arXiv subjects

Wu Zhou

Publications and source records attributed to Wu Zhou.

At least 37 records · Page 2Linked to original sources

arXiv2024

Coupling Between Local and Global Oscillations in Palladium-Catalysed Methane Oxidation

The interplay between order and disorder is crucial across various fields, especially in understanding oscillatory phenomena. Periodic oscillations are frequently observed in heterogeneous catalysis, yet their underlying mechanisms need deeper exploration. Here, we investigate how periodic oscillations arise during methane oxidation catalysed by palladium nanoparticles (Pd NPs), utilizing a suite of complementary operando techniques across various spatial scales. We found that reaction intensity and collective dynamic modes can be tuned by the reactant gas-flow rate. At lower gas-flow rates, we observed periodic facet reconstruction of Pd NPs correlated with repeated bubbling behaviour at the Pd/PdO interface, without evident global oscillatory responses. Conversely, at higher gas-flow rates, Pd NPs undergo chaotic transformations between metallic and oxidized states, resulting in overall oscillation. Integrating our observations at different gas-flow rates, we attributed the emergence of global oscillation to thermal coupling regulated by gas flow and connected local and global dynamics through a weak synchronization mechanism. This work demonstrates the correlations between open surfaces and interfaces, chaos and regularity, and dissipative processes and coupling behaviour. Our findings offer critical insights into the complexity behind catalytic oscillations and provide guidance for modulating oscillatory behaviours in catalytic processes, with significant implications for both science and industry.

physics.chem-ph↗

arXiv2024

Unusual charge density wave introduced by Janus structure in monolayer vanadium dichalcogenides

As a fundamental structural feature, the symmetry of materials determines the exotic quantum properties in transition metal dichalcogenides (TMDs) with charge density wave (CDW). Breaking the inversion symmetry, the Janus structure, an artificially constructed lattice, provides an opportunity to tune the CDW states and the related properties. However, limited by the difficulties in atomic-level fabrication and material stability, the experimental visualization of the CDW states in 2D TMDs with Janus structure is still rare. Here, using surface selenization of VTe2, we fabricated monolayer Janus VTeSe. With scanning tunneling microscopy, an unusual root13-root13 CDW state with threefold rotational symmetry breaking was observed and characterized. Combined with theoretical calculations, we find this CDW state can be attributed to the charge modulation in the Janus VTeSe, beyond the conventional electron-phonon coupling. Our findings provide a promising platform for studying the CDW states and artificially tuning the electronic properties toward the applications.

cond-mat.mtrl-sci↗

arXiv2024

Systematic Absences of Optical Phonon Modes in Phonon Dispersion Measured by Electron Microscopy

Phonon dispersion is widely used to elucidate the vibrational properties of materials. As an emerging technique, momentum-resolved vibrational spectroscopy in scanning transmission electron microscopy (STEM) offers an unparalleled approach to explore q-dependent phonon behavior at local structures. In this study, we systematically investigate the phonon dispersion of monolayer graphene across several Brillouin zones (BZs) using momentum-resolved vibrational spectroscopy and find that the optical phonon signals vanish at the Γ points with indices (hk0) satisfying h+2k=3n (n denoted integers). Theoretical analysis reveals that the observed phenomena arise from the complete destructive interference of the scattered waves from different basis atoms. This observation, corroborated by the study of diamond, should be a general characteristic of materials composed of symmetrically equivalent pairs of the same elements. Moreover, our results emphasize the importance of multiple scattering in interpreting the vibrational signals in bulk materials. We demonstrate that the systematic absences and dynamic effects, which have not been much appreciated before, offer new insights into the experimental assessment of local vibrational properties of materials.

cond-mat.mtrl-sci↗

arXiv2024

Controlled fabrication of freestanding monolayer SiC by electron irradiation

The design and preparation of novel quantum materials with atomic precision are crucial for exploring new physics and for device applications. Electron irradiation has demonstrated as an effective method for preparing novel quantum materials and quantum structures that could be challenging to obtain otherwise. It features the advantages of precise control over the patterning of such new materials and their integration with other materials with different functionalities. Here, we present a new strategy for fabricating freestanding monolayer SiC within nanopores of a graphene membrane. By regulating the energy of the incident electron beam and the in-situ heating temperature in a scanning transmission electron microscope (STEM), we can effectively control the patterning of nanopores and subsequent growth of monolayer SiC within the graphene lattice. The resultant SiC monolayers seamlessly connect with the graphene lattice, forming a planar structure distinct by a wide direct bandgap. Our in-situ STEM observations further uncover that the growth of monolayer SiC within the graphene nanopore is driven by a combination of bond rotation and atom extrusion, providing new insights into the atom-by-atom self-assembly of freestanding two-dimensional (2D) monolayers.

cond-mat.mtrl-sci↗

arXiv2024

Defect-Assisted Domain Nucleation Drives Unique Exchange Bias Phenomena in $\bf{MnBi_2Te_4}$

The study of the mechanism of exchange bias phenomena and the achievement of its efficient control are of great importance, as it promotes the revelation of unique exchange interactions and the development of exotic applications. However, it is challenging due to the elusive interface between magnetic phases. In this study, we report an unprecedented exchange bias phenomenon observed in ultrathin uncompensated antiferromagnetic MnBi$_2$Te$_4$. The magnitude and direction of the exchange field can be intentionally controlled by designing a magnetic field sweep protocol without a field cooling process. The combined experimental and theoretical simulation results indicate that the spin-flip process assisted by the ubiquitous defect-induced pinning domain sites with varying inner exchange interactions might give rise to the emergence and robustness of this peculiar exchange bias. The temperature and thickness dependence of the exchange bias phenomena are systematically investigated for further study and exploitation of its unique properties. This mechanism hold promise for highly tunable exchange bias in prevalent magnetic systems by engineering the properties of domain structures, and also offers promising avenues for the design of spintronic devices combing its topology based on MnBi$_2$Te$_4$.

cond-mat.mtrl-sci↗

arXiv2024

Thermal transport in a 2D amorphous material

Two-dimensional (2D) crystals proved revolutionary soon after graphene was discovered in 2004. However, 2D amorphous materials only became accessible in 2020 and remain largely unexplored. In particular, the thermophysical properties of amorphous materials are of great interest upon transition from 3D to 2D. Here, we probe thermal transport in 2D amorphous carbon. A cross-plane thermal conductivity ($κ$) down to 0.079 $\rm{Wm}^{-1}K^{-1}$ is measured for van der Waals stacked multilayers at room temperature, which is among the lowest reported to date. Meanwhile, an unexpectedly high in-plane $κ$ is obtained for freestanding monolayers which is a few times larger than what is predicted by conventional wisdom for 3D amorphous carbon with similar $\rm{sp}^{2}$ fraction. Our molecular dynamics simulations reveal the role of disorder and highlight the impact of dimensionality. Amorphous materials at the 2D limit open up new avenues for understanding and manipulating heat at the atomic scale.

cond-mat.mtrl-sci↗

arXiv2024

An Order-Complexity Aesthetic Assessment Model for Aesthetic-aware Music Recommendation

Computational aesthetic evaluation has made remarkable contribution to visual art works, but its application to music is still rare. Currently, subjective evaluation is still the most effective form of evaluating artistic works. However, subjective evaluation of artistic works will consume a lot of human and material resources. The popular AI generated content (AIGC) tasks nowadays have flooded all industries, and music is no exception. While compared to music produced by humans, AI generated music still sounds mechanical, monotonous, and lacks aesthetic appeal. Due to the lack of music datasets with rating annotations, we have to choose traditional aesthetic equations to objectively measure the beauty of music. In order to improve the quality of AI music generation and further guide computer music production, synthesis, recommendation and other tasks, we use Birkhoff's aesthetic measure to design a aesthetic model, objectively measuring the aesthetic beauty of music, and form a recommendation list according to the aesthetic feeling of music. Experiments show that our objective aesthetic model and recommendation method are effective.

cs.CV↗

arXiv2024

Stoichiometric control of electron mobility and 2D superconductivity at LaAlO$_3$-SrTiO$_3$ interfaces

SrTiO$_3$-based conducting interfaces, which exhibit coexistence of gate-tunable 2D superconductivity and strong Rashba spin-orbit coupling (RSOC), are candidates to host topological superconductive phases. Yet, superconductivity is usually in the dirty limit, which tends to suppress nonconventional pairing and therefore challenges these expectations. Here we report on LaAlO$_3$/SrTiO$_3$ (LAO/STO) interfaces with remarkably large mobility and mean free paths comparable to the superconducting coherence length, approaching the clean limit for superconductivity. We further show that the carrier density, mobility, and formation of the superconducting condensate are controlled by the fine-tuning of La/Al chemical ratio in the LAO film. Interestingly, we find a region in the superconducting phase diagram where the critical temperature is not suppressed below the Lifshitz transition, at odds with previous experimental investigations. These findings point out the relevance of achieving a clean-limit regime to enhance the observation of unconventional pairing mechanisms in these systems

cond-mat.supr-con↗

arXiv2023

Empowering high-dimensional optical fiber communications with integrated photonic processors

Mode division multiplexing (MDM) in optical fibers enables multichannel capabilities for various applications, including data transmission, quantum networks, imaging, and sensing. However, MDM optical fiber systems, usually necessities bulk-optics approaches for launching different orthogonal fiber modes into the multimode optical fiber, and multiple-input multiple-output digital electronic signal processing at the receiver side to undo the arbitrary mode scrambling in a circular-core optical fiber. Here we show that a high-dimensional optical fiber communication system can be entirely implemented by a reconfigurable integrated photonic processor, featuring kernels of multichannel mode multiplexing transmitter and all-optical descrambling receiver. High-speed and inter-chip communications involving six spatial- and polarization modes have been experimentally demonstrated with high efficiency and high-quality eye diagrams, despite the presence of random mode scrambling and polarization rotation in a circular-core few-mode fiber. The proposed photonic integration approach holds promising prospects for future space-division multiplexing applications.

physics.optics↗

arXiv2023

Ultra-compact and efficient integrated multichannel mode multiplexer in silicon for few-mode fibers

Space-division multiplexing (SDM) is one of the key enabling technologies to increase the capacity of fiber communication systems. However, implementing SDM-based systems using multimode fiber has been challenging with the need for compact, low-cost, and scalable mode de/multiplexer (DE/MUX). Here we present a novel integrated mode MUX for few-mode fibers (FMFs) which can launch up to eight spatial and polarization channels. The new design is composed of a two-dimensional multimode grating coupler (MMGC), highly compact mode size converters (MSCs), and adiabatic directional couplers (ADCs). Eight data lanes in FMFs can be selectively launched with integrated optical phase shifters. Experimental results reveal efficient chip-to-fiber coupling with peak efficiencies of -3.8 dB, -5.5 dB, -3.6 dB, and -4.1 dB for LP01, LP11a, LP11b, and LP21b modes, respectively. Meanwhile, the proposed design can efficiently couple all the degenerate LP modes in a two-mode FMF, allowing signal descrambling in the demultiplexer. Thanks to the use of integrated subwavelength Mikaelian lens for mode-independent field size conversion with loss $\leq$0.25 dB, the total footprint of the MMGC and MSCs is only 35x35 $μ$m$^{2}$. The proposed design shows great potential for densely integrated photonic circuits in future SDM applications.

physics.optics↗

arXiv2023

Phonon vortices at heavy impurities in two-dimensional materials

The advent of monochromated electron energy-loss spectroscopy has enabled atomic-resolution vibrational spectroscopy, which triggered interest in spatially localized or quasi-localized vibrational modes in materials. Here we report the discovery of phonon vortices at heavy impurities in two-dimensional materials. We use density-functional-theory calculations for two configurations of Si impurities in graphene, Si-C3 and Si-C4, to examine atom-projected phonon densities of states and display the atomic-displacement patterns for select modes that are dominated by impurity displacements. The vortices are driven by large displacements of the impurities, and reflect local symmetries. Similar vortices are found at phosphorus impurities in hexagonal boron nitride, suggesting that they may be a feature of heavy impurities in crystalline materials. Phonon vortices at defects are expected to play a role in thermal conductivity and other properties.

cond-mat.mtrl-sci↗

arXiv2023

Controlling the 2D magnetism of CrBr$_3$ by van der Waals stacking engineering

The manipulation of two-dimensional (2D) magnetic order is of significant importance to facilitate future 2D magnets for low-power and high-speed spintronic devices. Van der Waals stacking engineering makes promises for controllable magnetism via interlayer magnetic coupling. However, directly examining the stacking order changes accompanying magnetic order transitions at the atomic scale and preparing device-ready 2D magnets with controllable magnetic orders remain elusive. Here, we demonstrate effective control of interlayer stacking in exfoliated CrBr$_3$ via thermally assisted strain engineering. The stable interlayer ferromagnetic (FM), antiferromagnetic (AFM), and FM-AFM coexistent ground states confirmed by the magnetic circular dichroism measurements are realized. Combined with the first-principles calculations, the atomically-resolved imaging technique reveals the correlation between magnetic order and interlay stacking order in the CrBr$_3$ flakes unambiguously. A tunable exchange bias effect is obtained in the mixed phase of FM and AFM states. This work will introduce new magnetic properties by controlling the stacking order, and sequence of 2D magnets, providing ample opportunities for their application in spintronic devices.

cond-mat.mtrl-sci↗

arXiv2023

Teeth And Root Canals Segmentation Using ZXYFormer With Uncertainty Guidance And Weight Transfer

This study attempts to segment teeth and root-canals simultaneously from CBCT images, but there are very challenging problems in this process. First, the clinical CBCT image data is very large (e.g., 672 *688 * 688), and the use of downsampling operation will lose useful information about teeth and root canals. Second, teeth and root canals are very different in morphology, and it is difficult for a simple network to identify them precisely. In addition, there are weak edges at the tooth, between tooth and root canal, which makes it very difficult to segment such weak edges. To this end, we propose a coarse-to-fine segmentation method based on inverse feature fusion transformer and uncertainty estimation to address above challenging problems. First, we use the downscaled volume data (e.g., 128 * 128 * 128) to conduct coarse segmentation and map it to the original volume to obtain the area of teeth and root canals. Then, we design a transformer with reverse feature fusion, which can bring better segmentation effect of different morphological objects by transferring deeper features to shallow features. Finally, we design an auxiliary branch to calculate and refine the difficult areas in order to improve the weak edge segmentation performance of teeth and root canals. Through the combined tooth and root canal segmentation experiment of 157 clinical high-resolution CBCT data, it is verified that the proposed method is superior to the existing tooth or root canal segmentation methods.

cs.CV↗

arXiv2023

An Order-Complexity Model for Aesthetic Quality Assessment of Homophony Music Performance

Although computational aesthetics evaluation has made certain achievements in many fields, its research of music performance remains to be explored. At present, subjective evaluation is still a ultimate method of music aesthetics research, but it will consume a lot of human and material resources. In addition, the music performance generated by AI is still mechanical, monotonous and lacking in beauty. In order to guide the generation task of AI music performance, and to improve the performance effect of human performers, this paper uses Birkhoff's aesthetic measure to propose a method of objective measurement of beauty. The main contributions of this paper are as follows: Firstly, we put forward an objective aesthetic evaluation method to measure the music performance aesthetic; Secondly, we propose 10 basic music features and 4 aesthetic music features. Experiments show that our method performs well on performance assessment.

cs.SD↗

arXiv2023

An Order-Complexity Model for Aesthetic Quality Assessment of Symbolic Homophony Music Scores

Computational aesthetics evaluation has made great achievements in the field of visual arts, but the research work on music still needs to be explored. Although the existing work of music generation is very substantial, the quality of music score generated by AI is relatively poor compared with that created by human composers. The music scores created by AI are usually monotonous and devoid of emotion. Based on Birkhoff's aesthetic measure, this paper proposes an objective quantitative evaluation method for homophony music score aesthetic quality assessment. The main contributions of our work are as follows: first, we put forward a homophony music score aesthetic model to objectively evaluate the quality of music score as a baseline model; second, we put forward eight basic music features and four music aesthetic features.

cs.SD↗

arXiv2022

Superconductivity and orbital-selective nematic order in a new titanium-based kagome metal CsTi3Bi5

Fabrication of new types of superconductors with novel physical properties has always been a major thread in the research of superconducting materials. An example is the enormous interests generated by the cascade of correlated topological quantum states in the newly discovered vanadium-based kagome superconductors AV3Sb5 (A=K, Rb, and Cs) with a Z2 topological band structure. Here we report the successful fabrication of single-crystals of titanium-based kagome metal CsTi3Bi5 and the observation of superconductivity and electronic nematicity. The onset of the superconducting transition temperature Tc is around 4.8 K. In sharp contrast to the charge density wave superconductor AV3Sb5, we find that the kagome superconductor CsTi3Bi5 preserves translation symmetry, but breaks rotational symmetry and exhibits an electronic nematicity. The angular-dependent magnetoresistivity shows a remarkable two-fold rotational symmetry as the magnetic field rotates in the kagome plane. The scanning tunneling microscopy and spectroscopic imaging detect rotational-symmetry breaking C2 quasiparticle interference patterns (QPI) at low energies, providing further microscopic evidence for electronic nematicity. Combined with first-principle calculations, we find that the nematic QPI is orbital-selective and dominated by the Ti dxz and dyz orbitals, possibly originating from the intriguing orbital bond nematic order. Our findings in the new "135" material CsTi3Bi5 provide new directions for exploring the multi-orbital correlation effect and the role of orbital or bond order in the electron liquid crystal phases evidenced by the symmetry breaking states in kagome superconductors.

cond-mat.supr-con↗

arXiv2022

Titanium doped kagome superconductor CsV3-xTixSb5 and two distinct phases

The vanadium-based kagome superconductor CsV3Sb5 has attracted tremendous attention due to its unexcepted anomalous Hall effect (AHE), charge density waves (CDWs), nematicity, and a pseudogap pair density wave (PDW) coexisting with unconventional strong-coupling superconductivity (SC). The origins of CDWs, unconventional SC, and their correlation with different electronic states in this kagome system are of great significance, but so far, are still under debate. Chemical doping in the kagome layer provides one of the most direct ways to reveal the intrinsic physics, but remains unexplored. Here, we report, for the first time, the synthesis of Ti-substituted CsV3Sb5 single crystals and its rich phase diagram mapping the evolution of intertwining electronic states. The Ti atoms directly substitute for V in the kagome layers. CsV3-xTixSb5 shows two distinct SC phases upon substitution. The Ti slightly-substituted phase displays an unconventional V-shaped SC gap, coexisting with weakening CDW, PDW, AHE, and nematicity. The Ti highly-substituted phase has a U-shaped SC gap concomitant with a short-range rotation symmetry breaking CDW, while long-range CDW, twofold symmetry of in-plane resistivity, AHE, and PDW are absent. Furthermore, we also demonstrate the chemical substitution of V atoms with other elements such as Cr and Nb, showing a different modulation on the SC phase and CDWs. These findings open up a way to synthesise a new family of doped CsV3Sb5 materials, and further representing a new platform for tuning the different correlated electronic states and superconducting pairing in kagome superconductors.

cond-mat.supr-con↗

arXiv2022

Aesthetic Visual Question Answering of Photographs

Aesthetic assessment of images can be categorized into two main forms: numerical assessment and language assessment. Aesthetics caption of photographs is the only task of aesthetic language assessment that has been addressed. In this paper, we propose a new task of aesthetic language assessment: aesthetic visual question and answering (AVQA) of images. If we give a question of images aesthetics, model can predict the answer. We use images from \textit{www.flickr.com}. The objective QA pairs are generated by the proposed aesthetic attributes analysis algorithms. Moreover, we introduce subjective QA pairs that are converted from aesthetic numerical labels and sentiment analysis from large-scale pre-train models. We build the first aesthetic visual question answering dataset, AesVQA, that contains 72,168 high-quality images and 324,756 pairs of aesthetic questions. Two methods for adjusting the data distribution have been proposed and proved to improve the accuracy of existing models. This is the first work that both addresses the task of aesthetic VQA and introduces subjectiveness into VQA tasks. The experimental results reveal that our methods outperform other VQA models on this new task.

cs.CV↗