arXiv subjects

Xinshu Zhang

Publications and source records attributed to Xinshu Zhang.

9 recordsLinked to original sources

arXiv2025

Dynamical crossover between stretched- and compressed-exponential relaxation in a photoexcited crystal

Anomalous relaxation is one of the hallmarks of disordered systems. Following perturbation by an external source, many glassy, jammed and amorphous systems relax as a stretched or compressed exponential as a function of time. However, despite their ubiquity, the origins of and the connection between these phenomenological relaxation functions remains to be understood. Here, we observe a tunable crossover from stretched- to compressed-exponential relaxation by photoexciting single crystal Ca3Ru2O7 across a structural phase transition. We present a simple lattice model that shows how spatial inhomogeneity and local, strain-mediated interactions cooperate to produce the dynamical crossover. Our work reveals anomalous relaxation dynamics in an idealized single crystal material and establishes photoexcited solids as promising platforms for probing the mechanisms underlying anomalous relaxation.

cond-mat.str-el↗

arXiv2025

Jeff = 1/2 Diamond Magnet CaCo2TeO6: A Pathway toward New Spin Physics and Quantum Functions

Diamond lattice magnets, formed by a framework of corner-sharing tetrahedra of magnetic cations, offer unique opportunities to realize novel states of matter for potential utility in information technology. However, research has mostly focused on AB2X4 spinels with Td magnetic ions. This hinders the atomically enabled tunability of competing interactions at different energy scales and the ability to harness many-body electronic states in quantum materials, making the discovery of quantum fluctuations and spin dynamics less accessible. We discover a new material CaCo2TeO6 featuring a diamond lattice of two distinct Oh-Co2+ sites. This material displays strong quantum fluctuations, increased competing magnetic exchange interactions, and field-induced tunability of magnetic structures. The results demonstrate how simple, fundamental refinements in ligand fields can profoundly influence the phase space of quantum matter.

cond-mat.mtrl-sci↗

arXiv2024

Directionally asymmetric nonlinear optics in planar chiral MnTiO$_3$

Planar chiral structures possess a two dimensional handedness that is associated with broken mirror symmetry. Such motifs span vast length scales; examples include certain pinwheel molecules, nautilus shells, cyclone wind patterns and spiral galaxies. Although pervasive in nature, it has only recently been found that condensed matter systems can exhibit a form of planar chirality through toroidal arrangements of electric dipoles, known as ferro-rotational (FR) order. A key characteristic of such order is that enantiomorph conversion occurs when the solid is flipped by 180 degrees about an in-plane axis. Consequently, ferro-rotationally ordered materials may exhibit directionally asymmetric response functions, even while preserving inversion and time-reversal symmetry. Such an effect, however, has yet to be observed. Using second harmonic interferometry, we show here that when circularly polarized light is incident on MnTiO$_3$, the generated nonlinear signal exhibits directional asymmetry. Depending on whether the incident light is parallel or anti-parallel to the FR axis, we observe a different conversion efficiency of two right (left) circularly polarized photons into a frequency-doubled left (right) circularly polarized photon. Our work uncovers a fundamentally new optical effect in ordered solids and opens up the possibility for developing novel nonlinear and directionally asymmetric optical devices.

physics.optics↗

arXiv2024

Comparative Raman Scattering Study of Crystal Field Excitations in Co-based Quantum Magnets

Co-based materials have recently been explored due to potential to realise complex bond-dependent anisotropic magnetism. Prominent examples include Na$_2$Co$_2$TeO$_6$, BaCo$_2$(AsO$_4$)$_2$, Na$_2$BaCo(PO$_4$)$_2$, and CoX$_2$ (X = Cl, Br, I). In order to provide insight into the magnetic interactions in these compounds, we make a comparative analysis of their local crystal electric field excitations spectra via Raman scattering measurements. Combining these measurements with theoretical analysis confirms the validity of $j_{\rm eff} = 1/2$ single-ion ground states for all compounds, and provides accurate experimental estimates of the local crystal distortions, which play a prominent role in the magnetic couplings between spin-orbital coupled Co moments.

cond-mat.str-el↗

arXiv2024

Light-induced electronic polarization in antiferromagnetic Cr2O3

In a solid, the electronic subsystem can exhibit incipient order with lower point group symmetry than the crystal lattice. External fields that couple to electronic order parameters have rarely been investigated, however, despite their potential importance to inducing exotic effects. Here, we show that when inversion symmetry is broken by the antiferromagnetic (AFM) order in Cr2O3, transmitting a linearly polarized light pulse through the crystal gives rise to an in-plane rotational symmetry breaking (from C3 to C1) via optical rectification. Using interferometric time-resolved second harmonic generation, we show that the ultrafast timescale of the symmetry reduction is indicative of a purely electronic response; the underlying spin and crystal structures remain unaffected. The symmetry-broken state exhibits a dipole moment, and its polar axis can be controlled with the incident light. Our results establish a coherent nonlinear optical protocol by which to break electronic symmetries and produce unconventional electronic effects in solids.

cond-mat.str-el↗

arXiv2023

Evidence for bootstrap percolation dynamics in a photo-induced phase transition

Upon intense femtosecond photo-excitation, a many-body system can undergo a phase transition through a non-equilibrium route, but understanding these pathways remains an outstanding challenge. Here, we use time-resolved second harmonic generation to investigate a photo-induced phase transition in Ca$_3$Ru$_2$O$_7$ and show that mesoscale inhomogeneity profoundly influences the transition dynamics. We observe a marked slowing down of the characteristic time, $τ$, that quantifies the transition between two structures. $τ$ evolves non-monotonically as a function of photo-excitation fluence, rising from below 200~fs to $\sim$1.4~ps, then falling again to below 200~fs. To account for the observed behavior, we perform a bootstrap percolation simulation that demonstrates how local structural interactions govern the transition kinetics. Our work highlights the importance of percolating mesoscale inhomogeneity in the dynamics of photo-induced phase transitions and provides a model that may be useful for understanding such transitions more broadly.

cond-mat.str-el↗

arXiv2022

A magnetic continuum observed by terahertz spectroscopy in a quantum spin liquid candidate BaCo$_2$(AsO$_4$)$_2$

Quantum spin liquids (QSLs) are topologically ordered exotic states of matter that host fractionalized excitations. Kitaev proposed a particular route towards a QSL via strongly bond-dependent interactions on the hexagonal lattice. A number of candidate Kitaev QSL materials have been pursued, but all have appreciable non-Kitaev interactions, which put these systems far from the QSL regime. Using time-domain terahertz spectroscopy (TDTS) we observed a broad magnetic continuum over a wide range of temperature and field in the honeycomb cobalt-based magnet, BaCo$_2$(AsO$_4$)$_2$, which has been proposed to be more ideal versions of a Kitaev QSL. Applying a small in-plane magnetic field of $\sim$ 0.5 T suppresses the magnetic order and at at even higher fields gives rise to a spin-polarized state. With 4T magnetic field oriented principally out-of-plane, a broad magnetic continuum was observed that could be consistent with a field induced QSL. Our results indicate BaCo$_2$(AsO$_4$)$_2$ to be a promising QSL candidate.

cond-mat.str-el↗

arXiv2020

Low Energy Magneto-optics of Tb$_{2}$Ti$_{2}$O$_{7}$ in [111] Magnetic Field

The pyrochlore magnet Tb$_{2}$Ti$_{2}$O$_{7}$ shows a lack of magnetic order to low temperatures and is considered to be a quantum spin liquid candidate. We perform time-domain THz spectroscopy on high quality Tb$_{2}$Ti$_{2}$O$_{7}$ crystal and study the low energy excitations as a function of [111] magnetic field with high energy resolution. The low energy crystal field excitations change their energies anomalously under magnetic field. Despite several sharp field dependent changes, we show that the material's spectrum can be described not by a phase transitions, but by field dependent hybridization between the low energy crystal field levels. We highlight the strong coupling between spin and lattice degrees of freedom in Tb$_{2}$Ti$_{2}$O$_{7}$ as evidenced by the magnetic field tunable crystal field environment. Calculations based on single ion physics with field induced symmetry reduction of the crystal field environment can reproduce our data.

cond-mat.str-el↗

arXiv2018

Hierarchy of exchange interactions in the triangular-lattice spin-liquid YbMgGaO$_{4}$

The spin-1/2 triangular lattice antiferromagnet YbMgGaO$_{4}$ has attracted recent attention as a quantum spin-liquid candidate with the possible presence of off-diagonal anisotropic exchange interactions induced by spin-orbit coupling. Whether a quantum spin-liquid is stabilized or not depends on the interplay of various exchange interactions with chemical disorder that is inherent to the layered structure of the compound. We combine time-domain terahertz spectroscopy and inelastic neutron scattering measurements in the field polarized state of YbMgGaO$_{4}$ to obtain better microscopic insights on its exchange interactions. Terahertz spectroscopy in this fashion functions as high-field electron spin resonance and probes the spin-wave excitations at the Brillouin zone center, ideally complementing neutron scattering. A global spin-wave fit to all our spectroscopic data at fields over 4T, informed by the analysis of the terahertz spectroscopy linewidths, yields stringent constraints on $g$-factors and exchange interactions. Our results paint YbMgGaO$_{4}$ as an easy-plane XXZ antiferromagnet with the combined and necessary presence of sub-leading next-nearest neighbor and weak anisotropic off-diagonal nearest-neighbor interactions. Moreover, the obtained $g$-factors are substantially different from previous reports. This works establishes the hierarchy of exchange interactions in YbMgGaO$_{4}$ from high-field data alone and thus strongly constrains possible mechanisms responsible for the observed spin-liquid phenomenology.

cond-mat.str-el↗