arXiv subjects

Weibin Ni

Publications and source records attributed to Weibin Ni.

4 recordsLinked to original sources

arXiv2026

Hadamard sensing channel: deterministic artifact suppression for quantum sensors

Dynamical decoupling sequences are essential for nanoscale quantum sensing, but the finite duration of microwave pulses generates spurious responses. While phase randomization (PR) protocol can suppress these artifacts, they rely on probabilistic averaging. This introduces an inherent statistical variance that demands excessive sequence lengths and stringent hardware capabilities for true random phase generation. Here, we propose Hadamard sensing channel (HSC), a deterministic phase-design framework based on Hadamard matrices. HSC completely eliminates the statistical variance of PR by exactly and deterministically canceling spurious signals using a finite set of orthogonal phase patterns. Simulations confirm that HSC matches the ideal suppression of PR but exhibits superior robustness against control errors. HSC offers a mathematically exact and hardware-friendly solution for reliable high-resolution nanoscale nuclear magnetic resonance.

quant-ph↗

arXiv2026

Scalable quantum error mitigation for dynamical decoupling

Quantum coherence remains a fundamental challenge for advancing quantum technologies. Although dynamical decoupling can suppress decoherence noise, it frequently misestimates decoherence times due to control errors -- a previously underappreciated issue. Here, we present Hadamard phase cycling, a scalable non-Markovian quantum error mitigation method using group-structured phase configurations to filter spurious dynamics. Validated across molecular electron spins, nitrogen-vacancy centers in diamond, nuclear spins, trapped ions, and superconducting qubits, this technique enables accurate decoherence time characterization and enhanced state fidelity with linear complexity. Our results indicate that many reported ultralong decoherence times stem from artifacts like coherence-population mixing rather than genuine noise suppression. By ensuring dynamical authenticity, Hadamard phase cycling establishes a robust framework for reliable quantum control, paving the way for reassessment and advancement of coherence benchmarks in the NISQ era.

quant-ph↗

arXiv2026

Tunable spin-phonon polarons in a chiral molecular qubit framework

Chiral structures that produce asymmetric spin-phonon coupling can theoretically generate spin-phonon polarons -- quasiparticles exhibiting non-degenerate spin states with phonon displacements. These quasiparticles are speculated to be the origin of chirality-induced spin selectivity and presumably can display exotic dynamic behaviors. However, direct experimental evidence of spin-phonon polarons has been lacking. Using a chiral molecular qubit framework embedding stable semiquinone-like radicals, we report spin dynamic signatures that indicate the formation of spin-phonon polarons for the first time. Our non-adiabatic model reveals that these quasiparticles introduce an active spin relaxation channel when polaron reorganization energy approaches Zeeman splitting. This new channel manifests itself as anomalous, temperature-independent spin relaxation, which can be suppressed by high magnetic fields or pore-filling solvents (e.g. CH2Cl2, CS2). Such field- and guest-tunable relaxation is unattainable in conventional spin systems. Harnessing this mechanism could boost repetition rates in spin-based quantum information technologies without compromising coherence or quantum sensing performance.

cond-mat.mes-hall↗

arXiv2025

Ultralong Room-Temperature Qubit Lifetimes of Covalent Organic Frameworks

Molecular electron spin qubits offer atomic-level tunability and room-temperature quantum coherence. Their integration into engineered solid-state matrices can enhance performance towards ambient quantum information technologies. Herein, we demonstrate covalent organic frameworks (COFs) as programmable matrices of stable organic radical qubits allowing strategic optimization of spin-phonon and spin-spin interactions. Using two classic boronate-ester frameworks, COF-5 and COF-108, to host semiquinone-like radical qubits, we achieve ultralong spin relaxation time (T1 > 300 μs) at 298 K, which outperforms most molecular qubits and rivals inorganic spin defects. The suppression of spin relaxation is attributed to rigid and neutral structures as well as carbon-centered spin distributions that effectively weaken spin-phonon coupling. Employing dynamical decoupling methods to both COFs improves their quantum coherence and enables room-temperature detection of nuclear spins including 1H, 11B, and 13C. Our work establishes COFs as designer quantum materials, opening new avenues for quantum sensing of nuclear spins at room temperature.

quant-ph↗