arXiv subjects

Yangrui Liu

Publications and source records attributed to Yangrui Liu.

5 recordsLinked to original sources

arXiv2026

Room-Temperature Noncolinear Ferroelectricity in van der Waals WO$_2$Cl$_2$ with a Wide Bandgap

Low-dimensional ferroelectrics are attractive for their promising prospects in nanoelectronics. Compared with widely-used ferroelectric perovskites, most low-dimensional ferroelectrics exhibit several inborn weaknesses such as small bandgaps (mostly <2 eV, i.e. semiconductors-like) or faint polarizations (e.g. $<1$ $\mu$C/cm$^2$ for sliding ferroelectrics even if their bandgaps can be large). Here we experimentally demonstrate the room-temperature ferroelectricity of van der Waals WO$_2$Cl$_2$ . The well-tested d0 rule inherited from ferroelectric perovskites leads to a large dipole (~3 e\AA) from the off-center displacement of W$^6+$ ion and a wide bandgap of 2.80 eV. Its ferroelectricity is proved by multiple characterizations including second harmonic generation, piezoresponse force microscopy, and ferroelectric hysteresis loops. More interestingly, the exotic noncollinear dipole order is directly observed at the atomic level by integrated differential phase contrast scanning transmission electron microscopy. Our work paves an alternative route for low-dimensional ferroelectrics to pursue excellent ferroelectric performance and distinct physics of polarity.

cond-mat.mtrl-sci↗

arXiv2025

Understanding the atomically precise evolution of the miscibility of newly prepared face-centered cubic W-Cu nanoalloys and its asymmetry

According to classical Miedema theory, reducing crystals to the order of nanometer sizes might greatly modulate the mixing enthalpy of elements, thus enabling the invention of a lot of new bulk-immiscible alloys. Although numerous alloys with higher mixing enthalpies remain unexplored, this strategy is approaching its limit, as reflected by the critical diameter of recent alloys of 1.8 nm, which corresponds to ~150 atoms and hardly provides a crystalline order. Future development requires not only even smaller atomic-scale control but also a new surface energy-saving mechanism. Here, we report the formation of W-Cu nanoalloys with a very large miscibility gap in the bulk via the use of an atomically size-selected cluster beam source as an example. The face-centered cubic (FCC) structure was demonstrated through electron diffraction, which indicated a lattice constant of 3.88Å for W0.85Cu0.15 nanoalloys (~2280 atoms). In this comprehensive study that covers a large parameter space of W/Cu compositions and numbers of atoms, an asymmetric miscibility nanophase diagram in which W-rich compositions favor mixing and the critical size is approximately 6000 atoms, which far exceeds the approximately tens of atoms predicted via classical theory, was obtained for the first time. Density functional theory (DFT) calculations revealed a mutual strain-induced mechanism that simultaneously lowers the surface energies while reducing the size to the atomic scale. This approach paves the way for the development of new high-performance nonequilibrium phase alloys.

cond-mat.mtrl-sci↗

arXiv2025

Transformer-Driven Inverse Problem Transform for Fast Blind Hyperspectral Image Dehazing

Hyperspectral dehazing (HyDHZ) has become a crucial signal processing technology to facilitate the subsequent identification and classification tasks, as the airborne visible/infrared imaging spectrometer (AVIRIS) data portal reports a massive portion of haze-corrupted areas in typical hyperspectral remote sensing images. The idea of inverse problem transform (IPT) has been proposed in recent remote sensing literature in order to reformulate a hardly tractable inverse problem (e.g., HyDHZ) into a relatively simple one. Considering the emerging spectral super-resolution (SSR) technique, which spectrally upsamples multispectral data to hyperspectral data, we aim to solve the challenging HyDHZ problem by reformulating it as an SSR problem. Roughly speaking, the proposed algorithm first automatically selects some uncorrupted/informative spectral bands, from which SSR is applied to spectrally upsample the selected bands in the feature space, thereby obtaining a clean hyperspectral image (HSI). The clean HSI is then further refined by a deep transformer network to obtain the final dehazed HSI, where a global attention mechanism is designed to capture nonlocal information. There are very few HyDHZ works in existing literature, and this article introduces the powerful spatial-spectral transformer into HyDHZ for the first time. Remarkably, the proposed transformer-driven IPT-based HyDHZ (T2HyDHZ) is a blind algorithm without requiring the user to manually select the corrupted region. Extensive experiments demonstrate the superiority of T2HyDHZ with less color distortion.

cs.CV↗

arXiv2023

Direct visualization of molecular stacking in quasi-2D hexagonal ice

The structure and properties of water or ice are of great interest to researchers due to their importance in the biological, cryopreservation and environmental fields. Hexagonal ice (Ih) is a common ice phase in nature and has been extensively studied; however, microstructural investigations at the atomic or molecular scale are still lacking. In this paper, the fine structure of quasi-2-dimensional ice Ih films was directly examined using cryogenic transmission electron microscopy. Two types of thin Ih films were observed: perfect single crystals growing along the [0001] direction and crystals with stacking faults, including both basal (BSF) and prismatic (PSF) ones, along the orientation of [11-20]; these results were further confirmed by theoretical calculations. Importantly, for the first time, the stacking faults in ice Ih were directly visualized and resolved. In light of the extension behavior of the chair conformation composed of the water molecules, we elucidated the formation mechanism of BSF in Ih, namely, the Ic phase. This study not only determined the structural characteristics of ice structure at the molecular scale but also provided important concepts for researchers to more fully understand the growth kinetics of ice crystals at the atomic scale.

cond-mat.mtrl-sci↗

arXiv2021

Fast determination of thickness through scanning moiré fringe in scanning transmission electron microscopy

Sample thickness is an important parameter in transmission electron microscopy (TEM) imaging, for interpreting image contrast and understanding the relationship between properties and microstructure. In this study, we introduce a method for determining thickness in scanning transmission electron microscopy (STEM) mode based on scanning moiré fringe (SMF). Sample thickness can be determined in situ in the medium magnification using focal-series SMF imaging, with beam damage and contamination avoided to a large extent. This method provides a fast and convenient way for determining thickness in TEM imaging, which is particularly useful for beam-sensitive materials such as Metal-Organic Frameworks.

cond-mat.mtrl-sci↗