 K and room temperature. For this purpose, single crystals with Pd concentrations x = 0, 0.10, 0.15, 0.30, 0.45, 0.55, 0.85 and 1 have been grown from In self-flux and characterized by x-ray diffraction and microprobe analysis. Starting from the antiferromagnet Ce$_2$RhIn$_8$, the Néel temperature gradually decreases with increasing Pd concentration and the antiferromagnetism has disappeared for $x \ge 0.45$. Superconductivity has been observed only for Ce$_2$PdIn$_8$.

cond-mat.str-el↗

arXiv2015

Tuning the pressure-induced superconductivity in Pd-substituted CeRhIn5

The effect of substituting Rh in CeRh1-xPdxIn5 with Pd up to x = 0.25 has been studied on single crystals. The crystals have been grown by means of the In self-flux method and characterized by x-ray diffraction and microprobe. The tetragonal HoCoGa5-type of structure and the c/a ratio of the parent compound remains intact by the Pd substitution; the unit cell volume increases by 0.6 % with x = 0.25 of Pd. The low-temperature behavior of resistivity was studied also under hydrostatic pressure up to 2.25 GPa. The Pd substitution for Rh affects the magnetic behavior and the maximum value of the superconducting transition temperature measured at pressures above 2 GPa only negligibly. On the other hand, the results provide evidence that superconductivity in CeRh0.75Pd0.25In5 is induced at significantly lower pressures, i.e. the Pd substitution for Rh shifts the CeRh1-xPdxIn5 system closer to coexistence of magnetism and superconductivity at ambient pressure.

cond-mat.str-el↗

arXiv2014

Single crystal study of the layered heavy fermion compounds Ce$_2$PdIn$_8$, Ce$_3$PdIn$_{11}$, Ce$_2$PtIn$_8$ and Ce$_3$PtIn$_{11}$

We report on single crystal growth and crystallographic parameters results of Ce$_2$PdIn$_8$, Ce$_3$PdIn$_{11}$, Ce$_2$PtIn$_8$ and Ce$_3$PtIn$_{11}$. The Pt-systems Ce$_2$PtIn$_8$ and Ce$_3$PtIn$_{11}$ are synthesized for the first time. All these compounds are member of the Ce$_n$T$_m$In$_{3n+2m}$ (n = 1, 2,..; m = 1, 2,.. and T = transition metal) to which the extensively studied heavy fermion superconductor CeCoIn$_5$ belongs. Single crystals have been grown by In self-flux method. Differential scanning calorimetry studies were used to derive optimal growth conditions. Evidently, the maximum growth conditions for these materials should not exceed 750 $^{\circ}$C. Single crystal x-ray data show that Ce$_2$TIn$_8$ compounds crystallize in the tetragonal Ho$_2$CoGa$_8$ phase (space group P4/mmm) with lattice parameters a =4.6898(3) $Å$ and c =12.1490(8) $Å$ for the Pt-based one (Pd: a = 4.6881(4) $Å$ and c = 12.2031(8) Å). The Ce$_3$TIn$_{11}$ compounds adopt the Ce$_3$PdIn$_{11}$ structure with a = 4.6874(4) $Å$ and c = 16.8422(12) $Å$ for the Pt-based one (Pd: a = 4.6896 $Å$ and c = 16.891 Å). Specific heat experiments on Ce$_3$PtIn$_{11}$ and Ce$_3$PdIn$_{11}$ have revealed that both compounds undergo two successive magnetic transitions at T$_1$ ~ 2.2 K followed by T$_N$ ~ 2.0 K and T$_1$ ~ 1.7 K and T$_N$ ~ 1.5 K, respectively. Additionally, both compounds exhibit enhanced Sommerfeld coefficients yielding γ$_{Pt}$ = 0.300 J/mol K$^2$ Ce (γ$_{Pd}$ = 0.290 J/mol K$^2$ Ce), hence qualifying them as heavy fermion materials.

cond-mat.str-el↗

arXiv2010

Solution growth of Ce-Pd-In single crystals: characterization of the heavy-fermion superconductor Ce2PdIn8

Solution growth of single crystals of the recently reported new compound Ce2PdIn8 was investigated. When growing from a stoichiometry in a range 2:1:20 - 2:1:35, single crystals of CeIn3 covered by a thin (~50 um) single-crystalline layer of Ce2PdIn8 were mostly obtained. Using palladium richer compositions the thickness of the Ce2PdIn8 layers were increased, which allowed mechanical extraction of single-phase slabs of the desired compound suitable for a thorough study of magnetism and superconductivity. In some solution growth products also CePd3In6 (LaNi3In6 - type of structure) and traces of phases with the stoichiometry CePd2In7, Ce1.5Pd1.5In7 (determined only by EDX) have been identified. Magnetic measurements of the Ce2PdIn8 single crystals reveal paramagnetic behaviour of the Ce3+ ions with significant magnetocrystalline anisotropy. Above 70 K the magnetic susceptibility follows the Curie-Weiss law with considerably different values of the paramagnetic Curie temperature, for the magnetic field applied along the a- (-90 K) and c-(-50 K) axis. Below the reported critical temperature for superconductivity Tc (0.69 K) the electrical resistivity drops to zero. Comparative measurements of the electrical resistivity, heat capacity and AC susceptibility of several crystals reveal that the superconducting transition is strongly sample-dependent.

cond-mat.supr-con↗