arXiv subjects

Y. Saitoh

Publications and source records attributed to Y. Saitoh.

At least 37 records · Page 2Linked to original sources

arXiv2008

Electronic structure of Ga$_{1-x}$Cr$_{x}$N and Si-doping effects studied by photoemission and X-ray absorption spectroscopy

The electronic structure of the magnetic semiconductor Ga$_{1-x}$Cr$_{x}$N and the effect of Si doping on it have been investigated by photoemission and soft x-ray absorption spectroscopy. We have confirmed that Cr in GaN is predominantly trivalent substituting for Ga, and that Cr 3$d$ states appear within the band gap of GaN just above the N 2$p$-derived valence-band maximum. As a result of Si doping, downward shifts of the core levels (except for Cr 2$p$) and the formation of new states near the Fermi level were observed, which we attribute to the upward chemical potential shift and the formation of a small amount of Cr$^{2+}$ species caused by the electron doping. Possibility of Cr-rich cluster growth by Si doping are discussed based on the spectroscopic and magnetization data.

cond-mat.mtrl-sci↗

arXiv2008

Local electronic structure of Cr in the II-VI diluted ferromagnetic semiconductor Zn$_{1-x}$Cr$_x$Te

The electronic structure of the Cr ions in the diluted ferromagnetic semiconductor Zn$_{1-x}$Cr$_x$Te ($x=0.03$ and 0.15) thin films has been investigated using x-ray magnetic circular dichroism (XMCD) and photoemission spectroscopy (PES). Magnetic-field ($H$) and temperature ($T$) dependences of the Cr $2p$ XMCD spectra well correspond to the magnetization measured by a SQUID magnetometer. The line shape of the Cr $2p$ XMCD spectra is independent of $H$, $T$, and $x$, indicating that the ferromagnetism is originated from the same electronic states of the Cr ion. Cluster-model analysis indicates that although there are two or more kinds of Cr ions in the Zn$_{1-x}$Cr$_x$Te samples, the ferromagnetic XMCD signal is originated from Cr ions substituted for the Zn site. The Cr 3d partial density of states extracted using Cr $2p \to 3d$ resonant PES shows a broad feature near the top of the valence band, suggesting strong $s$,$p$-$d$ hybridization. No density of states is detected at the Fermi level, consistent with their insulating behavior. Based on these findings, we conclude that double exchange mechanism cannot explain the ferromagnetism in Zn$_{1-x}$Cr$_{x}$Te.

cond-mat.mtrl-sci↗

arXiv2008

Electronic Structures of Fe$_{3-x}V$_x$Si Probed by Photoemission Spectroscopy

The electronic structures of the Heusler type compounds Fe$_{3-x}V$_x$Si in the concentration range between x = 0 and x = 1 have been probed by photoemission spectroscopy (PES). The observed shift of Si 2p core- level and the main valence band structres indicate a chemical potential shift to higher energy with increasing x. It is also clarified that the density of state at Fermi edge is owing to the collaboration of V 3d and Fe 3d derived states. Besides the decrease of the spectral intensity near Fermi edge with increasing x suggests the formation of pseudo gap at large x.

cond-mat.mtrl-sci↗

arXiv2008

Hybridization between the conduction band and 3d orbitals in the oxide-based diluted magnetic semiconductor In$_{2-x}$V$_x$O$_3$

The electronic structure of In$_{2-x}$V$_x$O$_3$ ($x=0.08$) has been investigated using photoemission spectroscopy (PES) and x-ray absorption spectroscopy (XAS). The V $2p$ core-level PES and XAS spectra revealed trivalent electronic state of the V ion, consistent with the substitution of the V ion for the In site. The V 3d partial density of states obtained by the resonant PES technique showed a sharp peak above the O $2p$ band. While the O $1s$ XAS spectrum of In$_{2-x}$V$_x$O$_3$ was similar to that of In$_2$O$_3$, there were differences in the In $3p$ and 3d XAS spectra between V-doped and pure In$_2$O$_3$. The observations give clear evidence for hybridization between the In conduction band and the V 3d orbitals in In$_{2-x}$V$_x$O$_3$.

cond-mat.mtrl-sci↗

arXiv2008

Nature of magnetic coupling between Mn ions in as-grown Ga$_{1-x}$Mn$_{x}$As studied by x-ray magnetic circular dichroism

The magnetic properties of as-grown Ga$_{1-x}$Mn$_{x}$As have been investigated by the systematic measurements of temperature and magnetic field dependent soft x-ray magnetic circular dichroism (XMCD). The {\it intrinsic} XMCD intensity at high temperatures obeys the Curie-Weiss law, but residual spin magnetic moment appears already around 100 K, significantly above Curie temperature ($T_C$), suggesting that short-range ferromagnetic correlations are developed above $T_C$. The present results also suggest that antiferromagnetic interaction between the substitutional and interstitial Mn (Mn$_{int}$) ions exists and that the amount of the Mn$_{int}$ affects $T_C$.

cond-mat.mtrl-sci↗

arXiv2007

Systematic changes of the electronic structure of the diluted ferromagnetic oxide Li-doped Ni$_{1-x}$Fe$_x$O with hole doping

The electronic structure of Li-doped Ni$_{1-x}$Fe$_x$O has been investigated using photoemission spectroscopy (PES) and x-ray absorption spectroscopy (XAS). The Ni $2p$ core-level PES and XAS spectra were not changed by Li doping. In contrast, the Fe$^{3+}$ intensity increased with Li doping relative to the Fe$^{2+}$ intensity. However, the increase of Fe$^{3+}$ is only $\sim 5%$ of the doped Li content, suggesting that most of the doped holes enter the O $2p$ and/or the charge-transferred configuration Ni $3d^8\underline{L}$. The Fe 3d partial density of states and the host valence-band emission near valence-band maximum increased with Li content, consistent with the increase of electrical conductivity. Based on these findings, percolation of bound magnetic polarons is proposed as an origin of the ferromagnetic behavior.

cond-mat.mtrl-sci↗

arXiv2007

Soft x-ray magnetic circular dichroism study of Ca_1-xSr_xRuO_3 across the ferromagnetic quantum phase transition

Ca_1-xSr_xRuO_3, which is ferromagnetic for Sr concentration x > 0.3, has been studied by x-ray magnetic circular dichroism (XMCD) in Ru 3p and O 1s core-level x-ray absorption. XMCD signals appear at x ~ 0.3 and monotonically increases with x in the ferromagnetic phase. While the monotonic increase of the XMCD signals with x is of a typical Stoner-type, the absence of appreciable change in the spectral line shapes of both the Ru 3p and O 1s XMCD spectra indicate that the itinerant-electron ferromagnetism in Ca_1-xSr_xRuO_3 is influenced by strong electron correlation.

cond-mat.str-el↗

arXiv2007

Photoemission and x-ray absorption studies of valence states in (Ni,Zn,Fe,Ti)$_{3}$O$_{4}$ thin films exhibiting photo-induced magnetization

By means of photoemission and x-ray absorption spectroscopy, we have studied the electronic structure of (Ni,Zn,Fe,Ti)$_{3}$O$_{4}$ thin films, which exhibits a cluster glass behavior with a spin-freezing temperature $T_f$ of $\sim 230$ K and photo-induced magnetization (PIM) below $T_f$. The Ni and Zn ions were found to be in the divalent states. Most of the Fe and Ti ions in the thin films were trivalent (Fe$^{3+}$) and tetravalent (Ti$^{4+}$), respectively. While Ti doping did not affect the valence states of the Ni and Zn ions, a small amount of Fe$^{2+}$ ions increased with Ti concentration, consistent with the proposed charge-transfer mechanism of PIM.

cond-mat.mtrl-sci↗

arXiv2007

X-ray magnetic circular dichroism and photoemission study of the diluted ferromagnetic semiconductor Zn$_{1-x}$Cr$_x$Te

We have performed x-ray magnetic circular dichroism (XMCD) and valence-band photoemission studies of the diluted ferromagnetic semiconductor Zn$_{1-x}$Cr$_x$Te. XMCD signals due to ferromagnetism were observed at the Cr 2p absorption edge. Comparison with atomic multiplet calculations suggests that the magnetically active component of the Cr ion was divalent under the tetrahedral crystal field with tetragonal distortion along the crystalline a-, b-, and c-axes. In the valence-band spectra, spectral weight near the Fermi level was strongly suppressed, suggesting the importance of Jahn-Teller effect and the strong Coulomb interaction between the Cr 3d electrons.

cond-mat.mtrl-sci↗

arXiv2007

Phase Change Observed in Ultrathin Ba0.5Sr0.5TiO3 Films by in-situ Resonant Photoemission Spectroscopy

Epitaxial Ba0.5Sr0.5TiO3 thin films were prepared on Nb-doped SrTiO3 (100)substrates by the pulsed laser deposition technique, and were studied by measuring the Ti 2p - 3d resonant photoemission spectra in the valence-band region as a function of film thickness, both at room temperature and low temperature. Our results demonstrated an abrupt variation in the spectral structures between 2.8 nm (~7 monolayers) and 2.0 nm (~5 monolayers) Ba0.5Sr0.5TiO3 films, suggesting that there exists a critical thickness for phase change in the range of 2.0 nm to 2.8 nm. This may be ascribed mainly to the intrinsic size effects.

cond-mat.mtrl-sci↗

arXiv2007

Depth profile high-energy spectroscopic study of Mn-doped GaN prepared by thermal diffusion

We have performed an $in$-$situ$ depth profile study of Mn-doped GaN prepared by a low temperature thermal diffusion method using photoemission and x-ray absorption spectroscopy. It was revealed from the core-level photoemission measurements that Mn ions are diffused into a deep ($\sim$ 70 Å) region of the GaN substrates and that the line shapes of Mn 3$d$ partial density of states obtained by resonant photoemission measurements was close to that of Ga$_{1-x}$Mn$_x$N thin films grown by molecular-beam epitaxy. From x-ray absorption spectroscopy (XAS) and x-ray magnetic circular dichroism (XMCD) measurements at the Mn $L$-edge, it was revealed that the doped Mn ions were in the divalent Mn$^{2+}$ state and primarily paramagnetic. In magnetization measurements, weak hysteresis was detected in samples prepared using $p$-type GaN substrates while samples using $n$-type GaN substrates showed only paramagnetism.

cond-mat.mtrl-sci↗

arXiv2006

Soft x-ray magnetic circular dichroism study of weakly ferromagnetic Zn$_{1-x}$V$_x$O thin film

We performed a soft x-ray magnetic circular dichroism (XMCD) study of a Zn$_{1-x}$V$_x$O thin film which showed small ferromagnetic moment. Field and temperature dependences of V 2$p$ XMCD signals indicated the coexistence of Curie-Weiss paramagnetic, antiferromagnetic, and possibly ferromagnetic V ions, quantitatively consistent with the magnetization measurements. We attribute the paramagnetic signal to V ions substituting Zn sites which are somewhat elongated along the c-axis.

cond-mat.mtrl-sci↗

arXiv2006

Photoemission study of (V$_{1-x}$M$_x$)$_2$O$_3$ (M=Cr, Ti)

We present high-resolution bulk-sensitive photoemission spectra of (V$_{1-x}$M$_x$)$_2$O$_3$ (M=Cr, Ti). The measurements were made for the paramagnetic metal (PM), paramagnetic insulator (PI), and antiferromagnetic insulator (AFI) phases of (V$_{1-x}$M$_x$)$_2$O$_3$ with the samples of $x$ = 0, 0.012, and 0.028 for Cr-doping and $x$ = 0.01 for Ti-doping. In the PM phase, we observe a prominent quasiparticle peak in general agreement with theory, which combines dynamical mean-field theory with the local density approximation (LDA+DMFT). The quasiparticle peak shows a significantly larger peak width and weight than in the theory. For both the PI and AFI phases, the vanadium 3d parts of the valence spectra are not simple one peak structures. For the PI phase, there is not yet a good theoretical understanding of these structures. The size of the electron removal gap increases, and spectral weight accumulates in the energy range closer to the chemical potential, when the PI to AFI transition occurs. Spectra taken in the same phases with different compositions show interesting monotonic changes as the dopant concentration increases, regardless of the dopant species. With increased Cr-doping, the AFI phase gap decreases and the PI phase gap increases.

cond-mat.str-el↗

arXiv2005

Photoproduction of $η$-mesons off C and Cu nuclei for photon energies below 1.1 GeV

The $η$-meson photoproduction cross sections have been measured on the C and Cu targets for the photon energies between 600 and 1100 MeV to investigate the behavior of the $S_{11}$(1535) resonance in a nucleus. The excitation functions of the cross section as well as the angular and momentum distributions of $η$-mesons are in quantitative agreement with the Quantum Molecular Dynamics (QMD) model calculations in which the $η$-meson emission processes other than the $S_{11}$(1535) resonance are also incorporated as proposed in the $η$-MAID model. It is shown that the excitation of the $D_{15}$(1675) resonance might play an important role for $E_γ>900$ MeV.

nucl-ex↗

arXiv2005

Characterization of Magnetic Components in the Diluted Magnetic Semiconductor Zn$_{1-x}$Co$_x$O by X-ray Magnetic Circular Dichroism

We report on the results of x-ray absorption (XAS), x-ray magnetic circular dichroism (XMCD), and photoemission experiments on {\it n}-type Zn$_{1-x}$Co$_x$O ($x=0.05$) thin film, which shows ferromagnetism at room temperature. The XMCD spectra show a multiplet structure, characteristic of the Co$^{2+}$ ion tetrahedrally coordinated by oxygen, suggesting that the ferromagnetism comes from Co ions substituting the Zn site in ZnO. The magnetic field and temperature dependences of the XMCD spectra imply that the non-ferromagnetic Co ions are strongly coupled antiferromagnetically with each other.

cond-mat.mtrl-sci↗

arXiv2004

Technique for bulk Fermiology by photoemission applied to layered ruthenates

We report the Fermi surfaces of the superconductor Sr2RuO4 and the non-superconductor Sr1.8Ca0.2RuO4 probed by bulk-sensitive high-energy angle-resolved photoemission. It is found that there is one square-shaped hole-like, one square-shaped electron-like and one circle-shaped electron-like Fermi surface in both compounds. These results provide direct evidence for nesting instability giving rise to magnetic fluctuations. Our study clarifies that the electron correlation effects are changed with composition depending on the individual band.

cond-mat.str-el↗

arXiv2004

Mutual Experimental and Theoretical Validation of Bulk Photoemission Spectra of Sr1-xCaxVO3

We report high-resolution high-energy photoemission spectra together with parameter-free LDA+DMFT (local density approximation + dynamical mean-field theory) results for Sr1-xCaxVO3, a prototype 3d1 system. In contrast to earlier investigations the bulk spectra are found to be insensitive to x. The good agreement between experiment and theory confirms the bulk-sensitivity of the high-energy photoemission spectra.

cond-mat.str-el↗

arXiv2003

Genuine Electronic States of Vanadium Perovskites Revealed by High-Energy Photoemission

Bulk-sensitive high-resolution photoemission was carried out on a prototype 3d1 metallic Sr1-xCaxVO3. In a strong contrast to so far reported results, the bulk spectral functions are revealed to be insensitive to x. The conservation of the density of states at the Fermi level in spite of the electron correlation is clarified by the successful suppression and deconvolution of the surface contribution. Our study has demonstrated the importance of high-energy and high-resolution photoemission spectroscopy for revealing detailed bulk electronic states of transition metal oxides.

cond-mat.str-el↗