arXiv subjects

Y. Uwatoko

Publications and source records attributed to Y. Uwatoko.

At least 37 records · Page 2Linked to original sources

arXiv2020

Sample dependence of the half-integer quantized thermal Hall effect in the Kitaev candidate $α$-RuCl$_3$

We have investigated the sample dependence of the half-integer thermal Hall effect in $α$-RuCl$_3$ under a magnetic field tilted 45 degree from the $c$ axis to the $a$ axis. We find that the sample with the largest longitudinal thermal conductivity ($κ_{xx}$) shows the half-integer quantized thermal Hall effect expected in the Kitaev model. On the other hand, the quantized thermal Hall effect was not observed in the samples with smaller $κ_{xx}$. We suggest that suppressing the magnetic scattering effects on the phonon thermal conduction, which broaden the field-induced gap protecting the chiral edge current of the Majorana fermions, is important to observe the quantized thermal Hall effect.

cond-mat.str-el↗

arXiv2020

Large Enhancement of Thermoelectric Efficiency Due to a Pressure-Induced Lifshitz Transition in SnSe

Lifshitz transition, a change in Fermi surface topology, is likely to greatly influence exotic correlated phenomena in solids, such as high-temperature superconductivity and complex magnetism. However, since the observation of Fermi surfaces is generally difficult in the strongly correlated systems, a direct link between the Lifshitz transition and quantum phenomena has been elusive so far. Here, we report a marked impact of the pressure-induced Lifshitz transition on thermoelectric performance for SnSe, a promising thermoelectric material without strong electron correlation. By applying pressure up to 1.6 GPa, we have observed a large enhancement of thermoelectric power factor by more than 100% over a wide temperature range (10-300 K). Furthermore, the high carrier mobility enables the detection of quantum oscillations of resistivity, revealing the emergence of new Fermi pockets at ~0.86 GPa. The observed thermoelectric properties linked to the multi-valley band structure are quantitatively reproduced by first-principles calculations, providing novel insight into designing the SnSe-related materials for potential valleytronic as well as thermoelectric applications.

cond-mat.mtrl-sci↗

arXiv2019

Suppression of the antiferromagnetic metallic state in the pressurized MnBi2Te4 single crystal

MnBi2Te4 has attracted tremendous research interest recently as the first intrinsic antiferromagnetic (AF) topological insulator. It undergoes a long-range AF order at TN = 24 K accompanied with a cusp-like anomaly in the metallic resistivity. Here, we studied the effect of hydrostatic pressure on its electrical transport properties up to 12.5 GPa by using a cubic anvil cell apparatus. We find that TN determined from the resistivity anomaly first increases slightly with pressure and then decreases until vanished completely at ~7 GPa. Intriguingly, its resistivity rho(T) is enhanced gradually by pressure, and evolves from metallic to activated behavior as the AF order is suppressed. From the Hall resistivity measurements, we confirm that the n-type carriers dominate the transport properties and the carrier density is raised by pressure. In addition, the critical magnetic field Hc1 ~3.3 T at 0 GPa for the spin-flop transition to the canted AF state is found to increase to ~ 5 T and 7.5 T at 1 and 3 GPa. High-pressure XRD evidenced no structural transition up to 12.8 GPa. Based on the Hall resistivity results and first-principles calculations, we proposed that the intralayer direct AF interactions are strengthened by pressure and the competition between AF and FM interactions not only prevents long-range magnetic order but also promotes charge carrier localizations through enhance magnetic fluctuations at high pressures.

cond-mat.str-el↗

arXiv2019

Magnetic competition induced colossal magnetoresistance in n-type HgCr2Se4 under high pressures

The n-type HgCr2Se4 exhibits a sharp semiconductor-to-metal transition (SMT) in resistivity accompanying the ferromagnetic order at TC = 106 K. Here, we investigate the effects of pressure and magnetic field on the concomitant SMT and ferromagnetic order by measuring resistivity, dc and ac magnetic susceptibility, as well as single-crystal neutron diffraction under various pressures up to 8 GPa and magnetic fields up to 8 T. Our results demonstrate that the ferromagnetic metallic ground state of n-type HgCr2Se4 is destabilized and gradually replaced by an antiferromagnetic, most likely a spiral magnetic, and insulating ground state upon the application of high pressure. On the other hand, the application of external magnetic fields can restore the ferromagnetic metallic state again at high pressures, resulting in a colossal magnetoresistance (CMR) as high as ~ 3 * 10^11 % under 5 T and 2 K at 4 GPa. The present study demonstrates that n-type HgCr2Se4 is located at a peculiar critical point where the balance of competion between ferromagnetic and antiferromagnetic interactions can be easily tipped by the external stimuli, providing a new platform for achieving CMR in a single-valent system.

cond-mat.str-el↗

arXiv2019

Evolution of Magnetic Double Helix and Quantum Criticality near a Dome of Superconductivity in CrAs

At ambient pressure CrAs undergoes a first-order transition into a double-helical magnetic state at TN = 265 K, which is accompanied by a structural transition. The recent discovery of pressure-induced superconductivity in CrAs makes it important to clarify the nature of quantum phase transitions out of its coupled structural/helimagnetic order. Here we show, via neutron diffraction on the single-crystal CrAs under hydrostatic pressure (P), that the combined order is suppressed at Pc ~ 10 kbar, near which bulk superconductivity develops with a maximal transition temperature Tc ~ 2 K. We further show that the coupled order is also completely suppressed by phosphorus doping in CrAs1-xPx at a critical xc ~ 0.05, above which inelastic neutron scattering evidenced persistent antiferromagnetic correlations, providing a possible link between magnetism and superconductivity. In line with the presence of antiferromagnetic fluctuations near Pc (xc), the A coefficient of the quadratic temperature dependence of resistivity exhibits a dramatic enhancement as P (x) approaches Pc (xc), around which Res(T) has a non-Fermi-liquid form. Accordingly, the electronic specific-heat coefficient of CrAs1-xPx peaks out around xc. These properties provide clear evidences for quantum criticality, which we interpret as originating from a nearly second-order helimagnetic quantum phase transition that is concomitant with a first-order structural transition. Our findings in CrAs highlight the distinct characteristics of quantum criticality in bad metals, thereby bringing out new insights into the physics of unconventional superconductivity such as occurring in the high-Tc iron pnictides.

cond-mat.supr-con↗

arXiv2018

Novel Superconductivity in Endohedral Gallide Mo8Ga41

We report on synthesis and characterization of gallide cluster based Mo8Ga41 superconductor. Transport and magnetization measurements confirm the superconducting transition temperature to be 9.8 K. The upper critical field, lower critical field, Ginzburg-Landau coherence length and penetration depth are estimated to be 11.8T, 150G, 5.2nm, 148nm respectively. The electronic band structure, density of states and phonon dispersion curve calculations are obtained by using Density Functional Theory. The core level X-ray Photoelectron Spectroscopy (XPS) reveals the binding energy information of the constituting elements Mo and Ga in Mo8Ga41. The valence band spectra from XPS is in good agreement with calculated density of states (DOS). The zero field critical current density (Jc) at T = 2 K is ~ 3*10^5 A/cm^2 which is indicative of efficient flux pinning in the as grown compound. About two fold enhancement in critical current density with application of external pressure (1.1 GPa) is observed with marginal decrease in transition temperature. The fitting of current density to double exponential model confirms possibility of two gap superconductivity in Mo8Ga41.

cond-mat.supr-con↗

arXiv2018

Two different superconducting states and possible antiferromagnetic quantum critical points in S-doped FeSe under pressure

We performed $^{77}$Se-NMR measurements on FeSe$_{1-x}$S$_x$, ($x$ = 0.12) up to 3.0 GPa at an applied magnetic field of 6.02 T, and found that the superconducting (SC) phase exhibits a remarkable double-dome structure in the pressure($P$)-temperature($T$) phase diagram which is hidden at 0 T. From the relaxation rate $1/T_1$ divided by $T$, $1/T_1T$, a Lifshitz transition may occur at 1.0 GPa, and the dominant nesting vector could change due to topological changes in Fermi surfaces. In other words, two types of antiferromagnetic (AFM) fluctuations would exist in the $P-T$ phase diagram. We conclude that the SC double domes in 12%-S doped FeSe consist of two SC states each of which correlates to a different type of AFM fluctuation. Furthermore, the strong AFM fluctuation at ambient pressure could originate from a possible hidden AFM quantum critical point.

cond-mat.supr-con↗

arXiv2017

Slater Insulator in Iridate Perovskites with Strong Spin-Orbit Coupling

The perovskite SrIrO3 is an exotic narrow-band metal owing to a confluence of the strengths of the spin-orbit coupling (SOC) and the electron-electron correlations. It has been proposed that topological and magnetic insulating phases can be achieved by tuning the SOC, Hubbard interactions, and/or lattice symmetry. Here, we report that the substitution of nonmagnetic, isovalent Sn4+ for Ir4+ in the SrIr1-xSnxO3 perovskites synthesized under high pressure leads to a metal-insulator transition to an antiferromagnetic (AF) phase at TN > 225 K. The continuous change of the cell volume as detected by x-ray diffraction and the lamda-shape transition of the specific heat on cooling through TN demonstrate that the metal-insulator transition is of second-order. Neutron powder diffraction results indicate that the Sn substitution enlarges an octahedral-site distortion that reduces the SOC relative to the spin-spin exchange interaction and results in the type-G AF spin ordering below TN. Measurement of high-temperature magnetic susceptibility shows the evolution of magnetic coupling in the paramagnetic phase typical of weak itinerant-electron magnetism in the Sn-substituted samples. A reduced structural symmetry in the magnetically ordered phase leads to an electron gap opening at the Brillouin zone boundary below TN in the same way as proposed by Slater.

cond-mat.str-el↗

arXiv2017

High-Tc superconductivity up to 55 K under high pressure in the heavily electron doped Lix(NH3)yFe2Se2 single crystal

We report a high-pressure study on the heavily electron doped Lix(NH3)yFe2Se2 single crystal by using the cubic anvil cell apparatus. The superconducting transition temperature Tc = 44 K at ambient pressure is first suppressed to below 20 K upon increasing pressure to Pc = 2 GPa, above which the pressure dependence of Tc(P) reverses and Tc increases steadily to ca. 55 K at 11 GPa. These results thus evidenced a pressure-induced second high-Tc superconducting (SC-II) phase in Lix(NH3)yFe2Se2 with the highest Tcmax = 55K among the FeSe-based bulk materials. Hall data confirm that in the emergent SC-II phase the dominant electron-type carrier density undergoes a fourfold enhancement and tracks the same trend as Tc(P). Interesting, we find a nearly parallel scaling behavior between Tc and the inverse Hall coefficient for the SC-II phases of both Lix(NH3)yFe2Se2 and (Li,Fe)OHFeSe. The present work demonstrates that high pressure offers a distinctive means to further raising the maximum Tc of heavily electron doped FeSe-based materials by increasing the effective charge carrier concentration via a plausible Fermi surface reconstruction at Pc.

cond-mat.supr-con↗

arXiv2017

Maximizing Tc by tuning nematicity and magnetism in FeSe1-xSx superconductors

A fundamental issue concerning iron-based superconductivity is the roles of electronic nematicity and magnetism in realising high transition temperature ($T_{\rm c}$). To address this issue, FeSe is a key material, as it exhibits a unique pressure phase diagram involving nonmagnetic nematic and pressure-induced antiferromagnetic ordered phases. However, as these two phases in FeSe overlap with each other, the effects of two orders on superconductivity remain perplexing. Here we construct the three-dimensional electronic phase diagram, temperature ($T$) against pressure ($P$) and isovalent S-substitution ($x$), for FeSe$_{1-x}$S$_{x}$, in which we achieve a complete separation of nematic and antiferromagnetic phases. In between, an extended nonmagnetic tetragonal phase emerges, where we find a striking enhancement of $T_{\rm c}$. The completed phase diagram uncovers two superconducting domes with similarly high $T_{\rm c}$ on both ends of the dome-shaped antiferromagnetic phase. The $T_{\rm c}(P,x)$ variation implies that nematic fluctuations unless accompanying magnetism are not relevant for high-$T_{\rm c}$ superconductivity in this system.

cond-mat.supr-con↗

arXiv2017

Reemergence of high-Tc superconductivity in the (Li1-xFex)OHFe1-ySe under high pressure

The pressure-induced reemergence of the second high-Tc superconducting phase (SC-II) in the alkali-metal intercalated AxFe2-ySe2 (A = K, Rb, Cs, Tl) remains an enigma and proper characterizations on the superconducting- and normal-state properties of the SC-II phase were hampered by the intrinsic inhomogeneity and phase separation. To elucidate this intriguing problem, we performed a detailed high-pressure magnetotransport study on the recently discovered (Li1-xFex)OHFe1-ySe single crystals, which have high Tc~40 K and share similar Fermi surface topology as AxFe2-ySe2, but are free from the sample complications. We found that the ambient-pressure Tc~41 K is suppressed gradually to below 2 K upon increasing pressure to Pc ~5 GPa, above which a SC-II phase with higher Tc emerges and the Tc increases progressively to above 50 K up to 12.5 GPa. Interestingly, our high-precision resistivity data enable us to uncover the sharp transition of the normal state from a Fermi liquid for SC-I phase (0 < P < 5 GPa) to a non-Fermi-liquid for SC-II phase (P > 5GPa). In addition, the reemergence of high-Tc SC-II phase is found to accompany with a concurrent enhancement of electron carrier density. Since high-pressure structural study based on the synchrotron X-ray diffraction rules out the structural transition below 10 GPa, the observed SC-II phase with enhanced carrier density should be ascribed to an electronic origin associated with a pressure-induced Fermi surface reconstruction.

cond-mat.supr-con↗

arXiv2017

Evidence for conventional superconductivity in Sr0.1Bi2Se3 from high pressure studies

SrxBi2Se3 is recently reported to be a superconductor derived from topological insulator Bi2Se3. It shows a maximum resistive Tc of 3.25 K at ambient pressure. We report magnetic (upto 1 GPa) and transport properties (upro 8 Gpa) under pressure for single crystalline Sr0.1Bi2Se3 superconductor. Magnetic measurements show that Tc decreases from ~2.6 K (0 GPa) to ~1.9 K (0.81 GPa). Similar behavior is observed in transport properties as well without much change in the metallic characteristics in normal state resistivity. No reentrant superconducting phase (Physical Review B 93, 144514 (2016)) is observed at high pressure. Normal state resistivity near Tc is explained by Fermi liquid model. Above 100 K, a polaronic hopping conduction mechanism with two parallel channels for current flow is indicated. Band structure calculations indicate decreasing density of states at Fermi level with pressure. In consonance with transition temperature suppression in conventional BCS low Tc superconductors, the pressure effect in SrxBi2Se3 is well accounted by pressure induced band broadening.

cond-mat.supr-con↗

arXiv2016

High-Tc superconductivity in FeSe at high pressure: Dominant hole carriers and enhanced spin fluctuations

The importance of electron-hole interband interactions is widely acknowledged for iron-pnictide superconductors with high transition temperatures (Tc). However, high-Tc superconductivity without hole carriers has been suggested in FeSe single-layer films and intercalated iron-selenides, raising a fundamental question whether iron pnictides and chalcogenides have different pairing mechanisms. Here, we study the properties of electronic structure in the high-Tc phase induced by pressure in bulk FeSe from magneto-transport measurements and first-principles calculations. With increasing pressure, the low-Tc superconducting phase transforms into high-Tc phase, where we find the normal-state Hall resistivity changes sign from negative to positive, demonstrating dominant hole carriers in striking contrast to other FeSe-derived high-Tc systems. Moreover, the Hall coefficient is remarkably enlarged and the magnetoresistance exhibits anomalous scaling behaviors, evidencing strongly enhanced interband spin fluctuations in the high-Tc phase. These results in FeSe highlight similarities with high-Tc phases of iron pnictides, constituting a step toward a unified understanding of iron-based superconductivity.

cond-mat.supr-con↗

arXiv2016

Competition of superconductivity with the structural transition in Mo3Sb7

Prior to the superconducting transition at Tc = 2.3 K, Mo3Sb7 undergoes a symmetry-lowering, cubic-to-tetragonal structural transition at Ts = 53 K. We have monitored the pressure dependence of these two transitions by measuring the resistivity of Mo3Sb7 single crystals under various hydrostatic pressures up to 15 GPa. The application of external pressure enhances Tc but suppresses Ts until Pc ~ 10 GPa, above which a pressure-induced first order structural transition takes place and is manifested by the phase coexistence in the pressure range 8 < P < 12 GPa. The cubic phase above 12 GPa is also found to be superconducting with a higher Tc =6 K that decreases slightly with further increasing pressure. The variations with pressure of Tc and Ts satisfy the Bilbro-McMillan equation, i.e. Tc^nTs^(1-n) = constant, thus suggesting the competition of superconductivity with the structural transition that has been proposed to be accompanied with a spin-gap formation at Ts. This scenario is supported by our first-principles calculations which imply the plausible importance of magnetism that competes with the superconductivity in Mo3Sb7.

cond-mat.supr-con↗

arXiv2016

Pressure dependence of the magnetic ground states in MnP

MnP, a superconductor under pressure, exhibits a ferromagnetic order below TC~290 K followed by a helical order with the spins lying in the ab plane and the helical rotation propagating along the c axis below Ts~50 K at ambient pressure. We performed single crystal neutron diffraction experiments to determine the magnetic ground states under pressure. Both TC and Ts are gradually suppressed with increasing pressure and the helical order disappears at ~1.2 GPa. At intermediate pressures of 1.8 and 2.0 GPa, the ferromagnetic order first develops and changes to a conical or two-phase (ferromagnetic and helical) structure with the propagation along the b axis below a characteristic temperature. At 3.8 GPa, a helical magnetic order appears below 208 K, which hosts the spins in the ac plane and the propagation along the b axis. The period of this b axis modulation is shorter than that at 1.8 GPa. Our results indicate that the magnetic phase in the vicinity of the superconducting phase may have a helical magnetic correlation along the b axis.

cond-mat.supr-con↗

arXiv2015

Dome-shaped magnetic order competing with high-temperature superconductivity at high pressures in FeSe

The coexistence and competition between superconductivity and electronic orders, such as spin or charge density waves, have been a central issue in high transition-temperature (${T_{\rm c}}$) superconductors. Unlike other iron-based superconductors, FeSe exhibits nematic ordering without magnetism whose relationship with its superconductivity remains unclear. More importantly, a pressure-induced fourfold increase of ${T_{\rm c}}$ has been reported, which poses a profound mystery. Here we report high-pressure magnetotransport measurements in FeSe up to $\sim9$ GPa, which uncover a hidden magnetic dome superseding the nematic order. Above ${\sim6}$ GPa the sudden enhancement of superconductivity (${T_{\rm c}\le38.3}$ K) accompanies a suppression of magnetic order, demonstrating their competing nature with very similar energy scales. Above the magnetic dome we find anomalous transport properties suggesting a possible pseudogap formation, whereas linear-in-temperature resistivity is observed above the high-${T_{\rm c}}$ phase. The obtained phase diagram highlights unique features among iron-based superconductors, but bears some resemblance to that of high-${T_{\rm c}}$ cuprates.

cond-mat.supr-con↗

arXiv2015

Kondo effect in CeX$_{c}$ (X$_{c}$=S, Se, Te) studied by electrical resistivity under high pressure

We have measured the electrical resistivity of cerium monochalcogenices, CeS, CeSe, and CeTe, under high pressures up to 8 GPa. Pressure dependences of the antiferromagnetic ordering temperature $T_{N}$, crystal field splitting, and the $\ln T$ anomaly of the Kondo effect have been studied to cover the whole region from the magnetic ordering regime at low pressure to the Fermi liquid regime at high pressure. $T_{N}$ initially increases with increasing pressure, and starts to decrease at high pressure as expected from the Doniach's diagram. Simultaneously, the $\ln T$ behavior in the resistivity is enhanced, indicating the enhancement of the Kondo effect by pressure. It is also characteristic in CeX$_{c}$ that the crystal field splitting rapidly decreases at a common rate of $-12.2$ K/GPa. This leads to the increase in the degeneracy of the $f$ state and further enhancement of the Kondo effect. It is shown that the pressure dependent degeneracy of the $f$ state is a key factor to understand the pressure dependence of $T_{N}$, Kondo effect, magnetoresistance, and the peak structure in the temperature dependence of resistivity.

cond-mat.str-el↗

arXiv2015

Upper critical field, critical current density and activation energy of the new La1-xSmxOF0.5BiS2 (x = 0.2, 0.8) superconductor

Critical current density (Jc), thermal activation energy (U0), and upper critical field (Hc2) of La1-xSmxO0.5F0.5BiS2 (x = 0.2, 0.8) superconductors are investigated from magnetic field dependent \r{ho}(T) studies. The estimated upper critical field (Hc2) has low values of 1.04 T for x = 0.2 and 1.41 T for x = 0.8. These values are lower than Sm free LaO0.5F0.5BiS2 superconductor (1.9 T). The critical current density (Jc) is estimated to be 1.35*105 A/cm2 and 5.07 *105 A/cm2 (2 K) for x = 0.2 and 0.8 respectively, using the Bean's model. The thermal activation energy (U0/kB) is 61 K for x = 0.2 and 140 K for x =0.8 as calculated from Arrhenius plots at low magnetic field (1 T) and indicates a strong flux pinning potential which might be co-existing with applied magnetic field.

cond-mat.supr-con↗