arXiv subjects

Xinqiang Wang

Publications and source records attributed to Xinqiang Wang.

14 recordsLinked to original sources

arXiv2026

Fractional-Monolayer 2D-GaN/AlN Structures: Growth Kinetics and UVC-emitter Applications

The paper reports on fundamental properties of the GaN/AlN quantum wells (QWs) with nominal subcritical thicknesses of 0.75-2 monolayers (MLs). They are grown by plasma-activated molecular beam epitaxy, varying either the nominal thickness or the gallium-to-nitrogen flux ratio. In situ monitoring reveals difference in 2D nucleation and step-flow growth modes of the QWs. The emission charactestics of QWs with integer thicknesses of 1 and 2 MLs depend weakly on the growth mechanism. In contrast, the intensity and spectral position luminescence of QWs with fractional-ML thicknesses are determined by the growth mechanism. Using ab initio calculations, a phenomenological model is proposed that describes fractional-ML QWs either as arrays of 2D quantum disks or as arrays of 2D quantum ribbons, in cases where 2D nucleation or step-flow growth mechanisms predominate, respectively. This model is generally consistent with experimental data on photo- and cathodoluminescence of heterostructures with multiple (250) GaN/AlN QWs. These heterostructures, when pumped by electrom beam at an energy 12.5 keV with a maximum pulse current of 2 A, exhibit linear current dependences of optical peak powers up to 1 and 37 W for wavelengths of 228 and 256 nm, respectively, making them promising for use as powerfull ultraviolet-C emitters.

cond-mat.mtrl-sci↗

arXiv2024

Boundary conditions dictate frequency dependence of thermal conductivity in silicon

Non-Fourier thermal transports have drawn significant attention for decades. Among them, the frequency dependent thermal conductivity has been extensively explored by pump-probe techniques, such as time-domain thermoreflectance, which is employed to probe the spectra of phonon mean free paths. However, previous studies on silicon have not exhibited apparent frequency dependence despite its broad phonon distribution. Here, we report the frequency dependent thermal transport in Al/Si with an atomically sharp interface, where the matched Debye temperatures preserve non-equilibrium between low- and high-energy phonons in Si. The dependence vanishes in Al/SiO$_2$/Si at room temperature, since the SiO$_2$ interlayer facilitates phonon scattering and destroys thermal non-equilibrium. At 80 K, frequency dependence reemerges in Al/SiO$_2$/Si, due to reduced interfacial phonon scattering. Our findings highlight the significance of boundary conditions in frequency dependent thermal conductivity.

cond-mat.mtrl-sci↗

arXiv2024

Single-atom-resolved vibrational spectroscopy of a dislocation

Phonon resistance from dislocation scattering is often divided into short-range core interactions and long-range strain field interactions. Using electron energy-loss spectroscopy on a GaN dislocation, we report observations of vibrational modes localized at specific core atoms (short-range) and strain-driven phonon energy shifts around the dislocation (long-range). Ab initio calculations support these findings and draw out additional details. This study reveals atomically resolved vibrational spectra of dislocations, thus offering insights for engineering improved material functionalities.

cond-mat.mtrl-sci↗

arXiv2023

Al-Based Few-Hydrogen Metal-Bonded Perovskite High-$T_c$ Superconductor Al$_4$H up to 54 K under Atmospheric Pressure

Multi-hydrogen lanthanum hydrides have shown the highest critical temperature $T_c$ at 250-260 K under 170-200 GPa. However, such high pressure is a great challenge for sample preparation and practical application. To address this challenge, we propose a novel design strategy for ambient-pressure high-$T_c$ superconductors by constructing new few-hydrogen metal-bonded perovskite hydrides, such as Al-based superconductor $\rm {Al_4H}$, with better ductility than the well-known multi-hydrogen, cuprate and Fe-based superconductors. Based on the Migdal-Eliashberg theory, we predict that the structurally stable $\rm {Al_4H}$ has a favorable high $T_c$ up to 54 K under atmospheric pressure, similar to SmOFeAs.

cond-mat.supr-con↗

arXiv2023

Atomic-Scale Tracking Phase Transition Dynamics of Berezinskii-Kosterlitz-Thouless Polar Vortex-Antivortex

Particle-like topologies, such as vortex-antivortex (V-AV) pairs, have garnered significant attention in the field of condensed matter. However, the detailed phase transition dynamics of V-AV pairs, as exemplified by self-annihilation, motion, and dissociation, have yet to be verified in real space due to the lack of suitable experimental techniques. Here, we employ polar V-AV pairs as a model system and track their transition pathways at atomic resolution with the aid of in situ (scanning) transmission electron microscopy and phase field simulations. We demonstrate the absence of a Berezinskii-Kosterlitz-Thouless phase transition between the room-temperature quasi-long-range ordered ground phase and the high-temperature disordered phase. Instead, we observe polarization suppression in bound V-AV pairs as the temperature increases. Furthermore, electric fields can promote the vortex and antivortex to approach each other and annihilate near the interface. The elucidated intermediate dynamic behaviors of polar V-AV pairs under thermal- and electrical-fields lay the foundation for their potential applications in electronic devices. Moreover, the dynamic behaviors revealed at atomic scale provide us new insights into understanding topological phase of matter and their topological phase transitions.

physics.app-ph↗

arXiv2023

Metal-bonded perovskite lead hydride with phonon-mediated superconductivity up to 46 K under atmospheric pressure

In the search for high-temperature superconductivity in hydrides, a plethora of multi-hydrogen superconductors have been theoretically predicted, and some have been synthesized experimentally under ultrahigh pressures of several hundred GPa. However, the impracticality of these high-pressure methods has been a persistent issue. In response, we propose a new approach to achieve high-temperature superconductivity under atmospheric pressure by implanting hydrogen into lead to create a stable few-hydrogen metal-bonded perovskite, Pb$_4$H. This approach diverges from the popular design methodology of multi-hydrogen covalent high critical temperature ($T_c$) superconductors under ultrahigh pressure. By solving the anisotropic Migdal-Eliashberg (ME) equations, we demonstrate that perovskite Pb$_4$H is a typical phonon-mediated superconductor with a $T_c$ of 46 K, which is six times higher than that of bulk Pb (7.22 K) and higher than that of MgB$_2$ (39 K). The high $T_c$ can be attributed to the strong electron-phonon coupling (EPC) strength of 2.45, which arises from hydrogen implantation in lead that induces several high-frequency optical phonon modes with a relatively large phonon linewidth resulting from H atom vibration. The metallic-bonding in perovskite Pb$_4$H not only improves the structural stability but also guarantees better ductility than the widely investigated multi-hydrogen, iron-based, and cuprate superconductors. These results suggest that there is potential for the exploration of new high-temperature superconductors under atmospheric pressure and may reignite interest in their experimental synthesis soon.

cond-mat.supr-con↗

arXiv2022

Approximation of Images via Generalized Higher Order Singular Value Decomposition over Finite-dimensional Commutative Semisimple Algebra

Low-rank approximation of images via singular value decomposition is well-received in the era of big data. However, singular value decomposition (SVD) is only for order-two data, i.e., matrices. It is necessary to flatten a higher order input into a matrix or break it into a series of order-two slices to tackle higher order data such as multispectral images and videos with the SVD. Higher order singular value decomposition (HOSVD) extends the SVD and can approximate higher order data using sums of a few rank-one components. We consider the problem of generalizing HOSVD over a finite dimensional commutative algebra. This algebra, referred to as a t-algebra, generalizes the field of complex numbers. The elements of the algebra, called t-scalars, are fix-sized arrays of complex numbers. One can generalize matrices and tensors over t-scalars and then extend many canonical matrix and tensor algorithms, including HOSVD, to obtain higher-performance versions. The generalization of HOSVD is called THOSVD. Its performance of approximating multi-way data can be further improved by an alternating algorithm. THOSVD also unifies a wide range of principal component analysis algorithms. To exploit the potential of generalized algorithms using t-scalars for approximating images, we use a pixel neighborhood strategy to convert each pixel to "deeper-order" t-scalar. Experiments on publicly available images show that the generalized algorithm over t-scalars, namely THOSVD, compares favorably with its canonical counterparts.

cs.LG↗

arXiv2021

Drive high power UVC-LED wafer into low-cost 4-inch era: effect of strain modulation

Ultraviolet-C light-emitting diodes (UVC-LEDs) have great application in pathogen inactivation under various kinds of situations, especially in the fight against the COVID-19. Unfortunately, its epitaxial wafers are so far limited to 2-inch size, which greatly increases the cost of massive production. In this work, we report the 4-inch crack-free high-power UVC-LED wafer. This achievement relies on a proposed strain-tailored strategy, where a three-dimensional to two-dimensional (3D-2D) transition layer is introduced during the homo-epitaxy of AlN on high temperature annealed (HTA)-AlN template, which successfully drives the original compressive strain into tensile one and thus solves the challenge of realizing high quality Al$_{0.6}$Ga$_{0.4}$N layer with a flat surface. This smooth Al$_{0.6}$Ga$_{0.4}$N layer is nearly pseudomorphically grown on the strain-tailored HTA-AlN template, leading to 4-inch UVC-LED wafers with outstanding performances. Our strategy succeeds in compromising the bottlenecked contradictory in producing large-sized UVC-LED wafer on pronounced crystalline AlN template: The compressive strain in HTA-AlN allows for crack-free 4-inch wafer, but at the same time leads to a deterioration of the AlGaN morphology and crystal quality. The launch of 4-inch wafers makes the chip fabrication process of UVC-LEDs matches the mature blue one, and will definitely speed up the universal of UVC-LED in daily life.

cond-mat.mtrl-sci↗

arXiv2021

The exciton-polariton properties of hexagonal BN based microcavity and their potential applications in BEC and superconductivity

Microcavity exciton-polaritons are two-dimensional bosonic quasiparticles composed by excitons and photons. Using model Hamiltonian with parameters generated from ab initio density-functional theory and Bathe-Salpeter Equation calculations, we investigate the exciton and the exciton-polariton properties of hexagnonal boron nitride (hBN) based microcavity. We show that hBN based microcavities, including monolayer and all-dielectric ones, are promising in optoelectronic applications. Room temperature exciton-polariton Bose-Einstein Condensation can be achieved because of the large oscillating strength and binding energy of the exciton, and the strong interaction between the exciton-polaritons and the longitudinal optical phonons. Based on this BEC state, exciton-polariton mediated superconducting device can also be fabricated at such moderate temperatures using the microcavity structure proposed by Laussy et al.

cond-mat.mtrl-sci↗

arXiv2021

Generalized Image Reconstruction over T-Algebra

Principal Component Analysis (PCA) is well known for its capability of dimension reduction and data compression. However, when using PCA for compressing/reconstructing images, images need to be recast to vectors. The vectorization of images makes some correlation constraints of neighboring pixels and spatial information lost. To deal with the drawbacks of the vectorizations adopted by PCA, we used small neighborhoods of each pixel to form compounded pixels and use a tensorial version of PCA, called TPCA (Tensorial Principal Component Analysis), to compress and reconstruct a compounded image of compounded pixels. Our experiments on public data show that TPCA compares favorably with PCA in compressing and reconstructing images. We also show in our experiments that the performance of TPCA increases when the order of compounded pixels increases.

cs.CV↗

arXiv2020

The influence of high-energy local orbitals and electron-phonon interactions on the band gaps and optical spectra of hexagonal boron nitride

We report $ab$ $initio$ band diagram and optical absorption spectra of hexagonal boron nitride ($h$-BN), focusing on unravelling how the completeness of basis set for $GW$ calculations and how electron-phonon interactions (EPIs) impact on them. The completeness of basis set, an issue which was seldom discussed in previous optical spectra calculations of $h$-BN, is found crucial in providing converged quasiparticle band gaps. In the comparison among three different codes, we demonstrate that by including high-energy local orbitals in the all-electron linearized augmented plane waves based $GW$ calculations, the quasiparticle direct and fundamental indirect band gaps are widened by $\sim$0.2 eV, giving values of 6.81 eV and 6.25 eV respectively at the $GW_0$ level. EPIs, on the other hand, reduce them to 6.62 eV and 6.03 eV respectively at 0 K, and 6.60 eV and 5.98 eV respectively at 300 K. With clamped crystal structure, the first peak of the absorption spectrum is at 6.07 eV, originating from the direct exciton contributed by electron transitions around $K$ in the Brillouin zone. After including the EPIs-renormalized quasiparticles in the Bethe-Salpeter equation, the exciton-phonon coupling shifts the first peak to 5.83 eV at 300 K, lower than the experimental value of $\sim$6.00 eV. This accuracy is acceptable to an $ab$ $initio$ description of excited states with no fitting parameter.

cond-mat.mtrl-sci↗

arXiv2015

Quantitatively analyzing the mechanism of giant circular dichroism in extrinsic plasmonic chiral nanostructures by the interplay of electric and magnetic dipoles

The plasmonic chirality has drawn a lot of attention because of the tunable circular dichroism (CD) and the enhancement for the signal of chiral molecules. Different mechanisms have been proposed for explaining the plasmonic CD, however, a quantitative one like ab initio mechanism in chiral molecules is still unavailable. In this work, a mechanism similar to the chiral molecules is analyzed. The giant extrinsic circular dichroism of plasmonic splitting rectangle ring is quantitatively investigated theoretically. The interplay of electric and magnetic modes of the meta-structure is proposed to explain the giant CD. The interplay is analyzed both in an analytical coupled electric-magnetic dipoles model and finite element method model. The surface charge distributions show that the circular current yielded in the splitting rectangle ring makes it behave like a magneton at some resonant modes, which interact with electric modes and results in a mixing of the two kinds of modes. The strong interplay of the two kinds of modes is mainly responsible for the giant CD.The analysis of the chiral near field of the structure shows potential applications in chiral molecule sensing.

cond-mat.mes-hall↗

arXiv2014

Phase diagram of (Li1-xFex)OHFeSe: a bridge between iron selenide and arsenide superconductors

Previous experimental results have shown important differences between iron selenide and arsenide superconductors, which seem to suggest that the high temperature superconductivity in these two subgroups of iron-based family may arise from different electronic ground states. Here, we report the complete phase diagram of a newly synthesized superconducting (SC) system (Li1-xFex)OHFeSe with a similar structure to FeAs-based superconductors. In the non-SC samples, an antiferromagnetic (AFM) spin-density-wave (SDW) transition occurs at ~127 K. This is the first example to demonstrate such an SDW phase in FeSe-based superconductor system. Transmission electron microscopy (TEM) shows that a well-known sqrr(5) x sqrr(5) iron vacancy ordered state, resulting in an AFM order at ~ 500K in AyFe2-xSe2 (A = metal ions) superconductor system, is absent in both non-SC and SC samples, but a unique superstructure with a modulation wave vector q=1/2(1, 1, 0), identical to that seen in SC phase of KyFe2-xSe2, is dominant in the optimal SC sample (with an SC transition temperature Tc = 40 K). Hence, we conclude that the high-Tc superconductivity in (Li1-xFex)OHFeSe stems from the similarly weak AFM fluctuations as FeAs-based superconductors, suggesting a universal physical picture for both iron selenide and arsenide superconductors.

cond-mat.supr-con↗

arXiv2014

Generation and Electric Control of Spin-Coupled Valley Current in WSe2

The valley degree of freedom in layered transition-metal dichalcogenides (MX2) provides the opportunity to extend functionalities of novel spintronics and valleytronics devices. Due to spin splitting induced by spin-orbital coupling (SOC), the non-equilibrium charge carrier imbalance between two degenerate and inequivalent valleys to realize valley/spin polarization has been successfully demonstrated theoretically and supported by optical experiments. However, the generation of a valley/spin current by the valley polarization in MX2 remains elusive and a great challenge. Here, within an electric-double-layer transistor based on WSe2, we demonstrated a spin-coupled valley photocurrent whose direction and magnitude depend on the degree of circular polarization of the incident radiation and can be further greatly modulated with an external electric field. Such room temperature generation and electric control of valley/spin photocurrent provides a new property of electrons in MX2 systems, thereby enabling new degrees of control for quantum-confined spintronics devices.

cond-mat.mes-hall↗